2D Conductive Iron-Quinoid Magnets Ordering up to Tc = 105 K via Heterogenous Redox Chemistry

DeGayner, Jordan A.; Jeon, Ie -Rang; Sun, Lei; Dincă, Mircea; Harris, T. David

doi:10.1021/jacs.7b00705

Title: 2D Conductive Iron-Quinoid Magnets Ordering up to T_c = 105 K via Heterogenous Redox Chemistry

Abstract

We report the magnetism and conductivity for a redox pair of iron-quinoid metal–organic frameworks (MOFs). The oxidized compound, (Me₂NH₂)₂[Fe₂L₃]·2H₂O·6DMF (LH₂ = 2,5-dichloro-3,6-dihydroxo-1,4-benzoquinone) was previously shown to magnetically order below 80 K in its solvated form, with the ordering temperature decreasing to 26 K upon desolvation. Here, we demonstrate this compound to exhibit electrical conductivity values up to σ = 1.4(7) × 10^–2 S/cm (E_a = 0.26(1) cm^–1) and 1.0(3) × 10^–3 S/cm (E_a = 0.19(1) cm^–1) in its solvated and desolvated forms, respectively. Upon soaking in a DMF solution of Cp₂Co, the compound undergoes a single-crystal-to-single-crystal one-electron reduction to give (Cp₂Co)_1.43(Me₂NH₂)_1.57[Fe₂L₃]·_4.9DMF. Structural and spectroscopic analysis confirms this reduction to be ligand-based, and as such the trianionic framework is formulated as [Fe^III₂(L^3–•)₃]^3–. Magnetic measurements for this reduced compound reveal the presence of dominant intralayer metal–organic radical coupling to give a magnetically ordered phase below T_c = 105 K, one of the highest reported ordering temperatures for a MOF. This high ordering temperature is significantly increased relative to the oxidized compound, and stems from the overall increase in coupling strength afforded by an additional organic radical. In line with the high critical temperature, the new MOF exhibits magnetic hysteresis up to 100more »« less

Authors:

DeGayner, Jordan A. ^[1]; Jeon, Ie -Rang ^[1];

^[2];

^[1]

Northwestern Univ., Evanston, IL (United States)
Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)

Publication Date:: Thu Feb 23 00:00:00 EST 2017

Research Org.:: Energy Frontier Research Centers (EFRC) (United States). Center for Excitonics (CE)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1388516

Grant/Contract Number:: SC0001088; AC02-06CH11357; NNCI-154220; ECCS-154220; DMR-112126; DMR-135195

Resource Type:: Journal Article: Accepted Manuscript

Journal Name:: Journal of the American Chemical Society

Additional Journal Information:: Journal Volume: 139; Journal Issue: 11; Related Information: CE partners with Massachusetts Institute of Technology (lead); Brookhaven National Laboratory; Harvard University; Journal ID: ISSN 0002-7863

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; solar (photovoltaic); solid state lighting; photosynthesis (natural and artificial); charge transport; optics; synthesis (novel materials); synthesis (self-assembly); synthesis (scalable processing)

Citation Formats


                    DeGayner, Jordan A., Jeon, Ie -Rang, Sun, Lei, Dincă, Mircea, and Harris, T. David. 2D Conductive Iron-Quinoid Magnets Ordering up to Tc = 105 K via Heterogenous Redox Chemistry.  United States: N. p., 2017. 
        Web.  doi:10.1021/jacs.7b00705.

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                    DeGayner, Jordan A., Jeon, Ie -Rang, Sun, Lei, Dincă, Mircea, & Harris, T. David. 2D Conductive Iron-Quinoid Magnets Ordering up to Tc = 105 K via Heterogenous Redox Chemistry.  United States.  https://doi.org/10.1021/jacs.7b00705

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                    DeGayner, Jordan A., Jeon, Ie -Rang, Sun, Lei, Dincă, Mircea, and Harris, T. David. 2017.  
        "2D Conductive Iron-Quinoid Magnets Ordering up to Tc = 105 K via Heterogenous Redox Chemistry".  United States.  https://doi.org/10.1021/jacs.7b00705.  https://www.osti.gov/servlets/purl/1388516.

