Ru(bpy) 3 2+ derivatized polystyrenes constructed by nitroxide-mediated radical polymerization. Relationship between polymer chain length, structure and photophysical properties

Leem, Gyu; Keinan, Shahar; Jiang, Junlin; Chen, Zhuo; Pho, Toan; Morseth, Zachary A.; Hu, Zhenya; Puodziukynaite, Egle; Fang, Zhen; Papanikolas, John M.; Reynolds, John R.; Schanze, Kirk S.

doi:10.1039/C5PY01289A

Title: Ru(bpy) ₃ ²⁺ derivatized polystyrenes constructed by nitroxide-mediated radical polymerization. Relationship between polymer chain length, structure and photophysical properties

Journal Article · Thu Jan 01 00:00:00 EST 2015 · Polymer Chemistry

DOI:https://doi.org/10.1039/C5PY01289A· OSTI ID:1386930

Leem, Gyu ^[1]; Keinan, Shahar ^[2]; Jiang, Junlin ^[1]; Chen, Zhuo ^[1]; Pho, Toan ^[3]; Morseth, Zachary A. ^[2]; Hu, Zhenya ^[2]; Puodziukynaite, Egle ^[1]; Fang, Zhen ^[2]; Papanikolas, John M. ^[2]; Reynolds, John R. ^[2]; Schanze, Kirk S. ^[1]

Department of Chemistry; University of Florida; Gainesville; USA 32611
Department of Chemistry; University of North Carolina at Chapel Hill; Chapel Hill; USA 27599
School of Chemistry and Biochemistry; School of Materials Science and Engineering; Center for Organic Photonics and Electronics; Georgia Institute of Technology; Atlanta

A series of polystyrene-based light harvesting polymers featuring pendant polypyridyl ruthenium complexes has been synthesized.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Solar Fuels (UNC EFRC)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: SC0001011

OSTI ID:: 1386930

Journal Information:: Polymer Chemistry, Vol. 6, Issue 47; Related Information: UNC partners with University of North Carolina (lead); Duke University; University of Florida; Georgia Institute of Technology; University; North Carolina Central University; Research Triangle Institute; ISSN 1759-9954

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

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Title: Ru(bpy) 3 2+ derivatized polystyrenes constructed by nitroxide-mediated radical polymerization. Relationship between polymer chain length, structure and photophysical properties

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Title: Ru(bpy) ₃ ²⁺ derivatized polystyrenes constructed by nitroxide-mediated radical polymerization. Relationship between polymer chain length, structure and photophysical properties