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Title: Na-Ion Battery Anodes: Materials and Electrochemistry

Journal Article · · Accounts of Chemical Research
 [1];  [1];  [2];  [1];  [2];  [1]
  1. Univ. of Maryland, College Park, MD (United States)
  2. Oregon State Univ., Corvallis, OR (United States)

The intermittent nature of renewable energy sources, such as solar and wind, calls for sustainable electrical energy storage (EES) technologies for stationary applications. Li will be simply too rare for Li-ion batteries (LIBs) to be used for large-scale storage purposes. In contrast, Na-ion batteries (NIBs) are highly promising to meet the demand of grid-level storage because Na is truly earth abundant and ubiquitous around the globe. Furthermore, NIBs share a similar rocking-chair operation mechanism with LIBs, which potentially provides high reversibility and long cycling life. Here, it would be most efficient to transfer knowledge learned on LIBs during the last three decades to the development of NIBs. Following this logic, rapid progress has been made in NIB cathode materials, where layered metal oxides and polyanionic compounds exhibit encouraging results. On the anode side, pure graphite as the standard anode for LIBs can only form NaC64 in NIBs if solvent co-intercalation does not occur due to the unfavorable thermodynamics. In fact, it was the utilization of a carbon anode in LIBs that enabled the commercial successes. Anodes of metal-ion batteries determine key characteristics, such as safety and cycling life; thus, it is indispensable to identify suitable anode materials for NIBs.

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Nanostructures for Electrical Energy Storage (NEES)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC0001160
OSTI ID:
1388518
Journal Information:
Accounts of Chemical Research, Vol. 49, Issue 2; Related Information: NEES partners with University of Maryland (lead); University of California, Irvine; University of Florida; Los Alamos National Laboratory; Sandia National Laboratories; Yale University; ISSN 0001-4842
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 780 works
Citation information provided by
Web of Science

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Advances and Challenges in Metal Sulfides/Selenides for Next-Generation Rechargeable Sodium-Ion Batteries journal June 2017
Alloy-Based Anode Materials toward Advanced Sodium-Ion Batteries journal June 2017
Selenium Phosphide (Se 4 P 4 ) as a New and Promising Anode Material for Sodium-Ion Batteries journal December 2016
Rational Assembly of Hollow Microporous Carbon Spheres as P Hosts for Long-Life Sodium-Ion Batteries journal November 2017
Controllable Chain-Length for Covalent Sulfur-Carbon Materials Enabling Stable and High-Capacity Sodium Storage journal January 2019
Antimonen: von der experimentellen Herstellung zur praktischen Anwendung journal November 2018
SnS 2 /Sb 2 S 3 Heterostructures Anchored on Reduced Graphene Oxide Nanosheets with Superior Rate Capability for Sodium-Ion Batteries journal February 2018
One‐Pot Synthesis of Novel B, N Co–Doped Carbon Materials for High‐Performance Sodium‐Ion Batteries journal June 2019
Tailoring NiO Nanostructured Arrays by Sulfate Anions for Sodium-Ion Batteries journal June 2018
Critical design factors for kinetically favorable P-based compounds toward alloying with Na ions for high-power sodium-ion batteries journal January 2019
Lignin-Derived Nitrogen-Doped Porous Carbon as a High-Rate Anode Material for Sodium Ion Batteries journal January 2019
Synthesis of CuS@CoS 2 Double‐Shelled Nanoboxes with Enhanced Sodium Storage Properties journal May 2019
Bullet‐like Cu 9 S 5 Hollow Particles Coated with Nitrogen‐Doped Carbon for Sodium‐Ion Batteries journal May 2019
Three-Dimensional Architectures Constructed from Transition-Metal Dichalcogenide Nanomaterials for Electrochemical Energy Storage and Conversion journal December 2017
Spatially controlled synthesis of superlattice-like SnS/nitrogen-doped graphene hybrid nanobelts as high-rate and durable anode materials for sodium-ion batteries journal January 2019
3D CoMoSe4 Nanosheet Arrays Converted Directly from Hydrothermally Processed CoMoO4 Nanosheet Arrays by Plasma-Assisted Selenization Process Toward Excellent Anode Material in Sodium-Ion Battery journal June 2019
Superior Low-Temperature Power and Cycle Performances of Na-Ion Battery over Li-Ion Battery journal March 2017
First-Principles Study of Sodium Intercalation in Crystalline Na x Si24 (0 ≤ x ≤ 4) as Anode Material for Na-ion Batteries journal July 2017
Colloidal Antimony Sulfide Nanoparticles as a High-Performance Anode Material for Li-ion and Na-ion Batteries journal February 2020
Micro-nano structure hard carbon as a high performance anode material for sodium-ion batteries journal October 2016
Hierarchical Nitrogen-Doped Porous Carbon Microspheres as Anode for High Performance Sodium Ion Batteries journal October 2019
Tin and Tin Compound Materials as Anodes in Lithium-Ion and Sodium-Ion Batteries: A Review journal March 2020
Biobased Functional Carbon Materials: Production, Characterization, and Applications—A Review journal August 2018
Poly (3,4-Ethylenedioxythiophene) (PEDOT) Nanofibers Decorated Graphene Oxide (GO) as High-Capacity, Long Cycle Anodes for Sodium Ion Batteries journal October 2018