Continuous injection synthesis of indium arsenide quantum dots emissive in the short-wavelength infrared

Franke, Daniel; Harris, Daniel K.; Chen, Ou; Bruns, Oliver T.; Carr, Jessica A.; Wilson, Mark W.  B.; Bawendi, Moungi G.

doi:10.1038/ncomms12749

Title: Continuous injection synthesis of indium arsenide quantum dots emissive in the short-wavelength infrared

Journal Article · Fri Nov 11 00:00:00 EST 2016 · Nature Communications

DOI:https://doi.org/10.1038/ncomms12749· OSTI ID:1388331

Franke, Daniel ^[1]; Harris, Daniel K. ^[1]; Chen, Ou ^[1];

^[1];

^[1]; Wilson, Mark W. B. ^[1]; Bawendi, Moungi G. ^[1]

Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Dept. of Chemistry

With the emergence of applications based on short-wavelength infrared light, indium arsenide quantum dots are promising candidates to address existing shortcomings of other infrared-emissive nanomaterials. However, III–V quantum dots have historically struggled to match the high-quality optical properties of II–VI quantum dots. Here we present an extensive investigation of the kinetics that govern indium arsenide nanocrystal growth. Based on these insights, we design a synthesis of large indium arsenide quantum dots with narrow emission linewidths. We further synthesize indium arsenide-based core-shell-shell nanocrystals with quantum yields up to 82% and improved photo- and long-term storage stability. We then demonstrate non-invasive through-skull fluorescence imaging of the brain vasculature of murine models, and show that our probes exhibit 2–3 orders of magnitude higher quantum yields than commonly employed infrared emitters across the entire infrared camera sensitivity range. Finally, we anticipate that these probes will not only enable new biomedical imaging applications, but also improved infrared nanocrystal-LEDs and photon-upconversion technology.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Excitonics (CE)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0001088

OSTI ID:: 1388331

Journal Information:: Nature Communications, Vol. 7; Related Information: CE partners with Massachusetts Institute of Technology (lead); Brookhaven National Laboratory; Harvard University; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 164 works

Citation information provided by
Web of Science

References (52)

