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Title: Selective gas capture via kinetic trapping

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Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
DOE Contract Number:  
Resource Type:
Journal Article
Journal Name:
Physical Chemistry Chemical Physics. PCCP (Print)
Additional Journal Information:
Journal Volume: 18; Journal Issue: 31; Related Information: CGS partners with University of California, Berkeley; University of California, Davis; Lawrence Berkeley National Laboratory; University of Minnesota; National Energy Technology Laboratory; Texas A&M University; Journal ID: ISSN 1463-9076
Royal Society of Chemistry
Country of Publication:
United States
membrane, carbon capture, materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing)

Citation Formats

Kundu, Joyjit, Pascal, Tod, Prendergast, David, and Whitelam, Stephen. Selective gas capture via kinetic trapping. United States: N. p., 2016. Web. doi:10.1039/c6cp03940e.
Kundu, Joyjit, Pascal, Tod, Prendergast, David, & Whitelam, Stephen. Selective gas capture via kinetic trapping. United States. doi:10.1039/c6cp03940e.
Kundu, Joyjit, Pascal, Tod, Prendergast, David, and Whitelam, Stephen. Fri . "Selective gas capture via kinetic trapping". United States. doi:10.1039/c6cp03940e.
title = {Selective gas capture via kinetic trapping},
author = {Kundu, Joyjit and Pascal, Tod and Prendergast, David and Whitelam, Stephen},
abstractNote = {},
doi = {10.1039/c6cp03940e},
journal = {Physical Chemistry Chemical Physics. PCCP (Print)},
issn = {1463-9076},
number = 31,
volume = 18,
place = {United States},
year = {2016},
month = {1}

Works referenced in this record:

Kinetic Separation of Propene and Propane in Metal−Organic Frameworks: Controlling Diffusion Rates in Plate-Shaped Crystals via Tuning of Pore Apertures and Crystallite Aspect Ratios
journal, April 2011

  • Lee, Chang Yeon; Bae, Youn-Sang; Jeong, Nak Cheon
  • Journal of the American Chemical Society, Vol. 133, Issue 14
  • DOI: 10.1021/ja200553m

Condensation of Methane in the Metal–Organic Framework IRMOF-1: Evidence for Two Critical Points
journal, August 2015

  • Höft, Nicolas; Horbach, Jürgen
  • Journal of the American Chemical Society, Vol. 137, Issue 32
  • DOI: 10.1021/jacs.5b04077

Tunable Rare Earth fcu -MOF Platform: Access to Adsorption Kinetics Driven Gas/Vapor Separations via Pore Size Contraction
journal, April 2015

  • Xue, Dong-Xu; Belmabkhout, Youssef; Shekhah, Osama
  • Journal of the American Chemical Society, Vol. 137, Issue 15
  • DOI: 10.1021/ja5131403

High-Capacity Methane Storage in Metal−Organic Frameworks M 2 (dhtp): The Important Role of Open Metal Sites
journal, April 2009

  • Wu, Hui; Zhou, Wei; Yildirim, Taner
  • Journal of the American Chemical Society, Vol. 131, Issue 13
  • DOI: 10.1021/ja900258t

Diffusion of Small Molecules in Metal Organic Framework Materials
journal, January 2013

Tuning Metal–Organic Frameworks with Open-Metal Sites and Its Origin for Enhancing CO 2 Affinity by Metal Substitution
journal, March 2012

  • Park, Joonho; Kim, Heejin; Han, Sang Soo
  • The Journal of Physical Chemistry Letters, Vol. 3, Issue 7
  • DOI: 10.1021/jz300047n

CO 2 Dynamics in a Metal–Organic Framework with Open Metal Sites
journal, August 2012

  • Kong, Xueqian; Scott, Eric; Ding, Wen
  • Journal of the American Chemical Society, Vol. 134, Issue 35
  • DOI: 10.1021/ja306822p

Materials challenges for the development of solid sorbents for post-combustion carbon capture
journal, January 2012

  • Drage, Trevor C.; Snape, Colin E.; Stevens, Lee A.
  • J. Mater. Chem., Vol. 22, Issue 7
  • DOI: 10.1039/C2JM12592G

Effect of Humidity on the Performance of Microporous Coordination Polymers as Adsorbents for CO 2 Capture
journal, May 2011

  • Kizzie, Austin C.; Wong-Foy, Antek G.; Matzger, Adam J.
  • Langmuir, Vol. 27, Issue 10
  • DOI: 10.1021/la200547k

Zeolitic Imidazolate Frameworks for Kinetic Separation of Propane and Propene
journal, August 2009

