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Title: Ultra-selective high-flux membranes from directly synthesized zeolite nanosheets

Authors:
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Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1388104
DOE Contract Number:  
SC0001015
Resource Type:
Journal Article
Journal Name:
Nature (London)
Additional Journal Information:
Journal Volume: 543; Journal Issue: 7647; Related Information: CGS partners with University of California, Berkeley; University of California, Davis; Lawrence Berkeley National Laboratory; University of Minnesota; National Energy Technology Laboratory; Texas A&M University; Journal ID: ISSN 0028-0836
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English
Subject:
membrane, carbon capture, materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing)

Citation Formats

Jeon, Mi Young, Kim, Donghun, Kumar, Prashant, Lee, Pyung Soo, Rangnekar, Neel, Bai, Peng, Shete, Meera, Elyassi, Bahman, Lee, Han Seung, Narasimharao, Katabathini, Basahel, Sulaiman Nasir, Al-Thabaiti, Shaeel, Xu, Wenqian, Cho, Hong Je, Fetisov, Evgenii O., Thyagarajan, Raghuram, DeJaco, Robert F., Fan, Wei, Mkhoyan, K. Andre, Siepmann, J. Ilja, and Tsapatsis, Michael. Ultra-selective high-flux membranes from directly synthesized zeolite nanosheets. United States: N. p., 2017. Web. doi:10.1038/nature21421.
Jeon, Mi Young, Kim, Donghun, Kumar, Prashant, Lee, Pyung Soo, Rangnekar, Neel, Bai, Peng, Shete, Meera, Elyassi, Bahman, Lee, Han Seung, Narasimharao, Katabathini, Basahel, Sulaiman Nasir, Al-Thabaiti, Shaeel, Xu, Wenqian, Cho, Hong Je, Fetisov, Evgenii O., Thyagarajan, Raghuram, DeJaco, Robert F., Fan, Wei, Mkhoyan, K. Andre, Siepmann, J. Ilja, & Tsapatsis, Michael. Ultra-selective high-flux membranes from directly synthesized zeolite nanosheets. United States. doi:10.1038/nature21421.
Jeon, Mi Young, Kim, Donghun, Kumar, Prashant, Lee, Pyung Soo, Rangnekar, Neel, Bai, Peng, Shete, Meera, Elyassi, Bahman, Lee, Han Seung, Narasimharao, Katabathini, Basahel, Sulaiman Nasir, Al-Thabaiti, Shaeel, Xu, Wenqian, Cho, Hong Je, Fetisov, Evgenii O., Thyagarajan, Raghuram, DeJaco, Robert F., Fan, Wei, Mkhoyan, K. Andre, Siepmann, J. Ilja, and Tsapatsis, Michael. Wed . "Ultra-selective high-flux membranes from directly synthesized zeolite nanosheets". United States. doi:10.1038/nature21421.
@article{osti_1388104,
title = {Ultra-selective high-flux membranes from directly synthesized zeolite nanosheets},
author = {Jeon, Mi Young and Kim, Donghun and Kumar, Prashant and Lee, Pyung Soo and Rangnekar, Neel and Bai, Peng and Shete, Meera and Elyassi, Bahman and Lee, Han Seung and Narasimharao, Katabathini and Basahel, Sulaiman Nasir and Al-Thabaiti, Shaeel and Xu, Wenqian and Cho, Hong Je and Fetisov, Evgenii O. and Thyagarajan, Raghuram and DeJaco, Robert F. and Fan, Wei and Mkhoyan, K. Andre and Siepmann, J. Ilja and Tsapatsis, Michael},
abstractNote = {},
doi = {10.1038/nature21421},
journal = {Nature (London)},
issn = {0028-0836},
number = 7647,
volume = 543,
place = {United States},
year = {2017},
month = {3}
}

Works referenced in this record:

Generalized Gradient Approximation Made Simple
journal, October 1996

  • Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
  • Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
  • DOI: 10.1103/PhysRevLett.77.3865

Oriented MFI Membranes by Gel-Less Secondary Growth of Sub-100 nm MFI-Nanosheet Seed Layers
journal, April 2015

