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Title: Photoinitiated multistep charge separation in ferrocene–zinc porphyrin–diiron hydrogenase model complex triads

Journal Article · · Energy & Environmental Science
DOI:https://doi.org/10.1039/C1EE01334C· OSTI ID:1386114

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Argonne-Northwestern Solar Energy Research Center (ANSER)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
SC0001059
OSTI ID:
1386114
Journal Information:
Energy & Environmental Science, Vol. 4, Issue 7; Related Information: ANSER partners with Northwestern University (lead); Argonne National Laboratory; University of Chicago; University of Illinois, Urbana-Champaign; Yale University; ISSN 1754-5692
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

References (64)

Probing the Efficiency of Electron Transfer through Porphyrin-Based Molecular Wires journal April 2007
Photoinduced electron transfer in supramolecular systems for artificial photosynthesis journal May 1992
Visible Light-Driven Electron Transfer and Hydrogen Generation Catalyzed by Bioinspired [2Fe2S] Complexes journal April 2008
Femtosecond Optical Switching of Electron Transport Direction in Branched Donor−Acceptor Arrays journal February 2000
BIOPHYSICS: Long Live Electronic Coherence! journal June 2007
Light-driven hydrogen production catalysed by transition metal complexes in homogeneous systems journal January 2009
Ru(II)-bipyridine complexes in supramolecular systems, devices and machines journal June 2006
Catalysis of the electrochemical H evolution by di-iron sub-site models journal August 2005
Bio-inspired, side-on attachment of a ruthenium photosensitizer to an iron hydrogenase active site model journal January 2006
Projection structures of three photosynthetic complexes from Rhodobacter sphaeroides : LH2 at 6 Å, LH1 and RC-LH1 at 25 Å 1 1Edited by K. Nagai journal October 1998
Ultrafast Photodriven Intramolecular Electron Transfer from a Zinc Porphyrin to a Readily Reduced Diiron Hydrogenase Model Complex journal July 2010
Electronic Absorption Spectrum of Ferrocene journal June 1967
Ionized and excited states of ferrocene: Symmetry adapted cluster–configuration–interaction study journal October 2002
A structural and functional mimic of the active site of NiFe hydrogenases journal January 2010
Electrocatalysis of hydrogen production by active site analogues of the iron hydrogenase enzyme: structure/function relationships journal January 2003
Hydrogenase sophistication journal January 1999
Diiron Proton Reduction Catalysts Possessing Electron-Rich and Electron-Poor Naphthalene-1,8-dithiolate Ligands journal August 2009
Synthesis and Structure of a Biomimetic Model of the Iron Hydrogenase Active Site Covalently Linked to a Ruthenium Photosensitizer journal July 2003
Visible Light-Driven H 2 Production by Hydrogenases Attached to Dye-Sensitized TiO 2 Nanoparticles journal December 2009
High-Turnover Photochemical Hydrogen Production Catalyzed by a Model Complex of the [FeFe]-Hydrogenase Active Site journal January 2010
From Hydrogenases to Noble Metal-Free Catalytic Nanomaterials for H2 Production and Uptake journal December 2009
BIOCHEMISTRY:Biological Hydrogen Production: Not So Elementary journal December 1998
A Theory of Sensitized Luminescence in Solids journal May 1953
The bio-organometallic chemistry of active site iron in hydrogenases journal September 2000
Making Hydrogen from Water Using a Homogeneous System Without Noble Metals journal July 2009
Noncovalent Assembly of a Metalloporphyrin and an Iron Hydrogenase Active-Site Model: Photo-Induced Electron Transfer and Hydrogen Generation journal July 2008
Intermolecular Electron Transfer from Photogenerated Ru(bpy) 3 + to [2Fe2S] Model Complexes of the Iron-Only Hydrogenase Active Site journal May 2007
Hydrogen Production by Molecular Photocatalysis journal October 2007
Electron Transfer at a Dithiolate-Bridged Diiron Assembly:  Electrocatalytic Hydrogen Evolution journal December 2004
Synthesis of an Amino-Functionalized Model of the Fe-Only Hydrogenase Active Site journal January 2003