Colloidal Quantum Dot Solar Cells Carey, Graham H.; Abdelhady, Ahmed L.; Ning, Zhijun Chemical Reviews, Vol. 115, Issue 23 https://doi.org/10.1021/acs.chemrev.5b00063	journal	June 2015
Solution-processed PbS quantum dot infrared photodetectors and photovoltaics McDonald, Steven A.; Konstantatos, Gerasimos; Zhang, Shiguo Nature Materials, Vol. 4, Issue 2 https://doi.org/10.1038/nmat1299	journal	January 2005
Absorption Cross-Section and Related Optical Properties of Colloidal InAs Quantum Dots Yu, Pingrong; Beard, Matthew C.; Ellingson, Randy J. The Journal of Physical Chemistry B, Vol. 109, Issue 15 https://doi.org/10.1021/jp046127i	journal	April 2005
Improved Precursor Chemistry for the Synthesis of III–V Quantum Dots Harris, Daniel K.; Bawendi, Moungi G. Journal of the American Chemical Society, Vol. 134, Issue 50 https://doi.org/10.1021/ja309863n	journal	December 2012
Colloidal chemical synthesis and characterization of InAs nanocrystal quantum dots Guzelian, A. A.; Banin, U.; Kadavanich, A. V. Applied Physics Letters, Vol. 69, Issue 10 https://doi.org/10.1063/1.117605	journal	September 1996
Epitaxial Seeded Growth of Rare-Earth Nanocrystals with Efficient 800 nm Near-Infrared to 1525 nm Short-Wavelength Infrared Downconversion Photoluminescence for In Vivo Bioimaging Wang, Rui; Li, Xiaomin; Zhou, Lei Angewandte Chemie International Edition, Vol. 53, Issue 45 https://doi.org/10.1002/anie.201407420	journal	September 2014
All-Quantum-Dot Infrared Light-Emitting Diodes Yang, Zhenyu; Voznyy, Oleksandr; Liu, Mengxia ACS Nano, Vol. 9, Issue 12 https://doi.org/10.1021/acsnano.5b05617	journal	October 2015
Epitaxial Growth of Highly Luminescent CdSe/CdS Core/Shell Nanocrystals with Photostability and Electronic Accessibility Peng, Xiaogang; Schlamp, Michael C.; Kadavanich, Andreas V. Journal of the American Chemical Society, Vol. 119, Issue 30, p. 7019-7029 https://doi.org/10.1021/ja970754m	journal	July 1997
Measurement of Emission Lifetime Dynamics and Biexciton Emission Quantum Yield of Individual InAs Colloidal Nanocrystals Bischof, Thomas S.; Correa, Raoul E.; Rosenberg, Danna Nano Letters, Vol. 14, Issue 12 https://doi.org/10.1021/nl502180w	journal	November 2014
Carbon nanotubes as in vivo bacterial probes Bardhan, Neelkanth M.; Ghosh, Debadyuti; Belcher, Angela M. Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5918	journal	September 2014
Selection of Quantum Dot Wavelengths for Biomedical Assays and Imaging Lim, Yong Taik; Kim, Sungjee; Nakayama, Akira Molecular Imaging, Vol. 2, Issue 1 https://doi.org/10.1162/153535003765276282	journal	January 2003
Absolute Photoluminescence Quantum Yields of IR-26 Dye, PbS, and PbSe Quantum Dots Semonin, Octavi E.; Johnson, Justin C.; Luther, Joseph M. The Journal of Physical Chemistry Letters, Vol. 1, Issue 16 https://doi.org/10.1021/jz100830r	journal	July 2010
Fluorescence Imaging In Vivo at Wavelengths beyond 1500 nm Diao, Shuo; Blackburn, Jeffrey L.; Hong, Guosong Angewandte Chemie International Edition, Vol. 54, Issue 49 https://doi.org/10.1002/anie.201507473	journal	October 2015
Insights into the Kinetics of Semiconductor Nanocrystal Nucleation and Growth Rempel, Jane Y.; Bawendi, Moungi G.; Jensen, Klavs F. Journal of the American Chemical Society, Vol. 131, Issue 12 https://doi.org/10.1021/ja809156t	journal	April 2009
Kinetics of II-VI and III-V Colloidal Semiconductor Nanocrystal Growth: “Focusing” of Size Distributions Peng, Xiaogang; Wickham, J.; Alivisatos, A. P. Journal of the American Chemical Society, Vol. 120, Issue 21 https://doi.org/10.1021/ja9805425	journal	June 1998
Synthetic Scheme for High-Quality InAs Nanocrystals Based on Self-Focusing and One-Pot Synthesis of InAs-Based Core-Shell Nanocrystals Xie, Renguo; Peng, Xiaogang Angewandte Chemie, Vol. 120, Issue 40 https://doi.org/10.1002/ange.200802867	journal	September 2008
Solid-state infrared-to-visible upconversion sensitized by colloidal nanocrystals Wu, Mengfei; Congreve, Daniel N.; Wilson, Mark W. B. Nature Photonics, Vol. 10, Issue 1 https://doi.org/10.1038/nphoton.2015.226	journal	November 2015
