Production of p -Methylstyrene and p -Divinylbenzene from Furanic Compounds

doi:10.1002/cssc.201601554

Title: Production of p -Methylstyrene and p -Divinylbenzene from Furanic Compounds

Authors:

^[1]; Saraçi, Erisa ^[1]; Dauenhauer, Paul ^[2];

^[1]

Catalysis Center for Energy Innovation, U.S. Department of Energy-Energy Frontier Research Center, University of Delaware, 150 Academy St. Newark DE 19716 USA; Department of Chemical and Biomolecular Engineering, University of Delaware, 150 Academy St. Newark DE 19716 USA
Catalysis Center for Energy Innovation, U.S. Department of Energy-Energy Frontier Research Center, University of Delaware, 150 Academy St. Newark DE 19716 USA; Department of Chemical Engineering and Materials Science, University of Minnesota, 421 Washington Ave. SE Minneapolis MN 55455 USA

Publication Date:: 2016-12-20

Research Org.:: Energy Frontier Research Centers (EFRC) (United States). Catalysis Center for Energy Innovation (CCEI)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

OSTI Identifier:: 1388497

DOE Contract Number:: SC0001004

Resource Type:: Journal Article

Journal Name:: ChemSusChem

Additional Journal Information:: Journal Volume: 10; Journal Issue: 1; Related Information: CCEI partners with the University of Delaware (lead); Brookhaven National Laboratory; California Institute of Technology; Columbia University; University of Delaware; Lehigh University; University of Massachusetts, Amherst; Massachusetts Institute of Technology; University of Minnesota; Pacific Northwest National Laboratory; University of Pennsylvania; Princeton University; Rutgers University; Journal ID: ISSN 1864-5631

Publisher:: ChemPubSoc Europe

Country of Publication:: United States

Language:: English

Subject:: catalysis (homogeneous), catalysis (heterogeneous), biofuels (including algae and biomass), bio-inspired, hydrogen and fuel cells, materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing)

Citation Formats


                    Koehle, Maura, Saraçi, Erisa, Dauenhauer, Paul, and Lobo, Raul F. Production of p -Methylstyrene and p -Divinylbenzene from Furanic Compounds.  United States: N. p., 2016. 
        Web.  doi:10.1002/cssc.201601554.

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                    Koehle, Maura, Saraçi, Erisa, Dauenhauer, Paul, & Lobo, Raul F. Production of p -Methylstyrene and p -Divinylbenzene from Furanic Compounds.  United States.  doi:10.1002/cssc.201601554.

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                    Koehle, Maura, Saraçi, Erisa, Dauenhauer, Paul, and Lobo, Raul F. Tue .  
        "Production of p -Methylstyrene and p -Divinylbenzene from Furanic Compounds".  United States.  doi:10.1002/cssc.201601554.

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@article{osti_1388497,

  title        = {Production of p -Methylstyrene and p -Divinylbenzene from Furanic Compounds},

  author       = {Koehle, Maura and Saraçi, Erisa and Dauenhauer, Paul and Lobo, Raul F.},

  abstractNote = {},

  doi          = {10.1002/cssc.201601554},

  journal      = {ChemSusChem},

  issn         = {1864-5631},

  number       = 1,

  volume       = 10,

  place        = {United States},

  year         = {2016},

  month        = {12}

}

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DOI: 10.1002/cssc.201601554

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Title: Production of p -Methylstyrene and p -Divinylbenzene from Furanic Compounds

Citation Formats

Shale Gas Revolution: An Opportunity for the Production of Biobased Chemicals? journal, October 2013

Lewis acidic zeolite Beta catalyst for the Meerwein–Ponndorf–Verley reduction of furfural journal, January 2016

Route to Renewable PET: Reaction Pathways and Energetics of Diels–Alder and Dehydrative Aromatization Reactions Between Ethylene and Biomass-Derived Furans Catalyzed by Lewis Acid Molecular Sieves journal, September 2015

On the mechanism of aromatic acylation over zeolites journal, August 2007

960. The interaction of alkylbenzenes with excess of Friedel–Crafts acetylating agent journal, January 1956

Zeolite Catalysts as Solid Solvents in Fine Chemicals Synthesis journal, September 2000

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Deactivation mechanistic studies of copper chromite catalyst for selective hydrogenation of 2-furfuraldehyde journal, March 2013

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The α:β ratio in the acetylation of furan and the “extended selectivity treatment” for electrophilic substitutions at the beta position of the furan ring journal, January 1971

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Acylation of furan by variously functionalized carboxylic acids in the presence of phosphonic ionexchange resins used as catalysts journal, February 1985

Diels–Alder and Dehydration Reactions of Biomass-Derived Furan and Acrylic Acid for the Synthesis of Benzoic Acid journal, October 2015

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Synthesis of terephthalic acid via Diels-Alder reactions with ethylene and oxidized variants of 5-hydroxymethylfurfural journal, May 2014

Cycloaddition of Biomass-Derived Furans for Catalytic Production of Renewable p -Xylene journal, April 2012

Elucidation of Diels–Alder Reaction Network of 2,5-Dimethylfuran and Ethylene on HY Zeolite Catalyst journal, December 2012

