Vapor Phase Hydrogenolysis of Furanics Utilizing Reduced Cobalt Mixed Metal Oxide Catalysts

doi:10.1002/cctc.201700228

Title: Vapor Phase Hydrogenolysis of Furanics Utilizing Reduced Cobalt Mixed Metal Oxide Catalysts

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Authors:

Sulmonetti, Taylor P. ^[1]; Hu, Bo ^[1]; Ifkovits, Zachary ^[1]; Lee, Sungsik ^[2]; Agrawal, Pradeep K. ^[1];

School of Chemical & Biomolecular Engineering, Georgia Institute of Technology, 311 Ferst Dr. Atlanta GA 30332 USA
Advanced Photon Source, Argonne National Laboratory, Lemont IL 60439 USA

Publication Date:: Thu May 11 00:00:00 EDT 2017

Research Org.:: Energy Frontier Research Centers (EFRC) (United States). Catalysis Center for Energy Innovation (CCEI)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

OSTI Identifier:: 1388986

DOE Contract Number:: SC0001004

Resource Type:: Journal Article

Resource Relation:: Journal Name: ChemCatChem; Journal Volume: 9; Journal Issue: 10; Related Information: CCEI partners with the University of Delaware (lead); Brookhaven National Laboratory; California Institute of Technology; Columbia University; University of Delaware; Lehigh University; University of Massachusetts, Amherst; Massachusetts Institute of Technology; University of Minnesota; Pacific Northwest National Laboratory; University of Pennsylvania; Princeton University; Rutgers University

Country of Publication:: United States

Language:: English

Subject:: catalysis (homogeneous), catalysis (heterogeneous), biofuels (including algae and biomass), bio-inspired, hydrogen and fuel cells, materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing)

Citation Formats


                    Sulmonetti, Taylor P., Hu, Bo, Ifkovits, Zachary, Lee, Sungsik, Agrawal, Pradeep K., and Jones, Christopher W.. Vapor Phase Hydrogenolysis of Furanics Utilizing Reduced Cobalt Mixed Metal Oxide Catalysts.  United States: N. p., 2017. 
        Web.  doi:10.1002/cctc.201700228.

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                    Sulmonetti, Taylor P., Hu, Bo, Ifkovits, Zachary, Lee, Sungsik, Agrawal, Pradeep K., & Jones, Christopher W.. Vapor Phase Hydrogenolysis of Furanics Utilizing Reduced Cobalt Mixed Metal Oxide Catalysts.  United States.  doi:10.1002/cctc.201700228.

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                    Sulmonetti, Taylor P., Hu, Bo, Ifkovits, Zachary, Lee, Sungsik, Agrawal, Pradeep K., and Jones, Christopher W.. Thu .  
        "Vapor Phase Hydrogenolysis of Furanics Utilizing Reduced Cobalt Mixed Metal Oxide Catalysts".  United States.  
        doi:10.1002/cctc.201700228.

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@article{osti_1388986,

  title        = {Vapor Phase Hydrogenolysis of Furanics Utilizing Reduced Cobalt Mixed Metal Oxide Catalysts},

  author       = {Sulmonetti, Taylor P. and Hu, Bo and Ifkovits, Zachary and Lee, Sungsik and Agrawal, Pradeep K. and Jones, Christopher W.},

  abstractNote = {},

  doi          = {10.1002/cctc.201700228},

  journal      = {ChemCatChem},

  number       = 10,

  volume       = 9,

  place        = {United States},

  year         = {Thu May 11 00:00:00 EDT 2017},

  month        = {Thu May 11 00:00:00 EDT 2017}

}

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Journal Article:

DOI: 10.1002/cctc.201700228

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Vapor Phase Hydrogenolysis of Furanics Utilizing Reduced Cobalt Mixed Metal Oxide Catalysts

Sulmonetti, Taylor P. ; Hu, Bo ; Ifkovits, Zachary ; ... - ChemCatChem

Vapor phase hydrogenolysis of both furfuryl alcohol and furfural were investigated over reduced Co based mixed metal oxides derived from the calcination of a layered double hydroxide precursor. Although a reduced cobalt aluminate sample displays promising selectivity towards 2-methylfuran (2-MF) production, the addition of an Fe dopant into the oxide matrix significantly enhances the activity and selectivity per gram of catalyst. Approximately 82% 2-MF yield is achieved at high conversion when furfuryl alcohol is fed into the reactor at 180 °C over the reduced 3Co-0.25Fe-0.75Al catalyst. Based on structural characterization studies including TPR, XPS, and in-situ XAS it is suggestedmore »« less
Cited by 1
DOI: 10.1002/cctc.201700228

Full Text Available
Vapor Phase Hydrogenolysis of Furanics Utilizing Reduced Cobalt Mixed Metal Oxide Catalysts

Sulmonetti, Taylor P. ; Hu, Bo ; Ifkovits, Zachary ; ... - ChemCatChem
Cited by 1
DOI: 10.1002/cctc.201700228
Vapor phase hydrogenation of furfural over nickel mixed metal oxide catalysts derived from layered double hydroxides

Sulmonetti, Taylor P. ; Pang, Simon H. ; Claure, Micaela Taborga ; ... - Applied Catalysis. A, General

The hydrogenation of furfural is investigated over various reduced nickel mixed metal oxides derived from layered double hydroxides (LDHs) containing Ni-Mg-Al and Ni-Co-Al. Upon reduction, relatively large Ni(0) domains develop in the Ni-Mg-Al catalysts, whereas in the Ni-Co-Al catalysts smaller metal particles of Ni(0) and Co(0), potentially as alloys, are formed, as evidenced by XAS, XPS, STEM and EELS. All the reduced Ni catalysts display similar selectivities towards major hydrogenation products (furfuryl alcohol and tetrahydrofurfuryl alcohol), though the side products varied with the catalyst composition. The 1.1Ni-0.8Co-Al catalyst showed the greatest activity per titrated site when compared to the othermore »« less
DOI: 10.1016/j.apcata.2016.03.005
Vapor phase hydrogenation of furfural over nickel mixed metal oxide catalysts derived from layered double hydroxides

Sulmonetti, Taylor P. ; Pang, Simon H. ; Claure, Micaela Taborga ; ... - Applied Catalysis. A, General
DOI: 10.1016/j.apcata.2016.03.005
Vapor phase hydrogenation of furfural over nickel mixed metal oxide catalysts derived from layered double hydroxides

Sulmonetti, Taylor P. ; Pang, Simon H. ; Claure, Micaela Taborga ; ... - Applied Catalysis. A, General

The hydrogenation of furfural is investigated over various reduced nickel mixed metal oxides derived from layered double hydroxides (LDHs) containing Ni-Mg-Al and Ni-Co-Al. Upon reduction, relatively large Ni(0) domains develop in the Ni-Mg-Al catalysts, whereas in the Ni-Co-Al catalysts smaller metal particles of Ni(0) and Co(0), potentially as alloys, are formed, as evidenced by XAS, XPS, STEM and EELS. All the reduced Ni catalysts display similar selectivities towards major hydrogenation products (furfuryl alcohol and tetrahydrofurfuryl alcohol), though the side products varied with the catalyst composition. The 1.1Ni-0.8Co-Al catalyst showed the greatest activity per titrated site when compared to the othermore »« less
Cited by 14
DOI: 10.1016/j.apcata.2016.03.005

Full Text Available