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Title: Vacancy-induced dislocations within grains for high-performance PbSe thermoelectrics

Authors:
; ; ; ; ; ; ; ;
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Solid-State Solar-Thermal Energy Conversion Center (S3TEC)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1388460
DOE Contract Number:  
SC0001299; FG02-09ER46577
Resource Type:
Journal Article
Journal Name:
Nature Communications
Additional Journal Information:
Journal Volume: 8; Related Information: S3TEC partners with Massachusetts Institute of Technology (lead); Boston College; Oak Ridge National Laboratory; Rensselaer Polytechnic Institute; Journal ID: ISSN 2041-1723
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English
Subject:
solar (photovoltaic), solar (thermal), solid state lighting, phonons, thermal conductivity, thermoelectric, defects, mechanical behavior, charge transport, spin dynamics, materials and chemistry by design, optics, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing)

Citation Formats

Chen, Zhiwei, Ge, Binghui, Li, Wen, Lin, Siqi, Shen, Jiawen, Chang, Yunjie, Hanus, Riley, Snyder, G. Jeffrey, and Pei, Yanzhong. Vacancy-induced dislocations within grains for high-performance PbSe thermoelectrics. United States: N. p., 2017. Web. doi:10.1038/ncomms13828.
Chen, Zhiwei, Ge, Binghui, Li, Wen, Lin, Siqi, Shen, Jiawen, Chang, Yunjie, Hanus, Riley, Snyder, G. Jeffrey, & Pei, Yanzhong. Vacancy-induced dislocations within grains for high-performance PbSe thermoelectrics. United States. doi:10.1038/ncomms13828.
Chen, Zhiwei, Ge, Binghui, Li, Wen, Lin, Siqi, Shen, Jiawen, Chang, Yunjie, Hanus, Riley, Snyder, G. Jeffrey, and Pei, Yanzhong. Wed . "Vacancy-induced dislocations within grains for high-performance PbSe thermoelectrics". United States. doi:10.1038/ncomms13828.
@article{osti_1388460,
title = {Vacancy-induced dislocations within grains for high-performance PbSe thermoelectrics},
author = {Chen, Zhiwei and Ge, Binghui and Li, Wen and Lin, Siqi and Shen, Jiawen and Chang, Yunjie and Hanus, Riley and Snyder, G. Jeffrey and Pei, Yanzhong},
abstractNote = {},
doi = {10.1038/ncomms13828},
journal = {Nature Communications},
issn = {2041-1723},
number = ,
volume = 8,
place = {United States},
year = {2017},
month = {1}
}

Works referenced in this record:

Thermopower enhancement in Pb1−xMnxTe alloys and its effect on thermoelectric efficiency
journal, September 2012

  • Pei, Yanzhong; Wang, Heng; Gibbs, Zachary M.
  • NPG Asia Materials, Vol. 4, Issue 9
  • DOI: 10.1038/am.2012.52

Formation of Vacancy-Impurity Complexes by Kinetic Processes in Highly As-Doped Si
journal, February 2002


Microstructure-Lattice Thermal Conductivity Correlation in Nanostructured PbTe 0.7 S 0.3 Thermoelectric Materials
journal, March 2010

  • He, Jiaqing; Girard, Steven N.; Kanatzidis, Mercouri G.
  • Advanced Functional Materials, Vol. 20, Issue 5
  • DOI: 10.1002/adfm.200901905

Low effective mass leading to high thermoelectric performance
journal, January 2012

  • Pei, Yanzhong; LaLonde, Aaron D.; Wang, Heng
  • Energy & Environmental Science, Vol. 5, Issue 7
  • DOI: 10.1039/c2ee21536e

Beneficial Contribution of Alloy Disorder to Electron and Phonon Transport in Half-Heusler Thermoelectric Materials
journal, April 2013

  • Xie, Hanhui; Wang, Heng; Pei, Yanzhong
  • Advanced Functional Materials, Vol. 23, Issue 41
  • DOI: 10.1002/adfm.201300663

Dislocation loops in quenched aluminium
journal, August 1958


Thermal equilibrium concentrations and effects of negatively charged Ga vacancies in n-type GaAs
journal, March 1993

  • Tan, T. Y.; You, H. -M.; G�sele, U. M.
  • Applied Physics A Solids and Surfaces, Vol. 56, Issue 3
  • DOI: 10.1007/BF00539483

Lattice Thermal Conductivity of Disordered Semiconductor Alloys at High Temperatures
journal, September 1963


Thermodynamische Eigenschaften von IV–VI-Verbindungen: Bleichalkogenide / Thermodynamic Properties of IV–VI-Compounds: Leadchalcogenides
journal, October 1974

  • Blachnik, Roger; Igel, Rudolf
  • Zeitschrift für Naturforschung B, Vol. 29, Issue 9-10
  • DOI: 10.1515/znb-1974-9-1012

