Critical design of heterogeneous catalysts for biomass valorization: current thrust and emerging prospects

De, Sudipta; Dutta, Saikat; Saha, Basudeb

doi:10.1039/c6cy01370h

Title: Critical design of heterogeneous catalysts for biomass valorization: current thrust and emerging prospects

Journal Article · Fri Aug 26 00:00:00 EDT 2016 · Catalysis Science and Technology

DOI:https://doi.org/10.1039/c6cy01370h· OSTI ID:1388762

De, Sudipta ^[1]; Dutta, Saikat ^[2]; Saha, Basudeb ^[2]

National Univ. of Singapore (Singapore). Dept. of Chemical and Biomolecular Engineering
Univ. of Delaware, Newark, DE (United States). Catalysis Center for Energy Innovation (CCEI), ISE Lab.

Catalysis in the heterogeneous phase plays a crucial role in the valorization of biorenewable substrates with controlled reactivity, efficient mechanical process separation, greater recyclability and minimization of environmental effects. In this minireview, we have critically analyzed the design aspects of catalysts with multifunctional properties in making biomass conversion processes more productive and sustainable. The catalytic systems have been categorized into subgroups such as metal oxides and phosphates, supported metals, functionalized porous materials, acidic and ion-exchange resins, zeolites and carbonaceous materials to discuss their structural features and active sites towards intrinsic reactivity and selectivity in the transformation of biomass intermediates via hydrolysis, dehydration, hydrodeoxygenation and oxidation pathways. Recent advances in photocatalytic materials for the oxidation of biomass-derived small molecules (such as sugars, alcohols, carboxylic acids) and lignin model compounds and the role of different heteroatoms in improving photo-electronic properties are discussed. The synergistic effect of metal nanoparticulate sites and acid–base supports of bimetallic catalytic systems in performing multistep cascade processes in one-pot are analyzed.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Catalysis Center for Energy Innovation (CCEI)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0001004

OSTI ID:: 1388762

Journal Information:: Catalysis Science and Technology, Vol. 6, Issue 20; Related Information: CCEI partners with the University of Delaware (lead); Brookhaven National Laboratory; California Institute of Technology; Columbia University; University of Delaware; Lehigh University; University of Massachusetts, Amherst; Massachusetts Institute of Technology; University of Minnesota; Pacific Northwest National Laboratory; University of Pennsylvania; Princeton University; Rutgers University; ISSN 2044-4753

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 95 works

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References (186)

