Minireview: direct catalytic conversion of sour natural gas (CH 4+ H 2S + CO 2) components to high value chemicals and fuels
Abstract
Direct sour natural gas catalytic conversion allows to obtain high value products, such as hydrocarbon and organosulfur chemicals, fuels and fertilizers.
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Center for Understanding and Control of Acid Gas-induced Evolution of Materials for Energy (UNCAGE-ME)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- OSTI Identifier:
- 1388886
- DOE Contract Number:
- SC0012577
- Resource Type:
- Journal Article
- Journal Name:
- Catalysis Science and Technology
- Additional Journal Information:
- Journal Volume: 7; Journal Issue: 14; Related Information: UNCAGE-ME partners with Georgia Institute of Technology (lead); Lehigh University; Oak Ridge National Laboratory; University of Alabama; University of Florida; University of Wisconsin; Washington University in St. Louis; Journal ID: ISSN 2044-4753
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- catalysis (heterogeneous), defects, membrane, carbon capture, materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing)
Citation Formats
Taifan, William, and Baltrusaitis, Jonas. Minireview: direct catalytic conversion of sour natural gas (CH4+ H2S + CO2) components to high value chemicals and fuels. United States: N. p., 2017.
Web. doi:10.1039/C7CY00272F.
Taifan, William, & Baltrusaitis, Jonas. Minireview: direct catalytic conversion of sour natural gas (CH4+ H2S + CO2) components to high value chemicals and fuels. United States. doi:10.1039/C7CY00272F.
Taifan, William, and Baltrusaitis, Jonas. Sun .
"Minireview: direct catalytic conversion of sour natural gas (CH4+ H2S + CO2) components to high value chemicals and fuels". United States. doi:10.1039/C7CY00272F.
@article{osti_1388886,
title = {Minireview: direct catalytic conversion of sour natural gas (CH4+ H2S + CO2) components to high value chemicals and fuels},
author = {Taifan, William and Baltrusaitis, Jonas},
abstractNote = {Direct sour natural gas catalytic conversion allows to obtain high value products, such as hydrocarbon and organosulfur chemicals, fuels and fertilizers.},
doi = {10.1039/C7CY00272F},
journal = {Catalysis Science and Technology},
issn = {2044-4753},
number = 14,
volume = 7,
place = {United States},
year = {2017},
month = {1}
}
DOI: 10.1039/C7CY00272F
Other availability
Find in Google Scholar
Search WorldCat to find libraries that may hold this journal
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Coke Formation and Carbon Atom Economy of Methanol-to-Olefins Reaction
journal, February 2012
- Wei, Yingxu; Yuan, Cuiyu; Li, Jinzhe
- ChemSusChem, Vol. 5, Issue 5
Heterogeneous catalytic synthesis of alkanethiols and dialkyl sulfides from alcohols and hydrogen sulfide
journal, December 1995
- Mashkina, Anna V.
- Russian Chemical Reviews, Vol. 64, Issue 12
Surface chemistry of H2S-sensitive tungsten oxide films
journal, March 1996
- Frühberger, B.; Grunze, M.; Dwyer, D. J.
- Sensors and Actuators B: Chemical, Vol. 31, Issue 3
Structural Characteristics and Catalytic Properties of Highly Dispersed ZrO 2 /SiO 2 and V 2 O 5 /ZrO 2 /SiO 2 Catalysts
journal, April 1999
- Gao, Xingtao; Fierro, J. L. G.; Wachs, Israel E.
- Langmuir, Vol. 15, Issue 9
Renewable energy based catalytic CH4 conversion to fuels
journal, January 2014
- Baltrusaitis, J.; Jansen, I.; Schuttlefield Christus, J. D.
- Catalysis Science & Technology, Vol. 4, Issue 8
Oxidation of sulfur dioxide to sulfur trioxide over supported vanadia catalysts
journal, November 1998
- Dunn, Joseph P.; Koppula, Prashanth R.; G. Stenger, Harvey
- Applied Catalysis B: Environmental, Vol. 19, Issue 2
H 2 S-Selective Catalytic Oxidation: Catalysts and Processes
journal, January 2015
- Zhang, Xin; Tang, Yuyin; Qu, Siqiu
- ACS Catalysis, Vol. 5, Issue 2
Reactions of alcohols with hydrogen sulfide over zeolites: III. The role of divalent cations in the reaction of C2 and C3 alcohols with H2S over X-type zeolite catalysts
journal, September 1990
- Zióe̵k, M.; Kujawa, J.