Inelastic x-ray scattering measurements of phonon dispersion and lifetimes in PbTe 1− x Se x alloys
journal, September 2015


CXVII. A theory of work-hardening of metal crystals
journal, November 1952

  • Mott, N. F.
  • The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science, Vol. 43, Issue 346
  • DOI: 10.1080/14786441108521024

Dislocation Loop Formation in Nonstoichiometric (Ba,Ca)TiO 3 and BaTiO 3 Ceramics
journal, January 2001


Convergence of electronic bands for high performance bulk thermoelectrics
journal, May 2011

  • Pei, Yanzhong; Shi, Xiaoya; LaLonde, Aaron
  • Nature, Vol. 473, Issue 7345, p. 66-69
  • DOI: 10.1038/nature09996

Mechanisms of dopant impurity diffusion in silicon
journal, September 1989

  • Nichols, C. S.; Van de Walle, C. G.; Pantelides, S. T.
  • Physical Review B, Vol. 40, Issue 8
  • DOI: 10.1103/PhysRevB.40.5484

Lower limit to the thermal conductivity of disordered crystals
journal, September 1992

  • Cahill, David G.; Watson, S. K.; Pohl, R. O.
  • Physical Review B, Vol. 46, Issue 10, p. 6131-6140
  • DOI: 10.1103/PhysRevB.46.6131

Convergence of Conduction Bands as a Means of Enhancing Thermoelectric Performance of n -Type Mg 2 Si 1 x Sn x Solid Solutions
journal, April 2012


High Thermoelectric Performance in PbTe Due to Large Nanoscale Ag2Te Precipitates and La Doping
journal, November 2010

  • Pei, Yanzhong; Lensch-Falk, Jessica; Toberer, Eric S.
  • Advanced Functional Materials, Vol. 21, Issue 2
  • DOI: 10.1002/adfm.201000878

High-performance bulk thermoelectrics with all-scale hierarchical architectures
journal, September 2012

  • Biswas, Kanishka; He, Jiaqing; Blum, Ivan D.
  • Nature, Vol. 489, Issue 7416, p. 414-418
  • DOI: 10.1038/nature11439

High Thermoelectric Figure of Merit in PbTe Alloys Demonstrated in PbTe-CdTe
journal, April 2012

  • Pei, Yanzhong; LaLonde, Aaron D.; Heinz, Nicholas A.
  • Advanced Energy Materials, Vol. 2, Issue 6
  • DOI: 10.1002/aenm.201100770

Purification of tellurium up to 5N by vacuum distillation
journal, July 2005


The role of dislocation scattering in n -type GaN films
journal, August 1998

  • Ng, H. M.; Doppalapudi, D.; Moustakas, T. D.
  • Applied Physics Letters, Vol. 73, Issue 6
  • DOI: 10.1063/1.122012

Phonon conduction in PbSe, PbTe, and PbTe 1 x Se x from first-principles calculations
journal, May 2012


Tellurium as a high-performance elemental thermoelectric
journal, January 2016

  • Lin, Siqi; Li, Wen; Chen, Zhiwei
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms10287

Ultralow thermal conductivity and high thermoelectric figure of merit in SnSe crystals
journal, April 2014

  • Zhao, Li-Dong; Lo, Shih-Han; Zhang, Yongsheng
  • Nature, Vol. 508, Issue 7496, p. 373-377
  • DOI: 10.1038/nature13184

Vacancy phonon scattering in thermoelectric In2Te3–InSb solid solutions
journal, March 2009

  • Pei, Yanzhong; Morelli, Donald T.
  • Applied Physics Letters, Vol. 94, Issue 12
  • DOI: 10.1063/1.3109788

General Theory of Impurity Diffusion in Semiconductors via the Vacancy Mechanism
journal, April 1969


Dislocations and point defects
journal, January 1957


The contrast factors of dislocations in cubic crystals: the dislocation model of strain anisotropy in practice
journal, October 1999

  • Ungár, T.; Dragomir, I.; Révész, Á.
  • Journal of Applied Crystallography, Vol. 32, Issue 5
  • DOI: 10.1107/S0021889899009334

Thermoelectric alloys between PbSe and PbS with effective thermal conductivity reduction and high figure of merit
journal, January 2014

  • Wang, Heng; Wang, Jianli; Cao, Xianlong
  • Journal of Materials Chemistry A, Vol. 2, Issue 9
  • DOI: 10.1039/c3ta14929c

LXXXVII. Theory of dislocations in germanium
journal, August 1954

  • Read, W. T.
  • The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science, Vol. 45, Issue 367
  • DOI: 10.1080/14786440808520491

