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Title: Presence of electrolyte promotes wetting and hydrophobic gating in nanopores with residual surface charges

Abstract

Single nanopores containing hydrophobic and hydrophilic islands on the pore walls exhibit salt concentration modulated hydrophobic gating, with more concentrated solutions promoting wetting.

Authors:
 [1];  [2];  [2];  [1];  [3]
  1. Department of Physics and Astronomy; University of California; Irvine; USA
  2. Department of Physics and Astronomy; University of California; Irvine; USA; Department of Physics
  3. Department of Physics and Astronomy; University of California; Irvine; USA; Department of Chemistry
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Nanostructures for Electrical Energy Storage (NEES)
Sponsoring Org.:
USDOE Advanced Research Projects Agency - Energy (ARPA-E)
OSTI Identifier:
1386077
DOE Contract Number:  
SC0001160
Resource Type:
Journal Article
Journal Name:
Analyst
Additional Journal Information:
Journal Volume: 140; Journal Issue: 14; Related Information: NEES partners with University of Maryland (lead); University of California, Irvine; University of Florida; Los Alamos National Laboratory; Sandia National Laboratories; Yale University; Journal ID: ISSN 0003-2654
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
77 NANOSCIENCE AND NANOTECHNOLOGY; bio-inspired, energy storage (including batteries and capacitors), defects, charge transport, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing)

Citation Formats

Innes, Laura, Gutierrez, Diego, Mann, William, Buchsbaum, Steven F., and Siwy, Zuzanna S. Presence of electrolyte promotes wetting and hydrophobic gating in nanopores with residual surface charges. United States: N. p., 2015. Web. doi:10.1039/C4AN02244K.
Innes, Laura, Gutierrez, Diego, Mann, William, Buchsbaum, Steven F., & Siwy, Zuzanna S. Presence of electrolyte promotes wetting and hydrophobic gating in nanopores with residual surface charges. United States. doi:10.1039/C4AN02244K.
Innes, Laura, Gutierrez, Diego, Mann, William, Buchsbaum, Steven F., and Siwy, Zuzanna S. Thu . "Presence of electrolyte promotes wetting and hydrophobic gating in nanopores with residual surface charges". United States. doi:10.1039/C4AN02244K.
@article{osti_1386077,
title = {Presence of electrolyte promotes wetting and hydrophobic gating in nanopores with residual surface charges},
author = {Innes, Laura and Gutierrez, Diego and Mann, William and Buchsbaum, Steven F. and Siwy, Zuzanna S.},
abstractNote = {Single nanopores containing hydrophobic and hydrophilic islands on the pore walls exhibit salt concentration modulated hydrophobic gating, with more concentrated solutions promoting wetting.},
doi = {10.1039/C4AN02244K},
journal = {Analyst},
issn = {0003-2654},
number = 14,
volume = 140,
place = {United States},
year = {2015},
month = {1}
}

Works referenced in this record:

Nanoconfined water under electric field at constant chemical potential undergoes electrostriction
journal, February 2014

  • Vanzo, Davide; Bratko, D.; Luzar, Alenka
  • The Journal of Chemical Physics, Vol. 140, Issue 7
  • DOI: 10.1063/1.4865126

Effect of Field Direction on Electrowetting in a Nanopore
journal, March 2007

  • Bratko, Dusan; Daub, Christopher D.; Leung, Kevin
  • Journal of the American Chemical Society, Vol. 129, Issue 9
  • DOI: 10.1021/ja0659370

Physical Adsorption Characterization of Nanoporous Materials
journal, June 2010


Electric-field-induced wetting and dewetting in single hydrophobic nanopores
journal, October 2011

  • Powell, Matthew R.; Cleary, Leah; Davenport, Matthew
  • Nature Nanotechnology, Vol. 6, Issue 12
  • DOI: 10.1038/nnano.2011.189

Current Rectification at Quartz Nanopipet Electrodes
journal, November 1997

  • Wei, Chang; Bard, Allen J.; Feldberg, Stephen W.
  • Analytical Chemistry, Vol. 69, Issue 22
  • DOI: 10.1021/ac970551g

Water Confinement in Hydrophobic Nanopores. Pressure-Induced Wetting and Drying
journal, August 2010

  • Smirnov, Sergei; Vlassiouk, Ivan; Takmakov, Pavel
  • ACS Nano, Vol. 4, Issue 9
  • DOI: 10.1021/nn101080k

