Engineering Copper Carboxylate Functionalities on Water Stable Metal–Organic Frameworks for Enhancement of Ammonia Removal Capacities

Joshi, Jayraj N.; Garcia-Gutierrez, Erika Y.; Moran, Colton M.; Deneff, Jacob I.; Walton, Krista S.

doi:10.1021/acs.jpcc.6b08610

Title: Engineering Copper Carboxylate Functionalities on Water Stable Metal–Organic Frameworks for Enhancement of Ammonia Removal Capacities

Journal Article · Tue Jan 17 00:00:00 EST 2017 · Journal of Physical Chemistry. C

DOI:https://doi.org/10.1021/acs.jpcc.6b08610· OSTI ID:1388628

Joshi, Jayraj N. ^[1]; Garcia-Gutierrez, Erika Y. ^[1]; Moran, Colton M. ^[1]; Deneff, Jacob I. ^[1];

^[1]

Georgia Inst. of Technology, Atlanta, GA (United States). School of Chemical and Biomolecular Engineering

Functionalization of copper carboxylate groups on a series of UiO-66 metal organic framework (MOF) analogues and their corresponding impact on humid and dry ammonia adsorption behavior were studied. Relative locations of possible carboxylic acid binding sites for copper on the MOF analogues were varied on ligand and missing linker defect sites. Materials after copper incorporation exhibited increased water vapor and ammonia affinity during isothermal adsorption and breakthrough experiments, respectively. The introduction of copper markedly increased ammonia adsorption capacities for all adsorbents possessing carboxyl binding sites. In particular, the new MOF UiO-66-(COOCu)₂ displayed the highest ammonia breakthrough capacities of 6.38 and 6.84 mmol g^–1 under dry and humid conditions, respectively, while retaining crystallinity and porosity. Relative carboxylic acid site locations were also found to impact sorbent stability, as missing linker defect functionalized materials degraded under humid conditions after copper incorporation. Finally, postsynthetic metal insertion provides a method for adding sites that are analogous to open metal sites while maintaining good structural stability.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Understanding and Control of Acid Gas-induced Evolution of Materials for Energy (UNCAGE-ME); Georgia Institute of Technology, Atlanta, GA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012577

OSTI ID:: 1388628

Journal Information:: Journal of Physical Chemistry. C, Vol. 121, Issue 6; Related Information: UNCAGE-ME partners with Georgia Institute of Technology (lead); Lehigh University; Oak Ridge National Laboratory; University of Alabama; University of Florida; University of Wisconsin; Washington University in St. Louis; ISSN 1932-7447

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 25 works

Citation information provided by
Web of Science

References (73)