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@article{osti_1388516,

  title        = {2D Conductive Iron-Quinoid Magnets Ordering up to Tc = 105 K via Heterogenous Redox Chemistry},

  author       = {DeGayner, Jordan A. and Jeon, Ie -Rang and Sun, Lei and Dincă, Mircea and Harris, T. David},

  abstractNote = {We report the magnetism and conductivity for a redox pair of iron-quinoid metal–organic frameworks (MOFs). The oxidized compound, (Me2NH2)2[Fe2L3]·2H2O·6DMF (LH2 = 2,5-dichloro-3,6-dihydroxo-1,4-benzoquinone) was previously shown to magnetically order below 80 K in its solvated form, with the ordering temperature decreasing to 26 K upon desolvation. Here, we demonstrate this compound to exhibit electrical conductivity values up to σ = 1.4(7) × 10–2 S/cm (Ea = 0.26(1) cm–1) and 1.0(3) × 10–3 S/cm (Ea = 0.19(1) cm–1) in its solvated and desolvated forms, respectively. Upon soaking in a DMF solution of Cp2Co, the compound undergoes a single-crystal-to-single-crystal one-electron reduction to give (Cp2Co)1.43(Me2NH2)1.57[Fe2L3]·4.9DMF. Structural and spectroscopic analysis confirms this reduction to be ligand-based, and as such the trianionic framework is formulated as [FeIII2(L3–•)3]3–. Magnetic measurements for this reduced compound reveal the presence of dominant intralayer metal–organic radical coupling to give a magnetically ordered phase below Tc = 105 K, one of the highest reported ordering temperatures for a MOF. This high ordering temperature is significantly increased relative to the oxidized compound, and stems from the overall increase in coupling strength afforded by an additional organic radical. In line with the high critical temperature, the new MOF exhibits magnetic hysteresis up to 100 K, as revealed by variable-field measurements. Lastly, this compound is electrically conductive, with values up to σ = 5.1(3) × 10–4 S/cm with Ea = 0.34(1) eV. Taken together, these results demonstrate the unique ability of metal-quinoid MOFs to simultaneously exhibit both high magnetic ordering temperatures and high electrical conductivity.},

  doi          = {10.1021/jacs.7b00705},

  url          = {https://www.osti.gov/biblio/1388516},
  journal      = {Journal of the American Chemical Society},

  issn         = {0002-7863},

  number       = 11,

  volume       = 139,

  place        = {United States},

  year         = {Thu Feb 23 00:00:00 EST 2017},

  month        = {Thu Feb 23 00:00:00 EST 2017}

}

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Postsynthetic modification of metal–organic frameworks journal, January 2009

A Chemically Functionalizable Nanoporous Material [Cu3(TMA)2(H2O)3]n journal, February 1999

Nanoporous Cobalt(II) MOF Exhibiting Four Magnetic Ground States and Changes in Gas Sorption upon Post-Synthetic Modification journal, March 2014

Electrically Conductive Porous Metal-Organic Frameworks journal, January 2016

An Electron-Transfer Ferromagnet with T c =107 K Based on a Three-Dimensional [Ru 2 ] 2 /TCNQ System journal, September 2008

MnII(TCNE)3/2(I3)1/2-A 3D Network-Structured Organic-Based Magnet and Comparison to a 2D Analog journal, May 2010

Structure and magnetic ordering of a 2-D MnII(TCNE)I(OH2) (TCNE = tetracyanoethylene) organic-based magnet (Tc = 171 K) journal, January 2011

Toward molecular magnets: the metal-radical approach journal, November 1989

High-spin molecules based on metal complexes of organic free radicals journal, July 2008

Radicals in metal–organic frameworks journal, January 2014

A Room-Temperature Molecular/Organic-Based Magnet journal, June 1991

High Electrical Conductivity in Ni 3 (2,3,6,7,10,11-hexaiminotriphenylene) 2 , a Semiconducting Metal–Organic Graphene Analogue journal, April 2014

Electrochemical oxygen reduction catalysed by Ni3(hexaiminotriphenylene)2 journal, March 2016

Coordination compounds of 1,4-dihydroxybenzoquinone and its homologues. Structures and properties journal, January 2002

Dihydroxybenzoquinone and chloranilic acid derivatives of rare earth metals journal, January 2002

A Novel Hybrid Supramolecular Network Assembled from Perfect ??? Stacking of an Anionic Inorganic Layer and a Cationic Hydronium-Ion-Mediated Organic Layer journal, November 2004

Coordination Polymers of 2,5-Dihydroxybenzoquinone and Chloranilic Acid with the (10,3)- a Topology journal, July 2011