  • Agrawal, Kumar Varoon; Topuz, Berna; Pham, Tung Cao Thanh
  • Advanced Materials, Vol. 27, Issue 21, p. 3243-3249
  • DOI: 10.1002/adma.201405893

Zeolite membranes – a review and comparison with MOFs
journal, January 2015

  • Rangnekar, N.; Mittal, N.; Elyassi, B.
  • Chemical Society Reviews, Vol. 44, Issue 20
  • DOI: 10.1039/C5CS00292C

Open-Pore Two-Dimensional MFI Zeolite Nanosheets for the Fabrication of Hydrocarbon-Isomer-Selective Membranes on Porous Polymer Supports
journal, April 2016

  • Zhang, Han; Xiao, Qiang; Guo, Xianghai
  • Angewandte Chemie International Edition, Vol. 55, Issue 25
  • DOI: 10.1002/anie.201601135

Influence of Framework Flexibility on the Adsorption Properties of Hydrocarbons in the Zeolite Silicalite
journal, December 2002

  • Vlugt, Thijs J. H.; Schenk, Merijn
  • The Journal of Physical Chemistry B, Vol. 106, Issue 49
  • DOI: 10.1021/jp0263931

Seven chemical separations to change the world
journal, April 2016

  • Sholl, David S.; Lively, Ryan P.
  • Nature, Vol. 532, Issue 7600
  • DOI: 10.1038/532435a

Solution-processable exfoliated zeolite nanosheets purified by density gradient centrifugation
journal, May 2013

  • Agrawal, Kumar Varoon; Topuz, Berna; Jiang, Zheyu
  • AIChE Journal, Vol. 59, Issue 9, p. 3458-3467
  • DOI: 10.1002/aic.14099

MFI zeolite membranes from a- and randomly oriented monolayers
journal, September 2006


Advances in nanosized zeolites
journal, January 2013

  • Mintova, Svetlana; Gilson, Jean-Pierre; Valtchev, Valentin
  • Nanoscale, Vol. 5, Issue 15
  • DOI: 10.1039/c3nr01629c

Silicalite-1 Growth from Clear Solution:  Effect of Alcohol Identity and Content on Growth Kinetics
journal, October 2005

  • Cheng, Chil-Hung; Shantz, Daniel F.
  • The Journal of Physical Chemistry B, Vol. 109, Issue 41
  • DOI: 10.1021/jp0524633

GROMACS: Fast, flexible, and free
journal, January 2005

  • Van Der Spoel, David; Lindahl, Erik; Hess, Berk
  • Journal of Computational Chemistry, Vol. 26, Issue 16
  • DOI: 10.1002/jcc.20291

From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999


GSAS-II : the genesis of a modern open-source all purpose crystallography software package
journal, March 2013


Layered zeolitic materials: an approach to designing versatile functional solids
journal, January 2014

  • Díaz, Urbano; Corma, Avelino
  • Dalton Transactions, Vol. 43, Issue 27
  • DOI: 10.1039/c3dt53181c

Gas and Organic Vapor Permeation through b -Oriented MFI Membranes
journal, June 2004

  • Lai, Zhiping; Tsapatsis, Michael
  • Industrial & Engineering Chemistry Research, Vol. 43, Issue 12
  • DOI: 10.1021/ie034096s

Separation of Xylene Isomer Vapors with Oriented MFI Membranes Made by Seeded Growth
journal, January 2001

  • Xomeritakis, George; Lai, Zhiping; Tsapatsis, Michael
  • Industrial & Engineering Chemistry Research, Vol. 40, Issue 2
  • DOI: 10.1021/ie000613k

Structural analysis of hierarchically organized zeolites
journal, October 2015

  • Mitchell, Sharon; Pinar, Ana B.; Kenvin, Jeffrey
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms9633

Nanoscale Control of Homoepitaxial Growth on a Two-Dimensional Zeolite
journal, December 2016

  • Shete, Meera; Kumar, Manjesh; Kim, Donghun
  • Angewandte Chemie International Edition, Vol. 56, Issue 2
  • DOI: 10.1002/anie.201607063

Molecular mechanics studies on MFI-typezeolites: Part 4. Energetics of crystal growth directing agents
journal, March 1993


On the Rotational Intergrowth of Hierarchical FAU/EMT Zeolites
journal, July 2014

