Liquid-Like Ionic Conduction in Solid Lithium and Sodium Monocarba- closo -Decaborates Near or at Room Temperature

Tang, Wan Si; Matsuo, Motoaki; Wu, Hui; Stavila, Vitalie; Zhou, Wei; Talin, Albert Alec; Soloninin, Alexei V.; Skoryunov, Roman V.; Babanova, Olga A.; Skripov, Alexander V.; Unemoto, Atsushi; Orimo, Shin-Ichi; Udovic, Terrence J.

doi:10.1002/aenm.201502237

Title: Liquid-Like Ionic Conduction in Solid Lithium and Sodium Monocarba- closo -Decaborates Near or at Room Temperature

Journal Article · Fri Feb 05 00:00:00 EST 2016 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201502237· OSTI ID:1387536

Tang, Wan Si ^[1]; Matsuo, Motoaki ^[2]; Wu, Hui ^[3]; Stavila, Vitalie ^[4]; Zhou, Wei ^[3]; Talin, Albert Alec ^[4]; Soloninin, Alexei V. ^[5]; Skoryunov, Roman V. ^[5]; Babanova, Olga A. ^[5]; Skripov, Alexander V. ^[5]; Unemoto, Atsushi ^[6]; Orimo, Shin-Ichi ^[7]; Udovic, Terrence J. ^[3]

Department of Materials Science and Engineering, University of Maryland, College Park MD 20742-2115 USA; NIST Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg MD 20899-6102 USA
Institute for Materials Research, Tohoku University, Sendai 980-8577 Japan
NIST Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg MD 20899-6102 USA
Energy Nanomaterials, Sandia National Laboratories, Livermore CA 94551 USA
Institute of Metal Physics, Ural Branch of the Russian Academy of Sciences, Ekaterinburg 620990 Russia
WPI-Advanced Institute for Materials Research, Tohoku University, Sendai 980-8577 Japan
Institute for Materials Research, Tohoku University, Sendai 980-8577 Japan; WPI-Advanced Institute for Materials Research, Tohoku University, Sendai 980-8577 Japan

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Nanostructures for Electrical Energy Storage (NEES)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

DOE Contract Number:: SC0001160

OSTI ID:: 1387536

Journal Information:: Advanced Energy Materials, Vol. 6, Issue 8; Related Information: NEES partners with University of Maryland (lead); University of California, Irvine; University of Florida; Los Alamos National Laboratory; Sandia National Laboratories; Yale University; ISSN 1614-6832

Publisher:: Wiley

Country of Publication:: United States

Language:: English

References (22)