Catalytic Asymmetric Allylic Alkylation in Water with a Recyclable Amphiphilic Resin-Supported P,N -Chelating Palladium Complex Uozumi, Yasuhiro; Shibatomi, Kazutaka Journal of the American Chemical Society, Vol. 123, Issue 12 https://doi.org/10.1021/ja005866j	journal	March 2001
Hydrolysis of cellulose by cellulase-mimetic solid catalyst Shuai, Li; Pan, Xuejun Energy & Environmental Science, Vol. 5, Issue 5 https://doi.org/10.1039/c2ee03373a	journal	January 2012
Efficient Utilization of Nanospace of Layered Transition Metal Oxide HNbMoO ₆ as a Strong, Water-Tolerant Solid Acid Catalyst Tagusagawa, Caio; Takagaki, Atsushi; Hayashi, Shigenobu Journal of the American Chemical Society, Vol. 130, Issue 23 https://doi.org/10.1021/ja802478d	journal	June 2008
Conversion of cellobiose into sorbitol in neutral water medium over carbon nanotube-supported ruthenium catalysts Deng, Weiping; Liu, Mi; Tan, Xuesong Journal of Catalysis, Vol. 271, Issue 1 https://doi.org/10.1016/j.jcat.2010.01.024	journal	April 2010
Dissolution of Cellose with Ionic Liquids Swatloski, Richard P.; Spear, Scott K.; Holbrey, John D. Journal of the American Chemical Society, Vol. 124, Issue 18, p. 4974-4975 https://doi.org/10.1021/ja025790m	journal	May 2002
A green process for efficient lignin (biomass) degradation and hydrogen production via water splitting using nanostructured C, N, S-doped ZnO under solar light Kadam, Sunil R.; Mate, Vivek R.; Panmand, Rajendra P. RSC Adv., Vol. 4, Issue 105 https://doi.org/10.1039/C4RA10760H	journal	January 2014
Effect of phosphoric acid pretreatment on enzymatic hydrolysis of microcrystalline cellulose Zhang, Juanhua; Zhang, Beixiao; Zhang, Jingqiang Biotechnology Advances, Vol. 28, Issue 5 https://doi.org/10.1016/j.biotechadv.2010.05.010	journal	September 2010
Insights into the Interplay of Lewis and Brønsted Acid Catalysts in Glucose and Fructose Conversion to 5-(Hydroxymethyl)furfural and Levulinic Acid in Aqueous Media Choudhary, Vinit; Mushrif, Samir H.; Ho, Christopher Journal of the American Chemical Society, Vol. 135, Issue 10 https://doi.org/10.1021/ja3122763	journal	March 2013
Zeolite-Catalyzed Isomerization of Triose Sugars Taarning, Esben; Saravanamurugan, Shunmugavel; Spangsberg Holm, Martin ChemSusChem, Vol. 2, Issue 7, p. 625-627 https://doi.org/10.1002/cssc.200900099	journal	July 2009
Titanium-Beta Zeolites Catalyze the Stereospecific Isomerization of d -Glucose to l -Sorbose via Intramolecular C5–C1 Hydride Shift Gounder, Rajamani; Davis, Mark E. ACS Catalysis, Vol. 3, Issue 7 https://doi.org/10.1021/cs400273c	journal	June 2013
Visible-Light Photocatalysis in Nitrogen-Doped Titanium Oxides Asahi, R. Science, Vol. 293, Issue 5528 https://doi.org/10.1126/science.1061051	journal	July 2001
Hydration of MCM-41 Studied by Sorption Calorimetry Kocherbitov, Vitaly; Alfredsson, Viveka The Journal of Physical Chemistry C, Vol. 111, Issue 35 https://doi.org/10.1021/jp072474r	journal	September 2007
Technology development for the production of biobased products from biorefinery carbohydrates—the US Department of Energy’s “Top 10” revisited Bozell, Joseph J.; Petersen, Gene R. Green Chemistry, Vol. 12, Issue 4, p. 539-554 https://doi.org/10.1039/b922014c	journal	January 2010
Sulfonated porous organic polymer as a highly efficient catalyst for the synthesis of biodiesel at room temperature Gomes, Ruth; Bhanja, Piyali; Bhaumik, Asim Journal of Molecular Catalysis A: Chemical, Vol. 411 https://doi.org/10.1016/j.molcata.2015.10.016	journal	January 2016
Hydration of Halide Anions in Ion-Exchange Resin and Their Dissociation from Cationic Groups Okada, Tetsuo; Harada, Makoto Analytical Chemistry, Vol. 76, Issue 15 https://doi.org/10.1021/ac049602h	journal	August 2004
Cellulose Hydrolysis by a New Porous Coordination Polymer Decorated with Sulfonic Acid Functional Groups Akiyama, George; Matsuda, Ryotaro; Sato, Hiroshi Advanced Materials, Vol. 23, Issue 29 https://doi.org/10.1002/adma.201101356	journal	June 2011
Conversion of Cellulose into Isosorbide over Bifunctional Ruthenium Nanoparticles Supported on Niobium Phosphate Sun, Peng; Long, Xiangdong; He, Hao ChemSusChem, Vol. 6, Issue 11 https://doi.org/10.1002/cssc.201300701	journal	September 2013
High-value chemicals obtained from selective photo-oxidation of glucose in the presence of nanostructured titanium photocatalysts Colmenares, Juan C.; Magdziarz, Agnieszka; Bielejewska, Anna Bioresource Technology, Vol. 102, Issue 24 https://doi.org/10.1016/j.biortech.2011.09.101	journal	December 2011
Room temperature versatile conversion of biomass-derived compounds by means of supported TiO2 photocatalysts Colmenares, Juan C.; Magdziarz, Agnieszka Journal of Molecular Catalysis A: Chemical, Vol. 366 https://doi.org/10.1016/j.molcata.2012.09.018	journal	January 2013
Biopolymer templated porous TiO2: An efficient catalyst for the conversion of unutilized sugars derived from hemicellulose De, Sudipta; Dutta, Saikat; Patra, Astam K. Applied Catalysis A: General, Vol. 435-436 https://doi.org/10.1016/j.apcata.2012.06.002	journal	September 2012
Hydrotalcite-supported gold-nanoparticle-catalyzed highly efficient base-free aqueous oxidation of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid under atmospheric oxygen pressure Gupta, Navneet Kumar; Nishimura, Shun; Takagaki, Atsushi Green Chemistry, Vol. 13, Issue 4 https://doi.org/10.1039/c0gc00911c	journal	January 2011
Cellulose Conversion under Heterogeneous Catalysis Dhepe, Paresh L.; Fukuoka, Atsushi ChemSusChem, Vol. 1, Issue 12 https://doi.org/10.1002/cssc.200800129	journal	December 2008
Epitaxially Grown Layered MFI–Bulk MFI Hybrid Zeolitic Materials Kim, Wun-gwi; Zhang, Xueyi; Lee, Jong Suk ACS Nano, Vol. 6, Issue 11 https://doi.org/10.1021/nn3036254	journal	October 2012
Selective Bifunctional Catalytic Conversion of Cellulose over Reshaped Ni Particles at the Tip of Carbon Nanofibers Van de Vyver, Stijn; Geboers, Jan; Dusselier, Michiel ChemSusChem, Vol. 3, Issue 6 https://doi.org/10.1002/cssc.201000087	journal	May 2010
Catalytic oxidation of biomass derived 5-hydroxymethylfurfural (HMF) over Ru III -incorporated zirconium phosphate catalyst Wang, Fan; Yuan, Ziliang; Liu, Bing Journal of Industrial and Engineering Chemistry, Vol. 38 https://doi.org/10.1016/j.jiec.2016.05.001	journal	June 2016
Catalytic Behavior of Brønsted Acid Sites in MWW and MFI Zeolites with Dual Meso- and Microporosity Liu, Dongxia; Bhan, Aditya; Tsapatsis, Michael ACS Catalysis, Vol. 1, Issue 1 https://doi.org/10.1021/cs100042r	journal	December 2010
Gold Nanoparticles Located at the Interface of Anatase/Rutile TiO ₂ Particles as Active Plasmonic Photocatalysts for Aerobic Oxidation Tsukamoto, Daijiro; Shiraishi, Yasuhiro; Sugano, Yoshitsune Journal of the American Chemical Society, Vol. 134, Issue 14 https://doi.org/10.1021/ja2120647	journal	April 2012
Xylose Isomerization to Xylulose and its Dehydration to Furfural in Aqueous Media Choudhary, Vinit; Pinar, Ana B.; Sandler, Stanley I. ACS Catalysis, Vol. 1, Issue 12 https://doi.org/10.1021/cs200461t	journal	October 2011
Photocatalytic selective oxidation of methanol to methyl formate in gas phase over titanium(IV) oxide in a flow-type reactor Kominami, Hiroshi; Sugahara, Hiroshi; Hashimoto, Keiji Catalysis Communications, Vol. 11, Issue 5 https://doi.org/10.1016/j.catcom.2009.11.014	journal	January 2010
Aerobic oxidation of 5-hydroxylmethylfurfural with homogeneous and nanoparticulate catalysts Saha, Basudeb; Dutta, Saikat; Abu-Omar, Mahdi M. Catal. Sci. Technol., Vol. 2, Issue 1 https://doi.org/10.1039/C1CY00321F	journal	January 2012
Conversion of Xylose to Furfural Using Lewis and Brønsted Acid Catalysts in Aqueous Media Choudhary, Vinit; Sandler, Stanley I.; Vlachos, Dionisios G. ACS Catalysis, Vol. 2, Issue 9 https://doi.org/10.1021/cs300265d	journal	August 2012