Rare-earth-doped biological composites as in vivo shortwave infrared reporters Naczynski, D. J.; Tan, M. C.; Zevon, M. Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3199	journal	July 2013
Ag ₂ S Quantum Dot: A Bright and Biocompatible Fluorescent Nanoprobe in the Second Near-Infrared Window Zhang, Yan; Hong, Guosong; Zhang, Yejun ACS Nano, Vol. 6, Issue 5 https://doi.org/10.1021/nn301218z	journal	April 2012
Tuning the Postfocused Size of Colloidal Nanocrystals by the Reaction Rate: From Theory to Application Abe, Sofie; Čapek, Richard Karel; De Geyter, Bram ACS Nano, Vol. 6, Issue 1 https://doi.org/10.1021/nn204008q	journal	December 2011
Nucleation and Growth of CdSe Nanocrystals in a Binary Ligand System ^† van Embden, Joel; Mulvaney, Paul Langmuir, Vol. 21, Issue 22 https://doi.org/10.1021/la051081l	journal	October 2005
Synthesis of InAs/CdSe/ZnSe Core/Shell1/Shell2 Structures with Bright and Stable Near-Infrared Fluorescence Aharoni, Assaf; Mokari, Taleb; Popov, Inna Journal of the American Chemical Society, Vol. 128, Issue 1 https://doi.org/10.1021/ja056326v	journal	January 2006
The Unexpected Influence of Precursor Conversion Rate in the Synthesis of III-V Quantum Dots Franke, Daniel; Harris, Daniel K.; Xie, Lisi Angewandte Chemie International Edition, Vol. 54, Issue 48 https://doi.org/10.1002/anie.201505972	journal	October 2015
Through-skull fluorescence imaging of the brain in a new near-infrared window Hong, Guosong; Diao, Shuo; Chang, Junlei Nature Photonics, Vol. 8, Issue 9 https://doi.org/10.1038/nphoton.2014.166	journal	August 2014
InAs(ZnCdS) Quantum Dots Optimized for Biological Imaging in the Near-Infrared Allen, Peter M.; Liu, Wenhao; Chauhan, Vikash P. Journal of the American Chemical Society, Vol. 132, Issue 2 https://doi.org/10.1021/ja908250r	journal	January 2010
Synthesis of Cadmium Arsenide Quantum Dots Luminescent in the Infrared Harris, Daniel K.; Allen, Peter M.; Han, Hee-Sun Journal of the American Chemical Society, Vol. 133, Issue 13 https://doi.org/10.1021/ja1101932	journal	April 2011
Mechanistic Insights into the Formation of InP Quantum Dots Allen, Peter M.; Walker, Brian J.; Bawendi, Moungi G. Angewandte Chemie International Edition, Vol. 49, Issue 4 https://doi.org/10.1002/anie.200905632	journal	December 2009
Facile synthesis of uniform large-sized InP nanocrystal quantum dots using tris(tert-butyldimethylsilyl)phosphine Joung, SoMyoung; Yoon, Sungwoo; Han, Chang-Soo Nanoscale Research Letters, Vol. 7, Issue 1 https://doi.org/10.1186/1556-276X-7-93	journal	January 2012
Dynamic Distribution of Growth Rates within the Ensembles of Colloidal II−VI and III−V Semiconductor Nanocrystals as a Factor Governing Their Photoluminescence Efficiency Talapin, Dmitri V.; Rogach, Andrey L.; Shevchenko, Elena V. Journal of the American Chemical Society, Vol. 124, Issue 20 https://doi.org/10.1021/ja0123599	journal	May 2002
PbS/CdS/ZnS Quantum Dots: A Multifunctional Platform for In Vivo Near-Infrared Low-Dose Fluorescence Imaging Benayas, Antonio; Ren, Fuqiang; Carrasco, Elisa Advanced Functional Materials, Vol. 25, Issue 42 https://doi.org/10.1002/adfm.201502632	journal	October 2015
A tunable library of substituted thiourea precursors to metal sulfide nanocrystals Hendricks, M. P.; Campos, M. P.; Cleveland, G. T. Science, Vol. 348, Issue 6240 https://doi.org/10.1126/science.aaa2951	journal	June 2015
Deep, noninvasive imaging and surgical guidance of submillimeter tumors using targeted M13-stabilized single-walled carbon nanotubes Ghosh, D.; Bagley, A. F.; Na, Y. J. Proceedings of the National Academy of Sciences, Vol. 111, Issue 38 https://doi.org/10.1073/pnas.1400821111	journal	September 2014
Core/Shell Semiconductor Nanocrystals Reiss, Peter; Protière, Myriam; Li, Liang Small, Vol. 5, Issue 2 https://doi.org/10.1002/smll.200800841	journal	January 2009
Synthesis of size-controlled colloidal InAs quantum dots using triphenylarsine as a stable arsenic source Uesugi, Hideo; Kita, Masao; Omata, Takahisa Journal of Crystal Growth, Vol. 416 https://doi.org/10.1016/j.jcrysgro.2015.01.031	journal	April 2015
