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Title: The Electrochemistry of Fe 3 O 4 /Polypyrrole Composite Electrodes in Lithium-Ion Cells: The Role of Polypyrrole in Capacity Retention

Authors:
; ; ; ; ; ;
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2M)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1388682
DOE Contract Number:  
SC0012673
Resource Type:
Journal Article
Journal Name:
Journal of the Electrochemical Society
Additional Journal Information:
Journal Volume: 164; Journal Issue: 1; Related Information: m2M partners with Stony Brook University (lead); Brookhaven National Laboratory; Columbia University; Georgia Institute of Technology; Oak Ridge National Laboratory; Rensselaer Polytechnic Institute; University of California, Berkeley; University of North Carolina at Chapel Hill; Journal ID: ISSN 0013-4651
Publisher:
The Electrochemical Society
Country of Publication:
United States
Language:
English
Subject:
energy storage (including batteries and capacitors), charge transport, mesostructured materials

Citation Formats

Bruck, Andrea M., Gannett, Cara N., Bock, David C., Smith, Paul F., Marschilok, Amy C., Takeuchi, Kenneth J., and Takeuchi, Esther S. The Electrochemistry of Fe 3 O 4 /Polypyrrole Composite Electrodes in Lithium-Ion Cells: The Role of Polypyrrole in Capacity Retention. United States: N. p., 2016. Web. doi:10.1149/2.0361701jes.
Bruck, Andrea M., Gannett, Cara N., Bock, David C., Smith, Paul F., Marschilok, Amy C., Takeuchi, Kenneth J., & Takeuchi, Esther S. The Electrochemistry of Fe 3 O 4 /Polypyrrole Composite Electrodes in Lithium-Ion Cells: The Role of Polypyrrole in Capacity Retention. United States. doi:10.1149/2.0361701jes.
Bruck, Andrea M., Gannett, Cara N., Bock, David C., Smith, Paul F., Marschilok, Amy C., Takeuchi, Kenneth J., and Takeuchi, Esther S. Thu . "The Electrochemistry of Fe 3 O 4 /Polypyrrole Composite Electrodes in Lithium-Ion Cells: The Role of Polypyrrole in Capacity Retention". United States. doi:10.1149/2.0361701jes.
@article{osti_1388682,
title = {The Electrochemistry of Fe 3 O 4 /Polypyrrole Composite Electrodes in Lithium-Ion Cells: The Role of Polypyrrole in Capacity Retention},
author = {Bruck, Andrea M. and Gannett, Cara N. and Bock, David C. and Smith, Paul F. and Marschilok, Amy C. and Takeuchi, Kenneth J. and Takeuchi, Esther S.},
abstractNote = {},
doi = {10.1149/2.0361701jes},
journal = {Journal of the Electrochemical Society},
issn = {0013-4651},
number = 1,
volume = 164,
place = {United States},
year = {2016},
month = {12}
}

Works referenced in this record:

Raman spectra of polypyrrole and its 2,5-13C-substituted and C-deuterated analogues in doped and undoped states
journal, June 1988


The mechanisms of pyrrole electropolymerization
journal, January 2000

  • Sabouraud, Guillaume; Sadki, Saïd; Brodie, Nancy
  • Chemical Society Reviews, Vol. 29, Issue 5
  • DOI: 10.1039/a807124a

Carbon nanotube–metal oxide composite electrodes for secondary lithium-based batteries
journal, June 2012

  • Marschilok, Amy C.; Schaffer, Corey P.; Takeuchi, Kenneth J.
  • Journal of Composite Materials, Vol. 47, Issue 1
  • DOI: 10.1177/0021998312446827

Electrodes for Nonaqueous Oxygen Reduction Based upon Conductive Polymer-Silver Composites
journal, January 2011

  • Marschilok, Amy C.; Zhu, Shali; Milleville, Christopher C.
  • Journal of The Electrochemical Society, Vol. 158, Issue 3
  • DOI: 10.1149/1.3527992

Challenges for Rechargeable Li Batteries
journal, February 2010

  • Goodenough, John B.; Kim, Youngsik
  • Chemistry of Materials, Vol. 22, Issue 3, p. 587-603
  • DOI: 10.1021/cm901452z

Electrochemical discharge of nanocrystalline magnetite: structure analysis using X-ray diffraction and X-ray absorption spectroscopy
journal, January 2013

  • Menard, Melissa C.; Takeuchi, Kenneth J.; Marschilok, Amy C.
  • Physical Chemistry Chemical Physics, Vol. 15, Issue 42
  • DOI: 10.1039/c3cp52870g

Uniform Hierarchical Fe 3 O 4 @Polypyrrole Nanocages for Superior Lithium Ion Battery Anodes
journal, April 2016


Magnetic and conducting Fe3O4-polypyrrole nanoparticles with core-shell structure
journal, January 2003

  • Deng, Jianguo; Peng, Yuxing; He, Chuanlan
  • Polymer International, Vol. 52, Issue 7
  • DOI: 10.1002/pi.1237

