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Title: Electrochemical oxidation of H 2 catalyzed by ruthenium hydride complexes bearing P 2 N 2 ligands with pendant amines as proton relays

Abstract

A new class of Ru electrocatalysts containing P 2N 2diphosphine ligands with pendant amines converts the chemical bond energy of H 2to electricity.

Authors:
 [1];  [1];  [1];  [1]
  1. Center for Molecular Electrocatalysis; Physical Sciences Division; Pacific Northwest National Laboratory; Richland, USA
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for Molecular Electrocatalysis (CME)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1386175
DOE Contract Number:  
AC05-76RL01830
Resource Type:
Journal Article
Journal Name:
Energy & Environmental Science
Additional Journal Information:
Journal Volume: 7; Journal Issue: 11; Related Information: CME partners with Pacific Northwest National Laboratory (lead); University of Illinois, Urbana-Champaign; Pennsylvania State University; University of Washington; University of Wyoming; Journal ID: ISSN 1754-5692
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
catalysis (homogeneous), catalysis (heterogeneous), solar (fuels), bio-inspired, energy storage (including batteries and capacitors), hydrogen and fuel cells, charge transport, materials and chemistry by design, synthesis (novel materials)

Citation Formats

Liu, Tianbiao, DuBois, Mary Rakowski, DuBois, Daniel L., and Bullock, R. Morris. Electrochemical oxidation of H 2 catalyzed by ruthenium hydride complexes bearing P 2 N 2 ligands with pendant amines as proton relays. United States: N. p., 2014. Web. doi:10.1039/C4EE01262C.
Liu, Tianbiao, DuBois, Mary Rakowski, DuBois, Daniel L., & Bullock, R. Morris. Electrochemical oxidation of H 2 catalyzed by ruthenium hydride complexes bearing P 2 N 2 ligands with pendant amines as proton relays. United States. doi:10.1039/C4EE01262C.
Liu, Tianbiao, DuBois, Mary Rakowski, DuBois, Daniel L., and Bullock, R. Morris. Wed . "Electrochemical oxidation of H 2 catalyzed by ruthenium hydride complexes bearing P 2 N 2 ligands with pendant amines as proton relays". United States. doi:10.1039/C4EE01262C.
@article{osti_1386175,
title = {Electrochemical oxidation of H 2 catalyzed by ruthenium hydride complexes bearing P 2 N 2 ligands with pendant amines as proton relays},
author = {Liu, Tianbiao and DuBois, Mary Rakowski and DuBois, Daniel L. and Bullock, R. Morris},
abstractNote = {A new class of Ru electrocatalysts containing P2N2diphosphine ligands with pendant amines converts the chemical bond energy of H2to electricity.},
doi = {10.1039/C4EE01262C},
journal = {Energy & Environmental Science},
issn = {1754-5692},
number = 11,
volume = 7,
place = {United States},
year = {2014},
month = {1}
}

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