Formation of High Quality InP and InAs Nanocrystals in a Noncoordinating Solvent Battaglia, David; Peng, Xiaogang Nano Letters, Vol. 2, Issue 9 https://doi.org/10.1021/nl025687v	journal	September 2002
Synthesis and Characterization of Strongly Luminescing ZnS-Capped CdSe Nanocrystals Hines, Margaret A.; Guyot-Sionnest, Philippe The Journal of Physical Chemistry, Vol. 100, Issue 2, p. 468-471 https://doi.org/10.1021/jp9530562	journal	January 1996
Precursor Conversion Kinetics and the Nucleation of Cadmium Selenide Nanocrystals Owen, Jonathan S.; Chan, Emory M.; Liu, Haitao Journal of the American Chemical Society, Vol. 132, Issue 51 https://doi.org/10.1021/ja106777j	journal	December 2010
Inverted Core/Shell Nanocrystals Continuously Tunable between Type-I and Type-II Localization Regimes Balet, L. P.; Ivanov, S. A.; Piryatinski, A. Nano Letters, Vol. 4, Issue 8 https://doi.org/10.1021/nl049146c	journal	August 2004
Type-II Quantum Dots: CdTe/CdSe(Core/Shell) and CdSe/ZnTe(Core/Shell) Heterostructures Kim, Sungjee; Fisher, Brent; Eisler, Hans-Jürgen Journal of the American Chemical Society, Vol. 125, Issue 38, p. 11466-11467 https://doi.org/10.1021/ja0361749	journal	September 2003
Covalency in semiconductor quantum dots R. Heath, James Chemical Society Reviews, Vol. 27, Issue 1 https://doi.org/10.1039/a827065z	journal	January 1998
Multifunctional in vivo vascular imaging using near-infrared II fluorescence Hong, Guosong; Lee, Jerry C.; Robinson, Joshua T. Nature Medicine, Vol. 18, Issue 12 https://doi.org/10.1038/nm.2995	journal	November 2012
In Vivo Imaging of Quantum Dots Encapsulated in Phospholipid Micelles Dubertret, B. Science, Vol. 298, Issue 5599 https://doi.org/10.1126/science.1077194	journal	November 2002
Investigation of Indium Phosphide Quantum Dot Nucleation and Growth Utilizing Triarylsilylphosphine Precursors Gary, Dylan C.; Glassy, Benjamin A.; Cossairt, Brandi M. Chemistry of Materials, Vol. 26, Issue 4 https://doi.org/10.1021/cm500102q	journal	February 2014
Calculated natural band offsets of all II–VI and III–V semiconductors: Chemical trends and the role of cation d orbitals Wei, Su-Huai; Zunger, Alex Applied Physics Letters, Vol. 72, Issue 16 https://doi.org/10.1063/1.121249	journal	April 1998
Epitaxial Seeded Growth of Rare-Earth Nanocrystals with Efficient 800 nm Near-Infrared to 1525 nm Short-Wavelength Infrared Downconversion Photoluminescence for In Vivo Bioimaging Wang, Rui; Li, Xiaomin; Zhou, Lei Angewandte Chemie, Vol. 126, Issue 45 https://doi.org/10.1002/ange.201407420	journal	September 2014
Selection of Quantum Dot Wavelengths for Biomedical Assays and Imaging Lim, Yong Taik; Kim, Sungjee; Nakayama, Akira Molecular Imaging, Vol. 2, Issue 1 https://doi.org/10.1162/15353500200302163	journal	January 2003
The Unexpected Influence of Precursor Conversion Rate in the Synthesis of III-V Quantum Dots Franke, Daniel; Harris, Daniel K.; Xie, Lisi Angewandte Chemie, Vol. 127, Issue 48 https://doi.org/10.1002/ange.201505972	journal	October 2015
Fluorescence Imaging In Vivo at Wavelengths beyond 1500 nm Diao, Shuo; Blackburn, Jeffrey L.; Hong, Guosong Angewandte Chemie, Vol. 127, Issue 49 https://doi.org/10.1002/ange.201507473	journal	October 2015
Mechanistic Insights into the Formation of InP Quantum Dots Allen, Peter M.; Walker, Brian J.; Bawendi, Moungi G. Angewandte Chemie, Vol. 122, Issue 4 https://doi.org/10.1002/ange.200905632	journal	December 2009
Through Skull Fluorescence Imaging of the Brain in a New Near-Infrared Window Hong, Guosong; Diao, Shuo; Chang, Junlei arXiv https://doi.org/10.48550/arxiv.1408.1719	text	January 2014
Review of short-wave infrared spectroscopy and imaging methods for biological tissue characterization Wilson, Robert H.; Nadeau, Kyle P.; Jaworski, Frank B. Journal of Biomedical Optics, Vol. 20, Issue 3 https://doi.org/10.1117/1.jbo.20.3.030901	journal	March 2015
Multifunctional in vivo vascular imaging using near-infrared II fluorescence Hong, Guosong; Lee, Jerry C.; Robinson, Joshua T. arXiv https://doi.org/10.48550/arxiv.1211.4269	text	January 2012