Photosynthetic Light-Harvesting Pigment−Protein Complexes:  Toward Understanding How and Why journal January 1996
An azadithiolate bridged Fe2S2 complex as active site model of FeFe-hydrogenase covalently linked to a Re(CO)3(bpy)(py) photosensitizer aiming for light-driven hydrogen production journal August 2008
Biomimetic Hydrogen Evolution Catalyzed by an Iron Carbonyl Thiolate journal September 2001
Redox chemistry and spectroscopy of 2-mercaptobenzoic acid and its manganese(II) and (III) complexes in dimethylsulphoxide journal January 1990
Molecular Rectification in Metal−SAM−Metal Oxide−Metal Junctions journal December 2009
Crystal structure of an integral membrane light-harvesting complex from photosynthetic bacteria journal April 1995
Tuning the electronic properties of Fe2(μ-arenedithiolate)(CO)6−n(PMe3)n (n=0, 2) complexes related to the [Fe–Fe]-hydrogenase active site journal August 2008
Two-dimensional structure of light harvesting complex II (LHII) from the purple bacterium Rhodovulum sulfidophilum and comparison with LHII from Rhodopseudomonas acidophila journal March 1996
Molecular rectification: why is it so rare? journal August 2002
Synthesis and properties of an iron hydrogenase active site model linked to a ruthenium tris-bipyridine photosensitizer journal August 2003
X-ray Crystal Structure of the Fe-Only Hydrogenase (CpI) from Clostridium pasteurianum to 1.8 Angstrom Resolution journal December 1998
Excited states and electronic spectrum of ferrocene journal December 1974
The Hydrophilic Phosphatriazaadamantane Ligand in the Development of H 2 Production Electrocatalysts:  Iron Hydrogenase Model Complexes journal September 2004
Hydrogenases: Hydrogen-Activating Enzymes journal March 2002
Model of the Iron Hydrogenase Active Site Covalently Linked to a Ruthenium Photosensitizer:  Synthesis and Photophysical Properties journal July 2004
Near-transform-limited visible and near-IR femtosecond pulses from optical parametric amplification using Type II β-barium borate journal January 1995
Nature of hydrogen interactions with Ni(II) complexes containing cyclic phosphine ligands with pendant nitrogen bases journal March 2007
A Structural Basis of Light Energy and Electron Transfer in Biology(Nobel Lecture) journal July 1989
A Biomimetic Model for the Active Site of Iron-Only Hydrogenases Covalently Bonded to a Porphyrin Photosensitizer journal February 2006
Light-Driven Hydrogen Generation: Efficient Iron-Based Water Reduction Catalysts journal December 2009
Molecular switches controlled by light journal January 2006
Iron hydrogenase active site mimics in supramolecular systems aiming for light-driven hydrogen production journal August 2005
Self-assembled biomimetic [2Fe2S]-hydrogenase-based photocatalyst for molecular hydrogen evolution journal January 2009
The Crystallographic Structure of the B800-820 LH3 Light-Harvesting Complex from the Purple Bacteria Rhodopseudomonas Acidophila Strain 7050 journal July 2001
Electrocatalytic Hydrogen Evolution at Low Overpotentials by Cobalt Macrocyclic Glyoxime and Tetraimine Complexes journal July 2007
The Active Site Model for Iron-Only Hydrogenases Coordinatively Bonded to a Metalloporphyrin Photosensitizer journal March 2007
Desulfovibrio desulfuricans iron hydrogenase: the structure shows unusual coordination to an active site Fe binuclear center journal January 1999
Small molecule mimics of hydrogenases: hydrides and redox journal January 2009
Hydrogen production using cobalt-based molecular catalysts containing a proton relay in the second coordination sphere journal January 2008
Introducing a dark reaction to photochemistry: photocatalytic hydrogen from [FeFe] hydrogenase active site model complexes journal January 2009
Structural and Functional Analogues of the Active Sites of the [Fe]-, [NiFe]-, and [FeFe]-Hydrogenases journal June 2009
Electronic structure of metallocenes journal July 1971
Preparation, characterization and electrochemistry of an iron-only hydrogenase active site model covalently linked to a ruthenium tris(bipyridine) photosensitizer journal June 2008
Inspired by nature: light driven organometallic catalysis by heterooligonuclear Ru(ii) complexes journal January 2007