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Title: Decoration of the layered manganese oxide birnessite with Mn(ii/iii) gives a new water oxidation catalyst with fifty-fold turnover number enhancement

Abstract

The role of the manganese average oxidation state (AOS) in water oxidation catalysis by birnessite was investigated.

Authors:
 [1];  [1];  [1];  [1];  [1]
  1. Department of Chemistry; Temple University; Philadelphia; USA
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for the Computational Design of Functional Layered Materials (CCDM)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1387350
DOE Contract Number:  
SC0012575
Resource Type:
Journal Article
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Volume: 44; Journal Issue: 29; Related Information: CCDM partners with Temple University (lead); Brookhaven National Laboratory; Drexel University; Duke University; North Carolina State University; Northeastern University; Princeton University; Rice University; University of Pennsylvania; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
catalysis (heterogeneous), solar (photovoltaic), energy storage (including batteries and capacitors), hydrogen and fuel cells, defects, mechanical behavior, materials and chemistry by design, synthesis (novel materials)

Citation Formats

McKendry, Ian G., Kondaveeti, Sandeep K., Shumlas, Samantha L., Strongin, Daniel R., and Zdilla, Michael J. Decoration of the layered manganese oxide birnessite with Mn(ii/iii) gives a new water oxidation catalyst with fifty-fold turnover number enhancement. United States: N. p., 2015. Web. doi:10.1039/C5DT01436K.
McKendry, Ian G., Kondaveeti, Sandeep K., Shumlas, Samantha L., Strongin, Daniel R., & Zdilla, Michael J. Decoration of the layered manganese oxide birnessite with Mn(ii/iii) gives a new water oxidation catalyst with fifty-fold turnover number enhancement. United States. doi:10.1039/C5DT01436K.
McKendry, Ian G., Kondaveeti, Sandeep K., Shumlas, Samantha L., Strongin, Daniel R., and Zdilla, Michael J. Thu . "Decoration of the layered manganese oxide birnessite with Mn(ii/iii) gives a new water oxidation catalyst with fifty-fold turnover number enhancement". United States. doi:10.1039/C5DT01436K.
@article{osti_1387350,
title = {Decoration of the layered manganese oxide birnessite with Mn(ii/iii) gives a new water oxidation catalyst with fifty-fold turnover number enhancement},
author = {McKendry, Ian G. and Kondaveeti, Sandeep K. and Shumlas, Samantha L. and Strongin, Daniel R. and Zdilla, Michael J.},
abstractNote = {The role of the manganese average oxidation state (AOS) in water oxidation catalysis by birnessite was investigated.},
doi = {10.1039/C5DT01436K},
journal = {Dalton Transactions},
issn = {1477-9226},
number = 29,
volume = 44,
place = {United States},
year = {2015},
month = {1}
}

Works referenced in this record:

Water-oxidation catalysis by synthetic manganese oxides – systematic variations of the calcium birnessite theme
journal, January 2014

  • Frey, Carolin E.; Wiechen, Mathias; Kurz, Philipp
  • Dalton Trans., Vol. 43, Issue 11
  • DOI: 10.1039/C3DT52604F

Photochemical Water Oxidation by Crystalline Polymorphs of Manganese Oxides: Structural Requirements for Catalysis
journal, February 2013

  • Robinson, David M.; Go, Yong Bok; Mui, Michelle
  • Journal of the American Chemical Society, Vol. 135, Issue 9
  • DOI: 10.1021/ja310286h

The synthesis of birnessite, cryptomelane, and some other oxides and hydroxides of manganese
journal, December 1971


XPS study of reductive dissolution of 7Å-birnessite by H3AsO3, with constraints on reaction mechanism
journal, June 1998


Relationship between Pb<SUP>2+</SUP> adsorption and average Mn oxidation state in synthetic birnessites
journal, October 2009


Active Mixed-Valent MnO x Water Oxidation Catalysts through Partial Oxidation (Corrosion) of Nanostructured MnO Particles
journal, October 2013

  • Indra, Arindam; Menezes, Prashanth W.; Zaharieva, Ivelina
  • Angewandte Chemie International Edition, Vol. 52, Issue 50
  • DOI: 10.1002/anie.201307543

Energetic basis of catalytic activity of layered nanophase calcium manganese oxides for water oxidation
journal, May 2013

  • Birkner, N.; Nayeri, S.; Pashaei, B.
  • Proceedings of the National Academy of Sciences, Vol. 110, Issue 22
  • DOI: 10.1073/pnas.1306623110

Solar Water Splitting Cells
journal, November 2010

  • Walter, Michael G.; Warren, Emily L.; McKone, James R.
  • Chemical Reviews, Vol. 110, Issue 11, p. 6446-6473
  • DOI: 10.1021/cr1002326

Oxygen-evolving complex of photosystem II: correlating structure with spectroscopy
journal, January 2014

  • Pokhrel, Ravi; Brudvig, Gary W.
  • Physical Chemistry Chemical Physics, Vol. 16, Issue 24
  • DOI: 10.1039/c4cp00493k

Inhibition of Charge Disproportionation of MnO 2 Electrocatalysts for Efficient Water Oxidation under Neutral Conditions
journal, October 2012

  • Takashima, Toshihiro; Hashimoto, Kazuhito; Nakamura, Ryuhei
  • Journal of the American Chemical Society, Vol. 134, Issue 44
  • DOI: 10.1021/ja306499n

Layered manganese oxides for water-oxidation: alkaline earth cations influence catalytic activity in a photosystem II-like fashion
journal, January 2012

  • Wiechen, Mathias; Zaharieva, Ivelina; Dau, Holger
  • Chemical Science, Vol. 3, Issue 7
  • DOI: 10.1039/c2sc20226c