Cited By (38)

Near-Infrared IIb Fluorescence Imaging of Vascular Regeneration with Dynamic Tissue Perfusion Measurement and High Spatial Resolution Ma, Zhuoran; Zhang, Mingxi; Yue, Jingying Advanced Functional Materials, Vol. 28, Issue 36 https://doi.org/10.1002/adfm.201803417	journal	July 2018
Molecular Imaging in the Second Near‐Infrared Window Wan, Hao; Du, Haotian; Wang, Feifei Advanced Functional Materials, Vol. 29, Issue 25 https://doi.org/10.1002/adfm.201900566	journal	April 2019
Efficient Near‐Infrared Light‐Emitting Diodes based on In(Zn)As–In(Zn)P–GaP–ZnS Quantum Dots Wijaya, Hadhi; Darwan, Daryl; Zhao, Xiaofei Advanced Functional Materials, Vol. 30, Issue 4 https://doi.org/10.1002/adfm.201906483	journal	November 2019
3D NIR‐II Molecular Imaging Distinguishes Targeted Organs with High‐Performance NIR‐II Bioconjugates Zhu, Shoujun; Herraiz, Sonia; Yue, Jingying Advanced Materials, Vol. 30, Issue 13 https://doi.org/10.1002/adma.201705799	journal	February 2018
Repurposing Cyanine NIR-I Dyes Accelerates Clinical Translation of Near-Infrared-II (NIR-II) Bioimaging Zhu, Shoujun; Hu, Zhubin; Tian, Rui Advanced Materials, Vol. 30, Issue 34 https://doi.org/10.1002/adma.201802546	journal	July 2018
Near‐Infrared‐II Molecular Dyes for Cancer Imaging and Surgery Zhu, Shoujun; Tian, Rui; Antaris, Alexander L. Advanced Materials https://doi.org/10.1002/adma.201900321	journal	April 2019
Atomic‐Precision Gold Clusters for NIR‐II Imaging Liu, Haile; Hong, Guosong; Luo, Zhentao Advanced Materials, Vol. 31, Issue 46 https://doi.org/10.1002/adma.201901015	journal	September 2019
Multiplexed NIR‐II Probes for Lymph Node‐Invaded Cancer Detection and Imaging‐Guided Surgery Tian, Rui; Ma, Huilong; Zhu, Shoujun Advanced Materials, Vol. 32, Issue 11 https://doi.org/10.1002/adma.201907365	journal	February 2020
Advanced NIR‐II Fluorescence Imaging Technology for In Vivo Precision Tumor Theranostics Li, Chunyan; Wang, Qiangbin Advanced Therapeutics, Vol. 2, Issue 9 https://doi.org/10.1002/adtp.201900053	journal	May 2019
Visualizing the Fate of Intra‐Articular Injected Mesenchymal Stem Cells In Vivo in the Second Near‐Infrared Window for the Effective Treatment of Supraspinatus Tendon Tears Yang, Yimeng; Chen, Jun; Shang, Xiliang Advanced Science, Vol. 6, Issue 19 https://doi.org/10.1002/advs.201901018	journal	August 2019
Multistage Microfluidic Platform for the Continuous Synthesis of III-V Core/Shell Quantum Dots Baek, Jinyoung; Shen, Yi; Lignos, Ioannis Angewandte Chemie, Vol. 130, Issue 34 https://doi.org/10.1002/ange.201805264	journal	July 2018
A Ligand System for the Flexible Functionalization of Quantum Dots via Click Chemistry Chen, Yue; Cordero, Jose M.; Wang, Hua Angewandte Chemie International Edition, Vol. 57, Issue 17 https://doi.org/10.1002/anie.201801113	journal	March 2018
Optical windows for head tissues in near-infrared and short-wave infrared regions: Approaching transcranial light applications Golovynskyi, Sergii; Golovynska, Iuliia; Stepanova, Ludmila I. Journal of Biophotonics, Vol. 11, Issue 12 https://doi.org/10.1002/jbio.201800141	journal	September 2018
Synthesis of NIR-Emitting InAs-Based Core/Shell Quantum Dots with the Use of Tripyrazolylarsane as Arsenic Precursor Tietze, Remo; Panzer, René; Starzynski, Thorben Particle & Particle Systems Characterization, Vol. 35, Issue 9 https://doi.org/10.1002/ppsc.201800175	journal	July 2018
Advances in nanomaterials for brain microscopy Del Bonis-O’Donnell, Jackson T.; Chio, Linda; Dorlhiac, Gabriel F. Nano Research, Vol. 11, Issue 10 https://doi.org/10.1007/s12274-018-2145-2	journal	August 2018
A Review on Eco-Friendly Quantum Dot Solar Cells: Materials and Manufacturing Processes Choi, Hyekyoung; Jeong, Sohee International Journal of Precision Engineering and Manufacturing-Green Technology, Vol. 5, Issue 2 https://doi.org/10.1007/s40684-018-0037-2	journal	April 2018
A bright future for colloidal quantum dot lasers Geiregat, Pieter; Van Thourhout, Dries; Hens, Zeger NPG Asia Materials, Vol. 11, Issue 1 https://doi.org/10.1038/s41427-019-0141-y	journal	August 2019
Boosting the down-shifting luminescence of rare-earth nanocrystals for biological imaging beyond 1500 nm Zhong, Yeteng; Ma, Zhuoran; Zhu, Shoujun Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00917-6	journal	September 2017
Next-generation in vivo optical imaging with short-wave infrared quantum dots Bruns, Oliver T.; Bischof, Thomas S.; Harris, Daniel K. Nature Biomedical Engineering, Vol. 1, Issue 4 https://doi.org/10.1038/s41551-017-0056	journal	April 2017