Charged dislocations in ionic crystals
journal, March 1975


Effects of Dislocations on Mobilities in Semiconductors
journal, June 1952


Weak electron-phonon coupling contributing to high thermoelectric performance in n-type PbSe
journal, May 2012

  • Wang, H.; Pei, Y.; LaLonde, A. D.
  • Proceedings of the National Academy of Sciences, Vol. 109, Issue 25
  • DOI: 10.1073/pnas.1111419109

Effect of Point Imperfections on Lattice Thermal Conductivity
journal, November 1960


Significant band engineering effect of YbTe for high performance thermoelectric PbTe
journal, January 2015

  • Jian, Zhengzhong; Chen, Zhiwei; Li, Wen
  • Journal of Materials Chemistry C, Vol. 3, Issue 48
  • DOI: 10.1039/C5TC03068D

The Scattering of Low-Frequency Lattice Waves by Static Imperfections
journal, December 1955


Stabilizing the Optimal Carrier Concentration for High Thermoelectric Efficiency
journal, November 2011

  • Pei, Yanzhong; LaLonde, Aaron D.; Heinz, Nicholas A.
  • Advanced Materials, Vol. 23, Issue 47
  • DOI: 10.1002/adma.201103153

Arsenic deactivation in Si: Electronic structure and charge states of vacancy-impurity clusters
journal, July 2003


Dense dislocation arrays embedded in grain boundaries for high-performance bulk thermoelectrics
journal, April 2015


Cubic AgPbmSbTe2+m: Bulk Thermoelectric Materials with High Figure of Merit
journal, February 2004


Cooling, Heating, Generating Power, and Recovering Waste Heat with Thermoelectric Systems
journal, September 2008


Intrinsically Minimal Thermal Conductivity in Cubic IVVI2 Semiconductors
journal, July 2008


CXXXIII. Impurity diffusion in crystals (mainly ionic crystals with the sodium chloride structure)
journal, November 1955

  • Lidiard, A. B.
  • The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science, Vol. 46, Issue 382
  • DOI: 10.1080/14786441108520633

Rapid consolidation of powdered materials by induction hot pressing
journal, February 2011

  • LaLonde, Aaron D.; Ikeda, Teruyuki; Snyder, G. Jeffrey
  • Review of Scientific Instruments, Vol. 82, Issue 2
  • DOI: 10.1063/1.3534080

Thermal Conductivity of Selenium and Tellurium Single Crystals and Phonon Drag of Tellurium
journal, January 1967


The Elimination of Vacancy-Cluster Formation in Dislocation-Free Silicon Crystals
journal, January 1971

  • de Kock, A. J. R.
  • Journal of The Electrochemical Society, Vol. 118, Issue 11
  • DOI: 10.1149/1.2407850

A Calculation of the Changes in the Conductivity of Metals Produced by Cold-Work
journal, January 1949


Dislocation Multiplication in Lithium Fluoride Crystals
journal, April 1960

  • Johnston, W. G.; Gilman, J. J.
  • Journal of Applied Physics, Vol. 31, Issue 4
  • DOI: 10.1063/1.1735655

Apparatus for Seebeck coefficient and electrical resistivity measurements of bulk thermoelectric materials at high temperature
journal, February 2005

  • Zhou, Zhenhua; Uher, Ctirad
  • Review of Scientific Instruments, Vol. 76, Issue 2
  • DOI: 10.1063/1.1835631

High-Thermoelectric Performance of Nanostructured Bismuth Antimony Telluride Bulk Alloys
journal, May 2008


Some Electrical and Optical Effects of Dislocations in Semiconductors
journal, October 1967

  • Meyer, M.; Miles, M. H.; Ninomiya, T.
  • Journal of Applied Physics, Vol. 38, Issue 11
  • DOI: 10.1063/1.1709153

Theory of Dislocations (2nd ed.)
journal, June 1983

  • Hirth, J. P.; Lothe, J.; Mura, T.
  • Journal of Applied Mechanics, Vol. 50, Issue 2
  • DOI: 10.1115/1.3167075

Contrasting role of antimony and bismuth dopants on the thermoelectric performance of lead selenide
journal, May 2014

  • Lee, Yeseul; Lo, Shih-Han; Chen, Changqiang
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms4640

    Works referencing / citing this record:

    Chalcogenide Thermoelectrics Empowered by an Unconventional Bonding Mechanism
    journal, August 2019

    • Yu, Yuan; Cagnoni, Matteo; Cojocaru‐Mirédin, Oana
    • Advanced Functional Materials
    • DOI: 10.1002/adfm.201904862

    Extraordinary n‐Type Mg 3 SbBi Thermoelectrics Enabled by Yttrium Doping
    journal, June 2019

    • Shi, Xuemin; Zhao, Tingting; Zhang, Xinyue
    • Advanced Materials, Vol. 31, Issue 36
    • DOI: 10.1002/adma.201903387