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Title: Self-Pillared, Single-Unit-Cell Sn-MFI Zeolite Nanosheets and Their Use for Glucose and Lactose Isomerization

Authors:
; ; ; ; ; ; ; ;
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Catalysis Center for Energy Innovation (CCEI)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1386132
DOE Contract Number:  
SC0001004
Resource Type:
Journal Article
Journal Name:
Angewandte Chemie (International Edition)
Additional Journal Information:
Journal Volume: 54; Journal Issue: 37; Related Information: CCEI partners with the University of Delaware (lead); Brookhaven National Laboratory; California Institute of Technology; Columbia University; University of Delaware; Lehigh University; University of Massachusetts, Amherst; Massachusetts Institute of Technology; University of Minnesota; Pacific Northwest National Laboratory; University of Pennsylvania; Princeton University; Rutgers University; Journal ID: ISSN 1433-7851
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
catalysis (homogeneous), catalysis (heterogeneous), biofuels (including algae and biomass), bio-inspired, hydrogen and fuel cells, materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing)

Citation Formats

Ren, Limin, Guo, Qiang, Kumar, Prashant, Orazov, Marat, Xu, Dandan, Alhassan, Saeed M., Mkhoyan, K. Andre, Davis, Mark E., and Tsapatsis, Michael. Self-Pillared, Single-Unit-Cell Sn-MFI Zeolite Nanosheets and Their Use for Glucose and Lactose Isomerization. United States: N. p., 2015. Web. doi:10.1002/anie.201505334.
Ren, Limin, Guo, Qiang, Kumar, Prashant, Orazov, Marat, Xu, Dandan, Alhassan, Saeed M., Mkhoyan, K. Andre, Davis, Mark E., & Tsapatsis, Michael. Self-Pillared, Single-Unit-Cell Sn-MFI Zeolite Nanosheets and Their Use for Glucose and Lactose Isomerization. United States. doi:10.1002/anie.201505334.
Ren, Limin, Guo, Qiang, Kumar, Prashant, Orazov, Marat, Xu, Dandan, Alhassan, Saeed M., Mkhoyan, K. Andre, Davis, Mark E., and Tsapatsis, Michael. Thu . "Self-Pillared, Single-Unit-Cell Sn-MFI Zeolite Nanosheets and Their Use for Glucose and Lactose Isomerization". United States. doi:10.1002/anie.201505334.
@article{osti_1386132,
title = {Self-Pillared, Single-Unit-Cell Sn-MFI Zeolite Nanosheets and Their Use for Glucose and Lactose Isomerization},
author = {Ren, Limin and Guo, Qiang and Kumar, Prashant and Orazov, Marat and Xu, Dandan and Alhassan, Saeed M. and Mkhoyan, K. Andre and Davis, Mark E. and Tsapatsis, Michael},
abstractNote = {},
doi = {10.1002/anie.201505334},
journal = {Angewandte Chemie (International Edition)},
issn = {1433-7851},
number = 37,
volume = 54,
place = {United States},
year = {2015},
month = {7}
}

Works referenced in this record:

Delaminated zeolite precursors as selective acidic catalysts
journal, November 1998

  • Corma, A.; Fornes, V.; Pergher, S. B.
  • Nature, Vol. 396, Issue 6709, p. 353-356
  • DOI: 10.1038/24592

Nucleation, Growth, and Robust Synthesis of SPP Zeolite: Effect of Ethanol, Sodium, and Potassium
journal, April 2015

  • Swindlehurst, Garrett R.; Kumar, Prashant; Xu, Dandan
  • Topics in Catalysis, Vol. 58, Issue 7-9
  • DOI: 10.1007/s11244-015-0396-7

Formation of Hierarchically Organized Zeolites by Sequential Intergrowth
journal, February 2013

  • Chaikittisilp, Watcharop; Suzuki, Yuki; Mukti, Rino R.
  • Angewandte Chemie, Vol. 125, Issue 12
  • DOI: 10.1002/ange.201209638

Understanding the Unusual Adsorption Behavior in Hierarchical Zeolite Nanosheets
journal, May 2014


On the Synthesis and Adsorption Properties of Single-Unit-Cell Hierarchical Zeolites Made by Rotational Intergrowths
journal, September 2013

  • Xu, Dandan; Swindlehurst, Garrett R.; Wu, Haohan
  • Advanced Functional Materials, Vol. 24, Issue 2
  • DOI: 10.1002/adfm.201301975

Directing Zeolite Structures into Hierarchically Nanoporous Architectures
journal, July 2011


Dynamic Nuclear Polarization NMR Enables the Analysis of Sn-Beta Zeolite Prepared with Natural Abundance 119 Sn Precursors
journal, April 2014

  • Gunther, William R.; Michaelis, Vladimir K.; Caporini, Marc A.
  • Journal of the American Chemical Society, Vol. 136, Issue 17
  • DOI: 10.1021/ja502113d

On the Rotational Intergrowth of Hierarchical FAU/EMT Zeolites
journal, July 2014

  • Khaleel, Maryam; Wagner, Andrew J.; Mkhoyan, K. Andre
  • Angewandte Chemie, Vol. 126, Issue 36
  • DOI: 10.1002/ange.201402024