A Family of Layered Chiral Porous Magnets Exhibiting Tunable Ordering Temperatures journal, August 2013

Role of NEt 4 + in Orienting and Locking Together [M 2 lig 3 ] 2– (6,3) Sheets (H 2 lig = Chloranilic or Fluoranilic Acid) to Generate Spacious Channels Perpendicular to the Sheets journal, February 2017

Density Functional Studies of a Heisenberg Spin Coupled Chromium−Semiquinone Complex and Its Chromium−Catechol Analog journal, November 1998

Spin Exchange Effects on the Physicochemical Properties of Tetraoxolene-Bridged Bimetallic Complexes journal, April 2007

Electronic structure of [Ga2(tren)2(CAsq,cat)](BPh4)2(BF4): An EPR, ENDOR, and density functional study journal, September 2008

Tetraoxolene radical stabilization by the interaction with transition-metal ions journal, June 1991

Electron Transfer in Dinuclear Cobalt Complexes with “Non-innocent” Bridging Ligands journal, May 1997

Characterization of the Chloranilate(•3−) π Radical as a Strong Spin-Coupling Bridging Ligand journal, August 2006

Synthesis, Structure, and Magnetic Properties of Valence Ambiguous Dinuclear Antiferromagnetically Coupled Cobalt and Ferromagnetically Coupled Iron Complexes Containing the Chloranilate(2−) and the Significantly Stronger Coupling Chloranilate(•3−) Radical Trianion journal, February 2007

An Azophenine Radical-Bridged Fe 2 Single-Molecule Magnet with Record Magnetic Exchange Coupling journal, October 2013

A series of tetraazalene radical-bridged M 2 (M = Cr III , Mn II , Fe II , Co II ) complexes with strong magnetic exchange coupling journal, January 2015

A 2D Semiquinone Radical-Containing Microporous Magnet with Solvent-Induced Switching from T c = 26 to 80 K journal, December 2015

Electronic Conductivity, Ferrimagnetic Ordering, and Reductive Insertion Mediated by Organic Mixed-Valence in a Ferric Semiquinoid Metal–Organic Framework journal, December 2015

Dihydroxybenzoquinone as Linker for the Synthesis of Permanently Porous Aluminum Metal–Organic Frameworks journal, July 2016

OLEX2 : a complete structure solution, refinement and analysis program journal, January 2009

Diamagnetic Corrections and Pascal's Constants journal, April 2008

Apparatus for two-probe conductivity measurements on compressed powders journal, August 1990

Freeze Drying Significantly Increases Permanent Porosity and Hydrogen Uptake in 4,4-Connected Metalâ€“Organic Frameworks journal, December 2009

Reduction of a Metal-Organic Framework by an Organometallic Complex: Magnetic Properties and Structure of the Inclusion Compound [(η5-C5H5)2Co]0.5@MIL-47(V) journal, July 2010

Reversible conversion of valence-tautomeric copper metal–organic frameworks dependent single-crystal-to-single-crystal oxidation/reduction: a redox-switchable catalyst for C–H bonds activation reaction journal, January 2015

Reversible Tuning Hydroquinone/Quinone Reaction in Metal–Organic Framework: Immobilized Molecular Switches in Solid State journal, September 2015

Reaction of Methyl Bromide with Dimethylformamide journal, November 1961

A Tale of Three Carboxylates: Cooperative Asymmetric Crystallization of a Three-Dimensional Microporous Framework from Achiral Precursors journal, January 2010

Direct X-ray Observation of Trapped CO 2 in a Predesigned Porphyrinic Metal-Organic Framework journal, May 2014

Design of Novel Inorganic−Organic Hybrid Materials Based on Iron-Chloranilate Mononuclear Complexes: Characteristics of Hydrogen-Bond-Supported Layers toward the Intercalation of Guests journal, January 2003

Preparation of a semiquinonate-bridged diiron(ii) complex and elucidation of its geometric and electronic structures journal, January 2013

Nature of the manganese(I)-dioxolene bonding as a function of the ligand oxidation state: UV-visible, IR, and resonance Raman spectroelectrochemical study of [Mn(CO)3Ln(Diox)]z (n = 0, 1; z = -2, -1, 0, +1) and [Mn(CO)2{P(OEt)3}m(Diox)]z (m = 1, 2; z = -1, 0, +1) complexes journal, April 1992

Reaction Coordinate of a Functional Model of Tyrosinase: Spectroscopic and Computational Characterization journal, April 2009

