skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Aerobic Oxidation of Isoeugenol to Vanillin with Copper Oxide Doped Reduced Graphene Oxide

Authors:
 [1];  [1];  [1];  [2];  [3]
  1. Laboratory of Catalysis, University of Delhi, North Campus Delhi 110007 India
  2. Green Chemistry Network Centre, Department of Chemistry, University of Delhi, Delhi- 110007 India
  3. Laboratory of Catalysis, University of Delhi, North Campus Delhi 110007 India; Catalysis Center for Energy Innovation, University of Delaware, Newark, DE 19716 USA
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Catalysis Center for Energy Innovation (CCEI)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1388980
DOE Contract Number:  
SC0001004
Resource Type:
Journal Article
Journal Name:
Chemistry Select
Additional Journal Information:
Journal Volume: 2; Journal Issue: 10; Related Information: CCEI partners with the University of Delaware (lead); Brookhaven National Laboratory; California Institute of Technology; Columbia University; University of Delaware; Lehigh University; University of Massachusetts, Amherst; Massachusetts Institute of Technology; University of Minnesota; Pacific Northwest National Laboratory; University of Pennsylvania; Princeton University; Rutgers University; Journal ID: ISSN 2365-6549
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
catalysis (homogeneous), catalysis (heterogeneous), biofuels (including algae and biomass), bio-inspired, hydrogen and fuel cells, materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing)

Citation Formats

Bohre, Ashish, Gupta, Dinesh, Alam, Md. Imteyaz, Sharma, Rakesh K., and Saha, Basudeb. Aerobic Oxidation of Isoeugenol to Vanillin with Copper Oxide Doped Reduced Graphene Oxide. United States: N. p., 2017. Web. doi:10.1002/slct.201700415.
Bohre, Ashish, Gupta, Dinesh, Alam, Md. Imteyaz, Sharma, Rakesh K., & Saha, Basudeb. Aerobic Oxidation of Isoeugenol to Vanillin with Copper Oxide Doped Reduced Graphene Oxide. United States. doi:10.1002/slct.201700415.
Bohre, Ashish, Gupta, Dinesh, Alam, Md. Imteyaz, Sharma, Rakesh K., and Saha, Basudeb. Mon . "Aerobic Oxidation of Isoeugenol to Vanillin with Copper Oxide Doped Reduced Graphene Oxide". United States. doi:10.1002/slct.201700415.
@article{osti_1388980,
title = {Aerobic Oxidation of Isoeugenol to Vanillin with Copper Oxide Doped Reduced Graphene Oxide},
author = {Bohre, Ashish and Gupta, Dinesh and Alam, Md. Imteyaz and Sharma, Rakesh K. and Saha, Basudeb},
abstractNote = {},
doi = {10.1002/slct.201700415},
journal = {Chemistry Select},
issn = {2365-6549},
number = 10,
volume = 2,
place = {United States},
year = {2017},
month = {4}
}

Works referenced in this record:

Biotransformation of isoeugenol to vanillin by a newly isolated Bacillus pumilus strain: Identification of major metabolites
journal, July 2007


Sulfonated Porous Polymeric Nanofibers as an Efficient Solid Acid Catalyst for the Production of 5-Hydroxymethylfurfural from Biomass
journal, September 2015


Cu 2 O/Reduced Graphene Oxide Composites for the Photocatalytic Conversion of CO 2
journal, February 2014


Multiplet Structures of Cu 2p-XPS in La 2 CuO 4 , CuO and Cu Halides
journal, July 1989

  • Okada, Kozo; Kotani, Akio
  • Journal of the Physical Society of Japan, Vol. 58, Issue 7
  • DOI: 10.1143/JPSJ.58.2578

Design of 3-Dimensionally Self-Assembled CeO 2 Nanocube as a Breakthrough Catalyst for Efficient Alkylarene Oxidation in Water
journal, August 2014

  • Deori, Kalyanjyoti; Gupta, Dinesh; Saha, Basudeb
  • ACS Catalysis, Vol. 4, Issue 9
  • DOI: 10.1021/cs500644j

Bioproduction of vanillin using an organic solvent-tolerant Brevibacillus agri 13
journal, August 2011

  • Wangrangsimagul, Nuttawat; Klinsakul, Kunticha; Vangnai, Alisa S.
  • Applied Microbiology and Biotechnology, Vol. 93, Issue 2
  • DOI: 10.1007/s00253-011-3510-1

