skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Nucleation, Growth, and Robust Synthesis of SPP Zeolite: Effect of Ethanol, Sodium, and Potassium

Authors:
; ; ; ; ;
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Catalysis Center for Energy Innovation (CCEI)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1387634
DOE Contract Number:  
SC0001004
Resource Type:
Journal Article
Journal Name:
Topics in Catalysis
Additional Journal Information:
Journal Volume: 58; Journal Issue: 7-9; Related Information: CCEI partners with the University of Delaware (lead); Brookhaven National Laboratory; California Institute of Technology; Columbia University; University of Delaware; Lehigh University; University of Massachusetts, Amherst; Massachusetts Institute of Technology; University of Minnesota; Pacific Northwest National Laboratory; University of Pennsylvania; Princeton University; Rutgers University; Journal ID: ISSN 1022-5528
Publisher:
Springer
Country of Publication:
United States
Language:
English
Subject:
catalysis (homogeneous), catalysis (heterogeneous), biofuels (including algae and biomass), bio-inspired, hydrogen and fuel cells, materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing)

Citation Formats

Swindlehurst, Garrett R., Kumar, Prashant, Xu, Dandan, Alhassan, Saeed M., Andre Mkhoyan, K., and Tsapatsis, Michael. Nucleation, Growth, and Robust Synthesis of SPP Zeolite: Effect of Ethanol, Sodium, and Potassium. United States: N. p., 2015. Web. doi:10.1007/s11244-015-0396-7.
Swindlehurst, Garrett R., Kumar, Prashant, Xu, Dandan, Alhassan, Saeed M., Andre Mkhoyan, K., & Tsapatsis, Michael. Nucleation, Growth, and Robust Synthesis of SPP Zeolite: Effect of Ethanol, Sodium, and Potassium. United States. doi:10.1007/s11244-015-0396-7.
Swindlehurst, Garrett R., Kumar, Prashant, Xu, Dandan, Alhassan, Saeed M., Andre Mkhoyan, K., and Tsapatsis, Michael. Fri . "Nucleation, Growth, and Robust Synthesis of SPP Zeolite: Effect of Ethanol, Sodium, and Potassium". United States. doi:10.1007/s11244-015-0396-7.
@article{osti_1387634,
title = {Nucleation, Growth, and Robust Synthesis of SPP Zeolite: Effect of Ethanol, Sodium, and Potassium},
author = {Swindlehurst, Garrett R. and Kumar, Prashant and Xu, Dandan and Alhassan, Saeed M. and Andre Mkhoyan, K. and Tsapatsis, Michael},
abstractNote = {},
doi = {10.1007/s11244-015-0396-7},
journal = {Topics in Catalysis},
issn = {1022-5528},
number = 7-9,
volume = 58,
place = {United States},
year = {2015},
month = {4}
}

Works referenced in this record:

Mechanisms of Structure Direction in the Synthesis of Pure-Silica Zeolites. 1. Synthesis of TPA/Si-ZSM-5
journal, May 1995

  • Burkett, Sandra L.; Davis, Mark E.
  • Chemistry of Materials, Vol. 7, Issue 5
  • DOI: 10.1021/cm00053a017

Direct Demonstration of Enhanced Diffusion in Mesoporous ZSM-5 Zeolite Obtained via Controlled Desilication
journal, January 2007

  • Groen, Johan C.; Zhu, Weidong; Brouwer, Sander
  • Journal of the American Chemical Society, Vol. 129, Issue 2
  • DOI: 10.1021/ja065737o

Silica Self-Assembly and Synthesis of Microporous and Mesoporous Silicates
journal, April 2006

  • Rimer, Jeffrey D.; Fedeyko, Joseph M.; Vlachos, Dionisios G.
  • Chemistry - A European Journal, Vol. 12, Issue 11
  • DOI: 10.1002/chem.200500684

Desilication: on the controlled generation of mesoporosity in MFI zeolites
journal, January 2006

