A Reversible Crystallinity-Preserving Phase Transition in Metal–Organic Frameworks: Discovery, Mechanistic Studies, and Potential Applications

Liu, Dahuan; Liu, Tian-Fu; Chen, Ying-Pin; Zou, Lanfang; Feng, Dawei; Wang, Kecheng; Zhang, Qiang; Yuan, Shuai; Zhong, Chongli; Zhou, Hong-Cai

doi:10.1021/jacs.5b02999

Title: A Reversible Crystallinity-Preserving Phase Transition in Metal–Organic Frameworks: Discovery, Mechanistic Studies, and Potential Applications

Journal Article · Tue May 26 00:00:00 EDT 2015 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.5b02999· OSTI ID:1386974

Liu, Dahuan ^[1]; Liu, Tian-Fu ^[2]; Chen, Ying-Pin ^[2]; Zou, Lanfang ^[2]; Feng, Dawei ^[2]; Wang, Kecheng ^[2]; Zhang, Qiang ^[2]; Yuan, Shuai ^[2]; Zhong, Chongli ^[3]; Zhou, Hong-Cai ^[2]

Texas A & M Univ., College Station, TX (United States); Beijing Univ. of Chemical Technology (China)
Texas A & M Univ., College Station, TX (United States)
Beijing Univ. of Chemical Technology (China)

We report a quenching-triggered reversible single-crystalto- single-crystal (SC-SC) phase transition was discovered in a metal–organic framework (MOF) PCN-526. During the phase transition, the one-dimensional channel of PCN-526 distorts from square to rectangular in shape while maintaining single crystallinity. Although SC-SC transformations have been frequently observed in MOFs, most reports have focused on describing the resulting structural alterations without shedding light on the mechanism for the transformation. Interestingly, modifying the occupancy or species of metal ions in the extraframework sites, which provides mechanistic insight into the causes for the transformation, can forbid this phase transition. Moreover, as a host scaffold, PCN-526 presents a platform for modulation of the photoluminescence properties by encapsulation of luminescent guest molecules. Through judicious choice of these guest molecules, responsive luminescence caused by SC-SC transformations can be detected, introducing a new strategy for the design of novel luminescent MOF materials.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations (CGS)

Sponsoring Organization:: USDOE Advanced Research Projects Agency - Energy (ARPA-E); USDOE Office of Science (SC), Basic Energy Sciences (BES); Robert A. Welch Foundation; US Department of the Navy, Office of Naval Research (ONR); National Natural Science Foundation of China (NSFC); National Key Basic Research Program of China; China Scholarship Council (CSC)

Grant/Contract Number:: SC0001015; AR0000249

OSTI ID:: 1386974

Journal Information:: Journal of the American Chemical Society, Vol. 137, Issue 24; Related Information: CGS partners with University of California, Berkeley; University of California, Davis; Lawrence Berkeley National Laboratory; University of Minnesota; National Energy Technology Laboratory; Texas A&M University; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 98 works

