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Title: Negating interfacial impedance in garnet-based solid-state Li metal batteries

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Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Nanostructures for Electrical Energy Storage (NEES)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
DOE Contract Number:  
Resource Type:
Journal Article
Journal Name:
Nature Materials
Additional Journal Information:
Journal Volume: 16; Journal Issue: 5; Related Information: NEES partners with University of Maryland (lead); University of California, Irvine; University of Florida; Los Alamos National Laboratory; Sandia National Laboratories; Yale University; Journal ID: ISSN 1476-1122
Nature Publishing Group
Country of Publication:
United States
bio-inspired, energy storage (including batteries and capacitors), defects, charge transport, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing)

Citation Formats

Han, Xiaogang, Gong, Yunhui, Fu, Kun, He, Xingfeng, Hitz, Gregory T., Dai, Jiaqi, Pearse, Alex, Liu, Boyang, Wang, Howard, Rubloff, Gary, Mo, Yifei, Thangadurai, Venkataraman, Wachsman, Eric D., and Hu, Liangbing. Negating interfacial impedance in garnet-based solid-state Li metal batteries. United States: N. p., 2016. Web. doi:10.1038/nmat4821.
Han, Xiaogang, Gong, Yunhui, Fu, Kun, He, Xingfeng, Hitz, Gregory T., Dai, Jiaqi, Pearse, Alex, Liu, Boyang, Wang, Howard, Rubloff, Gary, Mo, Yifei, Thangadurai, Venkataraman, Wachsman, Eric D., & Hu, Liangbing. Negating interfacial impedance in garnet-based solid-state Li metal batteries. United States. doi:10.1038/nmat4821.
Han, Xiaogang, Gong, Yunhui, Fu, Kun, He, Xingfeng, Hitz, Gregory T., Dai, Jiaqi, Pearse, Alex, Liu, Boyang, Wang, Howard, Rubloff, Gary, Mo, Yifei, Thangadurai, Venkataraman, Wachsman, Eric D., and Hu, Liangbing. Mon . "Negating interfacial impedance in garnet-based solid-state Li metal batteries". United States. doi:10.1038/nmat4821.
title = {Negating interfacial impedance in garnet-based solid-state Li metal batteries},
author = {Han, Xiaogang and Gong, Yunhui and Fu, Kun and He, Xingfeng and Hitz, Gregory T. and Dai, Jiaqi and Pearse, Alex and Liu, Boyang and Wang, Howard and Rubloff, Gary and Mo, Yifei and Thangadurai, Venkataraman and Wachsman, Eric D. and Hu, Liangbing},
abstractNote = {},
doi = {10.1038/nmat4821},
journal = {Nature Materials},
issn = {1476-1122},
number = 5,
volume = 16,
place = {United States},
year = {2016},
month = {12}

Works referenced in this record:

An All-Solid-State Li-Ion Battery with a Pre-Lithiated Si-Ti-Ni Alloy Anode
journal, January 2013

  • Yersak, Thomas A.; Son, Seoung-Bum; Cho, Jong Soo
  • Journal of The Electrochemical Society, Vol. 160, Issue 9
  • DOI: 10.1149/2.086309jes

Switching on Fast Lithium Ion Conductivity in Garnets: The Structure and Transport Properties of Li 3+ x Nd 3 Te 2− x Sb x O 12
journal, March 2008

  • O’Callaghan, Michael P.; Powell, Andrew S.; Titman, Jeremy J.
  • Chemistry of Materials, Vol. 20, Issue 6
  • DOI: 10.1021/cm703677q

Interface-Engineered All-Solid-State Li-Ion Batteries Based on Garnet-Type Fast Li + Conductors
journal, July 2016

  • van den Broek, Jan; Afyon, Semih; Rupp, Jennifer L. M.
  • Advanced Energy Materials, Vol. 6, Issue 19
  • DOI: 10.1002/aenm.201600736

All solid state lithium ion rechargeable batteries using NASICON structured electrolyte
journal, September 2013

Nebulized spray pyrolysis of Al-doped Li7La3Zr2O12 solid electrolyte for battery applications
journal, October 2014

Fast Solid-State Li Ion Conducting Garnet-Type Structure Metal Oxides for Energy Storage
journal, January 2015

  • Thangadurai, Venkataraman; Pinzaru, Dana; Narayanan, Sumaletha
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 2
  • DOI: 10.1021/jz501828v

Co-sinterable lithium garnet-type oxide electrolyte with cathode for all-solid-state lithium ion battery
journal, November 2014

Sodium Ion Diffusion in Al 2 O 3 : A Distinct Perspective Compared with Lithium Ion Diffusion
journal, October 2014

  • Jung, Sung Chul; Kim, Hyung-Jin; Choi, Jang Wook
  • Nano Letters, Vol. 14, Issue 11
  • DOI: 10.1021/nl503169v