In vivo molecular imaging for immunotherapy using ultra-bright near-infrared-IIb rare-earth nanoparticles Zhong, Yeteng; Ma, Zhuoran; Wang, Feifei Nature Biotechnology, Vol. 37, Issue 11 https://doi.org/10.1038/s41587-019-0262-4	journal	September 2019
Gd-DTPA-coupled Ag ₂ Se quantum dots for dual-modality magnetic resonance imaging and fluorescence imaging in the second near-infrared window Ma, Jiao-Jiao; Yu, Ming-Xia; Zhang, Zheng Nanoscale, Vol. 10, Issue 22 https://doi.org/10.1039/c8nr02017e	journal	January 2018
Selective antimony reduction initiating the nucleation and growth of InSb quantum dots Crisp, Ryan W.; Grimaldi, Gianluca; De Trizio, Luca Nanoscale, Vol. 10, Issue 23 https://doi.org/10.1039/c8nr02381f	journal	January 2018
Rational design of a super-contrast NIR-II fluorophore affords high-performance NIR-II molecular imaging guided microsurgery Tian, Rui; Ma, Huilong; Yang, Qinglai Chemical Science, Vol. 10, Issue 1 https://doi.org/10.1039/c8sc03751e	journal	January 2019
Towards the commercialization of colloidal quantum dot solar cells: perspectives on device structures and manufacturing Lee, Hyunho; Song, Hyung-Jun; Shim, Moonsub Energy & Environmental Science, Vol. 13, Issue 2 https://doi.org/10.1039/c9ee03348c	journal	January 2020
High photoluminescence of shortwave infrared-emitting anisotropic surface charged gold nanoclusters Musnier, Benjamin; Wegner, K. David; Comby-Zerbino, Clothilde Nanoscale, Vol. 11, Issue 25 https://doi.org/10.1039/c9nr04120f	journal	January 2019
Shortwave infrared fluorescence imaging with the clinically approved near-infrared dye indocyanine green Carr, Jessica A.; Franke, Daniel; Caram, Justin R. Proceedings of the National Academy of Sciences, Vol. 115, Issue 17 https://doi.org/10.1073/pnas.1718917115	journal	April 2018
Absorption by water increases fluorescence image contrast of biological tissue in the shortwave infrared Carr, Jessica A.; Aellen, Marianne; Franke, Daniel Proceedings of the National Academy of Sciences, Vol. 115, Issue 37 https://doi.org/10.1073/pnas.1803210115	journal	August 2018
Bright quantum dots emitting at ∼1,600 nm in the NIR-IIb window for deep tissue fluorescence imaging Zhang, Mingxi; Yue, Jingying; Cui, Ran Proceedings of the National Academy of Sciences, Vol. 115, Issue 26 https://doi.org/10.1073/pnas.1806153115	journal	June 2018
Recent advances of lanthanide-doped upconversion nanoparticles for biological applications Li, Hui; Wang, Xin; Huang, Dingxin Nanotechnology, Vol. 31, Issue 7 https://doi.org/10.1088/1361-6528/ab4f36	journal	November 2019
Excitons in InP, GaP, and ${Ga}_{x} {In}_{1 - x} P$ quantum dots: Insights from time-dependent density functional theory Ma, Xiaoyu; Min, Jingjing; Zeng, Zaiping Physical Review B, Vol. 100, Issue 24 https://doi.org/10.1103/physrevb.100.245404	journal	December 2019
Optical fluorescence imaging with shortwave infrared light emitter nanomaterials for in vivo cell tracking in regenerative medicine Fath‐Bayati, Leyla; Vasei, Mohammad; Sharif‐Paghaleh, Ehsan Journal of Cellular and Molecular Medicine, Vol. 23, Issue 12 https://doi.org/10.1111/jcmm.14670	journal	September 2019
Rare-Earth-Doped Nanoparticles for Short-Wave Infrared Fluorescence Bioimaging and Molecular Targeting of α _V β ₃ -Expressing Tumors Naczynski, Dominik Jan; Stafford, Jason H.; Türkcan, Silvan Molecular Imaging, Vol. 17 https://doi.org/10.1177/1536012118799131	journal	January 2018
Multistage Microfluidic Platform for the Continuous Synthesis of III-V Core/Shell Quantum Dots Baek, Jinyoung; Shen, Yi; Lignos, Ioannis Angewandte Chemie International Edition, Vol. 57, Issue 34 https://doi.org/10.1002/anie.201805264	journal	July 2018
A Ligand System for the Flexible Functionalization of Quantum Dots via Click Chemistry Chen, Yue; Cordero, Jose M.; Wang, Hua Angewandte Chemie, Vol. 130, Issue 17 https://doi.org/10.1002/ange.201801113	journal	March 2018
Excitons in InP, GaP, GaInP quantum dots: Insights from time-dependent density functional theory Ma, Xiaoyu; Min, Jingjing; Zeng, Zaiping arXiv https://doi.org/10.48550/arxiv.1908.09430	text	January 2019
The Many “Facets” of Halide Ions in the Chemistry of Colloidal Inorganic Nanocrystals Ghosh, Sandeep; Manna, Liberato Chemical Reviews, Vol. 118, Issue 16 https://doi.org/10.1021/acs.chemrev.8b00158	journal	July 2018
Design of AIEgens for near-infrared IIb imaging through structural modulation at molecular and morphological levels Li, Yuanyuan; Cai, Zhaochong; Liu, Shunjie Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-15095-1	journal	March 2020
Road Map for Nanocrystal Based Infrared Photodetectors Livache, Clément; Martinez, Bertille; Goubet, Nicolas Frontiers in Chemistry, Vol. 6 https://doi.org/10.3389/fchem.2018.00575	journal	November 2018

