A Generalized Law of Corresponding States for the Physisorption of Classical Gases with Cooperative Adsorbate–Adsorbate Interactions

Murialdo, Maxwell; Stadie, Nicholas P.; Ahn, Channing C.; Fultz, Brent

doi:10.1021/acs.jpcc.6b00289

Title: A Generalized Law of Corresponding States for the Physisorption of Classical Gases with Cooperative Adsorbate–Adsorbate Interactions

Journal Article · Thu May 12 00:00:00 EDT 2016 · Journal of Physical Chemistry. C

DOI:https://doi.org/10.1021/acs.jpcc.6b00289· OSTI ID:1387996

Murialdo, Maxwell ^[1]; Stadie, Nicholas P. ^[1]; Ahn, Channing C. ^[1]; Fultz, Brent ^[1]

California Inst. of Technology (CalTech), Pasadena, CA (United States)

The Law of Corresponding States for classical gases is well established. Recent attempts at developing an analogous Law of Corresponding States for gas physisorption, however, have had limited success, in part due to the omission of relevant adsorption considerations such as the adsorbate volume and cooperative adsorbate–adsorbate interactions. In this work, we modify a prior Law of Corresponding States for gas physisorption to account for adsorbate volume, and test it with experimental data and a generalized theoretical approach. Furthermore, we account for the recently reported cooperative adsorbate–adsorbate interactions on the surface of zeolite-templated carbon (ZTC) with an Ising-type model and in doing so show that the Law of Corresponding States for gas physisorption remains valid even in the presence of atypically enhanced adsorbate–adsorbate interactions.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Energy Frontier Research in Extreme Environments (EFree)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0001057

OSTI ID:: 1387996

Journal Information:: Journal of Physical Chemistry. C, Vol. 120, Issue 22; Related Information: EFree partners with Carnegie Institution of Washington (lead); California Institute of Technology; Colorado School of Mines; Cornell University; Lehigh University; Pennsylvania State University; ISSN 1932-7447

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 3 works

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References (16)

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Title: A Generalized Law of Corresponding States for the Physisorption of Classical Gases with Cooperative Adsorbate–Adsorbate Interactions

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