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Title: FeO 0.7 F 1.3 /C Nanocomposite as a High-Capacity Cathode Material for Sodium-Ion Batteries

 [1];  [2];  [3];  [1];  [3];  [1];  [2];  [4]
  1. Department of Chemistry, Brookhaven National Laboratory, Upton New York 11973 USA
  2. Materials Science and Engineering, Rutgers University, Piscataway New Jersey 08854 USA
  3. Energy Storage Research Group (ESRG), Rutgers University, North Brunswick New Jersey 08902 USA
  4. Department of Energy and Materials Engineering, Dongguk University-Seoul, 100715 Seoul Republic of Korea
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Northeastern Center for Chemical Energy Storage (NECCES)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
DOE Contract Number:  
Resource Type:
Journal Article
Journal Name:
Advanced Functional Materials
Additional Journal Information:
Journal Volume: 25; Journal Issue: 5; Related Information: NECCES partners with Stony Brook University (lead); Argonne National Laboratory; Binghamton University; Brookhaven National University; University of California, San Diego; University of Cambridge, UK; Lawrence Berkeley National Laboratory; Massachusetts Institute of Technology; University of Michigan; Rutgers University; Journal ID: ISSN 1616-301X
Country of Publication:
United States
energy storage (including batteries and capacitors), defects, charge transport, materials and chemistry by design, synthesis (novel materials)

Citation Formats

Zhou, Yong-Ning, Sina, Mahsa, Pereira, Nathalie, Yu, Xiqian, Amatucci, Glenn G., Yang, Xiao-Qing, Cosandey, Frederic, and Nam, Kyung-Wan. FeO 0.7 F 1.3 /C Nanocomposite as a High-Capacity Cathode Material for Sodium-Ion Batteries. United States: N. p., 2014. Web. doi:10.1002/adfm.201403241.
Zhou, Yong-Ning, Sina, Mahsa, Pereira, Nathalie, Yu, Xiqian, Amatucci, Glenn G., Yang, Xiao-Qing, Cosandey, Frederic, & Nam, Kyung-Wan. FeO 0.7 F 1.3 /C Nanocomposite as a High-Capacity Cathode Material for Sodium-Ion Batteries. United States. doi:10.1002/adfm.201403241.
Zhou, Yong-Ning, Sina, Mahsa, Pereira, Nathalie, Yu, Xiqian, Amatucci, Glenn G., Yang, Xiao-Qing, Cosandey, Frederic, and Nam, Kyung-Wan. Thu . "FeO 0.7 F 1.3 /C Nanocomposite as a High-Capacity Cathode Material for Sodium-Ion Batteries". United States. doi:10.1002/adfm.201403241.
title = {FeO 0.7 F 1.3 /C Nanocomposite as a High-Capacity Cathode Material for Sodium-Ion Batteries},
author = {Zhou, Yong-Ning and Sina, Mahsa and Pereira, Nathalie and Yu, Xiqian and Amatucci, Glenn G. and Yang, Xiao-Qing and Cosandey, Frederic and Nam, Kyung-Wan},
abstractNote = {},
doi = {10.1002/adfm.201403241},
journal = {Advanced Functional Materials},
issn = {1616-301X},
number = 5,
volume = 25,
place = {United States},
year = {2014},
month = {11}

Works referenced in this record:

Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries
journal, September 2000

  • Poizot, P.; Laruelle, S.; Grugeon, S.
  • Nature, Vol. 407, Issue 6803, p. 496-499
  • DOI: 10.1038/35035045

ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005

Mixed Transition-Metal Oxides: Design, Synthesis, and Energy-Related Applications
journal, January 2014

  • Yuan, Changzhou; Wu, Hao Bin; Xie, Yi
  • Angewandte Chemie International Edition, Vol. 53, Issue 6
  • DOI: 10.1002/anie.201303971

Carbon Metal Fluoride Nanocomposites: High-Capacity Reversible Metal Fluoride Conversion Materials as Rechargeable Positive Electrodes for Li Batteries
journal, January 2003

  • Badway, F.; Cosandey, F.; Pereira, N.
  • Journal of The Electrochemical Society, Vol. 150, Issue 10, p. A1318-A1327
  • DOI: 10.1149/1.1602454

Conversion reactions for sodium-ion batteries
journal, January 2013

  • Klein, Franziska; Jache, Birte; Bhide, Amrtha
  • Physical Chemistry Chemical Physics, Vol. 15, Issue 38
  • DOI: 10.1039/c3cp52125g