  • Groen, Johan C.; Moulijn, Jacob A.; Pérez-Ramírez, Javier
  • J. Mater. Chem., Vol. 16, Issue 22
  • DOI: 10.1039/B517510K

Investigation of the Mechanism of Colloidal Silicalite-1 Crystallization by Using DLS, SAXS, and 29Si NMR Spectroscopy
journal, January 2010

  • Aerts, Alexander; Haouas, Mohamed; Caremans, Tom P.
  • Chemistry - A European Journal, Vol. 16, Issue 9
  • DOI: 10.1002/chem.200901688

A Structural Resolution Cryo-TEM Study of the Early Stages of MFI Growth
journal, December 2008

  • Kumar, Sandeep; Wang, Zhuopeng; Penn, R. Lee
  • Journal of the American Chemical Society, Vol. 130, Issue 51
  • DOI: 10.1021/ja8063167

Mechanistic principles of nanoparticle evolution to zeolite crystals
journal, April 2006

  • Davis, Tracy M.; Drews, Timothy O.; Ramanan, Harikrishnan
  • Nature Materials, Vol. 5, Issue 5
  • DOI: 10.1038/nmat1636

Crystallisation of zeolitic molecular sieves: direct measurements of the growth behaviour of single crystals as a function of synthesis conditions
journal, January 1993

  • Cundy, Colin S.; Lowe, Barrie M.; Sinclair, Douglas M.
  • Faraday Discussions, Vol. 95
  • DOI: 10.1039/fd9939500235

Orientation and Morphological Evolution of Catalyst Nanoparticles During Carbon Nanotube Growth
journal, August 2010

  • Behr, Michael J.; Mkhoyan, K. Andre; Aydil, Eray S.
  • ACS Nano, Vol. 4, Issue 9
  • DOI: 10.1021/nn100944n

Silicalite-1 Growth from Clear Solution:  Effect of Alcohol Identity and Content on Growth Kinetics
journal, October 2005

  • Cheng, Chil-Hung; Shantz, Daniel F.
  • The Journal of Physical Chemistry B, Vol. 109, Issue 41
  • DOI: 10.1021/jp0524633

Assemblies of Mesoporous FAU-Type Zeolite Nanosheets
journal, January 2012

  • Inayat, Alexandra; Knoke, Isabel; Spiecker, Erdmann
  • Angewandte Chemie International Edition, Vol. 51, Issue 8
  • DOI: 10.1002/anie.201105738

Mesoporosity – a new dimension for zeolites
journal, January 2013

  • Möller, Karin; Bein, Thomas
  • Chemical Society Reviews, Vol. 42, Issue 9
  • DOI: 10.1039/c3cs35488a

Role of ethanol in sodalite crystallization in an ethanol–Na2O–Al2O3–SiO2–H2O system
journal, January 2011

  • Huang, Yi; Yao, Jianfeng; Zhang, Xueyi
  • CrystEngComm, Vol. 13, Issue 14
  • DOI: 10.1039/c1ce05194f

Direct Observation of “Pure MEL Type” Zeolite
journal, January 1996

  • Terasaki, Osamu; Ohsuna, Tetsu; Sakuma, Hiroshi
  • Chemistry of Materials, Vol. 8, Issue 2
  • DOI: 10.1021/cm950387i

Generation, Characterization, and Impact of Mesopores in Zeolite Catalysts
journal, January 2003

  • van Donk, Sander; Janssen, Andries H.; Bitter, Johannes H.
  • Catalysis Reviews, Vol. 45, Issue 2
  • DOI: 10.1081/CR-120023908

Oriented Molecular Sieve Membranes by Heteroepitaxial Growth
journal, November 2002

  • Jeong, Hae-Kwon; Krohn, John; Sujaoti, Khristina
  • Journal of the American Chemical Society, Vol. 124, Issue 44
  • DOI: 10.1021/ja020947w

A new structure-directing agent for the synthesis of pure-phase ZSM-11
journal, November 2001


Evidence for semi-regularly ordered sequences of mirror and inversion symmetry planes in ZSM-5/ZSM-11 shape-selective zeolitic catalysts
journal, January 1983