  • Li, Kunhao; Olson, David H.; Seidel, Jonathan
  • Journal of the American Chemical Society, Vol. 131, Issue 30
  • DOI: 10.1021/ja9039983

Ab initio carbon capture in open-site metal–organic frameworks
journal, August 2012

  • Dzubak, Allison L.; Lin, Li-Chiang; Kim, Jihan
  • Nature Chemistry, Vol. 4, Issue 10
  • DOI: 10.1038/nchem.1432

Carbon Dioxide Capture in Metal–Organic Frameworks
journal, September 2011

  • Sumida, Kenji; Rogow, David L.; Mason, Jarad A.
  • Chemical Reviews, Vol. 112, Issue 2, p. 724-781
  • DOI: 10.1021/cr2003272

Application of a High-Throughput Analyzer in Evaluating Solid Adsorbents for Post-Combustion Carbon Capture via Multicomponent Adsorption of CO 2 , N 2 , and H 2 O
journal, April 2015

  • Mason, Jarad A.; McDonald, Thomas M.; Bae, Tae-Hyun
  • Journal of the American Chemical Society, Vol. 137, Issue 14
  • DOI: 10.1021/jacs.5b00838

Enhanced Adsorption Selectivity of Hydrogen/Methane Mixtures in Metal−Organic Frameworks with Interpenetration: A Molecular Simulation Study
journal, June 2008

  • Liu, Bei; Yang, Qingyuan; Xue, Chunyu
  • The Journal of Physical Chemistry C, Vol. 112, Issue 26
  • DOI: 10.1021/jp802343n

Nanoporous Materials Can Tune the Critical Point of a Pure Substance
journal, September 2015

  • Braun, Efrem; Chen, Joseph J.; Schnell, Sondre K.
  • Angewandte Chemie International Edition, Vol. 54, Issue 48
  • DOI: 10.1002/anie.201506865

Small-Molecule Adsorption in Open-Site Metal–Organic Frameworks: A Systematic Density Functional Theory Study for Rational Design
journal, January 2015

  • Lee, Kyuho; Howe, Joshua D.; Lin, Li-Chiang
  • Chemistry of Materials, Vol. 27, Issue 3, p. 668-678
  • DOI: 10.1021/cm502760q

Computational and Experimental Studies on the Adsorption of CO, N 2 , and CO 2 on Mg-MOF-74
journal, June 2010

  • Valenzano, L.; Civalleri, B.; Chavan, S.
  • The Journal of Physical Chemistry C, Vol. 114, Issue 25
  • DOI: 10.1021/jp102574f

Evaluating metal–organic frameworks for post-combustion carbon dioxide capture via temperature swing adsorption
journal, January 2011

  • Mason, Jarad A.; Sumida, Kenji; Herm, Zoey R.
  • Energy & Environmental Science, Vol. 4, Issue 8, p. 3030-3040
  • DOI: 10.1039/c1ee01720a

Adsorption of CO2 and CH4 on a magnesium-based metal organic framework
journal, January 2011

Highly efficient separation of carbon dioxide by a metal-organic framework replete with open metal sites
journal, November 2009

  • Britt, D.; Furukawa, H.; Wang, B.
  • Proceedings of the National Academy of Sciences, Vol. 106, Issue 49, p. 20637-20640
  • DOI: 10.1073/pnas.0909718106

Capture of CO2 from high humidity flue gas by vacuum swing adsorption with zeolite 13X
journal, January 2008

High-throughput screening of small-molecule adsorption in MOF
journal, January 2013

  • Canepa, Pieremanuele; Arter, Calvin A.; Conwill, Eliot M.
  • Journal of Materials Chemistry A, Vol. 1, Issue 43
  • DOI: 10.1039/c3ta12395b

Metal−Organic Frameworks with Exceptionally High Capacity for Storage of Carbon Dioxide at Room Temperature
journal, December 2005

  • Millward, Andrew R.; Yaghi, Omar M.
  • Journal of the American Chemical Society, Vol. 127, Issue 51, p. 17998-17999
  • DOI: 10.1021/ja0570032

Cooperative insertion of CO2 in diamine-appended metal-organic frameworks
journal, March 2015

  • McDonald, Thomas M.; Mason, Jarad A.; Kong, Xueqian
  • Nature, Vol. 519, Issue 7543
  • DOI: 10.1038/nature14327

NMR study of small molecule adsorption in MOF-74-Mg
journal, April 2013

  • Lopez, M. G.; Canepa, Pieremanuele; Thonhauser, T.
  • The Journal of Chemical Physics, Vol. 138, Issue 15
  • DOI: 10.1063/1.4800952