Aqueous-phase hydrodeoxygenation of sorbitol: A comparative study of Pt/Zr phosphate and PtReOx/C Kim, Yong Tae; Dumesic, James A.; Huber, George W. Journal of Catalysis, Vol. 304 https://doi.org/10.1016/j.jcat.2013.03.022	journal	August 2013
Conversion of glucose into levulinic acid with solid metal(IV) phosphate catalysts Weingarten, Ronen; Kim, Yong Tae; Tompsett, Geoffrey A. Journal of Catalysis, Vol. 304 https://doi.org/10.1016/j.jcat.2013.03.023	journal	August 2013
Action of bimetallic nanocatalysts under reaction conditions and during catalysis: evolution of chemistry from high vacuum conditions to reaction conditions Tao, Franklin (Feng); Zhang, Shiran; Nguyen, Luan Chemical Society Reviews, Vol. 41, Issue 24 https://doi.org/10.1039/c2cs35185d	journal	January 2012
Conversion and kinetics study of fructose-to-5-hydroxymethylfurfural (HMF) using sulfonic and ionic liquid groups bi-functionalized mesoporous silica nanoparticles as recyclable solid catalysts in DMSO systems Lee, Yin-Ying; Wu, Kevin C. -W. Physical Chemistry Chemical Physics, Vol. 14, Issue 40 https://doi.org/10.1039/c2cp42751f	journal	January 2012
Hydrolysis of cellulose into glucose over carbons sulfonated at elevated temperatures Pang, Jifeng; Wang, Aiqin; Zheng, Mingyuan Chemical Communications, Vol. 46, Issue 37 https://doi.org/10.1039/c0cc02014a	journal	January 2010
Towards the Sulfuric Acid of Solids Harmer, Mark A.; Farneth, William E.; Sun, Qun Advanced Materials, Vol. 10, Issue 15 https://doi.org/10.1002/(SICI)1521-4095(199810)10:15<1255::AID-ADMA1255>3.0.CO;2-T	journal	October 1998
Depolymerization of Cellulose Assisted by a Nonthermal Atmospheric Plasma Benoit, Maud; Rodrigues, Anthony; Zhang, Qinghua Angewandte Chemie International Edition, Vol. 50, Issue 38 https://doi.org/10.1002/anie.201104123	journal	August 2011
Aerobic Oxidation of β-1 Lignin Model Compounds with Copper and Oxovanadium Catalysts Sedai, Baburam; Díaz-Urrutia, Christian; Baker, R. Tom ACS Catalysis, Vol. 3, Issue 12 https://doi.org/10.1021/cs400636k	journal	November 2013
Catalytic conversion of cellulose to hexitols with mesoporous carbon supported Ni-based bimetallic catalysts Pang, Jifeng; Wang, Aiqin; Zheng, Mingyuan Green Chemistry, Vol. 14, Issue 3 https://doi.org/10.1039/c2gc16364k	journal	January 2012
Catalytic Conversion of Cellulose into Sugar Alcohols Fukuoka, Atsushi; Dhepe, Paresh L. Angewandte Chemie International Edition, Vol. 45, Issue 31, p. 5161-5163 https://doi.org/10.1002/anie.200601921	journal	August 2006
Efficient mechano-catalytic depolymerization of crystalline cellulose by formation of branched glucan chains Dornath, Paul; Cho, Hong Je; Paulsen, Alex Green Chemistry, Vol. 17, Issue 2 https://doi.org/10.1039/C4GC02187H	journal	January 2015
Fabrication of nitrogen-doped hierarchically porous carbons through a hybrid dual-template route for CO2 capture and haemoperfusion Liu, Rui-Lin; Ji, Wen-Juan; He, Tian Carbon, Vol. 76 https://doi.org/10.1016/j.carbon.2014.04.052	journal	September 2014
Catalytic C−O Bond Cleavage of 2-Aryloxy-1-arylethanols and Its Application to the Depolymerization of Lignin-Related Polymers Nichols, Jason M.; Bishop, Lee M.; Bergman, Robert G. Journal of the American Chemical Society, Vol. 132, Issue 36 https://doi.org/10.1021/ja106101f	journal	September 2010
Dehydration of xylose into furfural over micro-mesoporous sulfonic acid catalysts Dias, A.; Pillinger, M.; Valente, A. Journal of Catalysis, Vol. 229, Issue 2 https://doi.org/10.1016/j.jcat.2004.11.016	journal	January 2005
Toward a rational control of solid acid catalysis for green synthesis and biomass conversion Shimizu, Ken-ichi; Satsuma, Atsushi Energy & Environmental Science, Vol. 4, Issue 9 https://doi.org/10.1039/c1ee01458g	journal	January 2011
Selective photocatalytic oxidation of aromatic alcohols to aldehydes in an aqueous suspension of gold nanoparticles supported on cerium(iv) oxide under irradiation of green light Tanaka, Atsuhiro; Hashimoto, Keiji; Kominami, Hiroshi Chemical Communications, Vol. 47, Issue 37 https://doi.org/10.1039/c1cc13801d	journal	January 2011
Pt Nanocatalysts Supported on Reduced Graphene Oxide for Selective Conversion of Cellulose or Cellobiose to Sorbitol Wang, Ding; Niu, Wenqi; Tan, Minghui ChemSusChem, Vol. 7, Issue 5 https://doi.org/10.1002/cssc.201301123	journal	March 2014
Preparation of Au/CeO ₂ Exhibiting Strong Surface Plasmon Resonance Effective for Selective or Chemoselective Oxidation of Alcohols to Aldehydes or Ketones in Aqueous Suspensions under Irradiation by Green Light Tanaka, Atsuhiro; Hashimoto, Keiji; Kominami, Hiroshi Journal of the American Chemical Society, Vol. 134, Issue 35 https://doi.org/10.1021/ja305225s	journal	August 2012
C-C or C-O Bond Cleavage in a Phenolic Lignin Model Compound: Selectivity Depends on Vanadium Catalyst Hanson, Susan K.; Wu, Ruilian; Silks, Louis A. “Pete” Angewandte Chemie International Edition, Vol. 51, Issue 14, p. 3410-3413 https://doi.org/10.1002/anie.201107020	journal	January 2012
Sulfonated Porous Polymeric Nanofibers as an Efficient Solid Acid Catalyst for the Production of 5-Hydroxymethylfurfural from Biomass Mondal, Sujan; Mondal, John; Bhaumik, Asim ChemCatChem, Vol. 7, Issue 21 https://doi.org/10.1002/cctc.201500709	journal	September 2015
Platinum–cobalt bimetallic nanoparticles in hollow carbon nanospheres for hydrogenolysis of 5-hydroxymethylfurfural Wang, Guang-Hui; Hilgert, Jakob; Richter, Felix Herrmann Nature Materials, Vol. 13, Issue 3 https://doi.org/10.1038/nmat3872	journal	February 2014
A Heterogeneous Nickel Catalyst for the Hydrogenolysis of Aryl Ethers without Arene Hydrogenation Sergeev, Alexey G.; Webb, Jonathan D.; Hartwig, John F. Journal of the American Chemical Society, Vol. 134, Issue 50, p. 20226-20229 https://doi.org/10.1021/ja3085912	journal	December 2012
Tandem Lewis acid/Brønsted acid-catalyzed conversion of carbohydrates to 5-hydroxymethylfurfural using zeolite beta Swift, T. Dallas; Nguyen, Hannah; Erdman, Zachary Journal of Catalysis, Vol. 333 https://doi.org/10.1016/j.jcat.2015.10.009	journal	January 2016
A new approach for the production of 2,5-furandicarboxylic acid by in situ oxidation of 5-hydroxymethylfurfural starting from fructose Kröger, Martin; Prüße, Ulf; Vorlop, Klaus‐Dieter Topics in Catalysis, Vol. 13, Issue 3, p. 237-242 https://doi.org/10.1023/A:1009017929727	journal	August 2000
Total Hydrogenation of Furfural and 5-Hydroxymethylfurfural over Supported Pd–Ir Alloy Catalyst Nakagawa, Yoshinao; Takada, Kana; Tamura, Masazumi ACS Catalysis, Vol. 4, Issue 8 https://doi.org/10.1021/cs500620b	journal	July 2014
Selective hydrolysis of cellulose into glucose over solid acid catalysts Onda, Ayumu; Ochi, Takafumi; Yanagisawa, Kazumichi Green Chemistry, Vol. 10, Issue 10 https://doi.org/10.1039/b808471h	journal	January 2008
Challenges of and Insights into Acid-Catalyzed Transformations of Sugars Caratzoulas, Stavros; Davis, Mark E.; Gorte, Raymond J. The Journal of Physical Chemistry C, Vol. 118, Issue 40 https://doi.org/10.1021/jp504358d	journal	August 2014
Mechanisms for High Selectivity in the Hydrodeoxygenation of 5-Hydroxymethylfurfural over PtCo Nanocrystals Luo, Jing; Yun, Hongseok; Mironenko, Alexander V. ACS Catalysis, Vol. 6, Issue 7 https://doi.org/10.1021/acscatal.6b00750	journal	May 2016
Photocatalysis with Organized Systems for the Oxofunctionalization of Hydrocarbons by O ₂ Maldotti, Andrea; Molinari, Alessandra; Amadelli, Rossano Chemical Reviews, Vol. 102, Issue 10 https://doi.org/10.1021/cr010364p	journal	October 2002
Supported ionic liquid silica nanoparticles (SILnPs) as an efficient and recyclable heterogeneous catalyst for the dehydration of fructose to 5-hydroxymethylfurfural Sidhpuria, Kalpesh B.; Daniel-da-Silva, Ana L.; Trindade, Tito Green Chemistry, Vol. 13, Issue 2 https://doi.org/10.1039/c0gc00690d	journal	January 2011
Producing Fuels and Fine Chemicals from Biomass Using Nanomaterials Luque, Rafael; Balu, Alina Mariana https://doi.org/10.1201/b15585	book	January 2013