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Crystallization and structural properties of a family of isotopological 3D-networks: the case of a 4,4′-bipy ligand–M ²⁺ triflate system Rizzato, Silvia; Moret, Massimo; Beghi, Fabio CrystEngComm, Vol. 20, Issue 26 https://doi.org/10.1039/c8ce00653a	journal	January 2018
Three new Zn-based metal–organic frameworks exhibiting selective fluorescence sensing and photocatalytic activity Wang, Jun-Jie; Zhang, You-Juan; Chen, Yan CrystEngComm, Vol. 20, Issue 27 https://doi.org/10.1039/c8ce00598b	journal	January 2018
Luminescent coordination polymers constructed using a mixed-ligand strategy for highly selective luminescence sensing of nitrobenzene, Fe ³⁺ and Cr ₂ O ₇ ²⁻ ions and photodegradation of rhodamine B Wang, Jun-Jie; Wu, Fei-Fan; Su, Ning CrystEngComm, Vol. 22, Issue 27 https://doi.org/10.1039/d0ce00677g	journal	January 2020
Metal-organic framework based on hinged cube tessellation as transformable mechanical metamaterial Jin, Eunji; Lee, In Seong; Kim, Dongwook Science Advances, Vol. 5, Issue 5 https://doi.org/10.1126/sciadv.aav4119	journal	May 2019
Haloalkane adsorption into 1-D ensembles’ channels: Zn(II) coordination polymers Lee, Haeri; Lee, Daseul; Jung, Ok-Sang Figshare https://doi.org/10.6084/m9.figshare.7067270	text	January 2018
Redox-switchable breathing behavior in tetrathiafulvalene-based metal–organic frameworks Su, Jian; Yuan, Shuai; Wang, Hai-Ying Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-02256-y	journal	December 2017
Hydrothermal Preparation of a Series of Luminescent Cadmium(II) and Zinc(II) Coordination Complexes and Enhanced Real-time Photo-luminescent Sensing for Benzaldehyde: Hydrothermal Preparation of a Series of Luminescent Cadmium(II) and Zinc(II) Coordination Complexes and Enhanced Real-time Photo-luminescent Sensing f Wang, Xin Rui; Wang, Xing Ze; Li, Yong Zeitschrift für anorganische und allgemeine Chemie, Vol. 644, Issue 6 https://doi.org/10.1002/zaac.201700463	journal	February 2018
Visualizing the Dynamics of Temperature- and Solvent-Responsive Soft Crystals Pang, Jiandong; Liu, Caiping; Huang, Yougui Angewandte Chemie, Vol. 128, Issue 26 https://doi.org/10.1002/ange.201603030	journal	May 2016
Flexible Zirconium Metal-Organic Frameworks as Bioinspired Switchable Catalysts Yuan, Shuai; Zou, Lanfang; Li, Haixia Angewandte Chemie, Vol. 128, Issue 36 https://doi.org/10.1002/ange.201604313	journal	June 2016
Haloalkane adsorption into 1-D ensembles’ channels: Zn(II) coordination polymers Lee, Haeri; Lee, Daseul; Jung, Ok-Sang Figshare https://doi.org/10.6084/m9.figshare.7067270.v2	text	January 2018
A Dual-Stimuli-Responsive Coordination Network Featuring Reversible Wide-Range Luminescence-Tuning Behavior Yao, Zhao-Quan; Xu, Jian; Zou, Bo Angewandte Chemie International Edition, Vol. 58, Issue 17 https://doi.org/10.1002/anie.201900190	journal	March 2019
Haloalkane adsorption into 1D ensembles’ channels: Zn(II) coordination polymers Lee, Haeri; Lee, Daseul; Jung, Ok-Sang Taylor & Francis https://doi.org/10.6084/m9.figshare.7067270.v1	text	January 2018
Haloalkane adsorption into 1-D ensembles’ channels: Zn(II) coordination polymers Lee, Haeri; Lee, Daseul; Jung, Ok-Sang Journal of Coordination Chemistry, Vol. 71, Issue 21 https://doi.org/10.1080/00958972.2018.1521518	journal	November 2018
Novel Phosphorus-Nitrogen-Containing Ionic Liquid Modified Metal-Organic Framework as an Effective Flame Retardant for Epoxy Resin Huang, Rong; Guo, Xiuyan; Ma, Shiyue Polymers, Vol. 12, Issue 1 https://doi.org/10.3390/polym12010108	journal	January 2020

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
membrane
carbon capture
materials and chemistry by design
synthesis (novel materials)
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CCDC 1063030: Experimental Crystal Structure Determination Liu, Dahuan; Liu, Tian-Fu; Chen, Ying-Pin https://doi.org/10.5517/ccdc.csd.cc14p599 The current record is supplemented by this dataset	dataset	January 2016
CCDC 1063032: Experimental Crystal Structure Determination Liu, Dahuan; Liu, Tian-Fu; Chen, Ying-Pin https://doi.org/10.5517/ccdc.csd.cc14p5cc The current record is supplemented by this dataset	dataset	January 2016
CCDC 1063029: Experimental Crystal Structure Determination Liu, Dahuan; Liu, Tian-Fu; Chen, Ying-Pin https://doi.org/10.5517/ccdc.csd.cc14p588 The current record is supplemented by this dataset	dataset	January 2016
CCDC 1063031: Experimental Crystal Structure Determination Liu, Dahuan; Liu, Tian-Fu; Chen, Ying-Pin https://doi.org/10.5517/ccdc.csd.cc14p5bb The current record is supplemented by this dataset	dataset	January 2016
CCDC 1063033: Experimental Crystal Structure Determination Liu, Dahuan; Liu, Tian-Fu; Chen, Ying-Pin https://doi.org/10.5517/ccdc.csd.cc14p5dd The current record is supplemented by this dataset	dataset	January 2016
CCDC 1063034: Experimental Crystal Structure Determination Liu, Dahuan; Liu, Tian-Fu; Chen, Ying-Pin https://doi.org/10.5517/ccdc.csd.cc14p5ff The current record is supplemented by this dataset	dataset	January 2016