skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Enhanced ethylene separation and plasticization resistance in polymer membranes incorporating metal–organic framework nanocrystals

Journal Article · · Nature Materials
DOI:https://doi.org/10.1038/nmat4621· OSTI ID:1387708

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
SC0001015
OSTI ID:
1387708
Journal Information:
Nature Materials, Vol. 15, Issue 8; Related Information: CGS partners with University of California, Berkeley; University of California, Davis; Lawrence Berkeley National Laboratory; University of Minnesota; National Energy Technology Laboratory; Texas A&M University; ISSN 1476-1122
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English

References (31)

CO2-induced plasticization phenomena in glassy polymers journal March 1999
Gas Separation Membrane Materials: A Perspective journal September 2014
The Effects of Crosslinking Chemistry on CO 2 Plasticization of Polyimide Gas Separation Membranes journal November 2002
Metal-organic framework nanosheets as building blocks for molecular sieving membranes journal December 2014
Mixed matrix membranes containing MOFs for ethylene/ethane separation Part A: Membrane preparation and characterization journal February 2013
Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites journal March 2012
Ultrathin, Molecular-Sieving Graphene Oxide Membranes for Selective Hydrogen Separation journal October 2013
Hydrocarbon Separations in Metal–Organic Frameworks journal September 2013
The Time Lag in Diffusion journal January 1957
Interfacial microfluidic processing of metal-organic framework hollow fiber membranes journal July 2014
Microporous Metal Organic Framework Membrane on Porous Support Using the Seeded Growth Method journal October 2009
Rod Packings and Metal−Organic Frameworks Constructed from Rod-Shaped Secondary Building Units journal February 2005
Ethene/ethane separation by the MOF membrane ZIF-8: Molecular correlation of permeation, adsorption, diffusion journal March 2011
Highly soluble polyimides from sterically hindered diamines journal July 1999
Selective Binding of O 2 over N 2 in a Redox–Active Metal–Organic Framework with Open Iron(II) Coordination Sites journal September 2011
Metal–organic framework nanosheets in polymer composite materials for gas separation journal November 2014
Membrane-based ethylene/ethane separation: The upper bound and beyond journal August 2013
CO2/N2 separations with mixed-matrix membranes containing Mg2(dobdc) nanocrystals journal January 2013
High Propene/Propane Selectivity in Isostructural Metal-Organic Frameworks with High Densities of Open Metal Sites journal January 2012
Metal–organic framework based mixed matrix membranes: a solution for highly efficient CO 2 capture? journal January 2015
Permeation and separation properties of polyimide membranes to olefins and paraffins journal December 1996
Polymers with Cavities Tuned for Fast Selective Transport of Small Molecules and Ions journal October 2007
Comprehensive study of carbon dioxide adsorption in the metal–organic frameworks M 2 (dobdc) (M = Mg, Mn, Fe, Co, Ni, Cu, Zn) journal January 2014
Metal–organic framework membranes: from synthesis to separation application journal January 2014
Fabrication of MMMs with improved gas separation properties using externally-functionalized MOF particles journal January 2015
High performance ZIF-8/6FDA-DAM mixed matrix membrane for propylene/propane separations journal February 2012
Ultimate Permeation Across Atomically Thin Porous Graphene journal April 2014
Selective adsorption of ethylene over ethane and propylene over propane in the metal–organic frameworks M2(dobdc) (M = Mg, Mn, Fe, Co, Ni, Zn) journal January 2013
Olefin/paraffin separation technology: a review journal October 1993
Dramatic Tuning of Carbon Dioxide Uptake via Metal Substitution in a Coordination Polymer with Cylindrical Pores
  • Caskey, Stephen R.; Wong-Foy, Antek G.; Matzger, Adam J.
  • Journal of the American Chemical Society, Vol. 130, Issue 33, p. 10870-10871 https://doi.org/10.1021/ja8036096
journal August 2008
Polyimide derived from 2,2'-bis(trifluoromethyl)-4,4'-diaminobiphenyl. 1. Synthesis and characterization of polyimides prepared with 2,2'-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride or pyromellitic dianhydride journal September 1991