Metal-organic frameworks with high capacity and selectivity for harmful gases Britt, D.; Tranchemontagne, D.; Yaghi, O. M. Proceedings of the National Academy of Sciences, Vol. 105, Issue 33, p. 11623-11627 https://doi.org/10.1073/pnas.0804900105	journal	August 2008
Metal–Organic Frameworks for Air Purification of Toxic Chemicals DeCoste, Jared B.; Peterson, Gregory W. Chemical Reviews, Vol. 114, Issue 11 https://doi.org/10.1021/cr4006473	journal	April 2014
Reticular synthesis and the design of new materials Yaghi, Omar M.; O'Keeffe, Michael; Ockwig, Nathan W. Nature, Vol. 423, Issue 6941, p. 705-714 https://doi.org/10.1038/nature01650	journal	June 2003
Brønsted Acidity in Metal–Organic Frameworks Jiang, Juncong; Yaghi, Omar M. Chemical Reviews, Vol. 115, Issue 14 https://doi.org/10.1021/acs.chemrev.5b00221	journal	June 2015
Chemical Modification of a Bridging Ligand Inside a Metal–Organic Framework while Maintaining the 3D Structure Costa, José Sánchez; Gamez, Patrick; Black, Cory A. European Journal of Inorganic Chemistry, Vol. 2008, Issue 10, p. 1551-1554 https://doi.org/10.1002/ejic.200800002	journal	April 2008
A Systematic Study on the Stability of Porous Coordination Polymers against Ammonia Kajiwara, Takashi; Higuchi, Masakazu; Watanabe, Daisuke Chemistry - A European Journal, Vol. 20, Issue 47 https://doi.org/10.1002/chem.201403542	journal	October 2014
Metal−Organic Frameworks with Functional Pores for Recognition of Small Molecules Chen, Banglin; Xiang, Shengchang; Qian, Guodong Accounts of Chemical Research, Vol. 43, Issue 8 https://doi.org/10.1021/ar100023y	journal	August 2010
Ammonia Vapor Removal by Cu₃(BTC)₂ and Its Characterization by MAS NMR Peterson, Gregory W.; Wagner, George W.; Balboa, Alex The Journal of Physical Chemistry C, Vol. 113, Issue 31, p. 13906-13917 https://doi.org/10.1021/jp902736z	journal	August 2009
Synthesis of Metal-Organic Frameworks (MOFs): Routes to Various MOF Topologies, Morphologies, and Composites Stock, Norbert; Biswas, Shyam Chemical Reviews, Vol. 112, Issue 2 https://doi.org/10.1021/cr200304e	journal	September 2011
Textile/Metal-Organic-Framework Composites as Self-Detoxifying Filters for Chemical-Warfare Agents López-Maya, Elena; Montoro, Carmen; Rodríguez-Albelo, L. Marleny Angewandte Chemie International Edition, Vol. 54, Issue 23 https://doi.org/10.1002/anie.201502094	journal	May 2015
Acid loaded porphyrin-based metal–organic framework for ammonia uptake Wilcox, Oliver T.; Fateeva, Alexandra; Katsoulidis, Alexandros P. Chemical Communications, Vol. 51, Issue 81 https://doi.org/10.1039/C5CC06209H	journal	January 2015
Acid-functionalized UiO-66(Zr) MOFs and their evolution after intra-framework cross-linking: structural features and sorption properties Ragon, Florence; Campo, Betiana; Yang, Qingyuan Journal of Materials Chemistry A, Vol. 3, Issue 7 https://doi.org/10.1039/C4TA03992K	journal	January 2015
Metal Insertion in a Microporous Metal−Organic Framework Lined with 2,2′-Bipyridine Bloch, Eric D.; Britt, David; Lee, Chain Journal of the American Chemical Society, Vol. 132, Issue 41, p. 14382-14384 https://doi.org/10.1021/ja106935d	journal	October 2010
Metal-Organic Frameworks: A Rapidly Growing Class of Versatile Nanoporous Materials Meek, Scott T.; Greathouse, Jeffery A.; Allendorf, Mark D. Advanced Materials, Vol. 23, Issue 2 https://doi.org/10.1002/adma.201002854	journal	October 2010
Metal Alkoxide Functionalization in Metal−Organic Frameworks for Enhanced Ambient-Temperature Hydrogen Storage Getman, Rachel B.; Miller, Jacob H.; Wang, Kenneth The Journal of Physical Chemistry C, Vol. 115, Issue 5 https://doi.org/10.1021/jp1094068	journal	December 2010
MOF-74 building unit has a direct impact on toxic gas adsorption Grant Glover, T.; Peterson, Gregory W.; Schindler, Bryan J. Chemical Engineering Science, Vol. 66, Issue 2, p. 163-170 https://doi.org/10.1016/j.ces.2010.10.002	journal	January 2011
Reversible CO Binding Enables Tunable CO/H ₂ and CO/N ₂ Separations in Metal–Organic Frameworks with Exposed Divalent Metal Cations Bloch, Eric D.; Hudson, Matthew R.; Mason, Jarad A. Journal of the American Chemical Society, Vol. 136, Issue 30 https://doi.org/10.1021/ja505318p	journal	July 2014
Molecular Simulations and Experimental Studies of CO ₂ , CO, and N ₂ Adsorption in Metal−Organic Frameworks Karra, Jagadeswara R.; Walton, Krista S. The Journal of Physical Chemistry C, Vol. 114, Issue 37 https://doi.org/10.1021/jp105519h	journal	August 2010
Tuning the Kinetic Water Stability and Adsorption Interactions of Mg-MOF-74 by Partial Substitution with Co or Ni Jiao, Yang; Morelock, Cody R.; Burtch, Nicholas C. Industrial & Engineering Chemistry Research, Vol. 54, Issue 49 https://doi.org/10.1021/acs.iecr.5b03843	journal	December 2015
