skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Fluoropolymer-Stabilized Chromophore-Catalyst Assemblies in Aqueous Buffer Solutions for Water-Oxidation Catalysis

Authors:
ORCiD logo [1];  [2];  [1];  [1];  [1];  [1];  [1]
  1. Department of Chemistry, University of North Carolina at Chapel Hill, CB 3290, Chapel Hill North Carolina 27599 USA
  2. Department of Chemistry, Daegu University, Gyeongsan 712-714 Republic of Korea
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for Solar Fuels (UNC EFRC)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1388129
DOE Contract Number:  
SC0001011
Resource Type:
Journal Article
Journal Name:
ChemSusChem
Additional Journal Information:
Journal Volume: 10; Journal Issue: 11; Related Information: UNC partners with University of North Carolina (lead); Duke University; University of Florida; Georgia Institute of Technology; University; North Carolina Central University; Research Triangle Institute; Journal ID: ISSN 1864-5631
Publisher:
ChemPubSoc Europe
Country of Publication:
United States
Language:
English
Subject:
catalysis (homogeneous), catalysis (heterogeneous), solar (photovoltaic), solar (fuels), photosynthesis (natural and artificial), hydrogen and fuel cells, electrodes - solar, charge transport, materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly)

Citation Formats

Eberhart, Michael S., Wee, Kyung-Ryang, Marquard, Seth, Skinner, Kasey, Wang, Degao, Nayak, Animesh, and Meyer, Thomas J. Fluoropolymer-Stabilized Chromophore-Catalyst Assemblies in Aqueous Buffer Solutions for Water-Oxidation Catalysis. United States: N. p., 2017. Web. doi:10.1002/cssc.201700630.
Eberhart, Michael S., Wee, Kyung-Ryang, Marquard, Seth, Skinner, Kasey, Wang, Degao, Nayak, Animesh, & Meyer, Thomas J. Fluoropolymer-Stabilized Chromophore-Catalyst Assemblies in Aqueous Buffer Solutions for Water-Oxidation Catalysis. United States. doi:10.1002/cssc.201700630.
Eberhart, Michael S., Wee, Kyung-Ryang, Marquard, Seth, Skinner, Kasey, Wang, Degao, Nayak, Animesh, and Meyer, Thomas J. Tue . "Fluoropolymer-Stabilized Chromophore-Catalyst Assemblies in Aqueous Buffer Solutions for Water-Oxidation Catalysis". United States. doi:10.1002/cssc.201700630.
@article{osti_1388129,
title = {Fluoropolymer-Stabilized Chromophore-Catalyst Assemblies in Aqueous Buffer Solutions for Water-Oxidation Catalysis},
author = {Eberhart, Michael S. and Wee, Kyung-Ryang and Marquard, Seth and Skinner, Kasey and Wang, Degao and Nayak, Animesh and Meyer, Thomas J.},
abstractNote = {},
doi = {10.1002/cssc.201700630},
journal = {ChemSusChem},
issn = {1864-5631},
number = 11,
volume = 10,
place = {United States},
year = {2017},
month = {5}
}

Works referenced in this record:

Mechanisms of Surface Electron Transfer. Proton-Coupled Electron Transfer
journal, December 1998

  • Trammell, Scott A.; Wimbish, John C.; Odobel, Fabrice
  • Journal of the American Chemical Society, Vol. 120, Issue 50
  • DOI: 10.1021/ja9821854

Single-Site, Catalytic Water Oxidation on Oxide Surfaces
journal, November 2009

  • Chen, Zuofeng; Concepcion, Javier J.; Jurss, Jonah W.
  • Journal of the American Chemical Society, Vol. 131, Issue 43, p. 15580-15581
  • DOI: 10.1021/ja906391w

Structure–Property Relationships in Phosphonate-Derivatized, Ru II Polypyridyl Dyes on Metal Oxide Surfaces in an Aqueous Environment
journal, July 2012

  • Hanson, Kenneth; Brennaman, M. Kyle; Ito, Akitaka
  • The Journal of Physical Chemistry C, Vol. 116, Issue 28
  • DOI: 10.1021/jp304088d

Low-Overpotential Water Oxidation by a Surface-Bound Ruthenium-Chromophore-Ruthenium-Catalyst Assembly
journal, November 2013

  • Norris, Michael R.; Concepcion, Javier J.; Fang, Zhen
  • Angewandte Chemie International Edition, Vol. 52, Issue 51
  • DOI: 10.1002/anie.201305951

Photostability of Phosphonate-Derivatized, Ru II Polypyridyl Complexes on Metal Oxide Surfaces
journal, February 2012

  • Hanson, Kenneth; Brennaman, M. Kyle; Luo, Hanlin
  • ACS Applied Materials & Interfaces, Vol. 4, Issue 3
  • DOI: 10.1021/am201717x

Thermal and oxidative degradation of poly(methyl methacrylate): weight loss
journal, July 1985