The influence of geometry, surface character, and flexibility on the permeation of ions and water through biological pores
journal, March 2004


Electric field-controlled water permeation coupled to ion transport through a nanopore
journal, March 2004

  • Dzubiella, J.; Allen, R. J.; Hansen, J. -P.
  • The Journal of Chemical Physics, Vol. 120, Issue 11
  • DOI: 10.1063/1.1665656

How Hofmeister ion interactions affect protein stability
journal, October 1996


Hydration Behavior under Confinement by Nanoscale Surfaces with Patterned Hydrophobicity and Hydrophilicity
journal, December 2006

  • Giovambattista, Nicolas; Debenedetti, Pablo G.; Rossky, Peter J.
  • The Journal of Physical Chemistry C, Vol. 111, Issue 3
  • DOI: 10.1021/jp065419b

Zur Lehre von der Wirkung der Salze: Dritte Mittheilung
journal, August 1888

  • Hofmeister, Franz
  • Archiv für Experimentelle Pathologie und Pharmakologie, Vol. 25, Issue 1
  • DOI: 10.1007/BF01838161

A Poisson/Nernst-Planck model for ionic transport through synthetic conical nanopores
journal, July 2005


Adsorption of water vapor and hydrophobicity of ordered mesoporous silica, FSM-16
journal, May 1998


Water-mediated ordering of nanoparticles in an electric field
journal, January 2009

  • Bratko, Dusan; Daub, Christopher D.; Luzar, Alenka
  • Faraday Discuss., Vol. 141
  • DOI: 10.1039/B809135H

Molecular control of ionic conduction in polymer nanopores
journal, January 2009

  • Cruz-Chu, Eduardo R.; Ritz, Thorsten; Siwy, Zuzanna S.
  • Faraday Discussions, Vol. 143
  • DOI: 10.1039/b906279n

Observation of hydrophobic-like behavior in geometrically patterned hydrophilic microchannels
journal, December 2010

  • Parikesit, G. O. F.; Vrouwe, E. X.; Blom, M. T.
  • Biomicrofluidics, Vol. 4, Issue 4
  • DOI: 10.1063/1.3499416

Electrical Conductance of Hydrophobic Membranes or What Happens below the Surface
journal, July 2007

  • Vlassiouk, Ivan; Rios, Fabian; Vail, Sean A.
  • Langmuir, Vol. 23, Issue 14
  • DOI: 10.1021/la070038q

Water flow at the flip of a switch
journal, December 2011


Liquid-vapor oscillations of water in hydrophobic nanopores
journal, May 2003

  • Beckstein, O.; Sansom, M. S. P.
  • Proceedings of the National Academy of Sciences, Vol. 100, Issue 12
  • DOI: 10.1073/pnas.1136844100

Fabrication and functionalization of single asymmetric nanochannels for electrostatic/hydrophobic association of protein molecules
journal, November 2008


Comparison of bipolar and unipolar ionic diodes
journal, June 2010


Reduced water density at hydrophobic surfaces: Effect of dissolved gases
journal, June 2005

  • Doshi, D. A.; Watkins, E. B.; Israelachvili, J. N.
  • Proceedings of the National Academy of Sciences, Vol. 102, Issue 27
  • DOI: 10.1073/pnas.0504034102

Ion-Current Rectification in Nanopores and Nanotubes with Broken Symmetry
journal, April 2006


Effects of salt on the ‘drying’ transition and hydrophobic interaction between nano-sized spherical solutes
journal, December 2013


Electrocapillarity of an electrolyte solution in a nanoslit with overlapped electric double layer: Continuum approach
journal, September 2014


Capillarity at the nanoscale
journal, January 2010

  • van Honschoten, Joost W.; Brunets, Nataliya; Tas, Niels R.
  • Chemical Society Reviews, Vol. 39, Issue 3
  • DOI: 10.1039/b909101g

Voltage-Gated Hydrophobic Nanopores
journal, August 2011

  • Smirnov, Sergei N.; Vlassiouk, Ivan V.; Lavrik, Nickolay V.
  • ACS Nano, Vol. 5, Issue 9
  • DOI: 10.1021/nn202392d

Large-scale molecular-dynamics simulation of nanoscale hydrophobic interaction and nanobubble formation
journal, November 2005

  • Koishi, Takahiro; Yasuoka, Kenji; Ebisuzaki, Toshikazu
  • The Journal of Chemical Physics, Vol. 123, Issue 20
  • DOI: 10.1063/1.2102906