  • Millward, G. Robert; Ramdas, Subramaniam; Thomas, John M.
  • Journal of the Chemical Society, Faraday Transactions 2, Vol. 79, Issue 7
  • DOI: 10.1039/f29837901075

TUD-C: A tunable, hierarchically structured mesoporous zeolite composite
journal, April 2009


The synthesis of discrete colloidal particles of TPA-silicalite-1
journal, September 1994


Architecture at the Nanoscale-Self-Pillared Zeolite Nanosheets
journal, November 2012


Zeolites and molecular sieves: not just ordinary catalysts
journal, August 1991

  • Davis, Mark E.
  • Industrial & Engineering Chemistry Research, Vol. 30, Issue 8
  • DOI: 10.1021/ie00056a001

Aggregative Growth of Silicalite-1
journal, April 2007

  • Kumar, Sandeep; Davis, Tracy M.; Ramanan, Harikrishnan
  • The Journal of Physical Chemistry B, Vol. 111, Issue 13
  • DOI: 10.1021/jp0677445

Hierarchical zeolites: enhanced utilisation of microporous crystals in catalysis by advances in materials design
journal, January 2008

  • Pérez-Ramírez, Javier; Christensen, Claus H.; Egeblad, Kresten
  • Chemical Society Reviews, Vol. 37, Issue 11
  • DOI: 10.1039/b809030k

Hierarchical nanofabrication of microporous crystals with ordered mesoporosity
journal, October 2008

  • Fan, Wei; Snyder, Mark A.; Kumar, Sandeep
  • Nature Materials, Vol. 7, Issue 12
  • DOI: 10.1038/nmat2302

Surface Patterned Porous Films by Convection-Assisted Dynamic Self-Assembly of Zeolite Nanoparticles
journal, May 2001

  • Wang, Huanting; Wang, Zhengbao; Huang, Limin
  • Langmuir, Vol. 17, Issue 9
  • DOI: 10.1021/la0102509

Mechanism of Structure Direction in the Synthesis of Pure-Silica Zeolites. 2. Hydrophobic Hydration and Structural Specificity
journal, August 1995

  • Burkett, Sandra L.; Davis, Mark E.
  • Chemistry of Materials, Vol. 7, Issue 8
  • DOI: 10.1021/cm00056a009

Solving the generalized indirect Fourier transformation (GIFT) by Boltzmann simplex simulated annealing (BSSA)
journal, October 2000


Formation of Hierarchically Organized Zeolites by Sequential Intergrowth
journal, February 2013

  • Chaikittisilp, Watcharop; Suzuki, Yuki; Mukti, Rino R.
  • Angewandte Chemie, Vol. 125, Issue 12
  • DOI: 10.1002/ange.201209638

Hydrothermal Synthesis of Zeolites with Three-Dimensionally Ordered Mesoporous-Imprinted Structure
journal, August 2011

  • Chen, Huiyong; Wydra, James; Zhang, Xueyi
  • Journal of the American Chemical Society, Vol. 133, Issue 32
  • DOI: 10.1021/ja2046815

Synthesis and identification of pentasil intergrowth structures
journal, September 1986


Understanding the Unusual Adsorption Behavior in Hierarchical Zeolite Nanosheets
journal, May 2014


On the Synthesis and Adsorption Properties of Single-Unit-Cell Hierarchical Zeolites Made by Rotational Intergrowths
journal, September 2013

  • Xu, Dandan; Swindlehurst, Garrett R.; Wu, Haohan
  • Advanced Functional Materials, Vol. 24, Issue 2
  • DOI: 10.1002/adfm.201301975

Zeolite and molecular sieve synthesis
journal, July 1992

  • Davis, Mark E.; Lobo, Raul F.
  • Chemistry of Materials, Vol. 4, Issue 4
  • DOI: 10.1021/cm00022a005

Stable single-unit-cell nanosheets of zeolite MFI as active and long-lived catalysts
journal, September 2009