Characterization and photocatalytic activity of K+-doped TiO2 photocatalysts Chen, Lung-Chuan; Huang, Chao-Ming; Tsai, Fu-Ren Journal of Molecular Catalysis A: Chemical, Vol. 265, Issue 1-2 https://doi.org/10.1016/j.molcata.2006.10.011	journal	March 2007
Metalloenzyme-like catalyzed isomerizations of sugars by Lewis acid zeolites Bermejo-Deval, R.; Assary, R. S.; Nikolla, E. Proceedings of the National Academy of Sciences, Vol. 109, Issue 25 https://doi.org/10.1073/pnas.1206708109	journal	June 2012
Effect of hydrogen donor on liquid phase catalytic transfer hydrogenation of furfural over a Ru/RuO2/C catalyst Panagiotopoulou, Paraskevi; Martin, Nickolas; Vlachos, Dionisios G. Journal of Molecular Catalysis A: Chemical, Vol. 392 https://doi.org/10.1016/j.molcata.2014.05.016	journal	October 2014
Mesocellular Siliceous Foams with Uniformly Sized Cells and Windows Schmidt-Winkel, Patrick; Lukens,, Wayne W.; Zhao, Dongyuan Journal of the American Chemical Society, Vol. 121, Issue 1 https://doi.org/10.1021/ja983218i	journal	January 1999
Titanium hydrogenphosphate: An efficient dual acidic catalyst for 5-hydroxymethylfurfural (HMF) production Alam, Md. Imteyaz; De, Sudipta; Singh, Bhagat Applied Catalysis A: General, Vol. 486 https://doi.org/10.1016/j.apcata.2014.08.019	journal	September 2014
Depolymerization of Cellulose Using Solid Catalysts in Ionic Liquids Rinaldi, Roberto; Palkovits, Regina; Schüth, Ferdi Angewandte Chemie International Edition, Vol. 47, Issue 42, p. 8047-8050 https://doi.org/10.1002/anie.200802879	journal	October 2008
Catalytic Transformations of Birch Kraft Pulp Käldström, Mats; Kumar, Narendra; Tenho, Mikko ACS Catalysis, Vol. 2, Issue 7 https://doi.org/10.1021/cs2006839	journal	June 2012
Base metal-Pt alloys: A general route to high selectivity and stability in the production of biofuels from HMF Luo, Jing; Lee, Jennifer D.; Yun, Hongseok Applied Catalysis B: Environmental, Vol. 199 https://doi.org/10.1016/j.apcatb.2016.06.051	journal	December 2016
Glucose Activation by Transient Cr ²⁺ Dimers Pidko, Evgeny A.; Degirmenci, Volkan; van Santen, Rutger A. Angewandte Chemie International Edition, Vol. 49, Issue 14 https://doi.org/10.1002/anie.201000250	journal	March 2010
Selective photocatalytic oxidation of benzyl alcohol and its derivatives into corresponding aldehydes by molecular oxygen on titanium dioxide under visible light irradiation Higashimoto, Shinya; Kitao, Naoya; Yoshida, Norio Journal of Catalysis, Vol. 266, Issue 2 https://doi.org/10.1016/j.jcat.2009.06.018	journal	September 2009
Tandem Lewis/Brønsted homogeneous acid catalysis: conversion of glucose to 5-hydoxymethylfurfural in an aqueous chromium( iii ) chloride and hydrochloric acid solution Dallas Swift, T.; Nguyen, Hannah; Anderko, Andrzej Green Chemistry, Vol. 17, Issue 10 https://doi.org/10.1039/C5GC01257K	journal	January 2015
Deglycerolization of Biodiesel Streams by Adsorption Over Silica Beds Yori, J. C.; D'Ippolito, S. A.; Pieck, C. L. Energy & Fuels, Vol. 21, Issue 1 https://doi.org/10.1021/ef060362d	journal	January 2007
Cooperative effect of cobalt acetylacetonate and silica in the catalytic cyclization and oxidation of fructose to 2,5-furandicarboxylic acid Ribeiro, Marcelo L.; Schuchardt, Ulf Catalysis Communications, Vol. 4, Issue 2 https://doi.org/10.1016/S1566-7367(02)00261-3	journal	February 2003
Production of Renewable Hexanols from Mechanocatalytically Depolymerized Cellulose by Using Ir-ReO _x /SiO ₂ catalyst Liu, Sibao; Okuyama, Yasuyo; Tamura, Masazumi ChemSusChem, Vol. 8, Issue 4 https://doi.org/10.1002/cssc.201403010	journal	November 2014
Pretreatment and fractionation of corn stover by ammonia recycle percolation process Kim, Tae Hyun; Lee, Yoon Y. Bioresource Technology, Vol. 96, Issue 18, p. 2007-2013 https://doi.org/10.1016/j.biortech.2005.01.015	journal	December 2005
Heterogeneous hydrolysis of cellulose with high polymer acids. Part 3. The acid hydrolysis of cellulose with finely divided cation-exchange resin in the hydrogen form Hartler, Nils; Hyllengren, Kari Journal of Polymer Science, Vol. 56, Issue 164 https://doi.org/10.1002/pol.1962.1205616413	journal	February 1962
Tuneable porous carbonaceous materials from renewable resources White, Robin J.; Budarin, Vitaly; Luque, Rafael Chemical Society Reviews, Vol. 38, Issue 12 https://doi.org/10.1039/b822668g	journal	January 2009
Discovery of optimal zeolites for challenging separations and chemical transformations using predictive materials modeling Bai, Peng; Jeon, Mi Young; Ren, Limin Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms6912	journal	January 2015
Highly Efficient and Selective Oxidation of Aromatic Alcohols Photocatalyzed by Nanoporous Hierarchical Pt/Bi ₂ WO ₆ in Organic Solvent-Free Environment Qamar, M.; Elsayed, Rami B.; Alhooshani, Khalid R. ACS Applied Materials & Interfaces, Vol. 7, Issue 2 https://doi.org/10.1021/am507428r	journal	January 2015
Direct conversion of biomass-derived carbohydrates to 5-hydroxymethylfurural over water-tolerant niobium-based catalysts Zhang, Yu; Wang, Jianjian; Li, Xiangcheng Fuel, Vol. 139 https://doi.org/10.1016/j.fuel.2014.08.047	journal	January 2015
Triblock Copolymer Syntheses of Mesoporous Silica with Periodic 50 to 300 Angstrom Pores Zhao, Dongyuan; Feng, Jianglin; Huo, Qisheng Science, Vol. 279, Issue 5350, p. 548-552 https://doi.org/10.1126/science.279.5350.548	journal	January 1998
The dehydration of fructose to 5-hydroxymethylfurfural efficiently catalyzed by acidic ion-exchange resin in ionic liquid Li, Yuan; Liu, Hui; Song, Changhua Bioresource Technology, Vol. 133 https://doi.org/10.1016/j.biortech.2013.01.038	journal	April 2013
Bimetallic catalysts for upgrading of biomass to fuels and chemicals Alonso, David Martin; Wettstein, Stephanie G.; Dumesic, James A. Chemical Society Reviews, Vol. 41, Issue 24, p. 8075-8098 https://doi.org/10.1039/c2cs35188a	journal	January 2012
Mechanism of Glucose Isomerization Using a Solid Lewis Acid Catalyst in Water Román-Leshkov, Yuriy; Moliner, Manuel; Labinger, Jay A. Angewandte Chemie International Edition, Vol. 49, Issue 47, p. 8954-8957 https://doi.org/10.1002/anie.201004689	journal	October 2010
Glucose production from saccharides using layered transition metal oxide and exfoliated nanosheets as a water-tolerant solid acid catalyst Takagaki, Atsushi; Tagusagawa, Caio; Domen, Kazunari Chemical Communications, Issue 42 https://doi.org/10.1039/b810346a	journal	January 2008
Non-Oxidative Vanadium-Catalyzed C-O Bond Cleavage: Application to Degradation of Lignin Model Compounds Son, Sunghee; Toste, F. Dean Angewandte Chemie International Edition, Vol. 49, Issue 22, p. 3791-3794 https://doi.org/10.1002/anie.201001293	journal	April 2010
Nanostructured Rutile TiO ₂ for Selective Photocatalytic Oxidation of Aromatic Alcohols to Aldehydes in Water Yurdakal, Sedat; Palmisano, Giovanni; Loddo, Vittorio Journal of the American Chemical Society, Vol. 130, Issue 5 https://doi.org/10.1021/ja709989e	journal	February 2008
Hierarchically porous titanium phosphate nanoparticles: an efficient solid acid catalyst for microwave assisted conversion of biomass and carbohydrates into 5-hydroxymethylfurfural Dutta, Arghya; Patra, Astam K.; Dutta, Saikat Journal of Materials Chemistry, Vol. 22, Issue 28 https://doi.org/10.1039/c2jm30623a	journal	January 2012
Conversion of fructose, glucose and sucrose to 5-hydroxymethyl-2-furfural over mesoporous zirconium phosphate catalyst Jain, Archana; Shore, Andrew M.; Jonnalagadda, Subash C. Applied Catalysis A: General, Vol. 489 https://doi.org/10.1016/j.apcata.2014.10.020	journal	January 2015
Synthesis of macroreticular p-(ω-sulfonic-perfluoroalkylated)polystyrene ion-exchange resin and its application as solid acid catalyst Lin, Zheng Huan; Guan, Chuan Jin; Feng, Xin Liang Journal of Molecular Catalysis A: Chemical, Vol. 247, Issue 1-2 https://doi.org/10.1016/j.molcata.2005.11.008	journal	March 2006