- Zeolites, Vol. 10, Issue 7
Selective transformation of methyl and ethyl mercaptans mixture to hydrocarbons and H2S on solid acid catalysts
journal, September 2014
- Cammarano, Claudia; Huguet, Edouard; Cadours, Renaud
- Applied Catalysis B: Environmental, Vol. 156-157
Catalytic methyl mercaptan coupling to ethylene in chabazite: DFT study of the first C C bond formation
journal, June 2016
- Baltrusaitis, J.; Bučko, T.; Michaels, W.
- Applied Catalysis B: Environmental, Vol. 187
Structural and textural properties of Fe 2 O 3 /γ-Al 2 O 3 catalysts and their importance in the catalytic reforming of CH 4 with H 2 S for hydrogen production
journal, August 2015
- Galindo-Hernández, Félix; Domínguez, J. M.; Portales, Benjamín
- Journal of Power Sources, Vol. 287
Structural determination of supported vanadium pentoxide-tungsten trioxide-titania catalysts by in situ Raman spectroscopy and x-ray photoelectron spectroscopy
journal, November 1991
- Vuurman, Michael A.; Wachs, Israel E.; Hirt, Andrew M.
- The Journal of Physical Chemistry, Vol. 95, Issue 24
Phase cooperation of V2O5 and Bi2O3 in the selective oxidation of H2S containing ammonia and water
journal, July 2002
- Cho, Young-Gu; Hwang, Byung-Ha; Park, Dae-Won
- Korean Journal of Chemical Engineering, Vol. 19, Issue 4
Four challenges for nickel steam-reforming catalysts
journal, January 2006
- Sehested, Jens
- Catalysis Today, Vol. 111, Issue 1-2
Selective oxidation of H2S to ammonium thiosulfate and elemental sulfur using mixtures of V-Bi-O and Sb2O4
journal, January 2004
- Kim, Bong-Kuk; Hwang, Byung-Ha; Lee, Hwa-Soo
- Korean Journal of Chemical Engineering, Vol. 21, Issue 1
Kinetics of catalytic reaction of methane and hydrogen sulphide over MoS2
journal, December 1997
- Megalofonos, S. K.; Papayannakos, N. G.
- Applied Catalysis A: General, Vol. 165, Issue 1-2
Isopropanol oxidation by pure metal oxide catalysts: number of active surface sites and turnover frequencies
journal, November 2002
- Kulkarni, Deepak; Wachs, Israel E.
- Applied Catalysis A: General, Vol. 237, Issue 1-2
Conversion of methyl mercaptan and methanol to hydrocarbons over solid acid catalysts – A comparative study
journal, January 2014
- Hulea, Vasile; Huguet, Edouard; Cammarano, Claudia
- Applied Catalysis B: Environmental, Vol. 144
Synthesis of methyl mercaptan from carbonyl sulfide over sulfide K2MoO4/SiO2
journal, June 2011
- Gutiérrez, Oliver Y.; Kaufmann, Christoph; Hrabar, Ana
- Journal of Catalysis, Vol. 280, Issue 2
Oxidative dehydrogenation of propane over niobia supported vanadium oxide catalysts
journal, April 1996
- Watling, T. C.; Deo, G.; Seshan, K.
- Catalysis Today, Vol. 28, Issue 1-2
Hydrogen sulfide reformation in the presence of methane
journal, September 2016
- El-Melih, A. M.; Al Shoaibi, A.; Gupta, A. K.
- Applied Energy, Vol. 178
On the Reaction Mechanism for Hydrocarbon Formation from Methanol over SAPO-34
journal, October 1994
- Dahl, I. M.; Kolboe, S.