Effects of Li source on microstructure and ionic conductivity of Al-contained Li6.75La3Zr1.75Ta0.25O12 ceramics
journal, February 2015

A Tale of Two Sites: On Defining the Carrier Concentration in Garnet-Based Ionic Conductors for Advanced Li Batteries
journal, March 2015

  • Thompson, Travis; Sharafi, Asma; Johannes, Michelle D.
  • Advanced Energy Materials, Vol. 5, Issue 11
  • DOI: 10.1002/aenm.201500096

All-solid-state Lithium Secondary Batteries Using Li 2 S–P 2 S 5 Solid Electrolytes and LiFePO 4 Electrode Particles with Amorphous Surface Layer
journal, March 2012

  • Sakuda, Atsushi; Kitaura, Hirokazu; Hayashi, Akitoshi
  • Chemistry Letters, Vol. 41, Issue 3
  • DOI: 10.1246/cl.2012.260

Characterizing the Li–Li7La3Zr2O12 interface stability and kinetics as a function of temperature and current density
journal, January 2016

A lithium superionic conductor
journal, July 2011

  • Kamaya, Noriaki; Homma, Kenji; Yamakawa, Yuichiro
  • Nature Materials, Vol. 10, Issue 9, p. 682-686
  • DOI: 10.1038/nmat3066

Fluorinated electrolytes for 5 V lithium-ion battery chemistry
journal, January 2013

  • Zhang, Zhengcheng; Hu, Libo; Wu, Huiming
  • Energy & Environmental Science, Vol. 6, Issue 6
  • DOI: 10.1039/c3ee24414h

First Principles Study of the Li10GeP2S12 Lithium Super Ionic Conductor Material
journal, December 2011

  • Mo, Yifei; Ong, Shyue Ping; Ceder, Gerbrand
  • Chemistry of Materials, Vol. 24, Issue 1, p. 15-17
  • DOI: 10.1021/cm203303y

Dielectric Modification of 5V-Class Cathodes for High-Voltage All-Solid-State Lithium Batteries
journal, March 2014

  • Yada, Chihiro; Ohmori, Akihiro; Ide, Kazuto
  • Advanced Energy Materials, Vol. 4, Issue 9
  • DOI: 10.1002/aenm.201301416

Concerted Migration Mechanism in the Li Ion Dynamics of Garnet-Type Li 7 La 3 Zr 2 O 12
journal, January 2013

  • Jalem, Randy; Yamamoto, Yoshihiro; Shiiba, Hiromasa
  • Chemistry of Materials, Vol. 25, Issue 3
  • DOI: 10.1021/cm303542x

Fabrication and performances of all solid-state symmetric sodium battery based on NASICON-related compounds
journal, July 2013

Antiperovskite Li 3 OCl Superionic Conductor Films for Solid-State Li-Ion Batteries
journal, February 2016

All solid-state sheet battery using lithium inorganic solid electrolyte, thio-LISICON
journal, December 2009

Atomic-Layer-Deposition Oxide Nanoglue for Sodium Ion Batteries
journal, December 2013

  • Han, Xiaogang; Liu, Yang; Jia, Zheng
  • Nano Letters, Vol. 14, Issue 1
  • DOI: 10.1021/nl4035626

How Do Li Atoms Pass through the Al 2 O 3 Coating Layer during Lithiation in Li-ion Batteries?
journal, July 2013

  • Jung, Sung Chul; Han, Young-Kyu
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 16
  • DOI: 10.1021/jz401231e

High rate capabilities of all-solid-state lithium secondary batteries using Li4Ti5O12-coated LiNi0.8Co0.15Al0.05O2 and a sulfide-based solid electrolyte
journal, August 2011

Structure and dynamics of the fast lithium ion conductor “Li7La3Zr2O12”
journal, January 2011

  • Buschmann, Henrik; Dölle, Janis; Berendts, Stefan
  • Physical Chemistry Chemical Physics, Vol. 13, Issue 43
  • DOI: 10.1039/c1cp22108f

Chemical stability of cubic Li7La3Zr2O12 with molten lithium at elevated temperature
journal, April 2013

Fast Lithium Ion Conduction in Garnet-Type Li7La3Zr2O12
journal, October 2007

  • Murugan, Ramaswamy; Thangadurai, Venkataraman; Weppner, Werner
  • Angewandte Chemie International Edition, Vol. 46, Issue 41, p. 7778-7781
  • DOI: 10.1002/anie.200701144

Interface behavior between garnet-type lithium-conducting solid electrolyte and lithium metal
journal, September 2014

Effect of Simultaneous Substitution of Alkali Earth Metals and Nb in Li7La3Zr2O12 on Lithium-Ion Conductivity
journal, January 2013