Highly selective separation of small hydrocarbons and carbon dioxide in a metal–organic framework with open copper(ii) coordination sites Duan, Xing; He, Yabing; Cui, Yuanjing RSC Advances, Vol. 4, Issue 44 https://doi.org/10.1039/c4ra03216k	journal	January 2014
Adsorption and separation of CO2 on Fe(II)-MOF-74: Effect of the open metal coordination site Lou, Wolong; Yang, Jiangfeng; Li, Libo Journal of Solid State Chemistry, Vol. 213 https://doi.org/10.1016/j.jssc.2014.03.005	journal	May 2014
Progress in adsorption-based CO ₂ capture by metal–organic frameworks Liu, Jian; Thallapally, Praveen K.; McGrail, B. Peter Chem. Soc. Rev., Vol. 41, Issue 6 https://doi.org/10.1039/C1CS15221A	journal	January 2012
Comprehensive study of carbon dioxide adsorption in the metal–organic frameworks M ₂ (dobdc) (M = Mg, Mn, Fe, Co, Ni, Cu, Zn) Queen, Wendy L.; Hudson, Matthew R.; Bloch, Eric D. Chem. Sci., Vol. 5, Issue 12 https://doi.org/10.1039/C4SC02064B	journal	January 2014
Water Stability and Adsorption in Metal–Organic Frameworks Burtch, Nicholas C.; Jasuja, Himanshu; Walton, Krista S. Chemical Reviews, Vol. 114, Issue 20, p. 10575-10612 https://doi.org/10.1021/cr5002589	journal	September 2014
Computational Screening of Metal Catecholates for Ammonia Capture in Metal–Organic Frameworks Kim, Ki Chul; Moghadam, Peyman Z.; Fairen-Jimenez, David Industrial & Engineering Chemistry Research, Vol. 54, Issue 13 https://doi.org/10.1021/ie504945w	journal	March 2015
Post-Synthesis Alkoxide Formation Within Metal−Organic Framework Materials: A Strategy for Incorporating Highly Coordinatively Unsaturated Metal Ions Mulfort, Karen L.; Farha, Omar K.; Stern, Charlotte L. Journal of the American Chemical Society, Vol. 131, Issue 11, p. 3866-3868 https://doi.org/10.1021/ja809954r	journal	March 2009
Metal–Organic Framework Nodes as Nearly Ideal Supports for Molecular Catalysts: NU-1000- and UiO-66-Supported Iridium Complexes Yang, Dong; Odoh, Samuel O.; Wang, Timothy C. Journal of the American Chemical Society, Vol. 137, Issue 23, p. 7391-7396 https://doi.org/10.1021/jacs.5b02956	journal	June 2015
Tuning Zr ₆ Metal–Organic Framework (MOF) Nodes as Catalyst Supports: Site Densities and Electron-Donor Properties Influence Molecular Iridium Complexes as Ethylene Conversion Catalysts Yang, Dong; Odoh, Samuel O.; Borycz, Joshua ACS Catalysis, Vol. 6, Issue 1 https://doi.org/10.1021/acscatal.5b02243	journal	December 2015
Synthesis of UiO-66-NH2 derived heterogeneous copper (II) catalyst and study of its application in the selective aerobic oxidation of alcohols Hou, Junying; Luan, Yi; Tang, Jia Journal of Molecular Catalysis A: Chemical, Vol. 407 https://doi.org/10.1016/j.molcata.2015.06.018	journal	October 2015
Counteranion effects on the catalytic activity of copper salts immobilized on the 2,2′-bipyridine-functionalized metal–organic framework MOF-253 Valvekens, Pieterjan; Bloch, Eric D.; Long, Jeffrey R. Catalysis Today, Vol. 246 https://doi.org/10.1016/j.cattod.2014.08.006	journal	May 2015
Structure and Mobility of Metal Clusters in MOFs: Au, Pd, and AuPd Clusters in MOF-74 Vilhelmsen, Lasse B.; Walton, Krista S.; Sholl, David S. Journal of the American Chemical Society, Vol. 134, Issue 30 https://doi.org/10.1021/ja305004a	journal	July 2012
A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851 https://doi.org/10.1021/ja8057953	journal	October 2008
Disclosing the Complex Structure of UiO-66 Metal Organic Framework: A Synergic Combination of Experiment and Theory Valenzano, Loredana; Civalleri, Bartolomeo; Chavan, Sachin Chemistry of Materials, Vol. 23, Issue 7, p. 1700-1718 https://doi.org/10.1021/cm1022882	journal	April 2011
Evaluation of MOFs for air purification and air quality control applications: Ammonia removal from air Jasuja, Himanshu; Peterson, Gregory W.; Decoste, Jared B. Chemical Engineering Science, Vol. 124 https://doi.org/10.1016/j.ces.2014.08.050	journal	March 2015
Engineering UiO-66-NH ₂ for Toxic Gas Removal Peterson, Gregory W.; DeCoste, Jared B.; Fatollahi-Fard, Farzin Industrial & Engineering Chemistry Research, Vol. 53, Issue 2 https://doi.org/10.1021/ie403366d	journal	January 2014
Postsynthetic Modification of a Metal–Organic Framework for Stabilization of a Hemiaminal and Ammonia Uptake Morris, William; Doonan, Christian J.; Yaghi, Omar M. Inorganic Chemistry, Vol. 50, Issue 15, p. 6853-6855 https://doi.org/10.1021/ic200744y	journal	August 2011