  • Hirata, T.; Kashiwagi, Takashi; Brown, J. E.
  • Macromolecules, Vol. 18, Issue 7
  • DOI: 10.1021/ma00149a010

Multilayer Deposition of Novel Organophosphonates with Zirconium(IV)
journal, December 1994


Preparation of phosphonated polypyridyl ligands to anchor transition-metal complexes on oxide surfaces: application for the conversion of light to electricity with nanocrystalline TiO 2 films
journal, January 1995

  • Péchy, Péter; Rotzinger, François P.; Nazeeruddin, Mohammed Khaja
  • J. Chem. Soc., Chem. Commun., Vol. 0, Issue 1
  • DOI: 10.1039/C39950000065

One Site is Enough. Catalytic Water Oxidation by [Ru(tpy)(bpm)(OH 2 )] 2+ and [Ru(tpy)(bpz)(OH 2 )] 2+
journal, December 2008

  • Concepcion, Javier J.; Jurss, Jonah W.; Templeton, Joseph L.
  • Journal of the American Chemical Society, Vol. 130, Issue 49
  • DOI: 10.1021/ja8059649

Mononuclear Ruthenium(II) Complexes That Catalyze Water Oxidation
journal, December 2008

  • Tseng, Huan-Wei; Zong, Ruifa; Muckerman, James T.
  • Inorganic Chemistry, Vol. 47, Issue 24
  • DOI: 10.1021/ic8014817

Stabilizing Small Molecules on Metal Oxide Surfaces Using Atomic Layer Deposition
journal, September 2013

  • Hanson, Kenneth; Losego, Mark D.; Kalanyan, Berç
  • Nano Letters, Vol. 13, Issue 10
  • DOI: 10.1021/nl402416s

Efficient photoinduced charge separation in layered zirconium viologen phosphonate compounds
journal, December 1993

  • Vermeulen, Lori A.; Snover, Jonathan L.; Sapochak, Linda S.
  • Journal of the American Chemical Society, Vol. 115, Issue 25
  • DOI: 10.1021/ja00078a015

Synthesis and photophysical characterization of porphyrin and porphyrin–Ru(ii) polypyridyl chromophore–catalyst assemblies on mesoporous metal oxides
journal, January 2014

  • Nayak, Animesh; Knauf, Robin R.; Hanson, Kenneth
  • Chemical Science, Vol. 5, Issue 8
  • DOI: 10.1039/c4sc00875h

Anchoring Groups for Dye-Sensitized Solar Cells
journal, February 2015

  • Zhang, Lei; Cole, Jacqueline M.
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 6
  • DOI: 10.1021/am507334m

Self-Assembled Bilayer Films of Ruthenium(II)/Polypyridyl Complexes through Layer-by-Layer Deposition on Nanostructured Metal Oxides
journal, November 2012

  • Hanson, Kenneth; Torelli, Daniel A.; Vannucci, Aaron K.
  • Angewandte Chemie International Edition, Vol. 51, Issue 51
  • DOI: 10.1002/anie.201206882

Driving Force Dependent, Photoinduced Electron Transfer at Degenerately Doped, Optically Transparent Semiconductor Nanoparticle Interfaces
journal, November 2014

  • Farnum, Byron H.; Morseth, Zachary A.; Brennaman, M. Kyle
  • Journal of the American Chemical Society, Vol. 136, Issue 45
  • DOI: 10.1021/ja508862h

Mechanism of Water Oxidation by Single-Site Ruthenium Complex Catalysts
journal, February 2010

  • Concepcion, Javier J.; Tsai, Ming-Kang; Muckerman, James T.
  • Journal of the American Chemical Society, Vol. 132, Issue 5, p. 1545-1557
  • DOI: 10.1021/ja904906v

Two Electrode Collector–Generator Method for the Detection of Electrochemically or Photoelectrochemically Produced O 2
journal, July 2016

  • Sherman, Benjamin D.; Sheridan, Matthew V.; Dares, Christopher J.
  • Analytical Chemistry, Vol. 88, Issue 14
  • DOI: 10.1021/acs.analchem.6b00738

Application of High Surface Area Tin-Doped Indium Oxide Nanoparticle Films as Transparent Conducting Electrodes
journal, September 2010

  • Hoertz, Paul G.; Chen, Zuofeng; Kent, Caleb A.
  • Inorganic Chemistry, Vol. 49, Issue 18
  • DOI: 10.1021/ic100719r

Low-Overpotential Water Oxidation by a Surface-Bound Ruthenium-Chromophore-Ruthenium-Catalyst Assembly
journal, November 2013

  • Norris, Michael R.; Concepcion, Javier J.; Fang, Zhen
  • Angewandte Chemie, Vol. 125, Issue 51
  • DOI: 10.1002/ange.201305951

Influence of a photoinitiator on the photochemical stability of poly(methyl methacrylate) studied with fourier transform infrared spectroscopy: Photochemical Stability of PMMA
journal, October 2009

