skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Ring-Opening Reaction of Furfural and Tetrahydrofurfuryl Alcohol on Hydrogen-Predosed Iridium(1 1 1) and Cobalt/Iridium(1 1 1) Surfaces

Authors:
 [1];  [2];  [2];  [2];  [1]
  1. Department of Chemical Engineering, Columbia University, 500 W. 120th St. New York NY 10027 USA; Catalysis Center for Energy Innovation (CCEI), University of Delaware, 221 Academy St. Newark DE 19716 USA
  2. Catalysis Center for Energy Innovation (CCEI), University of Delaware, 221 Academy St. Newark DE 19716 USA
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Catalysis Center for Energy Innovation (CCEI)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1388983
Alternate Identifier(s):
OSTI ID: 1401748
Grant/Contract Number:  
SC0001004; AC02-05CH11231
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
ChemCatChem
Additional Journal Information:
Journal Volume: 9; Journal Issue: 9; Related Information: CCEI partners with the University of Delaware (lead); Brookhaven National Laboratory; California Institute of Technology; Columbia University; University of Delaware; Lehigh University; University of Massachusetts, Amherst; Massachusetts Institute of Technology; University of Minnesota; Pacific Northwest National Laboratory; University of Pennsylvania; Princeton University; Rutgers University; Journal ID: ISSN 1867-3880
Publisher:
ChemPubSoc Europe
Country of Publication:
United States
Language:
English
Subject:
catalysis (homogeneous), catalysis (heterogeneous), biofuels (including algae and biomass), bio-inspired, hydrogen and fuel cells, materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing)

Citation Formats

Wan, Weiming, Jenness, Glen R., Xiong, Ke, Vlachos, Dionisios G., and Chen, Jingguang G. Ring-Opening Reaction of Furfural and Tetrahydrofurfuryl Alcohol on Hydrogen-Predosed Iridium(1 1 1) and Cobalt/Iridium(1 1 1) Surfaces. United States: N. p., 2017. Web. doi:10.1002/cctc.201601646.
Wan, Weiming, Jenness, Glen R., Xiong, Ke, Vlachos, Dionisios G., & Chen, Jingguang G. Ring-Opening Reaction of Furfural and Tetrahydrofurfuryl Alcohol on Hydrogen-Predosed Iridium(1 1 1) and Cobalt/Iridium(1 1 1) Surfaces. United States. doi:10.1002/cctc.201601646.
Wan, Weiming, Jenness, Glen R., Xiong, Ke, Vlachos, Dionisios G., and Chen, Jingguang G. Thu . "Ring-Opening Reaction of Furfural and Tetrahydrofurfuryl Alcohol on Hydrogen-Predosed Iridium(1 1 1) and Cobalt/Iridium(1 1 1) Surfaces". United States. doi:10.1002/cctc.201601646. https://www.osti.gov/servlets/purl/1388983.
@article{osti_1388983,
title = {Ring-Opening Reaction of Furfural and Tetrahydrofurfuryl Alcohol on Hydrogen-Predosed Iridium(1 1 1) and Cobalt/Iridium(1 1 1) Surfaces},
author = {Wan, Weiming and Jenness, Glen R. and Xiong, Ke and Vlachos, Dionisios G. and Chen, Jingguang G.},
abstractNote = {},
doi = {10.1002/cctc.201601646},
journal = {ChemCatChem},
issn = {1867-3880},
number = 9,
volume = 9,
place = {United States},
year = {2017},
month = {3}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 2 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Projector augmented-wave method
journal, December 1994


Catalytic Conversions of Furfural to Pentanediols
journal, August 2015

  • Nakagawa, Yoshinao; Tamura, Masazumi; Tomishige, Keiichi
  • Catalysis Surveys from Asia, Vol. 19, Issue 4
  • DOI: 10.1007/s10563-015-9194-2

Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996


Experimental and Theoretical Investigation of the Stability of Pt−3d−Pt(111) Bimetallic Surfaces under Oxygen Environment
journal, August 2006

  • Menning, Carl A.; Hwu, Henry H.; Chen, Jingguang G.
  • The Journal of Physical Chemistry B, Vol. 110, Issue 31
  • DOI: 10.1021/jp061697z