Pt Nanoclusters Confined within Metal–Organic Framework Cavities for Chemoselective Cinnamaldehyde Hydrogenation Guo, Zhiyong; Xiao, Chaoxian; Maligal-Ganesh, Raghu V. ACS Catalysis, Vol. 4, Issue 5, p. 1340-1348 https://doi.org/10.1021/cs400982n	journal	April 2014
An alternative UiO-66 synthesis for HCl-sensitive nanoparticle encapsulation Tulig, Karen; Walton, Krista S. RSC Adv., Vol. 4, Issue 93 https://doi.org/10.1039/C4RA08856E	journal	January 2014
Enhanced selectivity of CO2 over CH4 in sulphonate-, carboxylate- and iodo-functionalized UiO-66 frameworks Biswas, Shyam; Zhang, Jian; Li, Zhibao Dalton Transactions, Vol. 42, Issue 13 https://doi.org/10.1039/c3dt32288b	journal	January 2013
A General Strategy for the Synthesis of Functionalised UiO-66 Frameworks: Characterisation, Stability and CO ₂ Adsorption Properties Biswas, Shyam; Van Der Voort, Pascal European Journal of Inorganic Chemistry, Vol. 2013, Issue 12 https://doi.org/10.1002/ejic.201201228	journal	February 2013
Metal–Organic Framework (MOF) Defects under Control: Insights into the Missing Linker Sites and Their Implication in the Reactivity of Zirconium-Based Frameworks Gutov, Oleksii V.; Hevia, Miguel González; Escudero-Adán, Eduardo C. Inorganic Chemistry, Vol. 54, Issue 17 https://doi.org/10.1021/acs.inorgchem.5b01053	journal	August 2015
A facile synthesis of UiO-66, UiO-67 and their derivatives Katz, Michael J.; Brown, Zachary J.; Colón, Yamil J. Chemical Communications, Vol. 49, Issue 82 https://doi.org/10.1039/c3cc46105j	journal	January 2013
A UiO-66 analogue with uncoordinated carboxylic acids for the broad-spectrum removal of toxic chemicals DeCoste, Jared B.; Demasky, Tyler J.; Katz, Michael J. New Journal of Chemistry, Vol. 39, Issue 4 https://doi.org/10.1039/C4NJ02093F	journal	January 2015
A Modulated Hydrothermal (MHT) Approach for the Facile Synthesis of UiO-66-Type MOFs Hu, Zhigang; Peng, Yongwu; Kang, Zixi Inorganic Chemistry, Vol. 54, Issue 10 https://doi.org/10.1021/acs.inorgchem.5b00435	journal	April 2015
Defects in Metal–Organic Frameworks: Challenge or Opportunity? Sholl, David S.; Lively, Ryan P. The Journal of Physical Chemistry Letters, Vol. 6, Issue 17 https://doi.org/10.1021/acs.jpclett.5b01135	journal	August 2015
Isoreticular synthesis and modification of frameworks with the UiO-66 topology Garibay, Sergio J.; Cohen, Seth M. Chemical Communications, Vol. 46, Issue 41, p. 7700-7702 https://doi.org/10.1039/c0cc02990d	journal	January 2010
Defect-Engineered Metal-Organic Frameworks Fang, Zhenlan; Bueken, Bart; De Vos, Dirk E. Angewandte Chemie International Edition, Vol. 54, Issue 25 https://doi.org/10.1002/anie.201411540	journal	June 2015
Active site engineering in UiO-66 type metal–organic frameworks by intentional creation of defects: a theoretical rationalization Vandichel, Matthias; Hajek, Julianna; Vermoortele, Frederik CrystEngComm, Vol. 17, Issue 2 https://doi.org/10.1039/C4CE01672F	journal	January 2015
A Zn-based, pillared paddlewheel MOF containing free carboxylic acids via covalent post-synthesis elaboration Gadzikwa, Tendai; Farha, Omar K.; Mulfort, Karen L. Chemical Communications, Issue 25 https://doi.org/10.1039/b823392f	journal	January 2009
Definitive Molecular Level Characterization of Defects in UiO-66 Crystals Trickett, Christopher A.; Gagnon, Kevin J.; Lee, Seungkyu Angewandte Chemie International Edition, Vol. 54, Issue 38 https://doi.org/10.1002/anie.201505461	journal	August 2015
Metals@MOFs - Loading MOFs with Metal Nanoparticles for Hybrid Functions Meilikhov, Mikhail; Yusenko, Kirill; Esken, Daniel European Journal of Inorganic Chemistry, Vol. 2010, Issue 24, p. 3701-3714 https://doi.org/10.1002/ejic.201000473	journal	July 2010
Ionic Conductivity in the Metal-Organic Framework UiO-66 by Dehydration and Insertion of Lithium tert -Butoxide Ameloot, Rob; Aubrey, Michael; Wiers, Brian M. Chemistry - A European Journal, Vol. 19, Issue 18 https://doi.org/10.1002/chem.201300326	journal	March 2013
Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe, Co and Ni Biesinger, Mark C.; Payne, Brad P.; Grosvenor, Andrew P. Applied Surface Science, Vol. 257, Issue 7, p. 2717-2730 https://doi.org/10.1016/j.apsusc.2010.10.051	journal	January 2011
Active Sites in Copper-Based Metal–Organic Frameworks: Understanding Substrate Dynamics, Redox Processes, and Valence-Band Structure Duke, Audrey S.; Dolgopolova, Ekaterina A.; Galhenage, Randima P. The Journal of Physical Chemistry C, Vol. 119, Issue 49 https://doi.org/10.1021/acs.jpcc.5b08053	journal	November 2015
XPS study of the Cu@Cu2O core-shell nanoparticles Ghodselahi, T.; Vesaghi, M. A.; Shafiekhani, A. Applied Surface Science, Vol. 255, Issue 5 https://doi.org/10.1016/j.apsusc.2008.08.110	journal	December 2008
