Exploring supramolecular assembly and luminescent behavior in a series of RE-p-chlorobenzoic acid-1,10-phenanthroline complexes

Carter, Korey P.; Zulato, Cecília H.  F.; Cahill, Christopher L.

doi:10.1039/c4ce01806k

Title: Exploring supramolecular assembly and luminescent behavior in a series of RE-p-chlorobenzoic acid-1,10-phenanthroline complexes

Journal Article · Wed Jan 01 00:00:00 EST 2014 · CrystEngComm

DOI:https://doi.org/10.1039/c4ce01806k· OSTI ID:1385685

Carter, Korey P. ^[1]; Zulato, Cecília H. F. ^[2]; Cahill, Christopher L. ^[1]

Department of Chemistry; The George Washington University; Washington, USA
Department of Chemistry; The George Washington University; Washington, USA; Laboratory of Functional Materials; Institute of Chemistry

Eleven new rare earth (RE)-p-chlorobenzoic acid-1,10-phenanthroline complexes have been synthesized and their structural, supramolecular and luminescent properties have been explored.

Cite

Export

Save

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Materials Science of Actinides (MSA)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: SC0001089

OSTI ID:: 1385685

Journal Information:: CrystEngComm, Vol. 16, Issue 44; Related Information: MSA partners with University of Notre Dame (lead); University of California, Davis; Florida State University; George Washington University; University of Michigan; University of Minnesota; Oak Ridge National Laboratory; Oregon state University; Rensselaer Polytechnic Institute; Savannah River National Laboratory; ISSN 1466-8033

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

References (71)

