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Title: Electrochemical reduction of Ag 2 VP 2 O 8 composite electrodes visualized via in situ energy dispersive X-ray diffraction (EDXRD): unexpected conductive additive effects

Abstract

EDXRD of Li/C-Ag 2VP 2O 8revealed that higher-rate initial discharge (B) generated a more effective conductive matrixvia in situreduction-displacement-deposition of Ag 0.

Authors:
 [1];  [2];  [1];  [3];  [3];  [4]
  1. Energy Sciences Directorate; Brookhaven National Laboratory; Upton; USA
  2. Department of Chemistry; Stony Brook University; Stony Brook; USA
  3. Department of Chemistry; Stony Brook University; Stony Brook; USA; Department of Materials Science and Engineering
  4. Energy Sciences Directorate; Brookhaven National Laboratory; Upton; USA; Department of Chemistry
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2M)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1385996
DOE Contract Number:  
SC0012673
Resource Type:
Journal Article
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Volume: 3; Journal Issue: 35; Related Information: m2M partners with Stony Brook University (lead); Brookhaven National Laboratory; Columbia University; Georgia Institute of Technology; Oak Ridge National Laboratory; Rensselaer Polytechnic Institute; University of California, Berkeley; University of North Carolina at Chapel Hill; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
energy storage (including batteries and capacitors), charge transport, mesostructured materials

Citation Formats

Kirshenbaum, Kevin C., Bock, David C., Zhong, Zhong, Marschilok, Amy C., Takeuchi, Kenneth J., and Takeuchi, Esther S. Electrochemical reduction of Ag 2 VP 2 O 8 composite electrodes visualized via in situ energy dispersive X-ray diffraction (EDXRD): unexpected conductive additive effects. United States: N. p., 2015. Web. doi:10.1039/C5TA04523A.
Kirshenbaum, Kevin C., Bock, David C., Zhong, Zhong, Marschilok, Amy C., Takeuchi, Kenneth J., & Takeuchi, Esther S. Electrochemical reduction of Ag 2 VP 2 O 8 composite electrodes visualized via in situ energy dispersive X-ray diffraction (EDXRD): unexpected conductive additive effects. United States. doi:10.1039/C5TA04523A.
Kirshenbaum, Kevin C., Bock, David C., Zhong, Zhong, Marschilok, Amy C., Takeuchi, Kenneth J., and Takeuchi, Esther S. Thu . "Electrochemical reduction of Ag 2 VP 2 O 8 composite electrodes visualized via in situ energy dispersive X-ray diffraction (EDXRD): unexpected conductive additive effects". United States. doi:10.1039/C5TA04523A.
@article{osti_1385996,
title = {Electrochemical reduction of Ag 2 VP 2 O 8 composite electrodes visualized via in situ energy dispersive X-ray diffraction (EDXRD): unexpected conductive additive effects},
author = {Kirshenbaum, Kevin C. and Bock, David C. and Zhong, Zhong and Marschilok, Amy C. and Takeuchi, Kenneth J. and Takeuchi, Esther S.},
abstractNote = {EDXRD of Li/C-Ag2VP2O8revealed that higher-rate initial discharge (B) generated a more effective conductive matrixvia in situreduction-displacement-deposition of Ag0.},
doi = {10.1039/C5TA04523A},
journal = {Journal of Materials Chemistry. A},
issn = {2050-7488},
number = 35,
volume = 3,
place = {United States},
year = {2015},
month = {1}
}

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