Selective gas adsorption and separation in metal–organic frameworks
journal, January 2009

  • Li, Jian-Rong; Kuppler, Ryan J.; Zhou, Hong-Cai
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1477-1504
  • DOI: 10.1039/b802426j

Porous materials with optimal adsorption thermodynamics and kinetics for CO2 separation
journal, February 2013

  • Nugent, Patrick; Belmabkhout, Youssef; Burd, Stephen D.
  • Nature, Vol. 495, Issue 7439, p. 80-84
  • DOI: 10.1038/nature11893

Understanding Trends in CO 2 Adsorption in Metal–Organic Frameworks with Open-Metal Sites
journal, February 2014

  • Poloni, Roberta; Lee, Kyuho; Berger, Robert F.
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 5
  • DOI: 10.1021/jz500202x

Comprehensive study of carbon dioxide adsorption in the metal–organic frameworks M 2 (dobdc) (M = Mg, Mn, Fe, Co, Ni, Cu, Zn)
journal, January 2014

  • Queen, Wendy L.; Hudson, Matthew R.; Bloch, Eric D.
  • Chem. Sci., Vol. 5, Issue 12
  • DOI: 10.1039/C4SC02064B

Site-Specific CO2 Adsorption and Zero Thermal Expansion in an Anisotropic Pore Network
journal, December 2011

  • Queen, Wendy L.; Brown, Craig M.; Britt, David K.
  • The Journal of Physical Chemistry C, Vol. 115, Issue 50, p. 24915-24919
  • DOI: 10.1021/jp208529p

The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013

  • Furukawa, H.; Cordova, K. E.; O'Keeffe, M.
  • Science, Vol. 341, Issue 6149, p. 1230444-1230444
  • DOI: 10.1126/science.1230444

Design and synthesis of an exceptionally stable and highly porous metal-organic framework
journal, November 1999

  • Li, Hailian; Eddaoudi, Mohamed; M., O'Keeffe
  • Nature, Vol. 402, Issue 6759, p. 276-279
  • DOI: 10.1038/46248

Selective CO 2 Capture from Flue Gas Using Metal–Organic Frameworks―A Fixed Bed Study
journal, April 2012

  • Liu, Jian; Tian, Jian; Thallapally, Praveen K.
  • The Journal of Physical Chemistry C, Vol. 116, Issue 17
  • DOI: 10.1021/jp300961j

Enhanced H2 Adsorption in Isostructural Metal−Organic Frameworks with Open Metal Sites: Strong Dependence of the Binding Strength on Metal Ions
journal, November 2008

  • Zhou, Wei; Wu, Hui; Yildirim, Taner
  • Journal of the American Chemical Society, Vol. 130, Issue 46, p. 15268-15269
  • DOI: 10.1021/ja807023q

Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks
journal, August 2011

  • Li, Jian-Rong; Ma, Yuguang; McCarthy, M. Colin
  • Coordination Chemistry Reviews, Vol. 255, Issue 15-16
  • DOI: 10.1016/j.ccr.2011.02.012

Progress in adsorption-based CO 2 capture by metal–organic frameworks
journal, January 2012

  • Liu, Jian; Thallapally, Praveen K.; McGrail, B. Peter
  • Chem. Soc. Rev., Vol. 41, Issue 6
  • DOI: 10.1039/C1CS15221A

Dramatic Tuning of Carbon Dioxide Uptake via Metal Substitution in a Coordination Polymer with Cylindrical Pores
journal, August 2008

  • Caskey, Stephen R.; Wong-Foy, Antek G.; Matzger, Adam J.
  • Journal of the American Chemical Society, Vol. 130, Issue 33, p. 10870-10871
  • DOI: 10.1021/ja8036096

Investigating the Relative Influences of Molecular Dimensions and Binding Energies on Diffusivities of Guest Species Inside Nanoporous Crystalline Materials
journal, October 2012

  • Krishna, Rajamani; van Baten, Jasper M.
  • The Journal of Physical Chemistry C, Vol. 116, Issue 44
  • DOI: 10.1021/jp308971w

Self-Diffusion and Transport Diffusion of Light Gases in Metal-Organic Framework Materials Assessed Using Molecular Dynamics Simulations
journal, August 2005

  • Skoulidas, Anastasios I.; Sholl, David S.
  • The Journal of Physical Chemistry B, Vol. 109, Issue 33
  • DOI: 10.1021/jp051771y