- Journal of Catalysis, Vol. 149, Issue 2
Zeolite Catalysis: Water Can Dramatically Increase or Suppress Alkane C–H Bond Activation
journal, August 2014
- Chen, Kuizhi; Damron, Joshua; Pearson, Carlie
- ACS Catalysis, Vol. 4, Issue 9
CH 4 conversion to value added products: Potential, limitations and extensions of a single step heterogeneous catalysis
journal, December 2016
- Taifan, William; Baltrusaitis, Jonas
- Applied Catalysis B: Environmental, Vol. 198
The thermal decomposition of hydrogen sulfide over vanadium and molybdenum sulfides and mixed sulfide catalysts in quartz and thermal diffusion column reactors
journal, January 1987
- Chivers, T.; Lau, C.
- International Journal of Hydrogen Energy, Vol. 12, Issue 4
Cation synergies affect ammonia adsorption over VOX and (V,W)OX dispersed on α-Al2O3 (0001) and α-Fe2O3 (0001)
journal, September 2016
- McBriarty, Martin E.; Ellis, Donald E.
- Surface Science, Vol. 651
Experimental and modeling study of hydrogen production from catalytic steam reforming of methane mixture with hydrogen sulfide
journal, September 2015
- Sadooghi, Parham; Rauch, Reinhard
- International Journal of Hydrogen Energy, Vol. 40, Issue 33
Vanadium oxide supported on porous clay heterostructure for the partial oxidation of hydrogen sulphide to sulfur
journal, October 2015
- Soriano, M. D.; Cecilia, J. A.; Natoli, A.
- Catalysis Today, Vol. 254
Synthesis of methyl mercaptan from carbon oxides and H2S with tungsten—alumina catalysts
journal, September 1987
- Barrault, J.; Boulinguiez, M.; Forquy, C.
- Applied Catalysis, Vol. 33, Issue 2
The dynamic states of silica-supported metal oxide catalysts during methanol oxidation
journal, September 1996
- Jehng, Jih-Mirn; Hu, Hungchun; Gao, Xingtao
- Catalysis Today, Vol. 28, Issue 4
Enhanced Carbon-Resistant Dry Reforming Fe-Ni Catalyst: Role of Fe
journal, March 2015
- Theofanidis, Stavros Alexandros; Galvita, Vladimir V.; Poelman, Hilde
- ACS Catalysis, Vol. 5, Issue 5
Recent Advances in Transition Metal-Catalyzed Methylation Reactions
journal, April 2015
- Yan, Guobing; Borah, Arun Jyoti; Wang, Lianggui
- Advanced Synthesis & Catalysis, Vol. 357, Issue 7
Direct synthesis of methanethiol from H2S-rich syngas over sulfided Mo-based catalysts
journal, March 2008
- Chen, Aiping; Wang, Qi; Li, Qiaoling
- Journal of Molecular Catalysis A: Chemical, Vol. 283, Issue 1-2
Methanol thiolation over Al2O3 and WS2 catalysts modified with cesium
journal, January 2017
- Pashigreva, Anastasia V.; Kondratieva, Elena; Bermejo-Deval, Ricardo
- Journal of Catalysis, Vol. 345
Catalytic conversion of methane to more useful chemicals and fuels: a challenge for the 21st century
journal, December 2000
- Lunsford, Jack H.
- Catalysis Today, Vol. 63, Issue 2-4, p. 165-174
Effects of the Support on the Performance and Promotion of (Ni)MoS 2 Catalysts for Simultaneous Hydrodenitrogenation and Hydrodesulfurization
journal, April 2014
- Gutiérrez, Oliver Y.; Singh, Srujan; Schachtl, Eva
- ACS Catalysis, Vol. 4, Issue 5
Hydrogen production from natural gas and hydrogen sulphide
journal, January 1991
- Megalofonos, S.; Papayannakos, N.
- International Journal of Hydrogen Energy, Vol. 16, Issue 5
CO2 capture for refineries, a practical approach
journal, March 2010
- van Straelen, Jiri; Geuzebroek, Frank; Goodchild, Nicholas
- International Journal of Greenhouse Gas Control, Vol. 4, Issue 2
Influence of Potassium on the Synthesis of Methanethiol from Carbonyl Sulfide on Sulfided Mo/Al2O3 Catalyst
journal, July 2011
- Gutiérrez, Oliver Y.; Kaufmann, Christoph; Lercher, Johannes A.