Recent progress on metal core@semiconductor shell nanocomposites as a promising type of photocatalyst Zhang, Nan; Liu, Siqi; Xu, Yi-Jun Nanoscale, Vol. 4, Issue 7 https://doi.org/10.1039/c2nr00009a	journal	January 2012
Robust and Recyclable Nonprecious Bimetallic Nanoparticles on Carbon Nanotubes for the Hydrogenation and Hydrogenolysis of 5-Hydroxymethylfurfural Yu, Lili; He, Le; Chen, Jin ChemCatChem, Vol. 7, Issue 11 https://doi.org/10.1002/cctc.201500097	journal	May 2015
Efficient aqueous hydrogenation of biomass platform molecules using supported metal nanoparticles on Starbons® Luque, Rafael; Clark, James H.; Yoshida, Kenta Chemical Communications, Issue 35 https://doi.org/10.1039/b911877b	journal	January 2009
The effect of TiO2-photocatalytic pretreatment on the biological production of ethanol from lignocelluloses Yasuda, Masahide; Miura, Akiteru; Yuki, Ryota Journal of Photochemistry and Photobiology A: Chemistry, Vol. 220, Issue 2-3 https://doi.org/10.1016/j.jphotochem.2011.04.019	journal	May 2011
Carbon-coated Cu-Co bimetallic nanoparticles as selective and recyclable catalysts for production of biofuel 2,5-dimethylfuran Chen, Bingfeng; Li, Fengbo; Huang, Zhijun Applied Catalysis B: Environmental, Vol. 200 https://doi.org/10.1016/j.apcatb.2016.07.004	journal	January 2017
Chemocatalytic conversion of cellulose: opportunities, advances and pitfalls Geboers, Jan A.; Van de Vyver, Stijn; Ooms, Roselinde Catalysis Science & Technology, Vol. 1, Issue 5 https://doi.org/10.1039/c1cy00093d	journal	January 2011
A Unique Silk Mat-Like Structured Pd/CeO ₂ as an Efficient Visible Light Photocatalyst for Green Organic Transformation in Water Zhang, Yanhui; Zhang, Nan; Tang, Zi-Rong ACS Sustainable Chemistry & Engineering, Vol. 1, Issue 10 https://doi.org/10.1021/sc400116k	journal	July 2013
Zinc-Assisted Hydrodeoxygenation of Biomass-Derived 5-Hydroxymethylfurfural to 2,5-Dimethylfuran Saha, Basudeb; Bohn, Christine M.; Abu-Omar, Mahdi M. ChemSusChem, Vol. 7, Issue 11 https://doi.org/10.1002/cssc.201402530	journal	September 2014
Catalytic dehydration of fructose into 5-hydroxymethylfurfural by ion-exchange resin in mixed-aqueous system by microwave heating Qi, Xinhua; Watanabe, Masaru; Aida, Taku M. Green Chemistry, Vol. 10, Issue 7 https://doi.org/10.1039/b801641k	journal	January 2008
Efficient process for conversion of fructose to 5-hydroxymethylfurfural with ionic liquids Qi, Xinhua; Watanabe, Masaru; Aida, Taku M. Green Chemistry, Vol. 11, Issue 9 https://doi.org/10.1039/b905975j	journal	January 2009
Biomass into chemicals: One pot-base free oxidative esterification of 5-hydroxymethyl-2-furfural into 2,5-dimethylfuroate with gold on nanoparticulated ceria Casanova, O.; Iborra, S.; Corma, A. Journal of Catalysis, Vol. 265, Issue 1 https://doi.org/10.1016/j.jcat.2009.04.019	journal	July 2009
Simultaneous electronic and ionic surface conduction of catalyst supports: A general mechanism for spillover The role of water in the Pd-catalyzed hydrogenation of a carbon surface Keren, E. Journal of Catalysis, Vol. 50, Issue 1 https://doi.org/10.1016/0021-9517(77)90007-0	journal	October 1977
Selective photocatalytic degradation of aquatic pollutants by titania encapsulated into FAU-type zeolites Zhang, Guan; Choi, Wonyong; Kim, Seok Han Journal of Hazardous Materials, Vol. 188, Issue 1-3 https://doi.org/10.1016/j.jhazmat.2011.01.105	journal	April 2011
Framework and Extraframework Tin Sites in Zeolite Beta React Glucose Differently Bermejo-Deval, Ricardo; Gounder, Rajamani; Davis, Mark E. ACS Catalysis, Vol. 2, Issue 12 https://doi.org/10.1021/cs300474x	journal	November 2012
A novel approach for lignin modification and degradation Tian, Min; Wen, Jiali; MacDonald, Duncan Electrochemistry Communications, Vol. 12, Issue 4 https://doi.org/10.1016/j.elecom.2010.01.035	journal	April 2010
Starch saccharification by carbon-based solid acid catalyst Yamaguchi, Daizo; Hara, Michikazu Solid State Sciences, Vol. 12, Issue 6 https://doi.org/10.1016/j.solidstatesciences.2009.12.002	journal	June 2010
Hydrolysis of Cellulose by Amorphous Carbon Bearing SO ₃ H, COOH, and OH Groups Suganuma, Satoshi; Nakajima, Kiyotaka; Kitano, Masaaki Journal of the American Chemical Society, Vol. 130, Issue 38 https://doi.org/10.1021/ja803983h	journal	August 2008
Self-Pillared, Single-Unit-Cell Sn-MFI Zeolite Nanosheets and Their Use for Glucose and Lactose Isomerization Ren, Limin; Guo, Qiang; Kumar, Prashant Angewandte Chemie International Edition, Vol. 54, Issue 37 https://doi.org/10.1002/anie.201505334	journal	July 2015
Dehydration of fructose to 5-hydroxymethylfurfural in sub-critical water over heterogeneous zirconium phosphate catalysts Asghari, Feridoun Salak; Yoshida, Hiroyuki Carbohydrate Research, Vol. 341, Issue 14 https://doi.org/10.1016/j.carres.2006.06.025	journal	October 2006
Biomass Recalcitrance: Engineering Plants and Enzymes for Biofuels Production Himmel, M. E.; Ding, S.-Y.; Johnson, D. K. Science, Vol. 315, Issue 5813, p. 804-807 https://doi.org/10.1126/science.1137016	journal	February 2007
One-pot synthesis of 5-hydroxymethylfurfural: a significant biomass conversion over tin-promoted vanadium phosphate (Sn–VPO) catalyst Behera, Gobinda Chandra; Parida, K. M. Catalysis Science & Technology, Vol. 3, Issue 12 https://doi.org/10.1039/c3cy00481c	journal	January 2013
Selective, Nickel-Catalyzed Hydrogenolysis of Aryl Ethers Sergeev, A. G.; Hartwig, J. F. Science, Vol. 332, Issue 6028, p. 439-443 https://doi.org/10.1126/science.1200437	journal	April 2011
Selective conversion of furfural to methylfuran over silica-supported NiFe bimetallic catalysts Sitthisa, Surapas; An, Wei; Resasco, Daniel E. Journal of Catalysis, Vol. 284, Issue 1 https://doi.org/10.1016/j.jcat.2011.09.005	journal	November 2011
Zeolites: On the Synthesis and Adsorption Properties of Single-Unit-Cell Hierarchical Zeolites Made by Rotational Intergrowths (Adv. Funct. Mater. 2/2014) Xu, Dandan; Swindlehurst, Garrett R.; Wu, Haohan Advanced Functional Materials, Vol. 24, Issue 2 https://doi.org/10.1002/adfm.201470011	journal	January 2014
Which Controls the Depolymerization of Cellulose in Ionic Liquids: The Solid Acid Catalyst or Cellulose? Rinaldi, Roberto; Meine, Niklas; vom Stein, Julia ChemSusChem, Vol. 3, Issue 2 https://doi.org/10.1002/cssc.200900281	journal	February 2010
Cellulose pretreatment with 1-n-butyl-3-methylimidazolium chloride for solid acid-catalyzed hydrolysis Kim, Soo-Jin; Dwiatmoko, Adid Adep; Choi, Jae Wook Bioresource Technology, Vol. 101, Issue 21 https://doi.org/10.1016/j.biortech.2010.06.047	journal	November 2010
Porphyrin-based porous organic polymer-supported iron(III) catalyst for efficient aerobic oxidation of 5-hydroxymethyl-furfural into 2,5-furandicarboxylic acid Saha, Basudeb; Gupta, Dinesh; Abu-Omar, Mahdi M. Journal of Catalysis, Vol. 299 https://doi.org/10.1016/j.jcat.2012.12.024	journal	March 2013
Biomass-Derived Porous Carbon Materials: Synthesis and Catalytic Applications De, Sudipta; Balu, Alina Mariana; van der Waal, Jan C. ChemCatChem, Vol. 7, Issue 11 https://doi.org/10.1002/cctc.201500081	journal	May 2015
Selective Aerobic Oxidation of HMF to 2,5-Diformylfuran on Covalent Triazine Frameworks-Supported Ru Catalysts Artz, Jens; Mallmann, Sabrina; Palkovits, Regina ChemSusChem, Vol. 8, Issue 4 https://doi.org/10.1002/cssc.201403078	journal	January 2015
The Pt-Enriched PtNi Alloy Surface and its Excellent Catalytic Performance in Hydrolytic Hydrogenation of Cellulose Liang, Guanfeng; He, Limin; Arai, Masahiko ChemSusChem, Vol. 7, Issue 5 https://doi.org/10.1002/cssc.201301204	journal	March 2014
Self-assembly of mesoporous TiO2 nanospheres via aspartic acid templating pathway and its catalytic application for 5-hydroxymethyl-furfural synthesis De, Sudipta; Dutta, Saikat; Patra, Astam K. Journal of Materials Chemistry, Vol. 21, Issue 43 https://doi.org/10.1039/c1jm13229f	journal	January 2011