Low-temperature fabrication of Cu( i ) sites in zeolites by using a vapor-induced reduction strategy Qin, Ju-Xiang; Wang, Zhi-Min; Liu, Xiao-Qin Journal of Materials Chemistry A, Vol. 3, Issue 23 https://doi.org/10.1039/C5TA02569A	journal	January 2015
Synthesis and characterization of first hetero-nuclear molybdenum copper cluster with highly delocalized Cu(I)/Cu(II) Sun, Ying-Hua; Yu, Jie-Hui; Jin, Xiang-Jun Inorganic Chemistry Communications, Vol. 9, Issue 11 https://doi.org/10.1016/j.inoche.2006.06.023	journal	November 2006
Efficient identification of hydrophobic MOFs: application in the capture of toxic industrial chemicals Moghadam, Peyman Z.; Fairen-Jimenez, David; Snurr, Randall Q. Journal of Materials Chemistry A, Vol. 4, Issue 2 https://doi.org/10.1039/C5TA06472D	journal	January 2016
How Water Fosters a Remarkable 5-Fold Increase in Low-Pressure CO ₂ Uptake within Mesoporous MIL-100(Fe) Soubeyrand-Lenoir, Estelle; Vagner, Christelle; Yoon, Ji Woong Journal of the American Chemical Society, Vol. 134, Issue 24 https://doi.org/10.1021/ja302787x	journal	June 2012
Ammonia Adsorption and Co-adsorption with Water in HKUST-1: Spectroscopic Evidence for Cooperative Interactions Nijem, Nour; Fürsich, Katrin; Bluhm, Hendrik The Journal of Physical Chemistry C, Vol. 119, Issue 44 https://doi.org/10.1021/acs.jpcc.5b05716	journal	October 2015
Water adsorption in UiO-66: the importance of defects Ghosh, Pritha; Colón, Yamil J.; Snurr, Randall Q. Chem. Commun., Vol. 50, Issue 77 https://doi.org/10.1039/C4CC04945D	journal	January 2014
Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Provisional) Sing, K. S. W. Pure and Applied Chemistry, Vol. 54, Issue 11 https://doi.org/10.1351/pac198254112201	journal	January 1982
Effect of Water Adsorption on Retention of Structure and Surface Area of Metal–Organic Frameworks Schoenecker, Paul M.; Carson, Cantwell G.; Jasuja, Himanshu Industrial & Engineering Chemistry Research, Vol. 51, Issue 18 https://doi.org/10.1021/ie202325p	journal	April 2012
Virtual High Throughput Screening Confirmed Experimentally: Porous Coordination Polymer Hydration Low, John J.; Benin, Annabelle I.; Jakubczak, Paulina Journal of the American Chemical Society, Vol. 131, Issue 43 https://doi.org/10.1021/ja9061344	journal	November 2009
The Chemistry and Applications of Metal-Organic Frameworks Furukawa, H.; Cordova, K. E.; O'Keeffe, M. Science, Vol. 341, Issue 6149, p. 1230444-1230444 https://doi.org/10.1126/science.1230444	journal	August 2013
Zirconium-based metal organic frameworks: Highly selective adsorbents for removal of phosphate from water and urine Lin, Kun-Yi Andrew; Chen, Shen-Yi; Jochems, Andrew P. Materials Chemistry and Physics, Vol. 160 https://doi.org/10.1016/j.matchemphys.2015.04.021	journal	June 2015
Effect of surface chemical and structural heterogeneity of copper-based MOF/graphite oxide composites on the adsorption of ammonia Bashkova, Svetlana; Bandosz, Teresa J. Journal of Colloid and Interface Science, Vol. 417 https://doi.org/10.1016/j.jcis.2013.11.010	journal	March 2014
Tailored Fe3C-derived carbons with embedded Fe nanoparticles for ammonia adsorption Mangarella, Michael C.; Walton, Krista S. Carbon, Vol. 95 https://doi.org/10.1016/j.carbon.2015.08.042	journal	December 2015
Hierarchical modeling of ammonia adsorption in functionalized metal–organic frameworks Yu, Decai; Ghosh, Pritha; Snurr, Randall Q. Dalton Transactions, Vol. 41, Issue 14 https://doi.org/10.1039/c2dt11908k	journal	January 2012
Molecular chemisorption on open metal sites in Cu3(benzenetricarboxylate)2: A spatially periodic density functional theory study Watanabe, Taku; Sholl, David S. The Journal of Chemical Physics, Vol. 133, Issue 9 https://doi.org/10.1063/1.3479041	journal	September 2010
Interactions of NO ₂ with Zr-Based MOF: Effects of the Size of Organic Linkers on NO ₂ Adsorption at Ambient Conditions Ebrahim, Amani M.; Levasseur, Benoit; Bandosz, Teresa J. Langmuir, Vol. 29, Issue 1 https://doi.org/10.1021/la302869m	journal	December 2012
Computational Characterization of Defects in Metal–Organic Frameworks: Spontaneous and Water-Induced Point Defects in ZIF-8 Zhang, Chenyang; Han, Chu; Sholl, David S. The Journal of Physical Chemistry Letters, Vol. 7, Issue 3 https://doi.org/10.1021/acs.jpclett.5b02683	journal	January 2016
Facet-Specific Stability of ZIF-8 in the Presence of Acid Gases Dissolved in Aqueous Solutions Pang, Simon H.; Han, Chu; Sholl, David S. Chemistry of Materials, Vol. 28, Issue 19 https://doi.org/10.1021/acs.chemmater.6b02643	journal	September 2016