Electron Transfer, Linkage Isomerization, Bulk Magnetic Order, and Spin-Glass Behavior in the Iron Hexacyanomanganate Prussian Blue Analogue journal, October 1999

Structural and magnetic properties of tris(o-semiquinone) complexes of iron(III) and chromium(III) journal, December 1978

[MII(tcne)2]⋅x CH2Cl2 (M=Mn, Fe, Co, Ni) Molecule-Based Magnets withTc Values Above 100 K and Coercive Fields up to 6500 Oe journal, March 1998

Magnetic properties and critical behavior of Fe ( tetracyanoethylene ) 2 ⋅ x ( CH 2 Cl 2 ) : A high- T c molecule-based magnet journal, January 2000

Vanadium [dicyanoperfluorostilbene]2·yTHF: a molecule-based magnet with Tc ca. 205 K journal, January 2000

Magnetically Ordered ( T c = 200 K) Bis(tetracyanopyrazine)vanadium, V[TCNP] 2 · y CH 2 Cl 2 journal, March 2004

Magnetic Ordering ( T c = 90 K) Observed for Layered [Fe II (TCNE •- )(NCMe) 2 ] + [Fe III Cl 4 ] - (TCNE = Tetracyanoethylene) journal, December 2006

Glassy Magnets Composed of Metals Coordinated to 7,7,8,8-tetracyanoquinodimethane: M(TCNQ) 2 (M = Mn, Fe, Co, Ni) † journal, May 2003

Reversible Magnetism between an Antiferromagnet and a Ferromagnet Related to Solvation/Desolvation in a Robust Layered [Ru 2 ] 2 TCNQ Charge-Transfer System journal, August 2010

Million-Fold Electrical Conductivity Enhancement in Fe 2 (DEBDC) versus Mn 2 (DEBDC) (E = S, O) journal, May 2015

Electrical conductive coordination polymers journal, January 2012

Solid-State Redox Switching of Magnetic Exchange and Electronic Conductivity in a Benzoquinoid-Bridged Mn II Chain Compound journal, May 2016

Measuring and Reporting Electrical Conductivity in Metal–Organic Frameworks: Cd 2 (TTFTB) as a Case Study journal, October 2016

Title: 2D Conductive Iron-Quinoid Magnets Ordering up to T_c = 105 K via Heterogenous Redox Chemistry

Spin-Driven Resistance in Organic-Based Magnetic Semiconductor V[TCNE]x
journal, September 2002

Hybrid inorganic–organic materials: a new family in condensed matter physics
journal, February 2008

Magnetic metal–organic frameworks
journal, January 2009

Microporous magnets
journal, January 2011

Magnetic nanoporous coordination polymers
journal, January 2004

Molecular spintronics
journal, January 2011

Challenges for semiconductor spintronics
journal, March 2007

Spin injection/detection using an organic-based magnetic semiconductor
journal, July 2010

Spintronics: Fundamentals and applications
journal, April 2004

The present and the future of spintronics
journal, November 2008

Selective binding and removal of guests in a microporous metal–organic framework
journal, December 1995

Reticular synthesis and the design of new materials
journal, June 2003

The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013

Coexistence of ferromagnetism and metallic conductivity in a molecule-based layered compound
journal, November 2000

Generation and O ₂ Adsorption Studies of the Microporous Magnets CsNi[Cr(CN) ₆ ] ( T _C = 75 K) and Cr ₃ [Cr(CN) ₆ ] ₂ ·6H ₂ O ( T _N = 219 K)
journal, November 2008

Conductivity, Doping, and Redox Chemistry of a Microporous Dithiolene-Based Metal−Organic Framework
journal, July 2010

Tunable Electrical Conductivity in Metal-Organic Framework Thin-Film Devices
journal, December 2013

Dynamic and Redox Active Pillared Bilayer Open Framework: Single-Crystal-to-Single-Crystal Transformations upon Guest Removal, Guest Exchange, and Framework Oxidation
journal, December 2004

A homochiral metal–organic porous material for enantioselective separation and catalysis
journal, April 2000

Postsynthetic modification of metal–organic frameworks
journal, January 2009

A Chemically Functionalizable Nanoporous Material [Cu₃(TMA)₂(H₂O)₃]_n
journal, February 1999

Nanoporous Cobalt(II) MOF Exhibiting Four Magnetic Ground States and Changes in Gas Sorption upon Post-Synthetic Modification
journal, March 2014