Supramolecular Synthons in Crystal Engineering—A New Organic Synthesis Desiraju, Gautam R. Angewandte Chemie International Edition in English, Vol. 34, Issue 21 https://doi.org/10.1002/anie.199523111	journal	November 1995
A robust near infrared luminescent ytterbium metal–organic framework for sensing of small molecules Guo, Zhiyong; Xu, Hui; Su, Shengqun Chemical Communications, Vol. 47, Issue 19 https://doi.org/10.1039/c1cc10897b	journal	January 2011
WinGX and ORTEP for Windows : an update Farrugia, Louis J. Journal of Applied Crystallography, Vol. 45, Issue 4 https://doi.org/10.1107/S0021889812029111	journal	July 2012
Tunable Rare-Earth fcu-MOFs: A Platform for Systematic Enhancement of CO₂ Adsorption Energetics and Uptake Xue, Dong-Xu; Cairns, Amy J.; Belmabkhout, Youssef Journal of the American Chemical Society, Vol. 135, Issue 20, p. 7660-7667 https://doi.org/10.1021/ja401429x	journal	May 2013
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
Lanthanide Coordination Polymers Constructed from Dinuclear Building Blocks: Novel Structure Evolution from One-Dimensional Chains to Three-Dimensional Architectures Ye, Junwei; Zhang, Jingying; Ning, Guiling Crystal Growth & Design, Vol. 8, Issue 8 https://doi.org/10.1021/cg800310j	journal	August 2008
A critical account on π–π stacking in metal complexes with aromatic nitrogen-containing ligands † Janiak, Christoph Journal of the Chemical Society, Dalton Transactions, Issue 21 https://doi.org/10.1039/b003010o	journal	January 2000
Anion-Directed Self-Assembly in Coordination Networks: Architectural Control via Cooperative Noncovalent Interactions Notash, Behrouz; Safari, Nasser; Khavasi, Hamid Reza Inorganic Chemistry, Vol. 49, Issue 24 https://doi.org/10.1021/ic101387c	journal	December 2010
The exploration of supramolecular interactions stemming from the [UO ₂ (NCS) ₄ (H ₂ O)] ²⁻ tecton and substituted pyridinium cations Surbella III, Robert G.; Cahill, Christopher L. CrystEngComm, Vol. 16, Issue 12 https://doi.org/10.1039/C3CE42106F	journal	January 2014
Lanthanide-based emitting materials in light-emitting diodes de Bettencourt-Dias, Ana Dalton Transactions, Issue 22 https://doi.org/10.1039/b702341c	journal	January 2007
Charge Transport and Sensitized 1.5 μm Electroluminescence Properties of Full Solution-Processed NIR-OLED based on Novel Er(III) Fluorinated β-Diketonate Ternary Complex Martín-Ramos, Pablo; Coya, Carmen; Álvarez, Ángel L. The Journal of Physical Chemistry C, Vol. 117, Issue 19 https://doi.org/10.1021/jp402174s	journal	May 2013
Metal–organic hybrids involving the [UO ₂ Cl ₃ (NO ₃ )] ²⁻ tecton and the role of halogen polarizability Andrews, Michael B.; Cahill, Christopher L. CrystEngComm, Vol. 15, Issue 16 https://doi.org/10.1039/C2CE26561C	journal	January 2013
A mesoporous lanthanide–organic framework constructed from a dendritic hexacarboxylate with cages of 2.4 nm He, Yabing; Furukawa, Hiroyasu; Wu, Chuande CrystEngComm, Vol. 15, Issue 45 https://doi.org/10.1039/c3ce41062e	journal	January 2013
Synthon crossover between halogen⋯π and halogen⋯halogen interaction Khavasi, Hamid Reza; Ghanbarpour, Alireza; Tehrani, Alireza Azhdari CrystEngComm, Vol. 16, Issue 5 https://doi.org/10.1039/C3CE41853G	journal	January 2014
Homo- and heterometallic coordination polymers from the f elements Cahill, Christopher L.; de Lill, Daniel T.; Frisch, Mark CrystEngComm, Vol. 9, Issue 1 https://doi.org/10.1039/B615696G	journal	January 2007
Luminescent Functional Metal–Organic Frameworks Cui, Yuanjing; Yue, Yanfeng; Qian, Guodong Chemical Reviews, Vol. 112, Issue 2 https://doi.org/10.1021/cr200101d	journal	June 2011