Furfural steam reforming over Ni-based catalysts. Influence of Ni incorporation method
journal, March 2014


Molybdenum Carbide as a Highly Selective Deoxygenation Catalyst for Converting Furfural to 2-Methylfuran
journal, April 2014


Selective deoxygenation of aldehydes and alcohols on molybdenum carbide (Mo 2 C) surfaces
journal, December 2014


Selective hydrogenolysis of tetrahydrofurfuryl alcohol to 1,5-pentanediol over vanadium modified Ir/SiO2 catalyst
journal, May 2015


Direct catalytic conversion of furfural to 1,5-pentanediol by hydrogenolysis of the furan ring under mild conditions over Pt/Co2AlO4 catalyst
journal, January 2011

  • Xu, Wenjie; Wang, Haifeng; Liu, Xiaohui
  • Chemical Communications, Vol. 47, Issue 13
  • DOI: 10.1039/c0cc05775d

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996


From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999


Mechanistic Insights into Metal Lewis Acid-Mediated Catalytic Transfer Hydrogenation of Furfural to 2-Methylfuran
journal, June 2015

  • Gilkey, Matthew J.; Panagiotopoulou, Paraskevi; Mironenko, Alexander V.
  • ACS Catalysis, Vol. 5, Issue 7
  • DOI: 10.1021/acscatal.5b00586

Ab initio molecular-dynamics simulation of the liquid-metal–amorphous-semiconductor transition in germanium
journal, May 1994


One-pot selective conversion of furfural into 1,5-pentanediol over a Pd-added Ir–ReO x /SiO 2 bifunctional catalyst
journal, January 2014

  • Liu, Sibao; Amada, Yasushi; Tamura, Masazumi
  • Green Chem., Vol. 16, Issue 2
  • DOI: 10.1039/C3GC41335G

Reaction Pathways of Biomass-Derived Oxygenates over Metals and Carbides: From Model Surfaces to Supported Catalysts
journal, March 2015


Towards understanding the mechanism for the selective hydrogenation of maleic anhydride to tetrahydrofuran over palladium
journal, May 1999


The hydrodeoxygenation of bioderived furans into alkanes
journal, April 2013

  • Sutton, Andrew D.; Waldie, Fraser D.; Wu, Ruilian
  • Nature Chemistry, Vol. 5, Issue 5, p. 428-432
  • DOI: 10.1038/nchem.1609

Monolayer bimetallic surfaces: Experimental and theoretical studies of trends in electronic and chemical properties
journal, May 2008


Vapor phase hydrogenation of furfural to furfuryl alcohol over environmentally friendly Cu–Ca/SiO2 catalyst
journal, September 2005


Ab initiomolecular dynamics for liquid metals
journal, January 1993


Reaction pathways of furfural, furfuryl alcohol and 2-methylfuran on Cu(111) and NiCu bimetallic surfaces
journal, October 2016


Chemoselective hydrogenolysis of tetrahydrofurfuryl alcohol to 1,5-pentanediol over Ir-MoOx/SiO2 catalyst
journal, July 2014


Reaction Pathways and Intermediates in Selective Ring Opening of Biomass-Derived Heterocyclic Compounds by Iridium
journal, September 2016


Effects of carbon and manganese impurities on cerium incorporation in iron oxides scales
journal, January 1996


C–O bond hydrogenolysis of cyclic ethers with OH groups over rhenium-modified supported iridium catalysts
journal, October 2012


Ring-Opening and Oxidation Pathways of Furanic Oxygenates on Oxygen-Precovered Pd(111)
journal, November 2014

  • Williams, Rhea M.; Pang, Simon H.; Medlin, J. Will
  • The Journal of Physical Chemistry C, Vol. 118, Issue 48
  • DOI: 10.1021/jp509284d

Experimental and theoretical study of reactivity trends for methanol on Co∕Pt(111) and Ni∕Pt(111) bimetallic surfaces
journal, September 2007

  • Skoplyak, Orest; Menning, Carl A.; Barteau, Mark A.
  • The Journal of Chemical Physics, Vol. 127, Issue 11
  • DOI: 10.1063/1.2768520

An overview of aqueous-phase catalytic processes for production of hydrogen and alkanes in a biorefinery
journal, January 2006