Vanilla Production: Technological, Chemical, and Biosynthetic Aspects
journal, February 2001

  • Dignum, Mark J. W.; Kerler, Josef; Verpoorte, Rob
  • Food Reviews International, Vol. 17, Issue 2
  • DOI: 10.1081/FRI-100000269

Oxidation of isoeugenol by Nocardia iowensis
journal, December 2008


A highly efficient approach to vanillin starting from 4-cresol
journal, January 2014

  • Jiang, Jian-An; Chen, Cheng; Guo, Ying
  • Green Chemistry, Vol. 16, Issue 5
  • DOI: 10.1039/c4gc00003j

Kinetic Study of the Graphite Oxide Reduction: Combined Structural and Gravimetric Experiments under Isothermal and Nonisothermal Conditions
journal, November 2010

  • Barroso-Bujans, Fabienne; Alegría, Ángel; Colmenero, Juan
  • The Journal of Physical Chemistry C, Vol. 114, Issue 49
  • DOI: 10.1021/jp108905j

Agent-free synthesis of graphene oxide/transition metal oxide composites and its application for hydrogen storage
journal, May 2012


Fabrication of anchored copper oxide nanoparticles on graphene oxide nanosheets via an electrostatic coprecipitation and its application as supercapacitor
journal, January 2013


Fabrication of a graphene–cuprous oxide composite
journal, September 2009


New poly(ether urethane)s based on lignin derived aromatic chemicals via A-B monomer approach: Synthesis and characterization
journal, October 2015


Sustainable recovery of pure natural vanillin from fermentation media in a single pervaporation step
journal, January 2011

  • Brazinha, Carla; Barbosa, Dalje S.; Crespo, João G.
  • Green Chemistry, Vol. 13, Issue 8
  • DOI: 10.1039/c1gc15308k

Catalytic Alkaline Oxidation of Lignin and its Model Compounds: a Pathway to Aromatic Biochemicals
journal, June 2013


One-Pot, Clean Synthesis of Vanillic Acid from Ferulic Acid
journal, March 2016

  • Delisi, Riccardo; Ciriminna, Rosaria; Parrino, Francesco
  • ChemistrySelect, Vol. 1, Issue 3
  • DOI: 10.1002/slct.201600111

Synthesis of porous reduced graphene oxide as metal-free carbon for adsorption and catalytic oxidation of organics in water
journal, January 2013

  • Peng, Wenchao; Liu, Shizhen; Sun, Hongqi
  • Journal of Materials Chemistry A, Vol. 1, Issue 19
  • DOI: 10.1039/c3ta10592j

Carbocatalysis by Graphene-Based Materials
journal, April 2014

  • Navalon, Sergio; Dhakshinamoorthy, Amarajothi; Alvaro, Mercedes
  • Chemical Reviews, Vol. 114, Issue 12
  • DOI: 10.1021/cr4007347

Enzymes and Bioconversions of Industrial, Pharmaceutical, and Biotechnological Significance
journal, January 2011

  • Sanchez, Sergio; Demain, Arnold L.
  • Organic Process Research & Development, Vol. 15, Issue 1
  • DOI: 10.1021/op100302x

Synthesis of Vanillin from Glucose
journal, October 1998

  • Li, Kai; Frost, J. W.
  • Journal of the American Chemical Society, Vol. 120, Issue 40
  • DOI: 10.1021/ja9817747

Multicomponent kinetic analysis and theoretical studies on the phenolic intermediates in the oxidation of eugenol and isoeugenol catalyzed by laccase
journal, January 2015

  • Qi, Yan-Bing; Wang, Xiao-Lei; Shi, Ting
  • Physical Chemistry Chemical Physics, Vol. 17, Issue 44
  • DOI: 10.1039/C5CP03475B

Oxidation of isoeugenol to vanillin by the “H2O2–vanadate–pyrazine-2-carboxylic acid” reagent
journal, November 2012

  • Gusevskaya, Elena V.; Menini, Luciano; Parreira, Luciana A.
  • Journal of Molecular Catalysis A: Chemical, Vol. 363-364
  • DOI: 10.1016/j.molcata.2012.06.001

Graphene Oxide, Highly Reduced Graphene Oxide, and Graphene: Versatile Building Blocks for Carbon-Based Materials
journal, March 2010


Valence states of copper ions and electronic structure of LiCu 2 O 2
journal, February 1998