  • Kihira, Y.; Ohta, S.; Imagawa, H.
  • ECS Electrochemistry Letters, Vol. 2, Issue 7
  • DOI: 10.1149/2.001307eel

Si nanotubes ALD coated with TiO 2 , TiN or Al 2 O 3 as high performance lithium ion battery anodes
journal, January 2014

  • Lotfabad, Elmira Memarzadeh; Kalisvaart, Peter; Kohandehghan, Alireza
  • J. Mater. Chem. A, Vol. 2, Issue 8
  • DOI: 10.1039/C3TA14302C

Fast Lithium-Ion Conducting Thin-Film Electrolytes Integrated Directly on Flexible Substrates for High-Power Solid-State Batteries
journal, November 2011

  • Ihlefeld, Jon F.; Clem, Paul G.; Doyle, Barney L.
  • Advanced Materials, Vol. 23, Issue 47, p. 5663-5667
  • DOI: 10.1002/adma.201102980

The origin of high electrolyte–electrode interfacial resistances in lithium cells containing garnet type solid electrolytes
journal, January 2014

  • Cheng, Lei; Crumlin, Ethan J.; Chen, Wei
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 34
  • DOI: 10.1039/C4CP02921F

Interfacial phenomena in solid-state lithium battery with sulfide solid electrolyte
journal, October 2012

All-solid-state lithium ion battery using garnet-type oxide and Li3BO3 solid electrolytes fabricated by screen-printing
journal, September 2013

All-solid-state lithium battery with LiBH4 solid electrolyte
journal, March 2013

Li 7 La 3 Zr 2 O 12 Interface Modification for Li Dendrite Prevention
journal, April 2016

  • Tsai, Chih-Long; Roddatis, Vladimir; Chandran, C. Vinod
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 16
  • DOI: 10.1021/acsami.6b00831

In-situ Li7La3Zr2O12/LiCoO2 interface modification for advanced all-solid-state battery
journal, August 2014

Commentary: The Materials Project: A materials genome approach to accelerating materials innovation
journal, July 2013

  • Jain, Anubhav; Ong, Shyue Ping; Hautier, Geoffroy
  • APL Materials, Vol. 1, Issue 1
  • DOI: 10.1063/1.4812323

Novel 5 V Spinel Cathode Li 2 FeMn 3 O 8 for Lithium Ion Batteries
journal, November 1998

  • Kawai, Hiroo; Nagata, Mikito; Tabuchi, Mitsuharu
  • Chemistry of Materials, Vol. 10, Issue 11
  • DOI: 10.1021/cm9807182

Self-Organized Core–Shell Structure for High-Power Electrode in Solid-State Lithium Batteries
journal, September 2011

  • Xu, Xiaoxiong; Takada, Kazunori; Watanabe, Ken
  • Chemistry of Materials, Vol. 23, Issue 17
  • DOI: 10.1021/cm103665w

Tuning electrochemical performance of Si-based anodes for lithium-ion batteries by employing atomic layer deposition alumina coating
journal, January 2014

  • Li, Ying; Sun, Yujie; Xu, Guanjie
  • J. Mater. Chem. A, Vol. 2, Issue 29
  • DOI: 10.1039/c4ta01562b

LiNbO3-coated LiCoO2 as cathode material for all solid-state lithium secondary batteries
journal, July 2007

All-solid-state lithium secondary batteries with metal-sulfide-coated LiCoO2 prepared by thermal decomposition of dithiocarbamato complexes
journal, January 2012

  • Sakuda, Atsushi; Nakamoto, Naoyuki; Kitaura, Hirokazu
  • Journal of Materials Chemistry, Vol. 22, Issue 30
  • DOI: 10.1039/c2jm32490c

Tailoring ceramics for specific applications: A case study of the development of all-solid-state lithium batteries
journal, January 2005

  • Thangadurai, V.; Schwenzel, J.; Weppner, W.
  • Ionics, Vol. 11, Issue 1-2
  • DOI: 10.1007/BF02430397

Silicon nanowire lithium-ion battery anodes with ALD deposited TiN coatings demonstrate a major improvement in cycling performance
journal, January 2013

  • Kohandehghan, Alireza; Kalisvaart, Peter; Cui, Kai
  • Journal of Materials Chemistry A, Vol. 1, Issue 41
  • DOI: 10.1039/c3ta12964k

Novel Fast Lithium Ion Conduction in Garnet-Type Li 5 La 3 M 2 O 12 (M = Nb, Ta)
journal, March 2003

Atomic layer deposited coatings to significantly stabilize anodes for Li ion batteries: effects of coating thickness and the size of anode particles
journal, January 2014

  • Wang, Dongniu; Yang, Jinli; Liu, Jian
  • Journal of Materials Chemistry A, Vol. 2, Issue 7
  • DOI: 10.1039/c3ta13677a