Fabrication of a Synthetic Nanopore Ion Pump
journal, October 2002


Infiltration of Electrolytes in Molecular-Sized Nanopores
journal, May 2009


Effect of Ions on the Hydrophobic Interaction between Two Plates
journal, April 2007

  • Zangi, Ronen; Hagen, Morten; Berne, B. J.
  • Journal of the American Chemical Society, Vol. 129, Issue 15
  • DOI: 10.1021/ja068305m

Sorption Isotherms of Water in Nanopores: Relationship Between Hydropohobicity, Adsorption Pressure, and Hysteresis
journal, July 2014

  • Factorovich, Matías H.; Gonzalez Solveyra, Estefanía; Molinero, Valeria
  • The Journal of Physical Chemistry C, Vol. 118, Issue 29
  • DOI: 10.1021/jp5000396

Access resistance of a small circular pore
journal, October 1975


Ion Current Rectification at Nanopores in Glass Membranes
journal, March 2008


Conical-Nanotube Ion-Current Rectifiers:  The Role of Surface Charge
journal, September 2004

  • Siwy, Zuzanna; Heins, Elizabeth; Harrell, C. Chad
  • Journal of the American Chemical Society, Vol. 126, Issue 35
  • DOI: 10.1021/ja047675c

Electric-field-controlled water and ion permeation of a hydrophobic nanopore
journal, June 2005

  • Dzubiella, J.; Hansen, J. -P.
  • The Journal of Chemical Physics, Vol. 122, Issue 23
  • DOI: 10.1063/1.1927514

Diode-like single-ion track membrane prepared by electro-stopping
journal, November 2001

  • Apel, P. Yu.; Korchev, Yu. E.; Siwy, Z.
  • Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 184, Issue 3, p. 337-346
  • DOI: 10.1016/S0168-583X(01)00722-4

Biosensing with Nanofluidic Diodes
journal, June 2009

  • Vlassiouk, Ivan; Kozel, Thomas R.; Siwy, Zuzanna S.
  • Journal of the American Chemical Society, Vol. 131, Issue 23
  • DOI: 10.1021/ja901120f

How Ions Affect the Structure of Water
journal, October 2002

  • Hribar, Barbara; Southall, Noel T.; Vlachy, Vojko
  • Journal of the American Chemical Society, Vol. 124, Issue 41
  • DOI: 10.1021/ja026014h

Activation Barrier Scaling for the Spontaneous Evaporation of Confined Water
journal, December 2004

  • Luzar, Alenka
  • The Journal of Physical Chemistry B, Vol. 108, Issue 51
  • DOI: 10.1021/jp0470703

Control of Nanopore Wetting by a Photochromic Spiropyran: A Light-Controlled Valve and Electrical Switch
journal, May 2006

  • Vlassiouk, Ivan; Park, Choong-Do; Vail, Sean A.
  • Nano Letters, Vol. 6, Issue 5
  • DOI: 10.1021/nl060313d

Charge density-dependent strength of hydration and biological structure
journal, January 1997


Engineered voltage-responsive nanopores
journal, January 2010

  • Siwy, Zuzanna S.; Howorka, Stefan
  • Chem. Soc. Rev., Vol. 39, Issue 3
  • DOI: 10.1039/B909105J

A hydrophobic entrance enhances ion current rectification and induces dewetting in asymmetric nanopores
journal, January 2012

  • Pevarnik, Matthew; Healy, Ken; Davenport, Matthew
  • The Analyst, Vol. 137, Issue 13
  • DOI: 10.1039/c2an16139g

Semiquantitative Study of the EDC/NHS Activation of Acid Terminal Groups at Modified Porous Silicon Surfaces
journal, January 2010

  • Sam, S.; Touahir, L.; Salvador Andresa, J.
  • Langmuir, Vol. 26, Issue 2
  • DOI: 10.1021/la902220a

Current Rectification with Poly- l -Lysine-Coated Quartz Nanopipettes
journal, November 2006

  • Umehara, Senkei; Pourmand, Nader; Webb, Chris D.
  • Nano Letters, Vol. 6, Issue 11
  • DOI: 10.1021/nl061681k

Field-exposed water in a nanopore: liquid or vapour?
journal, January 2008

  • Bratko, Dusan; Daub, Christopher D.; Luzar, Alenka
  • Physical Chemistry Chemical Physics, Vol. 10, Issue 45
  • DOI: 10.1039/b809072f