  • Choi, Minkee; Na, Kyungsu; Kim, Jeongnam
  • Nature, Vol. 461, Issue 7261, p. 246-249
  • DOI: 10.1038/nature08288

Ordered porous materials for emerging applications
journal, June 2002


Synthesis of Self-Pillared Zeolite Nanosheets by Repetitive Branching
journal, June 2012


Mechanism of Structure Direction in the Synthesis of Si-ZSM-5: An Investigation by Intermolecular 1H-29Si CP MAS NMR
journal, April 1994

  • Burkett, Sandra L.; Davis, Mark E.
  • The Journal of Physical Chemistry, Vol. 98, Issue 17
  • DOI: 10.1021/j100068a027

Alkylammonium polycations as structure-directing agents in MFI zeolite synthesis
journal, June 1998


Heteroepitaxial Growth of a Zeolite
journal, March 2001


Variation of particle size and its distribution during the synthesis of silicalite-1 nanocrystals
journal, January 2012


Characterization of nanoporous materials from adsorption and desorption isotherms
journal, August 2001

  • Ravikovitch, Peter I.; Neimark, Alexander V.
  • Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 187-188
  • DOI: 10.1016/S0927-7757(01)00614-8

High-resolution electron microscopy study on the growth of zeolite L nanoclusters
journal, February 1996


Characterization of Zeolite L Nanoclusters
journal, September 1995

  • Tsapatsis, Michael; Lovallo, Mark; Okubo, Tatsuya
  • Chemistry of Materials, Vol. 7, Issue 9
  • DOI: 10.1021/cm00057a025

On the Direct Imaging of Offretite, Cancrinite, Chabazite and other Related ABC-6 Zeolites and their Intergrowths
journal, May 1985

  • Millward, G. R.; Ramdas, S.; Thomas, J. M.
  • Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 399, Issue 1816
  • DOI: 10.1098/rspa.1985.0047

Sub-40 nm Zeolite Suspensions via Disassembly of Three-Dimensionally Ordered Mesoporous-Imprinted Silicalite-1
journal, January 2011

  • Lee, Pyung-Soo; Zhang, Xueyi; Stoeger, Jared A.
  • Journal of the American Chemical Society, Vol. 133, Issue 3, p. 493-502
  • DOI: 10.1021/ja107942n

Evolution of Self-Assembled Silica−Tetrapropylammonium Nanoparticles at Elevated Temperatures
journal, July 2005

  • Rimer, Jeffrey D.; Vlachos, Dionisios G.; Lobo, Raul F.
  • The Journal of Physical Chemistry B, Vol. 109, Issue 26
  • DOI: 10.1021/jp052045y

Synthesis strategies in the search for hierarchical zeolites
journal, January 2013

  • Serrano, D. P.; Escola, J. M.; Pizarro, P.
  • Chem. Soc. Rev., Vol. 42, Issue 9
  • DOI: 10.1039/C2CS35330J

Enhanced Molecular Transport in Hierarchical Silicalite-1
journal, October 2013

  • Chang, Chun-Chih; Teixeira, Andrew R.; Li, Chao
  • Langmuir, Vol. 29, Issue 45
  • DOI: 10.1021/la403706r

2-dimensional zeolites
journal, May 2014


Mechanism of the Transformation of Silica Precursor Solutions into Si-MFI Zeolite
journal, July 2002


Connectivity Analysis of the Clear Sol Precursor of Silicalite: Are Nanoparticles Aggregated Oligomers or Silica Particles?
journal, August 2009

  • Petry, David P.; Haouas, Mohamed; Wong, Stephen C. C.
  • The Journal of Physical Chemistry C, Vol. 113, Issue 49
  • DOI: 10.1021/jp906276g

Pillared MFI Zeolite Nanosheets of a Single-Unit-Cell Thickness
journal, March 2010

  • Na, Kyungsu; Choi, Minkee; Park, Woojin
  • Journal of the American Chemical Society, Vol. 132, Issue 12, p. 4169-4177
  • DOI: 10.1021/ja908382n