Cited By (5)

Adsorption and Detection of Hazardous Trace Gases by Metal-Organic Frameworks Woellner, Michelle; Hausdorf, Steffen; Klein, Nicole Advanced Materials, Vol. 30, Issue 37 https://doi.org/10.1002/adma.201704679	journal	June 2018
Defective Metal-Organic Frameworks Dissegna, Stefano; Epp, Konstantin; Heinz, Werner R. Advanced Materials, Vol. 30, Issue 37 https://doi.org/10.1002/adma.201704501	journal	January 2018
Metal–organic frameworks (MOFs): potential and challenges for capture and abatement of ammonia Vikrant, Kumar; Kumar, Vanish; Kim, Ki-Hyun Journal of Materials Chemistry A, Vol. 5, Issue 44 https://doi.org/10.1039/c7ta07847a	journal	January 2017
Kinetic stability of metal–organic frameworks for corrosive and coordinating gas capture Rieth, Adam J.; Wright, Ashley M.; Dincă, Mircea Nature Reviews Materials, Vol. 4, Issue 11 https://doi.org/10.1038/s41578-019-0140-1	journal	September 2019
Scalable, room temperature, and water-based synthesis of functionalized zirconium-based metal–organic frameworks for toxic chemical removal Chen, Zhijie; Wang, Xingjie; Noh, Hyunho CrystEngComm, Vol. 21, Issue 14 https://doi.org/10.1039/c9ce00213h	journal	January 2019

