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Title: Catalytic production of methyl acrylates by gold-mediated cross coupling of unsaturated aldehydes with methanol

Journal Article · · Surface Science

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Integrated Mesoscale Architectures for Sustainable Catalysis (IMASC)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
SC0012573
OSTI ID:
1387547
Journal Information:
Surface Science, Vol. 652, Issue C; Related Information: IMASC partners with Harvard University (lead); Fritz Haber Institute; Lawrence Berkeley National Laboratory; Lawrence Livermore National Laboratory; University of Kansas; Tufts University; ISSN 0039-6028
Publisher:
Elsevier
Country of Publication:
United States
Language:
English

References (30)

Modified extra-large mesoporous silica supported Au–Ni as a highly efficient catalyst for oxidative coupling of aldehydes with methanol journal January 2014
Pd–Pb/SDB Bimetallic Catalysts for The Direct Oxidative Esterification of Methacrolein to Methyl Methacrylate journal November 2012
Aerobic Oxidative Esterification of Aldehydes with Alcohols by Gold–Nickel Oxide Nanoparticle Catalysts with a Core–Shell Structure journal July 2013
Theoretical Study of O-Assisted Selective Coupling of Methanol on Au(111) journal February 2011
Solvent-free Oxidation of Primary Alcohols to Aldehydes using Supported Gold Catalysts journal September 2005
Gold-Catalyzed Carbon−Heteroatom Bond-Forming Reactions journal March 2011
Surface-Mediated Self-Coupling of Ethanol on Gold journal April 2009
Selectivity Control in Gold-Mediated Esterification of Methanol journal May 2009
Achieving Optimum Selectivity in Oxygen Assisted Alcohol Cross-Coupling on Gold journal November 2010
Oxidative coupling of alcohols on gold: Insights from experiments and theory journal January 2011
Dual-Function of Alcohols in Gold-Mediated Selective Coupling of Amines and Alcohols journal January 2012
A paradigm for predicting selective oxidation on noble metals: oxidative catalytic coupling of amines and aldehydes on metallic gold journal January 2011
Methyl ester synthesis catalyzed by nanoporous gold: from 10 −9 Torr to 1 atm journal January 2015
Exploiting basic principles to control the selectivity of the vapor phase catalytic oxidative cross-coupling of primary alcohols over nanoporous gold catalysts journal September 2015
van der Waals Interactions Determine Selectivity in Catalysis by Metallic Gold journal September 2014
Continuous Catalytic Production of Methyl Acrylates from Unsaturated Alcohols by Gold: The Strong Effect of C═C Unsaturation on Reaction Selectivity journal February 2016
Nanoporous Gold Leaf: ?Ancient Technology?/Advanced Material journal November 2004
Nanoporous Gold Catalysts for Selective Gas-Phase Oxidative Coupling of Methanol at Low Temperature journal January 2010
Atomic origins of the high catalytic activity of nanoporous gold journal August 2012
Atomic Observation of Catalysis-Induced Nanopore Coarsening of Nanoporous Gold journal February 2014
Partial Oxidation of Propene on Oxygen-Covered Au(111) journal August 2006
Silver residues as a possible key to a remarkable oxidative catalytic activity of nanoporous gold journal January 2011
From model studies on Au(111) to working conditions with unsupported nanoporous gold catalysts: Oxygen-assisted coupling reactions journal December 2013
Through the labyrinth of surface reaction mechanism: a personal account, 1964–1992 journal January 1994
Adsorption of oxygen on Au(111) by exposure to ozone journal August 1998
Enhancement of O 2 Dissociation on Au(111) by Adsorbed Oxygen:  Implications for Oxidation Catalysis journal June 2005
Facile Ester Synthesis on Ag-Modified Nanoporous Au: Oxidative Coupling of Ethanol and 1-Butanol Under UHV Conditions journal April 2015
Toward Controlled Modification of Nanoporous Gold. A Detailed Surface Science Study on Cleaning and Oxidation journal February 2012
Oxygen chemisorption on Au()-(1×2) I. Thermal desorption measurements journal February 2003
Ozone-Activated Nanoporous Gold: A Stable and Storable Material for Catalytic Oxidation journal June 2015

Cited By (2)

Identifying key descriptors in surface binding: interplay of surface anchoring and intermolecular interactions for carboxylates on Au(110) journal January 2018
Bio‐Acrylates Production: Recent Catalytic Advances and Perspectives of the Use of Lactic Acid and Their Derivates journal October 2018