Correlation between the lowest triplet state energy level of the ligand and lanthanide(III) luminescence quantum yield Latva, Martti; Takalo, Harri; Mukkala, Veli-Matti Journal of Luminescence, Vol. 75, Issue 2 https://doi.org/10.1016/S0022-2313(97)00113-0	journal	September 1997
Hybrid materials based on lanthanide organic complexes: a review Feng, Jing; Zhang, Hongjie Chem. Soc. Rev., Vol. 42, Issue 1 https://doi.org/10.1039/C2CS35069F	journal	January 2013
Structural Systematics of Rare Earth Complexes. XII Solvated 1 : 1 Adducts of Some Lanthanoid(III) Carboxylates with 1,10-Phenanthroline and 2,2′:6′,2″-Terpyridine Kepert, Cameron J.; Semenova, Lioubov I.; Wei-Min, Lu Australian Journal of Chemistry, Vol. 52, Issue 6 https://doi.org/10.1071/CH98043	journal	January 1999
Anion-controlled structural motif in one-dimensional coordination networks via cooperative weak noncovalent interactions Notash, Behrouz; Safari, Nasser; Khavasi, Hamid Reza CrystEngComm, Vol. 14, Issue 20 https://doi.org/10.1039/c2ce25554e	journal	January 2012
Lanthanide Luminescent Bioprobes (LLBs) Bünzli, Jean-Claude G. Chemistry Letters, Vol. 38, Issue 2 https://doi.org/10.1246/cl.2009.104	journal	February 2009
Isostructural neo -Pentoxide Derivatives of Group 3 and the Lanthanide Series Metals for the Production of Ln ₂ O ₃ Nanoparticles Boyle, Timothy J.; Ottley, Leigh Anna M.; Daniel-Taylor, Sherrika D. Inorganic Chemistry, Vol. 46, Issue 9 https://doi.org/10.1021/ic070253u	journal	March 2007
Pyridinderivate als Komplexbildner V. Die Metallkomplexe von 1,10-Phenanthrolin und ?, ??-Dipyridyl Anderegg, G. Helvetica Chimica Acta, Vol. 46, Issue 6 https://doi.org/10.1002/hlca.19630460657	journal	January 1963
Crystal engineering of 5,5′-bisdiazo-dipyrromethane with halogen⋯π synthons Yin, Zhenming; Wang, Wuyan; Du, Miao CrystEngComm, Vol. 11, Issue 11 https://doi.org/10.1039/b905568a	journal	January 2009
Supramolecular architecture of new lanthanide coordination polymers of 2-aminoterephthalic acid and 1,10-phenanthroline Liu, Chong-Bo; Sun, Chang-Yan; Jin, Lin-Pei New Journal of Chemistry, Vol. 28, Issue 8 https://doi.org/10.1039/b402803a	journal	January 2004
Electronic Energy Levels in the Trivalent Lanthanide Aquo Ions. I. Pr ³⁺ , Nd ³⁺ , Pm ³⁺ , Sm ³⁺ , Dy ³⁺ , Ho ³⁺ , Er ³⁺ , and Tm ³⁺ Carnall, W. T.; Fields, P. R.; Rajnak, K. The Journal of Chemical Physics, Vol. 49, Issue 10 https://doi.org/10.1063/1.1669893	journal	November 1968
Benefiting from the Unique Properties of Lanthanide Ions Bünzli, Jean-Claude G. Accounts of Chemical Research, Vol. 39, Issue 1 https://doi.org/10.1021/ar0400894	journal	January 2006
Carboxylate-Bridged Dinuclear Dy2 Single-Molecule Magnets: Synthesis, Structure, and Magnetic Studies Song, Yu-mei; Luo, Feng; Zhu, Yan Australian Journal of Chemistry, Vol. 66, Issue 1 https://doi.org/10.1071/CH12377	journal	January 2013
The pyridyl group in ligand design for selective metal ion complexation and sensing Hancock, Robert D. Chem. Soc. Rev., Vol. 42, Issue 4 https://doi.org/10.1039/C2CS35224A	journal	January 2013
Lanthanide Complexes for Second Order Nonlinear Optics: Evidence for the Direct Contribution of f Electrons to the Quadratic Hyperpolarizability ¹ Tancrez, Nicolas; Feuvrie, Christophe; Ledoux, Isabelle Journal of the American Chemical Society, Vol. 127, Issue 39 https://doi.org/10.1021/ja054065j	journal	October 2005
Tetrakis(μ-4-chlorobenzoato)bis[(4-chlorobenzoato)(1,10-phenanthroline)dysprosium(III)] Zhang, Bi-Song Acta Crystallographica Section E Structure Reports Online, Vol. 62, Issue 10 https://doi.org/10.1107/S1600536806036725	journal	September 2006