Similar Records

Engineering Copper Carboxylate Functionalities on Water Stable Metal–Organic Frameworks for Enhancement of Ammonia Removal Capacities

Journal Article · Thu Feb 02 00:00:00 EST 2017 · Journal of Physical Chemistry. C · OSTI ID:1388628

Joshi, Jayraj N.; Garcia-Gutierrez, Erika Y.; Moran, Colton M.; +2 more

Probing Metal–Organic Framework Design for Adsorptive Natural Gas Purification

Journal Article · Sun Jun 26 00:00:00 EDT 2016 · Langmuir · OSTI ID:1388628

Joshi, Jayraj N.; Zhu, Guanghui; Lee, Jason J.; +4 more

Synergistic Effect of Mixed Oxide on the Adsorption of Ammonia with Metal–Organic Frameworks

Journal Article · Fri May 27 00:00:00 EDT 2016 · Industrial and Engineering Chemistry Research · OSTI ID:1388628

Mounfield, III, William P.; Taborga Claure, Micaela; Agrawal, Pradeep K.; +2 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
42 ENGINEERING
catalysis (heterogeneous)
defects
membrane
carbon capture
materials and chemistry by design
synthesis (novel materials)
synthesis (self-assembly)
synthesis (scalable processing)

Title: Engineering Copper Carboxylate Functionalities on Water Stable Metal–Organic Frameworks for Enhancement of Ammonia Removal Capacities

Citation Formats

References (73)

Cited By (5)

Similar Records

Related Subjects