Assemblies of Mesoporous FAU-Type Zeolite Nanosheets
journal, January 2012

  • Inayat, Alexandra; Knoke, Isabel; Spiecker, Erdmann
  • Angewandte Chemie International Edition, Vol. 51, Issue 8
  • DOI: 10.1002/anie.201105738

Stable single-unit-cell nanosheets of zeolite MFI as active and long-lived catalysts
journal, September 2009

  • Choi, Minkee; Na, Kyungsu; Kim, Jeongnam
  • Nature, Vol. 461, Issue 7261, p. 246-249
  • DOI: 10.1038/nature08288

Synthesis and Catalytic Activity of Sn-MFI Nanosheets for the Baeyer–Villiger Oxidation of Cyclic Ketones
journal, November 2012

  • Luo, Helen Y.; Bui, Linh; Gunther, William R.
  • ACS Catalysis, Vol. 2, Issue 12
  • DOI: 10.1021/cs300543z

Synthesis of Self-Pillared Zeolite Nanosheets by Repetitive Branching
journal, June 2012


Metalloenzyme-like catalyzed isomerizations of sugars by Lewis acid zeolites
journal, June 2012

  • Bermejo-Deval, R.; Assary, R. S.; Nikolla, E.
  • Proceedings of the National Academy of Sciences, Vol. 109, Issue 25
  • DOI: 10.1073/pnas.1206708109

MCM-22: A Molecular Sieve with Two Independent Multidimensional Channel Systems
journal, June 1994


Monosaccharide and disaccharide isomerization over Lewis acid sites in hydrophobic and hydrophilic molecular sieves
journal, December 2013


Hierarchical Sn-MFI zeolites prepared by facile top-down methods for sugar isomerisation
journal, January 2014

  • Dapsens, Pierre Y.; Mondelli, Cecilia; Jagielski, Jakub
  • Catalysis Science & Technology, Vol. 4, Issue 8
  • DOI: 10.1039/c4cy00172a

Sn-zeolite beta as a heterogeneous chemoselective catalyst for Baeyer–Villiger oxidations
journal, July 2001

  • Corma, Avelino; Nemeth, Laszlo T.; Renz, Michael
  • Nature, Vol. 412, Issue 6845
  • DOI: 10.1038/35086546

Mesoporöse Nanoschichtaggregate vom Zeolithtyp FAU
journal, January 2012

  • Inayat, Alexandra; Knoke, Isabel; Spiecker, Erdmann
  • Angewandte Chemie, Vol. 124, Issue 8
  • DOI: 10.1002/ange.201105738

Productive sugar isomerization with highly active Sn in dealuminated β zeolites
journal, January 2013

  • Dijkmans, Jan; Gabriëls, Dries; Dusselier, Michiel
  • Green Chemistry, Vol. 15, Issue 10
  • DOI: 10.1039/c3gc41239c

Random-Graft Polymer-Directed Synthesis of Inorganic Mesostructures with Ultrathin Frameworks
journal, April 2014


Formation of Hierarchically Organized Zeolites by Sequential Intergrowth
journal, February 2013

  • Chaikittisilp, Watcharop; Suzuki, Yuki; Mukti, Rino R.
  • Angewandte Chemie International Edition, Vol. 52, Issue 12
  • DOI: 10.1002/anie.201209638

Characterization of nanoporous materials from adsorption and desorption isotherms
journal, August 2001

  • Ravikovitch, Peter I.; Neimark, Alexander V.
  • Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 187-188
  • DOI: 10.1016/S0927-7757(01)00614-8

Tin-containing zeolites are highly active catalysts for the isomerization of glucose in water
journal, March 2010

  • Moliner, M.; Roman-Leshkov, Y.; Davis, M. E.
  • Proceedings of the National Academy of Sciences, Vol. 107, Issue 14, p. 6164-6168
  • DOI: 10.1073/pnas.1002358107

Two-Dimensional Zeolites: Current Status and Perspectives
journal, February 2014

  • Roth, Wieslaw J.; Nachtigall, Petr; Morris, Russell E.
  • Chemical Reviews, Vol. 114, Issue 9
  • DOI: 10.1021/cr400600f

2-dimensional zeolites
journal, May 2014


Synthesis of Hierarchical Sn-MFI as Lewis Acid Catalysts for Isomerization of Cellulosic Sugars
journal, April 2014

  • Cho, Hong Je; Dornath, Paul; Fan, Wei
  • ACS Catalysis, Vol. 4, Issue 6
  • DOI: 10.1021/cs500295u

On the Rotational Intergrowth of Hierarchical FAU/EMT Zeolites
journal, July 2014

  • Khaleel, Maryam; Wagner, Andrew J.; Mkhoyan, K. Andre
  • Angewandte Chemie International Edition, Vol. 53, Issue 36
  • DOI: 10.1002/anie.201402024

Efficient Isomerization of Glucose to Fructose over Zeolites in Consecutive Reactions in Alcohol and Aqueous Media
journal, March 2013

  • Saravanamurugan, Shunmugavel; Paniagua, Marta; Melero, Juan A.
  • Journal of the American Chemical Society, Vol. 135, Issue 14
  • DOI: 10.1021/ja400097f