Similar Records

Next-generation in vivo optical imaging with short-wave infrared quantum dots

Journal Article · Mon Apr 10 00:00:00 EDT 2017 · Nature Biomedical Engineering (Online) · OSTI ID:1388331

Bruns, Oliver T.; Bischof, Thomas S.; Harris, Daniel K.; +21 more

Single Nanocrystal Spectroscopy of Shortwave Infrared Emitters

Journal Article · Fri Nov 30 00:00:00 EST 2018 · ACS Nano · OSTI ID:1388331

Bertram, Sophie N.; Spokoyny, Boris; Franke, Daniel; +5 more

Effect of indium alloying on the charge carrier dynamics of thick-shell InP/ZnSe quantum dots

Journal Article · Tue Apr 28 00:00:00 EDT 2020 · Journal of Chemical Physics · OSTI ID:1388331

Freymeyer, Nathaniel J.; Click, Sophia M.; Reid, Kemar R.; +4 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
solar (photovoltaic)
solid state lighting
photosynthesis (natural and artificial)
charge transport
optics
synthesis (novel materials)
synthesis (self-assembly)
synthesis (scalable processing)

Title: Continuous injection synthesis of indium arsenide quantum dots emissive in the short-wavelength infrared

Citation Formats

References (52)

Cited By (38)

Similar Records

Related Subjects