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Title: Photoinduced electron transfer from rylenediimide radical anions and dianions to Re(bpy)(CO) 3 using red and near-infrared light

Abstract

Photoinduced electron transfer dynamics are described for a set of dyads comprising rylenediimide anion chromophores and a Re(bpy)(CO) 3metal center.

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [2];  [2]; ORCiD logo [1];  [1];  [1];  [2]; ORCiD logo [1]
  1. Department of Chemistry; Argonne-Northwestern Solar Energy Research (ANSER) Center; Northwestern University; Evanston; USA
  2. Department of Chemistry; Argonne-Northwestern Solar Energy Research (ANSER) Center; Energy Sciences Institute; Yale University; New Haven
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Argonne-Northwestern Solar Energy Research Center (ANSER)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1388113
DOE Contract Number:  
SC0001059
Resource Type:
Journal Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Volume: 8; Journal Issue: 5; Related Information: ANSER partners with Northwestern University (lead); Argonne National Laboratory; University of Chicago; University of Illinois, Urbana-Champaign; Yale University; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
catalysis (homogeneous), catalysis (heterogeneous), solar (photovoltaic), solar (fuels), photosynthesis (natural and artificial), bio-inspired, hydrogen and fuel cells, electrodes - solar, defects, charge transport, spin dynamics, membrane, materials and chemistry by design, optics, synthesis (novel materials), synthesis (self-assembly)

Citation Formats

La Porte, Nathan T., Martinez, Jose F., Hedström, Svante, Rudshteyn, Benjamin, Phelan, Brian T., Mauck, Catherine M., Young, Ryan M., Batista, Victor S., and Wasielewski, Michael R. Photoinduced electron transfer from rylenediimide radical anions and dianions to Re(bpy)(CO) 3 using red and near-infrared light. United States: N. p., 2017. Web. doi:10.1039/C6SC05103K.
La Porte, Nathan T., Martinez, Jose F., Hedström, Svante, Rudshteyn, Benjamin, Phelan, Brian T., Mauck, Catherine M., Young, Ryan M., Batista, Victor S., & Wasielewski, Michael R. Photoinduced electron transfer from rylenediimide radical anions and dianions to Re(bpy)(CO) 3 using red and near-infrared light. United States. doi:10.1039/C6SC05103K.
La Porte, Nathan T., Martinez, Jose F., Hedström, Svante, Rudshteyn, Benjamin, Phelan, Brian T., Mauck, Catherine M., Young, Ryan M., Batista, Victor S., and Wasielewski, Michael R. Sun . "Photoinduced electron transfer from rylenediimide radical anions and dianions to Re(bpy)(CO) 3 using red and near-infrared light". United States. doi:10.1039/C6SC05103K.
@article{osti_1388113,
title = {Photoinduced electron transfer from rylenediimide radical anions and dianions to Re(bpy)(CO) 3 using red and near-infrared light},
author = {La Porte, Nathan T. and Martinez, Jose F. and Hedström, Svante and Rudshteyn, Benjamin and Phelan, Brian T. and Mauck, Catherine M. and Young, Ryan M. and Batista, Victor S. and Wasielewski, Michael R.},
abstractNote = {Photoinduced electron transfer dynamics are described for a set of dyads comprising rylenediimide anion chromophores and a Re(bpy)(CO)3metal center.},
doi = {10.1039/C6SC05103K},
journal = {Chemical Science},
issn = {2041-6520},
number = 5,
volume = 8,
place = {United States},
year = {2017},
month = {1}
}

Works referenced in this record:

Photodriven Electron and Energy Transfer from Copper Phenanthroline Excited States
journal, January 1996

  • Ruthkosky, Mark; Castellano, Felix N.; Meyer, Gerald J.
  • Inorganic Chemistry, Vol. 35, Issue 22
  • DOI: 10.1021/ic960503z

Femtosecond Optical Switching of Electron Transport Direction in Branched Donor−Acceptor Arrays
journal, February 2000

  • Lukas, Aaron S.; Miller, Scott E.; Wasielewski, Michael R.
  • The Journal of Physical Chemistry B, Vol. 104, Issue 5
  • DOI: 10.1021/jp993774e

Excited Doublet States of Electrochemically Generated Aromatic Imide and Diimide Radical Anions
journal, July 2000

  • Gosztola, David; Niemczyk, Mark P.; Svec, Walter
  • The Journal of Physical Chemistry A, Vol. 104, Issue 28
  • DOI: 10.1021/jp000706f

Bespoke Photoreductants: Tungsten Arylisocyanides
journal, January 2015

  • Sattler, Wesley; Henling, Lawrence M.; Winkler, Jay R.
  • Journal of the American Chemical Society, Vol. 137, Issue 3
  • DOI: 10.1021/ja510973h