Electrically Conductive Porous Metal-Organic Frameworks
journal, January 2016

An Electron-Transfer Ferromagnet with T _c =107 K Based on a Three-Dimensional [Ru ₂ ] ₂ /TCNQ System
journal, September 2008

MnII(TCNE)3/2(I3)1/2-A 3D Network-Structured Organic-Based Magnet and Comparison to a 2D Analog
journal, May 2010

Structure and magnetic ordering of a 2-D MnII(TCNE)I(OH2) (TCNE = tetracyanoethylene) organic-based magnet (Tc = 171 K)
journal, January 2011

Toward molecular magnets: the metal-radical approach
journal, November 1989

High-spin molecules based on metal complexes of organic free radicals
journal, July 2008

Radicals in metal–organic frameworks
journal, January 2014

A Room-Temperature Molecular/Organic-Based Magnet
journal, June 1991

High Electrical Conductivity in Ni ₃ (2,3,6,7,10,11-hexaiminotriphenylene) ₂ , a Semiconducting Metal–Organic Graphene Analogue
journal, April 2014

Electrochemical oxygen reduction catalysed by Ni3(hexaiminotriphenylene)2
journal, March 2016

Coordination compounds of 1,4-dihydroxybenzoquinone and its homologues. Structures and properties
journal, January 2002

Dihydroxybenzoquinone and chloranilic acid derivatives of rare earth metals
journal, January 2002

A Novel Hybrid Supramolecular Network Assembled from Perfect ??? Stacking of an Anionic Inorganic Layer and a Cationic Hydronium-Ion-Mediated Organic Layer
journal, November 2004

Coordination Polymers of 2,5-Dihydroxybenzoquinone and Chloranilic Acid with the (10,3)- a Topology
journal, July 2011

A Family of Layered Chiral Porous Magnets Exhibiting Tunable Ordering Temperatures
journal, August 2013

Role of NEt ₄ ⁺ in Orienting and Locking Together [M ₂ lig ₃ ] ^2– (6,3) Sheets (H ₂ lig = Chloranilic or Fluoranilic Acid) to Generate Spacious Channels Perpendicular to the Sheets
journal, February 2017

Density Functional Studies of a Heisenberg Spin Coupled Chromium−Semiquinone Complex and Its Chromium−Catechol Analog
journal, November 1998

Spin Exchange Effects on the Physicochemical Properties of Tetraoxolene-Bridged Bimetallic Complexes
journal, April 2007

Electronic structure of [Ga2(tren)2(CAsq,cat)](BPh4)2(BF4): An EPR, ENDOR, and density functional study
journal, September 2008

Tetraoxolene radical stabilization by the interaction with transition-metal ions
journal, June 1991

Electron Transfer in Dinuclear Cobalt Complexes with “Non-innocent” Bridging Ligands
journal, May 1997

Characterization of the Chloranilate(•3−) π Radical as a Strong Spin-Coupling Bridging Ligand
journal, August 2006

Synthesis, Structure, and Magnetic Properties of Valence Ambiguous Dinuclear Antiferromagnetically Coupled Cobalt and Ferromagnetically Coupled Iron Complexes Containing the Chloranilate(2−) and the Significantly Stronger Coupling Chloranilate(•3−) Radical Trianion
journal, February 2007

An Azophenine Radical-Bridged Fe ₂ Single-Molecule Magnet with Record Magnetic Exchange Coupling
journal, October 2013

A series of tetraazalene radical-bridged M ₂ (M = Cr ^III , Mn ^II , Fe ^II , Co ^II ) complexes with strong magnetic exchange coupling
journal, January 2015

A 2D Semiquinone Radical-Containing Microporous Magnet with Solvent-Induced Switching from T _c = 26 to 80 K
journal, December 2015

Electronic Conductivity, Ferrimagnetic Ordering, and Reductive Insertion Mediated by Organic Mixed-Valence in a Ferric Semiquinoid Metal–Organic Framework
journal, December 2015

Dihydroxybenzoquinone as Linker for the Synthesis of Permanently Porous Aluminum Metal–Organic Frameworks
journal, July 2016

OLEX2 : a complete structure solution, refinement and analysis program
journal, January 2009

Diamagnetic Corrections and Pascal's Constants
journal, April 2008

Apparatus for two-probe conductivity measurements on compressed powders
journal, August 1990

