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Title: Controlling Proton Delivery through Catalyst Structural Dynamics

Journal Article · · Angewandte Chemie (International Edition)
 [1];  [2];  [2];  [2];  [2];  [2];  [2];  [2];  [2]
  1. Center for Molecular Electrocatalysis, Pacific Northwest National Laboratory, P.O. Box 999, K2-57 Richland WA 99352 USA; 221 Science Center, State University of New York at Fredonia, Fredonia NY 14063 USA
  2. Center for Molecular Electrocatalysis, Pacific Northwest National Laboratory, P.O. Box 999, K2-57 Richland WA 99352 USA
+ Show Author Affiliations

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Center for Molecular Electrocatalysis (CME)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
AC05-76RL01830
OSTI ID:
1388790
Journal Information:
Angewandte Chemie (International Edition), Vol. 55, Issue 43; Related Information: CME partners with Pacific Northwest National Laboratory (lead); University of Illinois, Urbana-Champaign; Pennsylvania State University; University of Washington; University of Wyoming; ISSN 1433-7851
Publisher:
Wiley
Country of Publication:
United States
Language:
English

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X-ray Crystal Structure of the Fe-Only Hydrogenase (CpI) from Clostridium pasteurianum to 1.8 Angstrom Resolution journal December 1998
Acidic ionic liquid/water solution as both medium and proton source for electrocatalytic H2 evolution by [Ni(P2N2)2]2+ complexes journal June 2012
Effects of Solvent and Structural Dynamics on Electron Transfer Reactions of 4-Aminonaphthalene-1,8-dicarboximide Donor−Acceptor Molecules in Nematic Liquid Crystals and Isotropic Solvents journal January 2003
Flexibility, Diversity, and Cooperativity: Pillars of Enzyme Catalysis journal December 2011
Studies of a Series of [Ni(P R 2 N Ph 2 ) 2 (CH 3 CN)] 2+ Complexes as Electrocatalysts for H 2 Production: Substituent Variation at the Phosphorus Atom of the P 2 N 2 Ligand journal November 2011
Catalytic Turnover of [FeFe]-Hydrogenase Based on Single-Molecule Imaging journal October 2011
Ab Initio-Based Kinetic Modeling for the Design of Molecular Catalysts: The Case of H 2 Production Electrocatalysts journal August 2015
Keep on Moving: Discovering and Perturbing the Conformational Dynamics of Enzymes journal December 2014
Electrocatalytic H 2 production with a turnover frequency >10 7 s −1 : the medium provides an increase in rate but not overpotential journal January 2014
High Catalytic Rates for Hydrogen Production Using Nickel Electrocatalysts with Seven-Membered Cyclic Diphosphine Ligands Containing One Pendant Amine journal February 2013
Potential-sweep chronoamperometry: Kinetic currents for first-order chemical reaction parallel to electron-transfer process (catalytic currents) journal September 1965
Photoswitchable Catalysts: Correlating Structure and Conformational Dynamics with Reactivity by a Combined Experimental and Computational Approach journal January 2009
Conformational Dynamics and Proton Relay Positioning in Nickel Catalysts for Hydrogen Production and Oxidation journal November 2013
[Ni(P Ph 2 N C6H4X 2 ) 2 ] 2+ Complexes as Electrocatalysts for H 2 Production: Effect of Substituents, Acids, and Water on Catalytic Rates journal April 2011
Linking Structural Dynamics and Functional Diversity in Asymmetric Catalysis journal March 2009
Water-assisted proton delivery and removal in bio-inspired hydrogen production catalysts journal January 2015
[Ni(P Me 2 N Ph 2 ) 2 ](BF 4 ) 2 as an Electrocatalyst for H 2 Production journal March 2012
Multielectron, Multistep Molecular Catalysis of Electrochemical Reactions: Benchmarking of Homogeneous Catalysts journal June 2014
Direct Determination of Equilibrium Potentials for Hydrogen Oxidation/Production by Open Circuit Potential Measurements in Acetonitrile journal June 2012
Zirconocene Complexes with Cyclopenta[ l ]phenanthrene Ligands:  Syntheses, Structural Dynamics, and Properties as Olefin Polymerization Catalysts journal September 2000
Structure/Function Relationships of [NiFe]- and [FeFe]-Hydrogenases journal October 2007
Comprehensive Chirality Sensing: Development of Stereodynamic Probes with a Dual (Chir)optical Response journal June 2014
Hydrogenases journal March 2014
Dynamically Achieved Active Site Precision in Enzyme Catalysis journal December 2014
Development of Molecular Electrocatalysts for Energy Storage journal February 2014
Metals and Their Scaffolds To Promote Difficult Enzymatic Reactions journal August 2006
Production of hydrogen by electrocatalysis: making the H–H bond by combining protons and hydrides journal January 2014

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Related Subjects

catalysis (homogeneous)
catalysis (heterogeneous)
solar (fuels)
bio-inspired
energy storage (including batteries and capacitors)
hydrogen and fuel cells
charge transport
materials and chemistry by design
synthesis (novel materials)