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Title: Facile solvolysis of a surprisingly twisted tertiary amide

Abstract

A twisted 3° amide is cleaved at the same rate as a methyl ester under alkaline conditions at 22 °C.

Authors:
 [1];  [2];  [3];  [1];  [1]
  1. Department of Chemistry; Yale University; New Haven; USA; Energy Sciences Institute
  2. Energy Sciences Institute; Yale University; West Haven; USA; Yale School of Engineering and Applied Science
  3. Department of Chemistry; Yale University; New Haven; USA
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Argonne-Northwestern Solar Energy Research Center (ANSER)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1387826
DOE Contract Number:  
SC0001059
Resource Type:
Journal Article
Journal Name:
New Journal of Chemistry
Additional Journal Information:
Journal Volume: 40; Journal Issue: 3; Related Information: ANSER partners with Northwestern University (lead); Argonne National Laboratory; University of Chicago; University of Illinois, Urbana-Champaign; Yale University; Journal ID: ISSN 1144-0546
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
catalysis (homogeneous), catalysis (heterogeneous), solar (photovoltaic), solar (fuels), photosynthesis (natural and artificial), bio-inspired, hydrogen and fuel cells, electrodes - solar, defects, charge transport, spin dynamics, membrane, materials and chemistry by design, optics, synthesis (novel materials), synthesis (self-assembly)

Citation Formats

Bloomfield, Aaron J., Chaudhuri, Subhajyoti, Mercado, Brandon Q., Batista, Victor S., and Crabtree, Robert H. Facile solvolysis of a surprisingly twisted tertiary amide. United States: N. p., 2016. Web. doi:10.1039/C5NJ02449H.
Bloomfield, Aaron J., Chaudhuri, Subhajyoti, Mercado, Brandon Q., Batista, Victor S., & Crabtree, Robert H. Facile solvolysis of a surprisingly twisted tertiary amide. United States. doi:10.1039/C5NJ02449H.
Bloomfield, Aaron J., Chaudhuri, Subhajyoti, Mercado, Brandon Q., Batista, Victor S., and Crabtree, Robert H. Fri . "Facile solvolysis of a surprisingly twisted tertiary amide". United States. doi:10.1039/C5NJ02449H.
@article{osti_1387826,
title = {Facile solvolysis of a surprisingly twisted tertiary amide},
author = {Bloomfield, Aaron J. and Chaudhuri, Subhajyoti and Mercado, Brandon Q. and Batista, Victor S. and Crabtree, Robert H.},
abstractNote = {A twisted 3° amide is cleaved at the same rate as a methyl ester under alkaline conditions at 22 °C.},
doi = {10.1039/C5NJ02449H},
journal = {New Journal of Chemistry},
issn = {1144-0546},
number = 3,
volume = 40,
place = {United States},
year = {2016},
month = {1}
}

Works referenced in this record:

Inhomogeneous Electron Gas
journal, November 1964


Self-Consistent Equations Including Exchange and Correlation Effects
journal, November 1965


    Works referencing / citing this record: