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Title: Tandem Lewis/Brønsted homogeneous acid catalysis: conversion of glucose to 5-hydoxymethylfurfural in an aqueous chromium( iii ) chloride and hydrochloric acid solution

Abstract

Optimizing the concentrations of Lewis and Brønsted acids maximizes the 5-hydroxymethylfurfural yield from glucose in a single pot.

Authors:
 [1];  [1];  [2];  [1];  [1]
  1. Department of Chemical and Biomolecular Engineering; Catalysis Center for Energy Innovation; University of Delaware; Newark; USA
  2. OLI Systems Inc.; Cedar Knolls; USA
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Catalysis Center for Energy Innovation (CCEI)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1386759
DOE Contract Number:  
SC0001004
Resource Type:
Journal Article
Journal Name:
Green Chemistry
Additional Journal Information:
Journal Volume: 17; Journal Issue: 10; Related Information: CCEI partners with the University of Delaware (lead); Brookhaven National Laboratory; California Institute of Technology; Columbia University; University of Delaware; Lehigh University; University of Massachusetts, Amherst; Massachusetts Institute of Technology; University of Minnesota; Pacific Northwest National Laboratory; University of Pennsylvania; Princeton University; Rutgers University; Journal ID: ISSN 1463-9262
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
catalysis (homogeneous), catalysis (heterogeneous), biofuels (including algae and biomass), bio-inspired, hydrogen and fuel cells, materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing)

Citation Formats

Dallas Swift, T., Nguyen, Hannah, Anderko, Andrzej, Nikolakis, Vladimiros, and Vlachos, Dionisios G. Tandem Lewis/Brønsted homogeneous acid catalysis: conversion of glucose to 5-hydoxymethylfurfural in an aqueous chromium( iii ) chloride and hydrochloric acid solution. United States: N. p., 2015. Web. doi:10.1039/c5gc01257k.
Dallas Swift, T., Nguyen, Hannah, Anderko, Andrzej, Nikolakis, Vladimiros, & Vlachos, Dionisios G. Tandem Lewis/Brønsted homogeneous acid catalysis: conversion of glucose to 5-hydoxymethylfurfural in an aqueous chromium( iii ) chloride and hydrochloric acid solution. United States. doi:10.1039/c5gc01257k.
Dallas Swift, T., Nguyen, Hannah, Anderko, Andrzej, Nikolakis, Vladimiros, and Vlachos, Dionisios G. Thu . "Tandem Lewis/Brønsted homogeneous acid catalysis: conversion of glucose to 5-hydoxymethylfurfural in an aqueous chromium( iii ) chloride and hydrochloric acid solution". United States. doi:10.1039/c5gc01257k.
@article{osti_1386759,
title = {Tandem Lewis/Brønsted homogeneous acid catalysis: conversion of glucose to 5-hydoxymethylfurfural in an aqueous chromium( iii ) chloride and hydrochloric acid solution},
author = {Dallas Swift, T. and Nguyen, Hannah and Anderko, Andrzej and Nikolakis, Vladimiros and Vlachos, Dionisios G.},
abstractNote = {Optimizing the concentrations of Lewis and Brønsted acids maximizes the 5-hydroxymethylfurfural yield from glucose in a single pot.},
doi = {10.1039/c5gc01257k},
journal = {Green Chemistry},
issn = {1463-9262},
number = 10,
volume = 17,
place = {United States},
year = {2015},
month = {1}
}

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