  • Khaleel, Maryam; Wagner, Andrew J.; Mkhoyan, K. Andre
  • Angewandte Chemie International Edition, Vol. 53, Issue 36
  • DOI: 10.1002/anie.201402024

The nucleation period for TPA-silicalite-1 crystallization determined by a two-stage varying-temperature synthesis
journal, October 1999


Silicalite Crystal Growth Investigated by Atomic Force Microscopy
journal, January 2003

  • Agger, Jonathan R.; Hanif, Noreen; Cundy, Colin S.
  • Journal of the American Chemical Society, Vol. 125, Issue 3
  • DOI: 10.1021/ja020899f

Transport properties of alumina-supported MFI membranes made by secondary (seeded) growth
journal, July 2000

  • Xomeritakis, George; Nair, Sankar; Tsapatsis, Michael
  • Microporous and Mesoporous Materials, Vol. 38, Issue 1
  • DOI: 10.1016/S1387-1811(99)00300-5

The Hydrothermal Synthesis of Zeolites: History and Development from the Earliest Days to the Present Time
journal, March 2003

  • Cundy, Colin S.; Cox, Paul A.
  • Chemical Reviews, Vol. 103, Issue 3, p. 663-702
  • DOI: 10.1021/cr020060i

A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu
journal, April 2010

  • Grimme, Stefan; Antony, Jens; Ehrlich, Stephan
  • The Journal of Chemical Physics, Vol. 132, Issue 15
  • DOI: 10.1063/1.3382344

Electron Microscopic Study of Intergrowth of MFI and MEL:  Crystal Faults in B-MEL
journal, November 1997

  • Ohsuna, Tetsu; Terasaki, Osamu; Nakagawa, Yumi
  • The Journal of Physical Chemistry B, Vol. 101, Issue 48
  • DOI: 10.1021/jp971448y

High-Performance Randomly Oriented Zeolite Membranes Using Brittle Seeds and Rapid Thermal Processing
journal, September 2010

  • Yoo, Won Cheol; Stoeger, Jared A.; Lee, Pyung-Soo
  • Angewandte Chemie International Edition, Vol. 49, Issue 46
  • DOI: 10.1002/anie.201004029

Hierarchical nanofabrication of microporous crystals with ordered mesoporosity
journal, October 2008

  • Fan, Wei; Snyder, Mark A.; Kumar, Sandeep
  • Nature Materials, Vol. 7, Issue 12
  • DOI: 10.1038/nmat2302

Silicalite, a new hydrophobic crystalline silica molecular sieve
journal, February 1978

  • Flanigen, E. M.; Bennett, J. M.; Grose, R. W.
  • Nature, Vol. 271, Issue 5645
  • DOI: 10.1038/271512a0

Grain Boundary Defect Elimination in a Zeolite Membrane by Rapid Thermal Processing
journal, July 2009


Ethanol/water mixture pervaporation performance of b -oriented silicalite-1 membranes made by gel-free secondary growth
journal, December 2015

  • Elyassi, Bahman; Jeon, Mi Young; Tsapatsis, Michael
  • AIChE Journal, Vol. 62, Issue 2
  • DOI: 10.1002/aic.15124

Zeolite (MFI) Crystal Morphology Control Using Organic Structure-Directing Agents
journal, December 2004

  • Bonilla, Griselda; Díaz, Isabel; Tsapatsis, Michael
  • Chemistry of Materials, Vol. 16, Issue 26
  • DOI: 10.1021/cm048854w

Influence of force fields on the selective diffusion of para -xylene over ortho -xylene in 10-ring zeolites
journal, April 2015


Stable single-unit-cell nanosheets of zeolite MFI as active and long-lived catalysts
journal, September 2009

  • Choi, Minkee; Na, Kyungsu; Kim, Jeongnam
  • Nature, Vol. 461, Issue 7261, p. 246-249
  • DOI: 10.1038/nature08288

Structure of synthetic zeolite ZSM-5
journal, March 1978

  • Kokotailo, G. T.; Lawton, S. L.; Olson, D. H.
  • Nature, Vol. 272, Issue 5652
  • DOI: 10.1038/272437a0