Freeze Drying Significantly Increases Permanent Porosity and Hydrogen Uptake in 4,4-Connected Metalâ€“Organic Frameworks
journal, December 2009

Reduction of a Metal-Organic Framework by an Organometallic Complex: Magnetic Properties and Structure of the Inclusion Compound [(η5-C5H5)2Co]0.5@MIL-47(V)
journal, July 2010

Reversible conversion of valence-tautomeric copper metal–organic frameworks dependent single-crystal-to-single-crystal oxidation/reduction: a redox-switchable catalyst for C–H bonds activation reaction
journal, January 2015

Reversible Tuning Hydroquinone/Quinone Reaction in Metal–Organic Framework: Immobilized Molecular Switches in Solid State
journal, September 2015

Reaction of Methyl Bromide with Dimethylformamide
journal, November 1961

A Tale of Three Carboxylates: Cooperative Asymmetric Crystallization of a Three-Dimensional Microporous Framework from Achiral Precursors
journal, January 2010

Direct X-ray Observation of Trapped CO ₂ in a Predesigned Porphyrinic Metal-Organic Framework
journal, May 2014

Design of Novel Inorganic−Organic Hybrid Materials Based on Iron-Chloranilate Mononuclear Complexes: Characteristics of Hydrogen-Bond-Supported Layers toward the Intercalation of Guests
journal, January 2003

Preparation of a semiquinonate-bridged diiron(ii) complex and elucidation of its geometric and electronic structures
journal, January 2013

Nature of the manganese(I)-dioxolene bonding as a function of the ligand oxidation state: UV-visible, IR, and resonance Raman spectroelectrochemical study of [Mn(CO)3Ln(Diox)]z (n = 0, 1; z = -2, -1, 0, +1) and [Mn(CO)2{P(OEt)3}m(Diox)]z (m = 1, 2; z = -1, 0, +1) complexes
journal, April 1992

Reaction Coordinate of a Functional Model of Tyrosinase: Spectroscopic and Computational Characterization
journal, April 2009

Electron Transfer, Linkage Isomerization, Bulk Magnetic Order, and Spin-Glass Behavior in the Iron Hexacyanomanganate Prussian Blue Analogue
journal, October 1999

Structural and magnetic properties of tris(o-semiquinone) complexes of iron(III) and chromium(III)
journal, December 1978

[MII(tcne)2]⋅x CH2Cl2 (M=Mn, Fe, Co, Ni) Molecule-Based Magnets withTc Values Above 100 K and Coercive Fields up to 6500 Oe
journal, March 1998

Magnetic properties and critical behavior of $Fe (tetracyanoethylene)_{2} \cdot x ({CH}_{2} {Cl}_{2}) :$ A high- $T_{c}$ molecule-based magnet
journal, January 2000

Vanadium [dicyanoperfluorostilbene]2·yTHF: a molecule-based magnet with Tc ca. 205 K
journal, January 2000

Magnetically Ordered ( T _c = 200 K) Bis(tetracyanopyrazine)vanadium, V[TCNP] ₂ · y CH ₂ Cl ₂
journal, March 2004

Magnetic Ordering ( T _c = 90 K) Observed for Layered [Fe ^II (TCNE ^•- )(NCMe) ₂ ] ⁺ [Fe ^III Cl ₄ ] ^- (TCNE = Tetracyanoethylene)
journal, December 2006

Glassy Magnets Composed of Metals Coordinated to 7,7,8,8-tetracyanoquinodimethane: M(TCNQ) ₂ (M = Mn, Fe, Co, Ni) ^†
journal, May 2003

Reversible Magnetism between an Antiferromagnet and a Ferromagnet Related to Solvation/Desolvation in a Robust Layered [Ru ₂ ] ₂ TCNQ Charge-Transfer System
journal, August 2010

Million-Fold Electrical Conductivity Enhancement in Fe ₂ (DEBDC) versus Mn ₂ (DEBDC) (E = S, O)
journal, May 2015

Electrical conductive coordination polymers
journal, January 2012

Solid-State Redox Switching of Magnetic Exchange and Electronic Conductivity in a Benzoquinoid-Bridged Mn ^II Chain Compound
journal, May 2016

Measuring and Reporting Electrical Conductivity in Metal–Organic Frameworks: Cd ₂ (TTFTB) as a Case Study
journal, October 2016

Hybrid molecular conductors
journal, January 2005

Multifunctionality in hybrid molecular materials: Design of ferromagnetic molecular metals
journal, April 2003