L-Aspartate links for stable sodium metal–organic frameworks

Siman, Peter; Trickett, Christopher A.; Furukawa, Hiroyasu; Yaghi, Omar M.

doi:10.1039/C5CC07578E

Title: L-Aspartate links for stable sodium metal–organic frameworks

Journal Article · Wed Sep 30 00:00:00 EDT 2015 · ChemComm

DOI:https://doi.org/10.1039/C5CC07578E· OSTI ID:1386955

Siman, Peter ^[1]; Trickett, Christopher A. ^[1]; Furukawa, Hiroyasu ^[2]; Yaghi, Omar M. ^[2]

Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); King Fahd Univ. of Petroleum and Minerals, Dhahran (Saudi Arabia)

Metal–organic frameworks (MOFs) based purely on sodium are rare, typically due to large numbers of coordinating solvent ligands. In this work we designed a tetratopic aspartate-based linker with flexible carboxylate groups to enhance framework stability. We report two new air-stable sodium MOFs, MOF-705 and MOF-706, comprising 2D sodium oxide sheets.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS) and The Molecular Foundry (TMF)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); Ministry of Science and Technology of Israel

Grant/Contract Number:: SC0001015; AC02-05CH11231

OSTI ID:: 1386955

Journal Information:: ChemComm, Vol. 51, Issue 98; Related Information: CGS partners with University of California, Berkeley; University of California, Davis; Lawrence Berkeley National Laboratory; University of Minnesota; National Energy Technology Laboratory; Texas A&M University; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 23 works

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DUT-5 modified Pd metal-nanoparticles: synthesis, chemical stability, and hydrogen sorption studies Lestari, Witri Wahyu; Afifah, Elsanty Nur; Mohammed, Ouzzine Materials Research Express, Vol. 6, Issue 12 https://doi.org/10.1088/2053-1591/ab637c	journal	December 2019
Alkali Phosphonate Metal–Organic Frameworks Maares, Maria; Ayhan, M. Menaf; Yu, Kai. B. Chemistry – A European Journal https://doi.org/10.1002/chem.201902207	journal	July 2019

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