- ChemCatChem, Vol. 3, Issue 9
A highly efficient process for transforming methyl mercaptan into hydrocarbons and H2S on solid acid catalysts
journal, May 2013
- Huguet, Edouard; Coq, Bernard; Durand, Robert
- Applied Catalysis B: Environmental, Vol. 134-135
Atomic-Scale View of VO X –WO X Coreduction on the α-Al 2 O 3 (0001) Surface
journal, June 2015
- McBriarty, Martin E.; Campbell, Gavin P.; Drake, Tasha L.
- The Journal of Physical Chemistry C, Vol. 119, Issue 28
Surface chemistry and reactivity of well-defined multilayered supported M1Ox/M2Ox/SiO2 catalysts
journal, August 2008
- Lee, E.; Wachs, I.
- Journal of Catalysis, Vol. 258, Issue 1
The reaction of sulphur with hydrocarbons
journal, January 1957
- Thomas, W. J.; Strickland-Constable, R. F.
- Transactions of the Faraday Society, Vol. 53
Synthesis of Methanethiol from CS 2 on Ni-, Co-, and K-Doped MoS 2 /SiO 2 Catalysts
journal, June 2013
- Gutiérrez, Oliver Y.; Zhong, Liangshu; Zhu, Yongzhong
- ChemCatChem, Vol. 5, Issue 11
Selective removal of H2S from coke oven gas
journal, September 1998
- Won Park, Dae; Woo Chun, Sung; Yeol Jang, Jae
- Catalysis Today, Vol. 44, Issue 1-4
Selective oxidation of h2s in the presence of ammonia and water using co3o4/sio2 catalyst
journal, May 1997
- Chun, Sung Woo; Jang, Jae Yeol; Park, Dae Won
- Korean Journal of Chemical Engineering, Vol. 14, Issue 3
Production of ammonium thiosulfate by the oxidation of hydrogen sulfide over Nb-Fe mixed oxide catalysts
journal, September 2004
- Park, Dae-Won; Kim, Bong-Guk; Kim, Moon-Il
- Catalysis Today, Vol. 93-95
Liquid hydrogen production via hydrogen sulfide methane reformation
journal, January 2008
- Huang, Cunping; T-Raissi, Ali
- Journal of Power Sources, Vol. 175, Issue 1
Catalytic synthesis of methanethiol from hydrogen sulfide and carbon monoxide over vanadium-based catalysts
journal, February 2003
- Mul, Guido; Wachs, Israel E.; Hirschon, Albert S.
- Catalysis Today, Vol. 78, Issue 1-4
Unconventional Chemistry for Unconventional Natural Gas
journal, October 2012
- McFarland, E.
- Science, Vol. 338, Issue 6105
Probing the Nature of the Active Phase of Molybdenum-Supported Catalysts for the Direct Synthesis of Methylmercaptan from Syngas and H 2 S
journal, March 2015
- Cordova, A.; Blanchard, P.; Lancelot, C.
- ACS Catalysis, Vol. 5, Issue 5
Catalytic application of niobium compounds
journal, February 2003
- Tanabe, Kozo
- Catalysis Today, Vol. 78, Issue 1-4
Thermodynamic analyses of hydrogen production from sub-quality natural gas
journal, January 2007
- Huang, Cunping; T-Raissi, Ali
- Journal of Power Sources, Vol. 163, Issue 2
Onium Ylide chemistry. 1. Bifunctional acid-base-catalyzed conversion of heterosubstituted methanes into ethylene and derived hydrocarbons. The onium ylide mechanism of the C1 .fwdarw. C2 conversion
journal, April 1984
- Olah, George A.; Doggweiler, Hans; Felberg, Jeff D.
- Journal of the American Chemical Society, Vol. 106, Issue 7
Catalysis science of the solid acidity of model supported tungsten oxide catalysts
journal, August 2006
- Wachs, Israel E.; Kim, Taejin; Ross, Elizabeth I.