Die Schiefergasrevolution: eine Chance zur Herstellung von Chemikalien auf Biobasis? journal, October 2013

Halogen-free acylation of toluene over FeSBA-1 molecular sieves journal, March 2007

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Reactions of aromatic and heteroaromatic compounds bearing electron-acceptor substituents: X. Alkylation and acylation of furfural journal, May 1972

Friedel-Crafts Acylation of Aromatic Hydrocarbons Using Zeolites journal, March 1997

Production of renewable p -xylene from 2,5-dimethylfuran via Diels–Alder cycloaddition and dehydrative aromatization reactions over silica−alumina aerogel catalysts journal, October 2015

Acylation of Toluene with Acetic Anhydride over Beta Zeolites: Influence of Reaction Conditions and Physicochemical Properties of the Catalyst journal, October 2000

Selective Production of Aromatics from Alkylfurans over Solid Acid Catalysts journal, January 2013

Ultra-selective cycloaddition of dimethylfuran for renewable p-xylene with H-BEA journal, January 2014

Fast Pyrolysis of Forestry Residue. 2. Physicochemical Composition of Product Liquid journal, March 2003

Acylation of aromatic compounds on H-Beta zeolites journal, February 1999

Methods to delay deactivation of zeolites on furan acylation: continuous liquid-phase technology and solvent effects journal, January 2015

Shale Gas Revolution: An Opportunity for the Production of Biobased Chemicals?
journal, October 2013

Lewis acidic zeolite Beta catalyst for the Meerwein–Ponndorf–Verley reduction of furfural
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Route to Renewable PET: Reaction Pathways and Energetics of Diels–Alder and Dehydrative Aromatization Reactions Between Ethylene and Biomass-Derived Furans Catalyzed by Lewis Acid Molecular Sieves
journal, September 2015

On the mechanism of aromatic acylation over zeolites
journal, August 2007

960. The interaction of alkylbenzenes with excess of Friedel–Crafts acetylating agent
journal, January 1956

Zeolite Catalysts as Solid Solvents in Fine Chemicals Synthesis
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Friedel-Crafts acylation of toluene and p-xylene with carboxylic acids catalyzed by zeolites
journal, May 1986

Deactivation mechanistic studies of copper chromite catalyst for selective hydrogenation of 2-furfuraldehyde
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Acylation of veratrole by acetic anhydride over Hβ and HY zeolites
journal, August 2002

On the role of zeolite structure and acidity in toluene acylation with isobutyric acid derivatives
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Mild liquid-phase Friedel-Crafts acylation of heteroaromatic compounds over zeolite Beta
journal, June 2009

The α:β ratio in the acetylation of furan and the “extended selectivity treatment” for electrophilic substitutions at the beta position of the furan ring
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Acetylation of anisole by acetic anhydride over a HBEA zeolite—Origin of deactivation of the catalyst
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Acetylation of aromatic compounds over H-BEA zeolite: the influence of the substituents on the reactivity and on the catalyst stability
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Acylation of furan by variously functionalized carboxylic acids in the presence of phosphonic ionexchange resins used as catalysts
journal, February 1985

Diels–Alder and Dehydration Reactions of Biomass-Derived Furan and Acrylic Acid for the Synthesis of Benzoic Acid
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Lewis acid zeolites for tandem Diels–Alder cycloaddition and dehydration of biomass-derived dimethylfuran and ethylene to renewable p-xylene
journal, January 2016

Synthesis of terephthalic acid via Diels-Alder reactions with ethylene and oxidized variants of 5-hydroxymethylfurfural
journal, May 2014

Cycloaddition of Biomass-Derived Furans for Catalytic Production of Renewable p -Xylene
journal, April 2012

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journal, December 2012

Die Schiefergasrevolution: eine Chance zur Herstellung von Chemikalien auf Biobasis?
journal, October 2013

Halogen-free acylation of toluene over FeSBA-1 molecular sieves
journal, March 2007

Green and sustainable manufacture of chemicals from biomass: state of the art
journal, January 2014

Reactions of aromatic and heteroaromatic compounds bearing electron-acceptor substituents: X. Alkylation and acylation of furfural
journal, May 1972

Friedel-Crafts Acylation of Aromatic Hydrocarbons Using Zeolites
journal, March 1997

Production of renewable p -xylene from 2,5-dimethylfuran via Diels–Alder cycloaddition and dehydrative aromatization reactions over silica−alumina aerogel catalysts
journal, October 2015

Acylation of Toluene with Acetic Anhydride over Beta Zeolites: Influence of Reaction Conditions and Physicochemical Properties of the Catalyst
journal, October 2000

Selective Production of Aromatics from Alkylfurans over Solid Acid Catalysts
journal, January 2013

Ultra-selective cycloaddition of dimethylfuran for renewable p-xylene with H-BEA
journal, January 2014

Fast Pyrolysis of Forestry Residue. 2. Physicochemical Composition of Product Liquid
journal, March 2003

Acylation of aromatic compounds on H-Beta zeolites
journal, February 1999

Methods to delay deactivation of zeolites on furan acylation: continuous liquid-phase technology and solvent effects
journal, January 2015