Benzothiazole- and Benzoxazole-Substituted Pyridine-2-Carboxylates as Efficient Sensitizers of Europium Luminescence Shavaleev, Nail M.; Scopelliti, Rosario; Gumy, Frédéric Inorganic Chemistry, Vol. 48, Issue 13 https://doi.org/10.1021/ic9005136	journal	July 2009
Assembly and upconversion luminescence of lanthanide–organic frameworks with mixed acid ligands Sun, Chang-Yan; Zheng, Xiang-Jun; Chen, Xiao-Bo Inorganica Chimica Acta, Vol. 362, Issue 2 https://doi.org/10.1016/j.ica.2008.03.115	journal	January 2009
Structure validation in chemical crystallography Spek, Anthony L. Acta Crystallographica Section D Biological Crystallography, Vol. 65, Issue 2, p. 148-155 https://doi.org/10.1107/S090744490804362X	journal	January 2009
Lanthanide benzoates: a versatile building block for the construction of efficient light emitting materials Reddy, M. L. P.; Sivakumar, Sarika Dalton Trans., Vol. 42, Issue 8 https://doi.org/10.1039/C2DT32470A	journal	January 2013
Nonlinear optical activity in dipolar organic–lanthanide complexes Law, Ga-Lai; Wong, Ka-Leung; Lau, Kok-Kin Journal of Materials Chemistry, Vol. 20, Issue 20 https://doi.org/10.1039/b926376d	journal	January 2010
Supramolecular Synthons: Validation and Ranking of Intermolecular Interaction Energies Dunitz, J. D.; Gavezzotti, A. Crystal Growth & Design, Vol. 12, Issue 12 https://doi.org/10.1021/cg301293r	journal	November 2012
OH–π and halogen–π interactions as driving forces in the crystal organisations of tri-bromo and tri-iodo trityl alcohols Schollmeyer, Dieter; Shishkin, Oleg V.; Rühl, Thomas CrystEngComm, Vol. 10, Issue 6 https://doi.org/10.1039/b716442d	journal	January 2008
Influence of Halogen Bonding Interaction on Supramolecular Assembly of Coordination Compounds; Head-to-Tail N···X Synthon Repetitivity Khavasi, Hamid Reza; Azhdari Tehrani, Alireza Inorganic Chemistry, Vol. 52, Issue 6 https://doi.org/10.1021/ic3021113	journal	February 2013
A short history of SHELX Sheldrick, George M. Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122 https://doi.org/10.1107/S0108767307043930	journal	December 2007
Lanthanide-Containing Molecular and Supramolecular Polymetallic Functional Assemblies Bünzli, Jean-Claude G.; Piguet, Claude Chemical Reviews, Vol. 102, Issue 6 https://doi.org/10.1021/cr010299j	journal	June 2002
Supramolecular assemblies with water-soluble p-sulfonatothiacalix[6]arene lanthanide complexes: one-dimensional ‘ladder-type’ coordination polymers and one-dimensional hydrogen-bonded polymers Yamada, Manabu; Hamada, Fumio CrystEngComm, Vol. 15, Issue 28 https://doi.org/10.1039/c3ce40431e	journal	January 2013
Aromatic N-donor ligands as chelators and sensitizers of lanthanide ion emission de Bettencourt-Dias, Ana; Barber, Patrick S.; Viswanathan, Subha Coordination Chemistry Reviews, Vol. 273-274 https://doi.org/10.1016/j.ccr.2014.04.010	journal	August 2014
Supramolecular assemblies built from lanthanide ammoniocarboxylates and cucurbit[6]uril Thuéry, Pierre CrystEngComm, Vol. 14, Issue 23 https://doi.org/10.1039/c2ce25915j	journal	January 2012
Crystal structures, luminescent and thermal properties of a new series of lanthanide complexes with 4-ethylbenzoic acid Ye, Hong-Mei; Ren, Ning; Zhang, Jian-Jun New Journal of Chemistry, Vol. 34, Issue 3 https://doi.org/10.1039/b9nj00504h	journal	January 2010
Combining coordination and supramolecular chemistry for the formation of uranyl-organic hybrid materials Deifel, Nicholas P.; Cahill, Christopher L. Chemical Communications, Vol. 47, Issue 21 https://doi.org/10.1039/c1cc11116g	journal	January 2011
Lone pair–π interactions: a new supramolecular bond? Mooibroek, Tiddo J.; Gamez, Patrick; Reedijk, Jan CrystEngComm, Vol. 10, Issue 11 https://doi.org/10.1039/b812026a	journal	January 2008