Sodium superionic conduction in Na ₂ B ₁₂ H ₁₂ Udovic, Terrence J.; Matsuo, Motoaki; Unemoto, Atsushi Chem. Commun., Vol. 50, Issue 28 https://doi.org/10.1039/c3cc49805k	journal	January 2014
Nuclear Magnetic Resonance Study of Atomic Motion in A ₂ B ₁₂ H ₁₂ (A = Na, K, Rb, Cs): Anion Reorientations and Na ⁺ Mobility Skripov, Alexander V.; Babanova, Olga A.; Soloninin, Alexei V. The Journal of Physical Chemistry C, Vol. 117, Issue 49 https://doi.org/10.1021/jp4106585	journal	November 2013
Nanoconfined LiBH ₄ as a Fast Lithium Ion Conductor Blanchard, Didier; Nale, Angeloclaudio; Sveinbjörnsson, Dadi Advanced Functional Materials, Vol. 25, Issue 2 https://doi.org/10.1002/adfm.201402538	journal	October 2014
Anion Reorientations and Cation Diffusion in LiCB ₁₁ H ₁₂ and NaCB ₁₁ H ₁₂ : ¹ H, ⁷ Li, and ²³ Na NMR Studies Skripov, Alexander V.; Skoryunov, Roman V.; Soloninin, Alexei V. The Journal of Physical Chemistry C, Vol. 119, Issue 48 https://doi.org/10.1021/acs.jpcc.5b10055	journal	November 2015
Lithium Fast-Ionic Conduction in Complex Hydrides: Review and Prospects Matsuo, Motoaki; Orimo, Shin-ichi Advanced Energy Materials, Vol. 1, Issue 2 https://doi.org/10.1002/aenm.201000012	journal	January 2011
Anion Reorientations in the Superionic Conducting Phase of Na ₂ B ₁₂ H ₁₂ Verdal, Nina; Udovic, Terrence J.; Stavila, Vitalie The Journal of Physical Chemistry C, Vol. 118, Issue 31 https://doi.org/10.1021/jp506252c	journal	July 2014
First-order phase transition in the Li2B12H12 system Paskevicius, Mark; Pitt, Mark P.; Brown, David H. Physical Chemistry Chemical Physics, Vol. 15, Issue 38 https://doi.org/10.1039/c3cp53090f	journal	January 2013
The structure of monoclinic Na ₂ B ₁₀ H ₁₀ : a combined diffraction, spectroscopy, and theoretical approach Wu, Hui; Tang, Wan Si; Zhou, Wei CrystEngComm, Vol. 17, Issue 18 https://doi.org/10.1039/C5CE00369E	journal	January 2015
Stable Interface Formation between TiS ₂ and LiBH ₄ in Bulk-Type All-Solid-State Lithium Batteries Unemoto, Atsushi; Ikeshoji, Tamio; Yasaku, Syun Chemistry of Materials, Vol. 27, Issue 15 https://doi.org/10.1021/acs.chemmater.5b02110	journal	July 2015
Unparalleled lithium and sodium superionic conduction in solid electrolytes with large monovalent cage-like anions Tang, Wan Si; Unemoto, Atsushi; Zhou, Wei Energy & Environmental Science, Vol. 8, Issue 12 https://doi.org/10.1039/C5EE02941D	journal	January 2015
1-B ₉ H ₉ CH ^- and B ₁₁ H ₁₁ CH ^- Knoth, W. H. Journal of the American Chemical Society, Vol. 89, Issue 5 https://doi.org/10.1021/ja00981a048	journal	March 1967
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
Exceptional Superionic Conductivity in Disordered Sodium Decahydro- closo -decaborate Udovic, Terrence J.; Matsuo, Motoaki; Tang, Wan Si Advanced Materials, Vol. 26, Issue 45 https://doi.org/10.1002/adma.201403157	journal	October 2014
Structural Behavior of Li ₂ B ₁₀ H ₁₀ Wu, Hui; Tang, Wan Si; Stavila, Vitalie The Journal of Physical Chemistry C, Vol. 119, Issue 12 https://doi.org/10.1021/acs.jpcc.5b00533	journal	March 2015
Lithium superionic conduction in lithium borohydride accompanied by structural transition Matsuo, Motoaki; Nakamori, Yuko; Orimo, Shin-ichi Applied Physics Letters, Vol. 91, Issue 22 https://doi.org/10.1063/1.2817934	journal	November 2007
Complex Hydrides for Electrochemical Energy Storage Unemoto, Atsushi; Matsuo, Motoaki; Orimo, Shin-ichi Advanced Functional Materials, Vol. 24, Issue 16 https://doi.org/10.1002/adfm.201303147	journal	January 2014
Na ₃ PSe ₄ : A Novel Chalcogenide Solid Electrolyte with High Ionic Conductivity Zhang, Long; Yang, Kun; Mi, Jianli Advanced Energy Materials, Vol. 5, Issue 24 https://doi.org/10.1002/aenm.201501294	journal	October 2015
New, Highly Ion-Conductive Crystals Precipitated from Li₂S-P₂S₅ Glasses Mizuno, F.; Hayashi, A.; Tadanaga, K. Advanced Materials, Vol. 17, Issue 7, p. 918-921 https://doi.org/10.1002/adma.200401286	journal	April 2005
Complex high-temperature phase transitions in Li2B12H12 and Na2B12H12 Verdal, Nina; Her, Jae-Hyuk; Stavila, Vitalie Journal of Solid State Chemistry, Vol. 212 https://doi.org/10.1016/j.jssc.2014.01.006	journal	April 2014
A lithium superionic conductor Kamaya, Noriaki; Homma, Kenji; Yamakawa, Yuichiro Nature Materials, Vol. 10, Issue 9, p. 682-686 https://doi.org/10.1038/nmat3066	journal	July 2011
A Battery Made from a Single Material Han, Fudong; Gao, Tao; Zhu, Yujie Advanced Materials, Vol. 27, Issue 23 https://doi.org/10.1002/adma.201500180	journal	April 2015
Superionic Conduction of Sodium and Lithium in Anion-Mixed Hydroborates Na ₃ BH ₄ B ₁₂ H ₁₂ and (Li _0.7 Na _0.3 ) ₃ BH ₄ B ₁₂ H ₁₂ Sadikin, Yolanda; Brighi, Matteo; Schouwink, Pascal Advanced Energy Materials, Vol. 5, Issue 21 https://doi.org/10.1002/aenm.201501016	journal	August 2015

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Quantitative Assessment of B−B−B, B−H _b −B, and B−H _t Bonds: From BH ₃ to B ₁₂ H ₁₂ ²⁻ Sethio, Daniel; Daku, Latévi Max Lawson; Hagemann, Hans ChemPhysChem, Vol. 20, Issue 15 https://doi.org/10.1002/cphc.201900364	journal	July 2019
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The renaissance of hydrides as energy materials Mohtadi, Rana; Orimo, Shin-ichi Nature Reviews Materials, Vol. 2, Issue 3 https://doi.org/10.1038/natrevmats.2016.91	journal	December 2016
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