- Catalysis Today, Vol. 116, Issue 2
Methanol to Olefins (MTO): From Fundamentals to Commercialization
journal, February 2015
- Tian, Peng; Wei, Yingxu; Ye, Mao
- ACS Catalysis, Vol. 5, Issue 3
Thermodynamic analyses of hydrogen production from sub-quality natural gas
journal, January 2007
- Huang, Cunping; T-Raissi, Ali
- Journal of Power Sources, Vol. 163, Issue 2
One-step Synthesis of Methanethiol with Mixture Gases (CO/H2S/H2) over SBA-15 Supported Mo-based Catalysts
journal, January 2015
- Huang, Si; He, Sufang; Deng, Lian
- Procedia Engineering, Vol. 102
Catalytic Synthesis of Methanethiol from H2S-rich Syngas Over Sulfided SiO2-supported Mo-based Catalysts
journal, November 2007
- Chen, Ai Ping; Wang, Qi; Hao, Ying Juan
- Catalysis Letters, Vol. 121, Issue 3-4
Study on Methanethiol Synthesis from H2S-Rich Syngas Over K2MoO4 Catalyst Supported on Electrolessly Ni-Plated SiO2
journal, January 2009
- Hao, Yingjuan; Zhang, Yuanhua; Chen, Aiping
- Catalysis Letters, Vol. 129, Issue 3-4
An active and coke-resistant dry reforming catalyst comprising nickel–tungsten alloy nanoparticles
journal, September 2015
- Zhang, Shaohua; Shi, Chuan; Chen, Bingbing
- Catalysis Communications, Vol. 69
Recovery of sulfur from sour acid gas: A review of the technology
journal, October 2002
- Eow, John S.
- Environmental Progress, Vol. 21, Issue 3
ϵ-Caprolactam: new by-product free synthesis routes
journal, November 2001
- Dahlhoff, Gerd; Niederer, John P. M.; Hoelderich, Wolfgang F.
- Catalysis Reviews, Vol. 43, Issue 4
Synthesis of Methanethiol from Carbonyl Sulfide and Carbon Disulfide on (Co)K-Promoted Sulfide Mo/SiO 2 Catalysts
journal, October 2011
- Gutiérrez, Oliver Y.; Kaufmann, Christoph; Lercher, Johannes A.
- ACS Catalysis, Vol. 1, Issue 11
Production of elemental sulfur and ammonium thiosulfate by H2S oxidation over Nb2O5 supported on Fe-pillared clay
journal, August 2014
- Kim, Moon-Il; Lee, Goo-Hwa; Kim, Dong-Woo
- Korean Journal of Chemical Engineering, Vol. 31, Issue 12
Decomposition of alkanethiols to dialkyl sulfides and hydrogen sulfide
journal, May 1990
- Mashkina, A. V.; Grunvald, V. R.; Nasteka, V. I.
- Reaction Kinetics & Catalysis Letters, Vol. 41, Issue 2
Hydrogen production by methane reforming with H2S using Mo,Cr/ZrO2–SBA15 and Mo,Cr/ZrO2–La2O3 catalysts
journal, December 2015
- Martínez-Salazar, A. L.; Melo-Banda, J. A.; Reyes de la Torre, A. I.
- International Journal of Hydrogen Energy, Vol. 40, Issue 48
“Coking” of zeolites during methanol conversion: Basic reactions of the MTO-, MTP- and MTG processes
journal, September 2010
- Schulz, Hans
- Catalysis Today, Vol. 154, Issue 3-4
Worldwide development potential for sour gas
journal, January 2011
- Burgers, W. F. J.; Northrop, P. S.; Kheshgi, H. S.
- Energy Procedia, Vol. 4
The conversion of methanol and other O-compounds to hydrocarbons over zeolite catalysts
journal, May 1977
- Chang, C.
- Journal of Catalysis, Vol. 47, Issue 2
Kinetics of the catalytic reaction of methane and hydrogen sulphide over a PtAl2O3 catalyst
journal, April 1996
- Megalofonos, S. K.; Papayannakos, N. G.
- Applied Catalysis A: General, Vol. 138, Issue 1