Three-Dimensional Lanthanide Thiophenedicarboxylate Framework with an Unprecedented (4,5)-Connected Topology Wang, Jin-Gen; Huang, Chang-Cang; Huang, Xi-He Crystal Growth & Design, Vol. 8, Issue 3 https://doi.org/10.1021/cg7011342	journal	March 2008
Effect of Lanthanide Contraction on Crystal Structures of Three-Dimensional Lanthanide Based Metal–Organic Frameworks with Thiophene-2,5-Dicarboxylate and Oxalate Xu, Jing; Cheng, Jianwen; Su, Weiping Crystal Growth & Design, Vol. 11, Issue 6 https://doi.org/10.1021/cg101736e	journal	June 2011
Hydrothermal synthesis, crystal structure and luminescence properties of lanthanide fumarate coordination polymers containing 2,2′-bipyridine Li, Xia; Zhang, Ting-Ting; Zhang, ZhuO-Yong Journal of Coordination Chemistry, Vol. 60, Issue 24 https://doi.org/10.1080/00958970701308658	journal	December 2007
A microporous lanthanide-tricarboxylate framework with the potential for purification of natural gas He, Yabing; Xiang, Shengchang; Zhang, Zhangjing Chemical Communications, Vol. 48, Issue 88 https://doi.org/10.1039/c2cc35729a	journal	January 2012
1,10-Phenanthroline: A versatile building block for the construction of ligands for various purposes Bencini, Andrea; Lippolis, Vito Coordination Chemistry Reviews, Vol. 254, Issue 17-18 https://doi.org/10.1016/j.ccr.2010.04.008	journal	September 2010
Perdeuterated 2,2′-Bipyridine-6,6′-dicarboxylate: An Extremely Efficient Sensitizer for Thulium Luminescence in Solution Wahsner, Jessica; Seitz, Michael Inorganic Chemistry, Vol. 52, Issue 23 https://doi.org/10.1021/ic402652t	journal	November 2013
Picosecond time-resolved luminescence of Pr(III) complexes: Intramolecular excitation energy transfer from ligand to Pr(III) Hasegawa, Miki; Ishii, Ayumi; Kishi, Shinobu Journal of Photochemistry and Photobiology A: Chemistry, Vol. 178, Issue 2-3 https://doi.org/10.1016/j.jphotochem.2005.12.005	journal	March 2006
The application of single-crystal-to-single-crystal transformation towards adjustable SMM properties Song, Yu-mei; Luo, Feng; Luo, Ming-biao Chem. Commun., Vol. 48, Issue 7 https://doi.org/10.1039/C2CC17080A	journal	January 2012
Noncovalent Interactions under Extreme Conditions: High-Pressure and Low-Temperature Diffraction Studies of the Isostructural Metal−Organic Networks (4-Chloropyridinium) ₂ [CoX ₄ ] (X = Cl, Br) Mínguez Espallargas, Guillermo; Brammer, Lee; Allan, David R. Journal of the American Chemical Society, Vol. 130, Issue 28 https://doi.org/10.1021/ja8010868	journal	July 2008
Luminescent lanthanide complexes as photochemical supramolecular devices Sabbatini, Nanda; Guardigli, Massimo; Lehn, Jean-Marie Coordination Chemistry Reviews, Vol. 123, Issue 1-2, p. 201-228 https://doi.org/10.1016/0010-8545(93)85056-A	journal	February 1993
Organo Lanthanide Metal Complexes for Electroluminescent Materials Kido, Junji; Okamoto, Yoshi Chemical Reviews, Vol. 102, Issue 6 https://doi.org/10.1021/cr010448y	journal	June 2002
The Lanthanide Contraction Revisited Seitz, Michael; Oliver, Allen G.; Raymond, Kenneth N. Journal of the American Chemical Society, Vol. 129, Issue 36 https://doi.org/10.1021/ja072750f	journal	September 2007
The Cambridge Structural Database: a quarter of a million crystal structures and rising Allen, Frank H. Acta Crystallographica Section B Structural Science, Vol. 58, Issue 3 https://doi.org/10.1107/S0108768102003890	journal	May 2002
Structures of 2,4,6-tri-α-pyridyl-1,3,5-triazine complexes of the lanthanoid nitrates: A study in the lanthanoid contraction Cotton, Simon A.; Franckevicius, Vilius; Mahon, Mary F. Polyhedron, Vol. 25, Issue 4 https://doi.org/10.1016/j.poly.2005.12.012	journal	March 2006
