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Title: Structure of the high voltage phase of layered P2-Na 2/3-z[Mn 1/2Fe 1/2 ]O 2 and the positive effect of Ni substitution on its stability

Abstract

Using in-depth structural and spectroscopic analysis, we unravel the nature of phenomena specific to the Fe 3+/Fe 4+redox couple in P2-Na 0.67-z[Ni yMn 0.5+yFe 0.5-2y]O 2.

Authors:
 [1];  [1];  [2];  [2];  [1]
  1. Department of Chemistry; Waterloo Institute for Nanotechnology; University of Waterloo; Waterloo; Canada
  2. Department of Applied Physics and Materials Science; California Institute of Technology; Pasadena; USA
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Energy Frontier Research in Extreme Environments (EFree)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1386015
DOE Contract Number:  
SC0001057
Resource Type:
Journal Article
Resource Relation:
Journal Name: Energy & Environmental Science; Journal Volume: 8; Journal Issue: 8; Related Information: EFree partners with Carnegie Institution of Washington (lead); California Institute of Technology; Colorado School of Mines; Cornell University; Lehigh University; Pennsylvania State University
Country of Publication:
United States
Language:
English
Subject:
catalysis (heterogeneous), solar (photovoltaic), phonons, thermoelectric, energy storage (including batteries and capacitors), hydrogen and fuel cells, superconductivity, charge transport, mesostructured materials, materials and chemistry by design, synthesis (novel materials)

Citation Formats

Talaie, Elahe, Duffort, Victor, Smith, Hillary L., Fultz, Brent, and Nazar, Linda F. Structure of the high voltage phase of layered P2-Na2/3-z[Mn 1/2Fe 1/2 ]O2 and the positive effect of Ni substitution on its stability. United States: N. p., 2015. Web. doi:10.1039/c5ee01365h.
Talaie, Elahe, Duffort, Victor, Smith, Hillary L., Fultz, Brent, & Nazar, Linda F. Structure of the high voltage phase of layered P2-Na2/3-z[Mn 1/2Fe 1/2 ]O2 and the positive effect of Ni substitution on its stability. United States. doi:10.1039/c5ee01365h.
Talaie, Elahe, Duffort, Victor, Smith, Hillary L., Fultz, Brent, and Nazar, Linda F. Thu . "Structure of the high voltage phase of layered P2-Na2/3-z[Mn 1/2Fe 1/2 ]O2 and the positive effect of Ni substitution on its stability". United States. doi:10.1039/c5ee01365h.
@article{osti_1386015,
title = {Structure of the high voltage phase of layered P2-Na2/3-z[Mn 1/2Fe 1/2 ]O2 and the positive effect of Ni substitution on its stability},
author = {Talaie, Elahe and Duffort, Victor and Smith, Hillary L. and Fultz, Brent and Nazar, Linda F.},
abstractNote = {Using in-depth structural and spectroscopic analysis, we unravel the nature of phenomena specific to the Fe3+/Fe4+redox couple in P2-Na0.67-z[NiyMn0.5+yFe0.5-2y]O2.},
doi = {10.1039/c5ee01365h},
journal = {Energy & Environmental Science},
number = 8,
volume = 8,
place = {United States},
year = {Thu Jan 01 00:00:00 EST 2015},
month = {Thu Jan 01 00:00:00 EST 2015}
}