  • Kaczmarek, Halina; Gałka, Piotr; Kowalonek, Jolanta
  • Journal of Applied Polymer Science, Vol. 115, Issue 3
  • DOI: 10.1002/app.31166

Visible Light-Driven Water Splitting in Photoelectrochemical Cells with Supramolecular Catalysts on Photoanodes
journal, May 2014

  • Ding, Xin; Gao, Yan; Zhang, Linlin
  • ACS Catalysis, Vol. 4, Issue 7
  • DOI: 10.1021/cs500518k

Phosphonate-Based Bipyridine Dyes for Stable Photovoltaic Devices
journal, November 2001

  • Gillaizeau-Gauthier, Isabelle; Odobel, Fabrice; Alebbi, Monica
  • Inorganic Chemistry, Vol. 40, Issue 23
  • DOI: 10.1021/ic010192e

Stabilization of [Ru(bpy) 2 (4,4′-(PO 3 H 2 )bpy)] 2+ on Mesoporous TiO 2 with Atomic Layer Deposition of Al 2 O 3
journal, December 2012

  • Hanson, Kenneth; Losego, Mark D.; Kalanyan, Berç
  • Chemistry of Materials, Vol. 25, Issue 1
  • DOI: 10.1021/cm303172w

Stabilization of Ruthenium(II) Polypyridyl Chromophores on Nanoparticle Metal-Oxide Electrodes in Water by Hydrophobic PMMA Overlayers
journal, September 2014

  • Wee, Kyung-Ryang; Brennaman, M. Kyle; Alibabaei, Leila
  • Journal of the American Chemical Society, Vol. 136, Issue 39
  • DOI: 10.1021/ja506987a

Molecular Chromophore–Catalyst Assemblies for Solar Fuel Applications
journal, August 2015


A PMMA overlayer improving the surface-bound stability of photoanode for water splitting
journal, July 2016


Synthesis, self-assembly, and photophysical dynamics of stacked layers of porphyrin and viologen phosphonates
journal, October 1992

  • Ungashe, Solomon B.; Wilson, William L.; Katz, Howard E.
  • Journal of the American Chemical Society, Vol. 114, Issue 22
  • DOI: 10.1021/ja00048a065

Chemical Approaches to Artificial Photosynthesis. 2
journal, October 2005

  • Alstrum-Acevedo, James H.; Brennaman, M. Kyle; Meyer, Thomas J.
  • Inorganic Chemistry, Vol. 44, Issue 20
  • DOI: 10.1021/ic050904r

Mechanisms of Water Oxidation from the Blue Dimer to Photosystem II
journal, March 2008

  • Liu, Feng; Concepcion, Javier J.; Jurss, Jonah W.
  • Inorganic Chemistry, Vol. 47, Issue 6
  • DOI: 10.1021/ic701249s

A “Mix and Match” Ionic−Covalent Strategy for Self-Assembly of Inorganic Multilayer Films
journal, December 1997

  • Fang, Mingming; Kaschak, David M.; Sutorik, Anthony C.
  • Journal of the American Chemical Society, Vol. 119, Issue 50, p. 12184-12191
  • DOI: 10.1021/ja972569e

Dye Stabilization and Enhanced Photoelectrode Wettability in Water-Based Dye-Sensitized Solar Cells through Post-assembly Atomic Layer Deposition of TiO 2
journal, July 2013

  • Son, Ho-Jin; Prasittichai, Chaiya; Mondloch, Joseph E.
  • Journal of the American Chemical Society, Vol. 135, Issue 31
  • DOI: 10.1021/ja406538a

Electrochemical Instability of Phosphonate-Derivatized, Ruthenium(III) Polypyridyl Complexes on Metal Oxide Surfaces
journal, May 2015

  • Hyde, Jacob T.; Hanson, Kenneth; Vannucci, Aaron K.
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 18
  • DOI: 10.1021/acsami.5b01000

Water Oxidation Intermediates Applied to Catalysis: Benzyl Alcohol Oxidation
journal, February 2012

  • Vannucci, Aaron K.; Hull, Jonathan F.; Chen, Zuofeng
  • Journal of the American Chemical Society, Vol. 134, Issue 9
  • DOI: 10.1021/ja210718u

Self-assembled molecular p/n junctions for applications in dye-sensitized solar energy conversion
journal, June 2016

  • Farnum, Byron H.; Wee, Kyung-Ryang; Meyer, Thomas J.
  • Nature Chemistry, Vol. 8, Issue 9
  • DOI: 10.1038/nchem.2536

Self-Assembled Bilayer Films of Ruthenium(II)/Polypyridyl Complexes through Layer-by-Layer Deposition on Nanostructured Metal Oxides
journal, November 2012

  • Hanson, Kenneth; Torelli, Daniel A.; Vannucci, Aaron K.
  • Angewandte Chemie, Vol. 124, Issue 51
  • DOI: 10.1002/ange.201206882