Biotransformation of isoeugenol to vanillin by Pseudomonas putida IE27 cells
journal, August 2006

  • Yamada, Mamoru; Okada, Yukiyoshi; Yoshida, Toyokazu
  • Applied Microbiology and Biotechnology, Vol. 73, Issue 5
  • DOI: 10.1007/s00253-006-0569-1

Biorenewable chemicals: Feedstocks, technologies and the conflict with food production
journal, November 2015

  • Bardhan, Soubhik K.; Gupta, Shelaka; Gorman, M. E.
  • Renewable and Sustainable Energy Reviews, Vol. 51
  • DOI: 10.1016/j.rser.2015.06.013

Optical coupling of surface chemistry. Photoluminescent properties of a derivatized gallium arsenide surface undergoing redox chemistry
journal, April 1986

  • Van Ryswyk, Hal.; Ellis, Arthur B.
  • Journal of the American Chemical Society, Vol. 108, Issue 9
  • DOI: 10.1021/ja00269a058

Novel cobalt(II)-catalyzed oxidative cleavage of a carbon-carbon double bond
journal, April 1986

  • Drago, R. S.; Corden, B. B.; Barnes, C. W.
  • Journal of the American Chemical Society, Vol. 108, Issue 9
  • DOI: 10.1021/ja00269a057

Tandem mass spectrometric characterization of the conversion of xylose to furfural
journal, March 2015


Heteroatoms Increase the Selectivity in Oxidative Dehydrogenation Reactions on Nanocarbons
journal, September 2009

  • Frank, Benjamin; Zhang, Jian; Blume, Raoul
  • Angewandte Chemie International Edition, Vol. 48, Issue 37
  • DOI: 10.1002/anie.200901826

Nitrogen-doped mesoporous reduced graphene oxide for high-performance supercapacitors
journal, January 2014

  • Pham, Viet Hung; Nguyen-Phan, Thuy-Duong; Jang, Jinhee
  • RSC Advances, Vol. 4, Issue 43
  • DOI: 10.1039/c4ra03049d

Sonication assisted deposition of Cu2O nanoparticles on multiwall carbon nanotubes with polyol process
journal, January 2005


Copper-Catalyzed Aerobic Oxidative CH Functionalizations: Trends and Mechanistic Insights
journal, October 2011

  • Wendlandt, Alison E.; Suess, Alison M.; Stahl, Shannon S.
  • Angewandte Chemie International Edition, Vol. 50, Issue 47
  • DOI: 10.1002/anie.201103945

Supported Cu(II) polymer catalysts for aqueous phenol oxidation
journal, April 2009


Metabolism of isoeugenol via isoeugenol-diol by a newly isolated strain of Bacillus subtilis HS8
journal, August 2006

  • Zhang, Yongmei; Xu, Ping; Han, Shuai
  • Applied Microbiology and Biotechnology, Vol. 73, Issue 4
  • DOI: 10.1007/s00253-006-0544-x

Photocatalytic degradation of dyes over graphene–gold nanocomposites under visible light irradiation
journal, January 2010

  • Xiong, Zhigang; Zhang, Li Li; Ma, Jizhen
  • Chemical Communications, Vol. 46, Issue 33
  • DOI: 10.1039/c0cc01259a

Photocatalytic oxidation of trans-ferulic acid to vanillin on TiO2 and WO3-loaded TiO2 catalysts
journal, September 2015


A new rapid chemical route to prepare reduced graphene oxide using copper metal nanoparticles
journal, April 2013


Mixed-valence states in narrow-gap IV-VI semiconductors with rare-earth ions
journal, June 1999


Oxidative cleavage of isoeugenol to vanillin under molecular oxygen catalysed by cobalt porphyrin intercalated into lithium taeniolite clay
journal, September 2012

  • Adilina, Indri Badria; Hara, Takayoshi; Ichikuni, Nobuyuki
  • Journal of Molecular Catalysis A: Chemical, Vol. 361-362
  • DOI: 10.1016/j.molcata.2012.05.005

Cu(II)-Catalyzed Functionalizations of Aryl C−H Bonds Using O 2 as an Oxidant
journal, May 2006

  • Chen, Xiao; Hao, Xue-Shi; Goodhue, Charles E.
  • Journal of the American Chemical Society, Vol. 128, Issue 21
  • DOI: 10.1021/ja061715q