Sodium deintercalation from sodium iron oxide
journal, June 1994

Electrochemistry of V2ON with lithium
journal, June 2011

The Electrochemistry of Zn[sub 3]N[sub 2] and LiZnN
journal, January 2002

  • Pereira, N.; Klein, L. C.; Amatucci, G. G.
  • Journal of The Electrochemical Society, Vol. 149, Issue 3
  • DOI: 10.1149/1.1446079

A Novel Silver Molybdenum Oxyfluoride Perovskite as a Cathode Material for Lithium Batteries
journal, May 2009

  • Tong, W.; Yoon, W. -S.; Hagh, N. M.
  • Chemistry of Materials, Vol. 21, Issue 10
  • DOI: 10.1021/cm803322d

Scalable Synthesis of Tavorite LiFeSO4F and NaFeSO4F Cathode Materials
journal, October 2010

  • Tripathi, Rajesh; Ramesh, T. N.; Ellis, Brian L.
  • Angewandte Chemie International Edition, Vol. 49, Issue 46
  • DOI: 10.1002/anie.201003743

Synthesis, Structure, and Electrochemistry of Silver Niobium Oxyfluorides for Lithium Batteries
journal, January 2009

  • Tong, W.; Amatucci, G. G.
  • Electrochemical and Solid-State Letters, Vol. 12, Issue 11
  • DOI: 10.1149/1.3213565

Voltage, stability and diffusion barrier differences between sodium-ion and lithium-ion intercalation materials
journal, January 2011

  • Ong, Shyue Ping; Chevrier, Vincent L.; Hautier, Geoffroy
  • Energy & Environmental Science, Vol. 4, Issue 9
  • DOI: 10.1039/c1ee01782a

Tracking lithium transport and electrochemical reactions in nanoparticles
journal, January 2012

  • Wang, Feng; Yu, Hui-Chia; Chen, Min-Hua
  • Nature Communications, Vol. 3, Issue 1
  • DOI: 10.1038/ncomms2185

An FeF 3 ·0.5H 2 O Polytype: A Microporous Framework Compound with Intersecting Tunnels for Li and Na Batteries
journal, July 2013

  • Li, Chilin; Yin, Congling; Gu, Lin
  • Journal of the American Chemical Society, Vol. 135, Issue 31
  • DOI: 10.1021/ja402061q

Li-Storage via Heterogeneous Reaction in Selected Binary Metal Fluorides and Oxides
journal, January 2004

  • Li, Hong; Balaya, Palani; Maier, Joachim
  • Journal of The Electrochemical Society, Vol. 151, Issue 11, p. A1878-A1885
  • DOI: 10.1149/1.1801451

Accurate Control of Multishelled Co 3 O 4 Hollow Microspheres as High-Performance Anode Materials in Lithium-Ion Batteries
journal, May 2013

  • Wang, Jiangyan; Yang, Nailiang; Tang, Hongjie
  • Angewandte Chemie International Edition, Vol. 52, Issue 25
  • DOI: 10.1002/anie.201301622

Cathode properties of metal trifluorides in Li and Na secondary batteries
journal, May 2009

Carbon-Metal Fluoride Nanocomposites: Structure and Electrochemistry of FeF3 : C
journal, January 2003

  • Badway, F.; Pereira, N.; Cosandey, F.
  • Journal of The Electrochemical Society, Vol. 150, Issue 9, p. A1209-A1218
  • DOI: 10.1149/1.1596162

Na-ion batteries, recent advances and present challenges to become low cost energy storage systems
journal, January 2012

  • Palomares, Verónica; Serras, Paula; Villaluenga, Irune
  • Energy & Environmental Science, Vol. 5, Issue 3
  • DOI: 10.1039/c2ee02781j

The investigation on electrochemical reaction mechanism of CuF2 thin film with lithium
journal, February 2011

Origin of additional capacities in metal oxide lithium-ion battery electrodes
journal, November 2013

  • Hu, Yan-Yan; Liu, Zigeng; Nam, Kyung-Wan
  • Nature Materials, Vol. 12, Issue 12
  • DOI: 10.1038/nmat3784

Sodium-Ion Batteries
journal, May 2012

  • Slater, Michael D.; Kim, Donghan; Lee, Eungje
  • Advanced Functional Materials, Vol. 23, Issue 8, p. 947-958
  • DOI: 10.1002/adfm.201200691