Photo-driven electron transfer from the highly reducing excited state of naphthalene diimide radical anion to a CO 2 reduction catalyst within a molecular triad
journal, January 2017

  • Martinez, Jose F.; La Porte, Nathan T.; Mauck, Catherine M.
  • Faraday Discussions, Vol. 198
  • DOI: 10.1039/C6FD00219F

Tuning the Excited-State Properties of Platinum(II) Diimine Dithiolate Complexes
journal, January 1996

  • Cummings, Scott D.; Eisenberg, Richard
  • Journal of the American Chemical Society, Vol. 118, Issue 8
  • DOI: 10.1021/ja951345y

Electron Transfer from the Porphyrin S 2 State in a Zinc Porphyrin-Rhenium Bipyridyl Dyad having Carbon Dioxide Reduction Activity
journal, May 2009

  • Kiyosawa, Kuniomi; Shiraishi, Naoki; Shimada, Tetsuya
  • The Journal of Physical Chemistry C, Vol. 113, Issue 27
  • DOI: 10.1021/jp901548y

Generation of Powerful Tungsten Reductants by Visible Light Excitation
journal, July 2013

  • Sattler, Wesley; Ener, Maraia E.; Blakemore, James D.
  • Journal of the American Chemical Society, Vol. 135, Issue 29
  • DOI: 10.1021/ja4047119

Development of highly efficient supramolecular CO 2 reduction photocatalysts with high turnover frequency and durability
journal, January 2012

  • Tamaki, Yusuke; Watanabe, Katsuhiro; Koike, Kazuhide
  • Faraday Discuss., Vol. 155
  • DOI: 10.1039/C1FD00091H

Improving the Efficiency of the Photoinduced Charge-Separation Process in a Rhenium(I)–Zinc Porphyrin Dyad by Simple Chemical Functionalization
journal, March 2013

  • Gatti, Teresa; Cavigli, Paolo; Zangrando, Ennio
  • Inorganic Chemistry, Vol. 52, Issue 6
  • DOI: 10.1021/ic302663c

Ultrafast Excited-State Dynamics of Rhenium(I) Photosensitizers [Re(Cl)(CO) 3 (N,N)] and [Re(imidazole)(CO) 3 (N,N)] + : Diimine Effects
journal, April 2011

  • El Nahhas, Amal; Consani, Cristina; Blanco-Rodríguez, Ana María
  • Inorganic Chemistry, Vol. 50, Issue 7
  • DOI: 10.1021/ic102324p

Ultrafast Molecular Logic Gate Based on Optical Switching between Two Long-Lived Radical Ion Pair States
journal, March 2001

  • Lukas, Aaron S.; Bushard, Patrick J.; Wasielewski, Michael R.
  • Journal of the American Chemical Society, Vol. 123, Issue 10
  • DOI: 10.1021/ja0041122

Re(bipy-tBu)(CO) 3 Cl−improved Catalytic Activity for Reduction of Carbon Dioxide: IR-Spectroelectrochemical and Mechanistic Studies
journal, October 2010

  • Smieja, Jonathan M.; Kubiak, Clifford P.
  • Inorganic Chemistry, Vol. 49, Issue 20
  • DOI: 10.1021/ic1008363

Developing a Mechanistic Understanding of Molecular Electrocatalysts for CO 2 Reduction using Infrared Spectroelectrochemistry
journal, April 2014

  • Machan, Charles W.; Sampson, Matthew D.; Chabolla, Steven A.
  • Organometallics, Vol. 33, Issue 18
  • DOI: 10.1021/om500044a

Intermolecular and Intramolecular Electron Transfer Processes from Excited Naphthalene Diimide Radical Anions
journal, November 2014

  • Fujitsuka, Mamoru; Kim, Sung Sik; Lu, Chao
  • The Journal of Physical Chemistry B, Vol. 119, Issue 24
  • DOI: 10.1021/jp510850z

CO2 photoreduction with long-wavelength light: dyads and monomers of zinc porphyrin and rhenium bipyridine
journal, January 2012

  • Windle, Christopher D.; Câmpian, Marius V.; Duhme-Klair, Anne-K.
  • Chemical Communications, Vol. 48, Issue 66
  • DOI: 10.1039/c2cc33308b

A Highly Emissive Cu 2 N 2 Diamond Core Complex Supported by a [PNP] - Ligand
journal, February 2005

  • Harkins, Seth B.; Peters, Jonas C.
  • Journal of the American Chemical Society, Vol. 127, Issue 7
  • DOI: 10.1021/ja043092r