Crystallite Size Control and Resulting Electrochemistry of Magnetite, Fe[sub 3]O[sub 4]
journal, January 2009

  • Zhu, Shali; Marschilok, Amy C.; Takeuchi, Esther S.
  • Electrochemical and Solid-State Letters, Vol. 12, Issue 4
  • DOI: 10.1149/1.3078076

Structural and magnetic characterization of the lithiated iron oxide Li x Fe 3 O 4
journal, March 1986

  • Fontcuberta, J.; Rodríguez, J.; Pernet, M.
  • Journal of Applied Physics, Vol. 59, Issue 6
  • DOI: 10.1063/1.336420

Kinetics and mechanism of pyrrole chemical polymerization
journal, July 2013


Insights into Ionic Transport and Structural Changes in Magnetite during Multiple-Electron Transfer Reactions
journal, March 2016

  • Zhang, Wei; Bock, David C.; Pelliccione, Christopher J.
  • Advanced Energy Materials, Vol. 6, Issue 10
  • DOI: 10.1002/aenm.201502471

Mechanism of Iron Oxide Dissolution—A Review of Recent Literature
journal, December 1984

  • Frenier, Wayne W.; Growcock, Frederick B.
  • CORROSION, Vol. 40, Issue 12
  • DOI: 10.5006/1.3593905

A failure modes, mechanisms, and effects analysis (FMMEA) of lithium-ion batteries
journal, November 2015


Evidence of redox interactions between polypyrrole and Fe3O4 in polypyrrole–Fe3O4 composite films
journal, August 2010


Surfactant-free synthesis of Fe 3 O 4 @PANI and Fe 3 O 4 @PPy microspheres as adsorbents for isolation of PCR-ready DNA
journal, January 2013

  • Gai, Ligang; Han, Xiaoyun; Hou, Yunhua
  • Dalton Trans., Vol. 42, Issue 5
  • DOI: 10.1039/C2DT32164E

Iron-Oxide-Supported Nanocarbon in Lithium-Ion Batteries, Medical, Catalytic, and Environmental Applications
journal, July 2014

  • Tuček, Jiří; Kemp, Kingsley Christian; Kim, Kwang Soo
  • ACS Nano, Vol. 8, Issue 8
  • DOI: 10.1021/nn501836x

Raman spectroscopic study of magnetite (FeFe2O4): a new assignment for the vibrational spectrum
journal, September 2003


Revisit of Polypyrrole as Cathode Material for Lithium-Ion Battery
journal, January 2012

  • Qie, Long; Yuan, Li-Xia; Zhang, Wu-Xing
  • Journal of The Electrochemical Society, Vol. 159, Issue 10
  • DOI: 10.1149/2.042210jes

Carbon nanotube substrate electrodes for lightweight, long-life rechargeable batteries
journal, January 2011

  • Marschilok, Amy; Lee, Chia-Ying; Subramanian, Aditya
  • Energy & Environmental Science, Vol. 4, Issue 8
  • DOI: 10.1039/c1ee01507a

Study of polaron and bipolaron states in polypyrrole by in situ Raman spectroelectrochemistry
journal, June 2007


Toward Uniformly Dispersed Battery Electrode Composite Materials: Characteristics and Performance
journal, January 2016

  • Kwon, Yo Han; Huie, Matthew M.; Choi, Dalsu
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 5
  • DOI: 10.1021/acsami.5b11938

Dispersion of Nanocrystalline Fe 3 O 4 within Composite Electrodes: Insights on Battery-Related Electrochemistry
journal, April 2016

  • Bock, David C.; Pelliccione, Christopher J.; Zhang, Wei
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 18
  • DOI: 10.1021/acsami.6b01134

Nanostructured Fe3O4/SWNT Electrode: Binder-Free and High-Rate Li-Ion Anode
journal, May 2010

  • Ban, Chunmei; Wu, Zhuangchun; Gillaspie, Dane T.
  • Advanced Materials, Vol. 22, Issue 20, p. E145-E149
  • DOI: 10.1002/adma.200904285

Fe3O4/PPy composite nanospheres as anode for lithium-ion batteries with superior cycling performance
journal, March 2014


Investigating the Complex Chemistry of Functional Energy Storage Systems: The Need for an Integrative, Multiscale (Molecular to Mesoscale) Perspective
journal, April 2016


The preparation of polypyrrole–Fe3O4 nanocomposites by the use of common ion effect
journal, September 2003


Variation in the iron oxidation states of magnetite nanocrystals as a function of crystallite size: The impact on electrochemical capacity
journal, April 2013


Polypyrrole–NiO composite as high-performance lithium storage material
journal, August 2013


Effects of grain boundary width and crystallite size on conductivity and magnetic properties of magnetite nanoparticles
journal, June 2014

  • Lopez Maldonado, K. L.; de la Presa, P.; de la Rubia, M. A.
  • Journal of Nanoparticle Research, Vol. 16, Issue 7
  • DOI: 10.1007/s11051-014-2482-3

Magnetic and conducting particles: preparation of polypyrrole layer on Fe3O4 nanospheres
journal, September 2003