Selective hydrogenation of biomass-derived 5-hydroxymethylfurfural (HMF) to 2,5-dimethylfuran (DMF) under atmospheric hydrogen pressure over carbon supported PdAu bimetallic catalyst Nishimura, Shun; Ikeda, Naoya; Ebitani, Kohki Catalysis Today, Vol. 232 https://doi.org/10.1016/j.cattod.2013.10.012	journal	September 2014
Hydrolysis of Glucose to 5-Hydroxymethylfurfural Yang, Liu; Liu, Yu Huan; Ruan, Rong Sheng Advanced Materials Research, Vol. 335-336 https://doi.org/10.4028/www.scientific.net/AMR.335-336.1448	journal	September 2011
Heterogeneous photocatalytic reactions of organic acids and water. New reaction paths besides the photo-Kolbe reaction Sakata, Tadayoshi; Kawai, Tomoji; Hashimoto, Kazuhito The Journal of Physical Chemistry, Vol. 88, Issue 11 https://doi.org/10.1021/j150655a032	journal	May 1984
Studies on the Vanadium-Catalyzed Nonoxidative Depolymerization of Miscanthus giganteus-Derived Lignin Chan, Julian M. W.; Bauer, Stefan; Sorek, Hagit ACS Catalysis, Vol. 3, Issue 6 https://doi.org/10.1021/cs400333q	journal	April 2013
Hydrogen spillover and the rate of heterogeneous catalytic hydrogenation. Quantitative model Filikov, A. V.; Myasoedov, N. F. The Journal of Physical Chemistry, Vol. 90, Issue 21 https://doi.org/10.1021/j100412a007	journal	October 1986
A Mesoporous Carbon-Supported Pt Nanocatalyst for the Conversion of Lignocellulose to Sugar Alcohols Park, Dae Sung; Yun, Danim; Kim, Tae Yong ChemSusChem, Vol. 6, Issue 12 https://doi.org/10.1002/cssc.201300751	journal	November 2013
Biomass as feedstock for a bioenergy and bioproducts industry: The technical feasibility of a billion-ton annual supply Perlack, Robert D.; Wright, Lynn L.; Turhollow, Anthony F. https://doi.org/10.2172/1216415	report	April 2005
Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism Kresge, C. T.; Leonowicz, M. E.; Roth, W. J. Nature, Vol. 359, Issue 6397, p. 710-712 https://doi.org/10.1038/359710a0	journal	October 1992
Synthesis of sugar alcohols by hydrolytic hydrogenation of cellulose over supported metal catalysts Kobayashi, Hirokazu; Ito, Yukiko; Komanoya, Tasuku Green Chem., Vol. 13, Issue 2 https://doi.org/10.1039/C0GC00666A	journal	January 2011
Highly Active Mesoporous Nb-W Oxide Solid-Acid Catalyst Tagusagawa, Caio; Takagaki, Atsushi; Iguchi, Ai Angewandte Chemie International Edition, Vol. 49, Issue 6 https://doi.org/10.1002/anie.200904791	journal	February 2010
Biofuels and Biomass-To-Liquid Fuels in the Biorefinery: Catalytic Conversion of Lignocellulosic Biomass using Porous Materials Stöcker, Michael Angewandte Chemie International Edition, Vol. 47, Issue 48 https://doi.org/10.1002/anie.200801476	journal	October 2008
Effect of temperature and time in the hydrothermal treatment of HY zeolite Salman, N.; Rüscher, C. H.; Buhl, J. -Chr. Microporous and Mesoporous Materials, Vol. 90, Issue 1-3 https://doi.org/10.1016/j.micromeso.2005.09.032	journal	March 2006
Tandem catalysis for the production of alkyl lactates from ketohexoses at moderate temperatures Orazov, Marat; Davis, Mark E. Proceedings of the National Academy of Sciences, Vol. 112, Issue 38 https://doi.org/10.1073/pnas.1516466112	journal	September 2015
Engineering Preformed Cobalt-Doped Platinum Nanocatalysts For Ultraselective Hydrogenation Tsang, Shik Chi; Cailuo, Nick; Oduro, William ACS Nano, Vol. 2, Issue 12 https://doi.org/10.1021/nn800400u	journal	November 2008
Catalytic glucose and fructose conversions with TiO2 and ZrO2 in water at 473K: Relationship between reactivity and acid–base property determined by TPD measurement Watanabe, Masaru; Aizawa, Yuichi; Iida, Toru Applied Catalysis A: General, Vol. 295, Issue 2 https://doi.org/10.1016/j.apcata.2005.08.007	journal	November 2005
Hydrothermal Synthesis of Zeolites with Three-Dimensionally Ordered Mesoporous-Imprinted Structure Chen, Huiyong; Wydra, James; Zhang, Xueyi Journal of the American Chemical Society, Vol. 133, Issue 32 https://doi.org/10.1021/ja2046815	journal	August 2011
High selectivity in visible-light-driven partial photocatalytic oxidation of benzyl alcohol into benzaldehyde over single-crystalline rutile TiO2 nanorods Li, Cong-Ju; Xu, Guo-Rong; Zhang, Baohong Applied Catalysis B: Environmental, Vol. 115-116 https://doi.org/10.1016/j.apcatb.2011.12.003	journal	April 2012
Adsorption-Enhanced Hydrolysis of β-1,4-Glucan on Graphene-Based Amorphous Carbon Bearing SO ₃ H, COOH, and OH Groups Kitano, Masaaki; Yamaguchi, Daizo; Suganuma, Satoshi Langmuir, Vol. 25, Issue 9 https://doi.org/10.1021/la8040506	journal	May 2009
Catalytical conversion of fructose and glucose into 5-hydroxymethylfurfural in hot compressed water by microwave heating Qi, Xinhua; Watanabe, Masaru; Aida, Taku M. Catalysis Communications, Vol. 9, Issue 13 https://doi.org/10.1016/j.catcom.2008.04.025	journal	July 2008
Chemical Routes for the Transformation of Biomass into Chemicals Corma, Avelino; Iborra, Sara; Velty, Alexandra Chemical Reviews, Vol. 107, Issue 6, p. 2411-2502 https://doi.org/10.1021/cr050989d	journal	June 2007
Synthesis of 5-Hydroxymethylfurural from Carbohydrates using Large-Pore Mesoporous Tin Phosphate Dutta, Arghya; Gupta, Dinesh; Patra, Astam K. ChemSusChem, Vol. 7, Issue 3 https://doi.org/10.1002/cssc.201300766	journal	January 2014
Conversion of cellulose to glucose and levulinic acid via solid-supported acid catalysis Hegner, Jessica; Pereira, Kyle C.; DeBoef, Brenton Tetrahedron Letters, Vol. 51, Issue 17 https://doi.org/10.1016/j.tetlet.2010.02.148	journal	April 2010
Cleavage and hydrodeoxygenation (HDO) of C–O bonds relevant to lignin conversion using Pd/Zn synergistic catalysis Parsell, Trenton H.; Owen, Benjamin C.; Klein, Ian Chem. Sci., Vol. 4, Issue 2, p. 806-813 https://doi.org/10.1039/C2SC21657D	journal	January 2013
Catalytic One-Pot Production of Small Organics from Polysaccharides Verendel, J.; Church, Tamara; Andersson, Pher Synthesis, Vol. 2011, Issue 11 https://doi.org/10.1055/s-0030-1260008	journal	April 2011
Microwave assisted rapid conversion of carbohydrates into 5-hydroxymethylfurfural catalyzed by mesoporous TiO2 nanoparticles Dutta, Saikat; De, Sudipta; Patra, Astam K. Applied Catalysis A: General, Vol. 409-410 https://doi.org/10.1016/j.apcata.2011.09.037	journal	December 2011
One-Pot Conversion of Cellulose into n -Hexane over the Ir-ReO _x /SiO ₂ Catalyst Combined with HZSM-5 Liu, Sibao; Tamura, Masazumi; Nakagawa, Yoshinao ACS Sustainable Chemistry & Engineering, Vol. 2, Issue 7 https://doi.org/10.1021/sc5001463	journal	June 2014
Acid saccharification of ball-milled straw Sidiras, D. K.; Koukios, E. G. Biomass, Vol. 19, Issue 4 https://doi.org/10.1016/0144-4565(89)90073-5	journal	January 1989
Solar light induced photocatalytic oxidation of benzyl alcohol using heteropolyoxometalate catalysts of the type [S ₂ M ₁₈ O ₆₂ ] ⁴⁻ Rüther, Thomas; Bond, Alan M.; Jackson, W. Roy Green Chem., Vol. 5, Issue 4 https://doi.org/10.1039/B306521A	journal	January 2003
Hydrolysis of biomass by magnetic solid acid Lai, Da-ming; Deng, Li; Guo, Qing-xiang Energy & Environmental Science, Vol. 4, Issue 9 https://doi.org/10.1039/c1ee01526e	journal	January 2011
Sn-Beta zeolites with borate salts catalyse the epimerization of carbohydrates via an intramolecular carbon shift Gunther, William R.; Wang, Yuran; Ji, Yuewei Nature Communications, Vol. 3, Issue 1 https://doi.org/10.1038/ncomms2122	journal	January 2012
Mechanistic Insights into Metal Lewis Acid-Mediated Catalytic Transfer Hydrogenation of Furfural to 2-Methylfuran Gilkey, Matthew J.; Panagiotopoulou, Paraskevi; Mironenko, Alexander V. ACS Catalysis, Vol. 5, Issue 7 https://doi.org/10.1021/acscatal.5b00586	journal	June 2015
Synthesis of Self-Pillared Zeolite Nanosheets by Repetitive Branching Zhang, Xueyi; Liu, Dongxia; Xu, Dandan Science, Vol. 336, Issue 6089 https://doi.org/10.1126/science.1221111	journal	June 2012