Ultrafast Charge Separation in a Photoreactive Rhenium-Appended Porphyrin Assembly Monitored by Picosecond Transient Infrared Spectroscopy
journal, April 2006

  • Gabrielsson, Anders; Hartl, František; Zhang, Hong
  • Journal of the American Chemical Society, Vol. 128, Issue 13
  • DOI: 10.1021/ja0539802

Excited-state properties of a triply ortho-metalated iridium(III) complex
journal, March 1985

  • King, K. A.; Spellane, P. J.; Watts, Richard J.
  • Journal of the American Chemical Society, Vol. 107, Issue 5
  • DOI: 10.1021/ja00291a064

Unprecedented Intramolecular Electron Transfer from Excited Perylenediimide Radical Anion
journal, June 2016

  • Lu, Chao; Fujitsuka, Mamoru; Sugimoto, Akira
  • The Journal of Physical Chemistry C, Vol. 120, Issue 23
  • DOI: 10.1021/acs.jpcc.6b02454

Electrochemical Properties and CO 2 -Reduction Ability of m -Terphenyl Isocyanide Supported Manganese Tricarbonyl Complexes
journal, November 2016


Ultrafast Conformational Dynamics of Electron Transfer in ExBox 4+ ⊂Perylene
journal, November 2013

  • Young, Ryan M.; Dyar, Scott M.; Barnes, Jonathan C.
  • The Journal of Physical Chemistry A, Vol. 117, Issue 47
  • DOI: 10.1021/jp409883a

Photochemistry and Photophysics of a Pd(II) Metalloporphyrin: Re(I) Tricarbonyl Bipyridine Molecular Dyad and its Activity Toward the Photoreduction of CO 2 to CO
journal, December 2011

  • Schneider, Jacob; Vuong, Khuong Q.; Calladine, James A.
  • Inorganic Chemistry, Vol. 50, Issue 23
  • DOI: 10.1021/ic200243y

Picosecond Control of Photogenerated Radical Pair Lifetimes Using a Stable Third Radical
journal, April 2016

  • Horwitz, Noah E.; Phelan, Brian T.; Nelson, Jordan N.
  • The Journal of Physical Chemistry A, Vol. 120, Issue 18
  • DOI: 10.1021/acs.jpca.6b02621

Red-Light-Driven Photocatalytic Reduction of CO 2 using Os(II)–Re(I) Supramolecular Complexes
journal, September 2013

  • Tamaki, Yusuke; Koike, Kazuhide; Morimoto, Tatsuki
  • Inorganic Chemistry, Vol. 52, Issue 20
  • DOI: 10.1021/ic4015543

A light-induced redox reaction of bis(2,9-dimethyl-1,10-phenanthroline)copper(I)
journal, April 1977

  • McMillin, David R.; Buckner, Michael T.; Ahn, Byung Tae.
  • Inorganic Chemistry, Vol. 16, Issue 4
  • DOI: 10.1021/ic50170a046

Stable Aromatic Dianion in Water
journal, July 2008

  • Shirman, Elijah; Ustinov, Alona; Ben-Shitrit, Netanel
  • The Journal of Physical Chemistry B, Vol. 112, Issue 30
  • DOI: 10.1021/jp8029743

Chemical Redox Agents for Organometallic Chemistry
journal, January 1996

  • Connelly, Neil G.; Geiger, William E.
  • Chemical Reviews, Vol. 96, Issue 2
  • DOI: 10.1021/cr940053x

Optical parametric amplification of femtosecond pulses tunable from the blue to the infrared with microjoule energies
journal, January 1995

  • Greenfield, Scott R.; Wasielewski, Michael R.
  • Applied Optics, Vol. 34, Issue 15
  • DOI: 10.1364/AO.34.002688

    Works referencing / citing this record:

    Stable Bifunctional Perylene Imide Radicals for High-Performance Organic-Lithium Redox-Flow Batteries
    journal, August 2018

    • Li, Lei; Gong, Hai-Xian; Chen, Dong-Yang
    • Chemistry - A European Journal, Vol. 24, Issue 50
    • DOI: 10.1002/chem.201801443

    α-Benzyl-β-Alanine Containing Naphthalenediimide Promotes Photoresponsive Radical Anion
    journal, September 2018


    Doubly zwitterionic, di-reduced, highly electron-rich, air-stable naphthalenediimides: redox-switchable islands of aromatic–antiaromatic states
    journal, January 2019

    • Kumar, Sharvan; Shukla, Jyoti; Mandal, Kalyanashis
    • Chemical Science, Vol. 10, Issue 26
    • DOI: 10.1039/c9sc00962k