Synthetic, structural, and luminescence study of uranyl coordination polymers containing chelating terpyridine and trispyridyltriazine ligands

Thangavelu, Sonia G.; Pope, Simon J.  A.; Cahill, Christopher L.

doi:10.1039/c5ce00984g

Title: Synthetic, structural, and luminescence study of uranyl coordination polymers containing chelating terpyridine and trispyridyltriazine ligands

Journal Article · Mon Jul 13 00:00:00 EDT 2015 · CrystEngComm

DOI:https://doi.org/10.1039/c5ce00984g· OSTI ID:1386741

Thangavelu, Sonia G. ^[1]; Pope, Simon J. A. ^[2]; Cahill, Christopher L. ^[1]

George Washington Univ., Washington, DC (United States)
Cardiff Univ., Cardiff (United Kingdom)

In this work, seven uranyl coordination polymers [(UO₂)(BrC₈H₃O₄)(C₁₅H₁₁N₃)] (1), [(UO₂)(ClC₈H₃O₄)(C₁₅H₁₁N₃)] (2), [(UO₂)(BrC₈H₃O₄)(C₁₈H₁₂N₆)]·H₂O (3), [(UO₂)(ClC₈H₃O₄)(C₁₈H₁₂N₆)]·2H₂O (4), [(UO₂)(C₈H₃IO₄)(C₁₈H₁₂N₆)]·2C₃H₇O (5), [(UO₂)(C₉H₆O₄)(C₁₈H₁₂N₆)]·H₂O (6), and [(UO₂)(C₆H₂O₄S)(C₁₈H₁₂N₆)]·2H₂O (7) containing N-donor ligands 2,2':6',2''-terpyridine (TPY) and 2,4,6-tripyridyl s-triazine (TPTZ); and O-donor linkers thiophene 2,5-dicarboxylic acid (TDC) and X-1,4-benzene dicarboxylic acid (X-BDC, where X = Me, Cl, Br, I) were synthesized and characterized using single crystal X-ray diffraction (SC-XRD), powder X-ray diffraction (PXRD), and fluorescence spectroscopy. Each compound crystallizes as binuclear pseudo dimers containing a UO₂²⁺ pentagonal bipyramidal primary building unit. Fluorescence spectra of 1–4, and 6–7 show characteristic UO₂²⁺ emission whereas 5 is non-emissive. Red shifts within the emission of 1–4 are noted as a function of N-donor ligands TPY and TPTZ whereas emission shifts are not observed in TPTZ bearing compounds (3, 4, 6, 7) containing different O-donor linkers. Luminescent lifetimes of 1–7 were obtained and fitted with either bi-exponential or tri-exponential components.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Materials Science of Actinides (MSA)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0001089

OSTI ID:: 1386741

Journal Information:: CrystEngComm, Vol. 17, Issue 32; Related Information: MSA partners with University of Notre Dame (lead); University of California, Davis; Florida State University; George Washington University; University of Michigan; University of Minnesota; Oak Ridge National Laboratory; Oregon state University; Rensselaer Polytechnic Institute; Savannah River National Laboratory; ISSN 1466-8033

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 28 works

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