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Title: Vapor phase hydrodeoxygenation of furfural to 2-methylfuran on molybdenum carbide catalysts

; ; ; ;
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Catalysis Center for Energy Innovation (CCEI)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
DOE Contract Number:  
Resource Type:
Journal Article
Journal Name:
Catalysis Science and Technology
Additional Journal Information:
Journal Volume: 4; Journal Issue: 8; Related Information: CCEI partners with the University of Delaware (lead); Brookhaven National Laboratory; California Institute of Technology; Columbia University; University of Delaware; Lehigh University; University of Massachusetts, Amherst; Massachusetts Institute of Technology; University of Minnesota; Pacific Northwest National Laboratory; University of Pennsylvania; Princeton University; Rutgers University; Journal ID: ISSN 2044-4753
Royal Society of Chemistry
Country of Publication:
United States
catalysis (homogeneous), catalysis (heterogeneous), biofuels (including algae and biomass), bio-inspired, hydrogen and fuel cells, materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing)

Citation Formats

Lee, Wen-Sheng, Wang, Zhenshu, Zheng, Weiqing, Vlachos, Dionisios G., and Bhan, Aditya. Vapor phase hydrodeoxygenation of furfural to 2-methylfuran on molybdenum carbide catalysts. United States: N. p., 2014. Web. doi:10.1039/c4cy00286e.
Lee, Wen-Sheng, Wang, Zhenshu, Zheng, Weiqing, Vlachos, Dionisios G., & Bhan, Aditya. Vapor phase hydrodeoxygenation of furfural to 2-methylfuran on molybdenum carbide catalysts. United States. doi:10.1039/c4cy00286e.
Lee, Wen-Sheng, Wang, Zhenshu, Zheng, Weiqing, Vlachos, Dionisios G., and Bhan, Aditya. Wed . "Vapor phase hydrodeoxygenation of furfural to 2-methylfuran on molybdenum carbide catalysts". United States. doi:10.1039/c4cy00286e.
title = {Vapor phase hydrodeoxygenation of furfural to 2-methylfuran on molybdenum carbide catalysts},
author = {Lee, Wen-Sheng and Wang, Zhenshu and Zheng, Weiqing and Vlachos, Dionisios G. and Bhan, Aditya},
abstractNote = {},
doi = {10.1039/c4cy00286e},
journal = {Catalysis Science and Technology},
issn = {2044-4753},
number = 8,
volume = 4,
place = {United States},
year = {2014},
month = {1}

Works referenced in this record:

Selective Hydrodeoxygenation of Biomass-Derived Oxygenates to Unsaturated Hydrocarbons using Molybdenum Carbide Catalysts
journal, April 2013

Water-Gas-Shift Reaction on Molybdenum Carbide Surfaces:  Essential Role of the Oxycarbide
journal, October 2006

  • Liu, Ping; Rodriguez, José A.
  • The Journal of Physical Chemistry B, Vol. 110, Issue 39
  • DOI: 10.1021/jp0621629

Furfural-A Promising Platform for Lignocellulosic Biofuels
journal, December 2011

  • Lange, Jean-Paul; van der Heide, Evert; van Buijtenen, Jeroen
  • ChemSusChem, Vol. 5, Issue 1
  • DOI: 10.1002/cssc.201100648

Kinetics and mechanism of hydrogenation of furfural on Cu/SiO2 catalysts
journal, January 2011

Production of dimethylfuran for liquid fuels from biomass-derived carbohydrates
journal, June 2007

  • Román-Leshkov, Yuriy; Barrett, Christopher J.; Liu, Zhen Y.
  • Nature, Vol. 447, Issue 7147, p. 982-985
  • DOI: 10.1038/nature05923

Historical Developments in Hydroprocessing Bio-oils
journal, May 2007

  • Elliott, Douglas C.
  • Energy & Fuels, Vol. 21, Issue 3, p. 1792-1815
  • DOI: 10.1021/ef070044u

DFT Study of Furfural Conversion to Furan, Furfuryl Alcohol, and 2-Methylfuran on Pd(111)
journal, October 2012

  • Vorotnikov, Vassili; Mpourmpakis, Giannis; Vlachos, Dionisios G.
  • ACS Catalysis, Vol. 2, Issue 12
  • DOI: 10.1021/cs300395a

Hydrocracking of organocell lignin for phenol production
journal, January 1994

Deactivation mechanistic studies of copper chromite catalyst for selective hydrogenation of 2-furfuraldehyde
journal, March 2013

High Structure Sensitivity of Vapor-Phase Furfural Decarbonylation/Hydrogenation Reaction Network as a Function of Size and Shape of Pt Nanoparticles
journal, September 2012

  • Pushkarev, Vladimir V.; Musselwhite, Nathan; An, Kwangjin
  • Nano Letters, Vol. 12, Issue 10
  • DOI: 10.1021/nl3023127

Tungsten-Based Catalysts for Selective Deoxygenation
journal, April 2013

  • Gosselink, Robert W.; Stellwagen, Daniel R.; Bitter, Johannes H.
  • Angewandte Chemie International Edition, Vol. 52, Issue 19
  • DOI: 10.1002/anie.201209809

Hydrodeoxygenation of Furfural Over Supported Metal Catalysts: A Comparative Study of Cu, Pd and Ni
journal, March 2011

Catalysis over molybdenum carbides and nitrides I. Catalyst characterization
journal, November 1987

Molybdenum Carbide as a Highly Selective Deoxygenation Catalyst for Converting Furfural to 2-Methylfuran
journal, April 2014

Acid and base characteristics of molybdenum carbide catalysts
journal, September 2003