Gel-Free Secondary Growth of Uniformly Oriented Silica MFI Zeolite Films and Application for Xylene Separation
journal, July 2013

  • Pham, Tung Cao Thanh; Nguyen, Thanh Huu; Yoon, Kyung Byung
  • Angewandte Chemie International Edition, Vol. 52, Issue 33, p. 8693-8698
  • DOI: 10.1002/anie.201301766

In situ Observation of Nucleation and Crystal Growth in Zeolite Synthesis. A Small-Angle X-ray Scattering Investigation on Si-TPA-MFI
journal, March 1999

  • de Moor, Peter-Paul E. A.; Beelen, Theo P. M.; van Santen, Rutger A.
  • The Journal of Physical Chemistry B, Vol. 103, Issue 10
  • DOI: 10.1021/jp982553q

Ordered porous materials for emerging applications
journal, June 2002


Synthesis of Self-Pillared Zeolite Nanosheets by Repetitive Branching
journal, June 2012


Dispersible Exfoliated Zeolite Nanosheets and Their Application as a Selective Membrane
journal, October 2011


Two component permeation through thin zeolite MFI membranes
journal, September 1998


Inorganic Solid Acids and Their Use in Acid-Catalyzed Hydrocarbon Reactions
journal, May 1995


2D Zeolite Coatings: Langmuir-Schaefer Deposition of 3 nm Thick MFI Zeolite Nanosheets
journal, April 2015

  • Rangnekar, Neel; Shete, Meera; Agrawal, Kumar Varoon
  • Angewandte Chemie International Edition, Vol. 54, Issue 22
  • DOI: 10.1002/anie.201411791

Formation of Hierarchically Organized Zeolites by Sequential Intergrowth
journal, February 2013

  • Chaikittisilp, Watcharop; Suzuki, Yuki; Mukti, Rino R.
  • Angewandte Chemie International Edition, Vol. 52, Issue 12
  • DOI: 10.1002/anie.201209638

Semiempirical GGA-type density functional constructed with a long-range dispersion correction
journal, January 2006

  • Grimme, Stefan
  • Journal of Computational Chemistry, Vol. 27, Issue 15, p. 1787-1799
  • DOI: 10.1002/jcc.20495

High-flux MFI membranes
journal, May 2002


Sub-40 nm Zeolite Suspensions via Disassembly of Three-Dimensionally Ordered Mesoporous-Imprinted Silicalite-1
journal, January 2011

  • Lee, Pyung-Soo; Zhang, Xueyi; Stoeger, Jared A.
  • Journal of the American Chemical Society, Vol. 133, Issue 3, p. 493-502
  • DOI: 10.1021/ja107942n

Two-Dimensional Zeolites: Current Status and Perspectives
journal, February 2014

  • Roth, Wieslaw J.; Nachtigall, Petr; Morris, Russell E.
  • Chemical Reviews, Vol. 114, Issue 9
  • DOI: 10.1021/cr400600f

Lamellar zeolites: an oxymoron?
journal, January 2013

  • Ramos, F. Solânea O.; Pietre, Mendelssolm K. de; Pastore, Heloise O.
  • RSC Adv., Vol. 3, Issue 7
  • DOI: 10.1039/C2RA21573J

The hydrothermal synthesis of zeolites: Precursors, intermediates and reaction mechanism
journal, July 2005


cp2k: atomistic simulations of condensed matter systems
journal, June 2013

  • Hutter, Jürg; Iannuzzi, Marcella; Schiffmann, Florian
  • Wiley Interdisciplinary Reviews: Computational Molecular Science, Vol. 4, Issue 1
  • DOI: 10.1002/wcms.1159

    Works referencing / citing this record:

    Polycrystalline Advanced Microporous Framework Membranes for Efficient Separation of Small Molecules and Ions
    journal, July 2019


    Controlled release of siliceous species for the fabrication of highly b -oriented MFI zeolite films
    journal, January 2019

    • Peng, Yong; Xu, Ruilan; Lu, Xiaofei
    • CrystEngComm, Vol. 21, Issue 28
    • DOI: 10.1039/c9ce00817a

    Interfacial barriers to gas transport: probing solid-gas interfaces at the atomistic level
    journal, July 2019