The critical role of heterogeneous catalysis in lignocellulosic biomass conversion Lin, Yu-Chuan; Huber, George W. Energy Environ. Sci., Vol. 2, Issue 1 https://doi.org/10.1039/B814955K	journal	January 2009
A new hypercrosslinked supermicroporous polymer, with scope for sulfonation, and its catalytic potential for the efficient synthesis of biodiesel at room temperature Bhunia, Subhajit; Banerjee, Biplab; Bhaumik, Asim Chemical Communications, Vol. 51, Issue 24 https://doi.org/10.1039/C4CC09872B	journal	January 2015
Selective Aerobic Oxidation Mediated by TiO ₂ Photocatalysis Lang, Xianjun; Ma, Wanhong; Chen, Chuncheng Accounts of Chemical Research, Vol. 47, Issue 2 https://doi.org/10.1021/ar4001108	journal	October 2013
Plasmon-Driven Selective Oxidation of Aromatic Alcohols to Aldehydes in Water with Recyclable Pt/TiO2 Nanocomposites Zhai, Wanying; Xue, Shujie; Zhu, Anwei ChemCatChem, Vol. 3, Issue 1 https://doi.org/10.1002/cctc.201000303	journal	October 2010
The Role of Ru and RuO ₂ in the Catalytic Transfer Hydrogenation of 5-Hydroxymethylfurfural for the Production of 2,5-Dimethylfuran Jae, Jungho; Zheng, Weiqing; Karim, Ayman M. ChemCatChem, Vol. 6, Issue 3 https://doi.org/10.1002/cctc.201300945	journal	February 2014
Conversion of Sugars to Lactic Acid Derivatives Using Heterogeneous Zeotype Catalysts Holm, Martin Spangsberg; Saravanamurugan, Shunmugavel; Taarning, Esben Science, Vol. 328, Issue 5978, p. 602-605 https://doi.org/10.1126/science.1183990	journal	April 2010
Towards a Selective Heterogeneous Catalyst for Glucose Dehydration to 5-Hydroxymethylfurfural in Water: CrCl2 Catalysis in a Thin Immobilized Ionic Liquid Layer Degirmenci, Volkan; Pidko, Evgeny A.; Magusin, Pieter C. M. M. ChemCatChem, Vol. 3, Issue 6 https://doi.org/10.1002/cctc.201000426	journal	April 2011
Magnetically separable nanocomposites with photocatalytic activity under visible light for the selective transformation of biomass-derived platform molecules Balu, Alina M.; Baruwati, Babita; Serrano, Elena Green Chemistry, Vol. 13, Issue 10 https://doi.org/10.1039/c1gc15692f	journal	January 2011
High Surface Area Nafion ^† Resin/Silica Nanocomposites: A New Class of Solid Acid Catalyst Harmer, Mark A.; Farneth, William E.; Sun, Qun Journal of the American Chemical Society, Vol. 118, Issue 33 https://doi.org/10.1021/ja9541950	journal	January 1996
Starbons: New Starch-Derived Mesoporous Carbonaceous Materials with Tunable Properties Budarin, Vitaly; Clark, James H.; Hardy, Jeffrey J. E. Angewandte Chemie International Edition, Vol. 45, Issue 23 https://doi.org/10.1002/anie.200600460	journal	June 2006
A new 3D mesoporous carbon replicated from commercial silica as a catalyst support for direct conversion of cellulose into ethylene glycol Zhang, Yanhua; Wang, Aiqin; Zhang, Tao Chem. Commun., Vol. 46, Issue 6 https://doi.org/10.1039/B919182H	journal	January 2010
Nafion-Resin-Modified Mesocellular Silica Foam Catalyst for 5-Hydroxymethylfurfural Production from D -Fructose Huang, Zhen; Pan, Wenya; Zhou, Haibo ChemSusChem, Vol. 6, Issue 6 https://doi.org/10.1002/cssc.201200967	journal	May 2013
Metal Chlorides in Ionic Liquid Solvents Convert Sugars to 5-Hydroxymethylfurfural Zhao, H.; Holladay, J. E.; Brown, H. Science, Vol. 316, Issue 5831, p. 1597-1600 https://doi.org/10.1126/science.1141199	journal	June 2007
Tin-containing zeolites are highly active catalysts for the isomerization of glucose in water Moliner, M.; Roman-Leshkov, Y.; Davis, M. E. Proceedings of the National Academy of Sciences, Vol. 107, Issue 14, p. 6164-6168 https://doi.org/10.1073/pnas.1002358107	journal	March 2010
Sonication-Assisted Low-Temperature Routes for the Synthesis of Supported Fe-TiO ₂ Econanomaterials: Partial Photooxidation of Glucose and Phenol Aqueous Degradation Colmenares, Juan C.; Magdziarz, Agnieszka; Chernyayeva, Olga ChemCatChem, Vol. 5, Issue 8 https://doi.org/10.1002/cctc.201300025	journal	June 2013
Mechanism of Photooxidation of Alcohol over Nb ₂ O ₅ Shishido, Tetsuya; Miyatake, Toshiaki; Teramura, Kentaro The Journal of Physical Chemistry C, Vol. 113, Issue 43 https://doi.org/10.1021/jp901603p	journal	October 2009
Zeolite-Coated Mesostructured Cellular Silica Foams Trong On, Do; Kaliaguine, Serge Journal of the American Chemical Society, Vol. 125, Issue 3 https://doi.org/10.1021/ja028656a	journal	January 2003
Low-temperature ultrasound-promoted synthesis of Cr–TiO2-supported photocatalysts for valorization of glucose and phenol degradation from liquid phase Colmenares, Juan C.; Magdziarz, Agnieszka; Kurzydlowski, Krzysztof Applied Catalysis B: Environmental, Vol. 134-135 https://doi.org/10.1016/j.apcatb.2013.01.020	journal	May 2013
Shape-selective zeolite catalysis for bioplastics production Dusselier, Michiel; Van Wouwe, Pieter; Dewaele, Annelies Science, Vol. 349, Issue 6243 https://doi.org/10.1126/science.aaa7169	journal	July 2015
Copper-Zinc Alloy Nanopowder: A Robust Precious-Metal-Free Catalyst for the Conversion of 5-Hydroxymethylfurfural Bottari, Giovanni; Kumalaputri, Angela J.; Krawczyk, Krzysztof K. ChemSusChem, Vol. 8, Issue 8 https://doi.org/10.1002/cssc.201403453	journal	April 2015
Autocatalyzed and Ion-Exchange-Resin-Catalyzed Esterification Kinetics of Lactic Acid with Methanol Sanz, M. T.; Murga, R.; Beltrán, S. Industrial & Engineering Chemistry Research, Vol. 41, Issue 3 https://doi.org/10.1021/ie010454k	journal	February 2002
Selective photocatalytic oxidation of 4-substituted aromatic alcohols in water with rutile TiO2 prepared at room temperature Yurdakal, Sedat; Palmisano, Giovanni; Loddo, Vittorio Green Chemistry, Vol. 11, Issue 4 https://doi.org/10.1039/b819862d	journal	January 2009
Heterogeneous photocatalytic nanomaterials: prospects and challenges in selective transformations of biomass-derived compounds Colmenares, Juan Carlos; Luque, Rafael Chem. Soc. Rev., Vol. 43, Issue 3 https://doi.org/10.1039/C3CS60262A	journal	January 2014
Role of Silanol Group in Sn-Beta Zeolite for Glucose Isomerization and Epimerization Reactions Rai, Neeraj; Caratzoulas, Stavros; Vlachos, Dionisios G. ACS Catalysis, Vol. 3, Issue 10 https://doi.org/10.1021/cs400476n	journal	September 2013
Efficient Solid Acid Catalyst Containing Lewis and Brønsted Acid Sites for the Production of Furfurals Mazzotta, Michael G.; Gupta, Dinesh; Saha, Basudeb ChemSusChem, Vol. 7, Issue 8 https://doi.org/10.1002/cssc.201402007	journal	May 2014
Fermentable sugars by chemical hydrolysis of biomass Binder, J. B.; Raines, R. T. Proceedings of the National Academy of Sciences, Vol. 107, Issue 10, p. 4516-4521 https://doi.org/10.1073/pnas.0912073107	journal	March 2010
Bifunctional Solid Catalysts for the Selective Conversion of Fructose to 5-Hydroxymethylfurfural Crisci, Anthony J.; Tucker, Mark H.; Dumesic, James A. Topics in Catalysis, Vol. 53, Issue 15-18 https://doi.org/10.1007/s11244-010-9560-2	journal	May 2010
Pyrene-Based Porous Organic Polymers as Efficient Catalytic Support for the Synthesis of Biodiesels at Room Temperature Kundu, Sudipta K.; Bhaumik, Asim ACS Sustainable Chemistry & Engineering, Vol. 3, Issue 8 https://doi.org/10.1021/acssuschemeng.5b00238	journal	July 2015
Effects of Catalyst Pore Structure and Acid Properties on the Dehydration of Glycerol Choi, Youngbo; Park, Hongseok; Yun, Yang Sik ChemSusChem, Vol. 8, Issue 6 https://doi.org/10.1002/cssc.201402925	journal	November 2014
Photocatalytic Aerobic Oxidation of Alcohols on TiO2: The Acceleration Effect of a Brønsted Acid Wang, Qi; Zhang, Miao; Chen, Chuncheng Angewandte Chemie International Edition, Vol. 49, Issue 43 https://doi.org/10.1002/anie.201001533	journal	July 2010
Selective Oxidation of Alcohols in Gas Phase Using Light-Activated Titanium Dioxide Pillai, U. Journal of Catalysis, Vol. 211, Issue 2 https://doi.org/10.1016/S0021-9517(02)93771-1	journal	October 2002