Electrochemistry of Cu[sub 3]N with Lithium
journal, January 2003

  • Pereira, N.; Dupont, L.; Tarascon, J. M.
  • Journal of The Electrochemical Society, Vol. 150, Issue 9
  • DOI: 10.1149/1.1599845

P2-type Nax[Fe1/2Mn1/2]O2 made from earth-abundant elements for rechargeable Na batteries
journal, April 2012

  • Yabuuchi, Naoaki; Kajiyama, Masataka; Iwatate, Junichi
  • Nature Materials, Vol. 11, Issue 6
  • DOI: 10.1038/nmat3309

Growth and Electrochemical Characterization versus Lithium of Fe3O4 Electrodes Made by Electrodeposition
journal, November 2006

  • Mitra, S.; Poizot, P.; Finke, A.
  • Advanced Functional Materials, Vol. 16, Issue 17
  • DOI: 10.1002/adfm.200500753

Electrochemically active silver molybdenum oxyfluoride perovskite: Synthesis and in situ electrochemical characterization
journal, October 2010

Structural phase transformation and Fe valence evolution in FeOxF2−x/C nanocomposite electrodes during lithiation and de-lithiation processes
journal, January 2013

  • Sina, M.; Nam, K. -W.; Su, D.
  • Journal of Materials Chemistry A, Vol. 1, Issue 38
  • DOI: 10.1039/c3ta12109g

Novel synthesis and electrochemical properties of perovskite-type NaFeF3 for a sodium-ion battery
journal, January 2012

Enhanced Potential of Amorphous Electrode Materials: Case Study of RuO2
journal, February 2008

Iron Oxyfluorides as High Capacity Cathode Materials for Lithium Batteries
journal, January 2009

  • Pereira, N.; Badway, F.; Wartelsky, M.
  • Journal of The Electrochemical Society, Vol. 156, Issue 6, p. A407-A416
  • DOI: 10.1149/1.3106132

Synthesis, Structure, and Electrochemical Properties of the Layered Sodium Insertion Cathode Material: NaNi 1 / 3 Mn 1 / 3 Co 1 / 3 O 2
journal, April 2012

  • Sathiya, M.; Hemalatha, K.; Ramesha, K.
  • Chemistry of Materials, Vol. 24, Issue 10
  • DOI: 10.1021/cm300466b

Mesoporous and nanowire Co 3 O 4 as negative electrodes for rechargeable lithium batteries
journal, January 2007

  • Shaju, Kuthanapillil M.; Jiao, Feng; Débart, Aurélie
  • Phys. Chem. Chem. Phys., Vol. 9, Issue 15
  • DOI: 10.1039/B617519H

Synthesis of porous-CoN nanoparticles and their application as a high capacity anode for lithium-ion batteries
journal, January 2012

  • Das, B.; Reddy, M. V.; Rao, G. V. Subba
  • Journal of Materials Chemistry, Vol. 22, Issue 34
  • DOI: 10.1039/c2jm31969a

The electrochemistry of nanostructured In2O3 with lithium
journal, November 2006

Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries
journal, May 2012

  • Kim, Sung-Wook; Seo, Dong-Hwa; Ma, Xiaohua
  • Advanced Energy Materials, Vol. 2, Issue 7, p. 710-721
  • DOI: 10.1002/aenm.201200026

Nonstoichiometric, Rutile-Type, Solid Solutions in the FeIIF2–FeIIIOF System
journal, October 2001

  • Brink, Frank J.; Withers, Ray L.; Norén, Lasse
  • Journal of Solid State Chemistry, Vol. 161, Issue 1
  • DOI: 10.1006/jssc.2001.9243

Comprehensive Insights into the Structural and Chemical Changes in Mixed-Anion FeOF Electrodes by Using Operando PDF and NMR Spectroscopy
journal, March 2013

  • Wiaderek, Kamila M.; Borkiewicz, Olaf J.; Castillo-Martínez, Elizabeth
  • Journal of the American Chemical Society, Vol. 135, Issue 10
  • DOI: 10.1021/ja400229v

Electron Diffraction Based Analysis of Phase Fractions and Texture in Nanocrystalline Thin Films, Part III: Application Examples
journal, March 2012

Structure and Electrochemistry of Copper Fluoride Nanocomposites Utilizing Mixed Conducting Matrices
journal, August 2007

  • Badway, F.; Mansour, A. N.; Pereira, N.
  • Chemistry of Materials, Vol. 19, Issue 17, p. 4129-4141
  • DOI: 10.1021/cm070421g