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Title: Ru(bpy) 3 2+ derivatized polystyrenes constructed by nitroxide-mediated radical polymerization. Relationship between polymer chain length, structure and photophysical properties

Abstract

A series of polystyrene-based light harvesting polymers featuring pendant polypyridyl ruthenium complexes has been synthesized.

Authors:
 [1];  [2];  [1];  [1];  [3];  [2];  [2];  [1];  [2];  [2];  [2];  [1]
  1. Department of Chemistry; University of Florida; Gainesville; USA 32611
  2. Department of Chemistry; University of North Carolina at Chapel Hill; Chapel Hill; USA 27599
  3. School of Chemistry and Biochemistry; School of Materials Science and Engineering; Center for Organic Photonics and Electronics; Georgia Institute of Technology; Atlanta
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for Solar Fuels (UNC EFRC)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1386930
DOE Contract Number:  
SC0001011
Resource Type:
Journal Article
Journal Name:
Polymer Chemistry
Additional Journal Information:
Journal Volume: 6; Journal Issue: 47; Related Information: UNC partners with University of North Carolina (lead); Duke University; University of Florida; Georgia Institute of Technology; University; North Carolina Central University; Research Triangle Institute; Journal ID: ISSN 1759-9954
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
catalysis (homogeneous), catalysis (heterogeneous), solar (photovoltaic), solar (fuels), photosynthesis (natural and artificial), hydrogen and fuel cells, electrodes - solar, charge transport, materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly)

Citation Formats

Leem, Gyu, Keinan, Shahar, Jiang, Junlin, Chen, Zhuo, Pho, Toan, Morseth, Zachary A., Hu, Zhenya, Puodziukynaite, Egle, Fang, Zhen, Papanikolas, John M., Reynolds, John R., and Schanze, Kirk S. Ru(bpy) 3 2+ derivatized polystyrenes constructed by nitroxide-mediated radical polymerization. Relationship between polymer chain length, structure and photophysical properties. United States: N. p., 2015. Web. doi:10.1039/C5PY01289A.
Leem, Gyu, Keinan, Shahar, Jiang, Junlin, Chen, Zhuo, Pho, Toan, Morseth, Zachary A., Hu, Zhenya, Puodziukynaite, Egle, Fang, Zhen, Papanikolas, John M., Reynolds, John R., & Schanze, Kirk S. Ru(bpy) 3 2+ derivatized polystyrenes constructed by nitroxide-mediated radical polymerization. Relationship between polymer chain length, structure and photophysical properties. United States. doi:10.1039/C5PY01289A.
Leem, Gyu, Keinan, Shahar, Jiang, Junlin, Chen, Zhuo, Pho, Toan, Morseth, Zachary A., Hu, Zhenya, Puodziukynaite, Egle, Fang, Zhen, Papanikolas, John M., Reynolds, John R., and Schanze, Kirk S. Thu . "Ru(bpy) 3 2+ derivatized polystyrenes constructed by nitroxide-mediated radical polymerization. Relationship between polymer chain length, structure and photophysical properties". United States. doi:10.1039/C5PY01289A.
@article{osti_1386930,
title = {Ru(bpy) 3 2+ derivatized polystyrenes constructed by nitroxide-mediated radical polymerization. Relationship between polymer chain length, structure and photophysical properties},
author = {Leem, Gyu and Keinan, Shahar and Jiang, Junlin and Chen, Zhuo and Pho, Toan and Morseth, Zachary A. and Hu, Zhenya and Puodziukynaite, Egle and Fang, Zhen and Papanikolas, John M. and Reynolds, John R. and Schanze, Kirk S.},
abstractNote = {A series of polystyrene-based light harvesting polymers featuring pendant polypyridyl ruthenium complexes has been synthesized.},
doi = {10.1039/C5PY01289A},
journal = {Polymer Chemistry},
issn = {1759-9954},
number = 47,
volume = 6,
place = {United States},
year = {2015},
month = {1}
}