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An Insight into the Valorization of Hemicellulose Fraction of Biomass into Furfural: Catalytic Conversion and Product Separation Dulie, Negesso Wakushie; Woldeyes, Belay; Demsash, Hundessa Dessalegn Waste and Biomass Valorization https://doi.org/10.1007/s12649-020-00946-1	journal	February 2020
Hf-based metal–organic frameworks as acid–base catalysts for the transformation of biomass-derived furanic compounds into chemicals Rojas-Buzo, Sergio; García-García, Pilar; Corma, Avelino Green Chemistry, Vol. 20, Issue 13 https://doi.org/10.1039/c8gc00806j	journal	January 2018
Task-Specific Organic Salts and Ionic Liquids Binary Mixtures: A Combination to Obtain 5-Hydroxymethylfurfural From Carbohydrates Marullo, Salvatore; Rizzo, Carla; D'Anna, Francesca Frontiers in Chemistry, Vol. 7 https://doi.org/10.3389/fchem.2019.00134	journal	March 2019
Heterogeneous Catalytic Upgrading of Biofuranic Aldehydes to Alcohols Long, Jingxuan; Xu, Yufei; Zhao, Wenfeng Frontiers in Chemistry, Vol. 7 https://doi.org/10.3389/fchem.2019.00529	journal	July 2019
Metal Carbides for Biomass Valorization Chan-Thaw, Carine; Villa, Alberto Applied Sciences, Vol. 8, Issue 2 https://doi.org/10.3390/app8020259	journal	February 2018
Bimetallic Nanoparticles in Alternative Solvents for Catalytic Purposes Dang-Bao, Trung; Pla, Daniel; Favier, Isabelle Catalysts, Vol. 7, Issue 7 https://doi.org/10.3390/catal7070207	journal	July 2017
Alternatives for Chemical and Biochemical Lignin Valorization: Hot Topics from a Bibliometric Analysis of the Research Published During the 2000–2016 Period Abejón, Ricardo; Pérez-Acebo, Heriberto; Clavijo, Leonardo Processes, Vol. 6, Issue 8 https://doi.org/10.3390/pr6080098	journal	July 2018
An overview on recent advances in the synthesis of sulfonated organic materials, sulfonated silica materials, and sulfonated carbon materials and their catalytic applications in chemical processes Sharghi, Hashem; Shiri, Pezhman; Aberi, Mahdi Beilstein Journal of Organic Chemistry, Vol. 14 https://doi.org/10.3762/bjoc.14.253	journal	January 2018

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
09 BIOMASS FUELS
catalysis (homogeneous)
catalysis (heterogeneous)
biofuels (including algae and biomass)
bio-inspired
hydrogen and fuel cells
materials and chemistry by design
synthesis (novel materials)
synthesis (self-assembly)
synthesis (scalable processing)