Carbon Nanofiber Supported Transition-Metal Carbide Catalysts for the Hydrodeoxygenation of Guaiacol
journal, July 2013

  • Jongerius, Anna L.; Gosselink, Robert W.; Dijkstra, Jelmer
  • ChemCatChem, Vol. 5, Issue 10
  • DOI: 10.1002/cctc.201300280

Carbon-Supported Molybdenum Carbide Catalysts for the Conversion of Vegetable Oils
journal, February 2012

  • Han, Junxing; Duan, Jinzhao; Chen, Ping
  • ChemSusChem, Vol. 5, Issue 4, p. 727-733
  • DOI: 10.1002/cssc.201100476

Conversion of furfural and 2-methylpentanal on Pd/SiO2 and Pd–Cu/SiO2 catalysts
journal, May 2011

Recent Advances in Hydrotreating of Pyrolysis Bio-Oil and Its Oxygen-Containing Model Compounds
journal, April 2013

  • Wang, Huamin; Male, Jonathan; Wang, Yong
  • ACS Catalysis, Vol. 3, Issue 5
  • DOI: 10.1021/cs400069z

Catalytic Reduction of Biomass-Derived Furanic Compounds with Hydrogen
journal, October 2013

  • Nakagawa, Yoshinao; Tamura, Masazumi; Tomishige, Keiichi
  • ACS Catalysis, Vol. 3, Issue 12
  • DOI: 10.1021/cs400616p

Selective conversion of furfural to methylfuran over silica-supported NiFe bimetallic catalysts
journal, November 2011

Comparison of Reaction Pathways of Ethylene Glycol, Acetaldehyde, and Acetic Acid on Tungsten Carbide and Ni-Modified Tungsten Carbide Surfaces
journal, February 2012

  • Yu, Weiting; Mellinger, Zachary J.; Barteau, Mark A.
  • The Journal of Physical Chemistry C, Vol. 116, Issue 9
  • DOI: 10.1021/jp210756f

Synthesis of High-Quality Diesel with Furfural and 2-Methylfuran from Hemicellulose
journal, August 2012

Synergies between Bio- and Oil Refineries for the Production of Fuels from Biomass
journal, September 2007

  • Huber, George W.; Corma, Avelino
  • Angewandte Chemie International Edition, Vol. 46, Issue 38, p. 7184-7201
  • DOI: 10.1002/anie.200604504

Study on Cu–Mn–Si catalysts for synthesis of cyclohexanone and 2-methylfuran through the coupling process
journal, March 2008

Hydroprocessing of Bio-Oils and Oxygenates to Hydrocarbons. Understanding the Reaction Routes
journal, January 2009

  • Donnis, Bjørn; Egeberg, Rasmus Gottschalck; Blom, Peder
  • Topics in Catalysis, Vol. 52, Issue 3
  • DOI: 10.1007/s11244-008-9159-z

Elementary steps of syngas reactions on Mo2C(001): Adsorption thermochemistry and bond dissociation
journal, June 2012

Properties of Copper Chromite Catalysts in Hydrogenation Reactions
journal, October 1997

202. The hydrogenation of furfuraldehyde to furfuryl alcohol and sylvan (2-methylfuran)
journal, January 1947

  • Bremner, John G. M.; Keeys, Richard K. F.
  • Journal of the Chemical Society (Resumed)
  • DOI: 10.1039/jr9470001068

Advances in conversion of hemicellulosic biomass to furfural and upgrading to biofuels
journal, January 2012

  • Dutta, Saikat; De, Sudipta; Saha, Basudeb
  • Catalysis Science & Technology, Vol. 2, Issue 10
  • DOI: 10.1039/c2cy20235b

Acid-Catalyzed Polycondensation of Furfuryl Alcohol:  Mechanisms of Chromophore Formation and Cross-Linking
journal, January 1996

  • Choura, Mekki; Belgacem, Naceur M.; Gandini, Alessandro
  • Macromolecules, Vol. 29, Issue 11
  • DOI: 10.1021/ma951522f

A study of furfural decarbonylation on K-doped Pd/Al2O3 catalysts
journal, February 2011

CC Bond Formation Reactions for Biomass-Derived Molecules
journal, August 2010

  • Subrahmanyam, Ayyagari V.; Thayumanavan, Sankaran; Huber, George W.
  • ChemSusChem, Vol. 3, Issue 10
  • DOI: 10.1002/cssc.201000136

Molybdenum carbide catalysts I. Synthesis of unsupported powders
journal, July 1987

Influence of the Degree of Carburization on the Density of Sites and Hydrogenating Activity of Molybdenum Carbides
journal, July 2000

  • Choi, Jae-Soon; Bugli, Guy; Djéga-Mariadassou, Gérald
  • Journal of Catalysis, Vol. 193, Issue 2
  • DOI: 10.1006/jcat.2000.2894

Carbon and oxygen atom mobility during activation of Mo2C catalysts
journal, October 1986

Experimental criterion for the absence of artifacts in the measurement of rates of heterogeneous catalytic reactions
journal, November 1982

  • Madon, Rostam J.; Boudart, Michel
  • Industrial & Engineering Chemistry Fundamentals, Vol. 21, Issue 4, p. 438-447
  • DOI: 10.1021/i100008a022

Effects of adsorbed carbon and oxygen on the chemisorption of H2 and Co on Mo(100)
journal, August 1981

Preparation and surface composition of tungsten carbide powders with high specific surface area
journal, September 1991

  • Ribeiro, F. H.; Dalla Betta, R. A.; Guskey, G. J.
  • Chemistry of Materials, Vol. 3, Issue 5
  • DOI: 10.1021/cm00017a015