Lanthanide Single-Molecule Magnets Woodruff, Daniel N.; Winpenny, Richard E. P.; Layfield, Richard A. Chemical Reviews, Vol. 113, Issue 7 https://doi.org/10.1021/cr400018q	journal	March 2013
A series of Ln-p-chlorobenzoic acid–terpyridine complexes: lanthanide contraction effects, supramolecular interactions and luminescent behavior Carter, Korey P.; Pope, Simon J. A.; Cahill, Christopher L. CrystEngComm, Vol. 16, Issue 10 https://doi.org/10.1039/c3ce42267d	journal	January 2014
Simultaneous electrophile–nucleophile Cl⋯π interactions stabilizing solid state inclusions: a new tool for supramolecular crystal engineering Csöregh, Ingeborg; Weber, Edwin; Hens, Thomas J. Chem. Soc., Perkin Trans. 2, Issue 12 https://doi.org/10.1039/P29960002733	journal	January 1996
Halogen Bonded Supramolecular Assemblies of [Ru(bipy)(CN) ₄ ] ²⁻ Anions and N -Methyl-Halopyridinium Cations in the Solid State and in Solution Derossi, Sofia; Brammer, Lee; Hunter, Christopher A. Inorganic Chemistry, Vol. 48, Issue 4 https://doi.org/10.1021/ic8021529	journal	February 2009
Synthesis, Crystal Structures, and Photophysical Properties of Homodinuclear Lanthanide Xanthene-9-carboxylates Shyni, R.; Biju, S.; Reddy, M. L. P. Inorganic Chemistry, Vol. 46, Issue 26 https://doi.org/10.1021/ic701075u	journal	December 2007
A new tetrakis β-diketone ligand for NIR emitting LnIII ions: luminescent doped PMMA films and flexible resins for advanced photonic applications Biju, Silvanose; Eom, Yu Kyung; Bünzli, Jean-Claude G. Journal of Materials Chemistry C, Vol. 1, Issue 42 https://doi.org/10.1039/c3tc31181c	journal	January 2013
Crystal Structures and Magnetic and Luminescent Properties of a Series of Homodinuclear Lanthanide Complexes with 4-Cyanobenzoic Ligand Li, Yan; Zheng, Fa-Kun; Liu, Xi Inorganic Chemistry, Vol. 45, Issue 16 https://doi.org/10.1021/ic0602603	journal	August 2006
Sensitization of Visible and NIR Emitting Lanthanide(III) Ions in Noncentrosymmetric Complexes of Hexafluoroacetylacetone and Unsubstituted Monodentate Pyrazole Ahmed, Zubair; Iftikhar, K. The Journal of Physical Chemistry A, Vol. 117, Issue 44 https://doi.org/10.1021/jp403668j	journal	October 2013
Structural characterization of lanthanide coordination polymers assembled from V-shaped 4,4′-oxybis(benzoate) ligand Łyszczek, Renata; Mazur, Liliana Inorganic Chemistry Communications, Vol. 15 https://doi.org/10.1016/j.inoche.2011.10.006	journal	January 2012
Taking advantage of luminescent lanthanide ions Bünzli, Jean-Claude G.; Piguet, Claude Chemical Society Reviews, Vol. 34, Issue 12 https://doi.org/10.1039/b406082m	journal	January 2005

Similar Records

Exploring supramolecular assembly and luminescent behavior in a series of RE-p-chlorobenzoic acid-1,10-phenanthroline complexes

Journal Article · Fri Sep 26 00:00:00 EDT 2014 · CrystEngComm · OSTI ID:1385685

Carter, K. P.; Zulato, C.; Cahill, Christopher L.

A series of Ln-p-chlorobenzoic acid–terpyridine complexes: lanthanide contraction effects, supramolecular interactions and luminescent behavior

Journal Article · Wed Jan 01 00:00:00 EST 2014 · CrystEngComm · OSTI ID:1385685

Carter, Korey P.; Pope, Simon J. A.; Cahill, Christopher L.

Exploring the Promotion of Synthons of Choice: Halogen Bonding in Molecular Lanthanide Complexes Characterized via X-ray Diffraction, Luminescence Spectroscopy, and Magnetic Measurements

Journal Article · Fri Sep 29 00:00:00 EDT 2017 · Zeitschrift fuer Anorganische und Allgemeine Chemie · OSTI ID:1385685

Carter, Korey P.; Pope, Simon J. A.; Kalaj, Mark; +3 more

Related Subjects

nuclear (including radiation effects)
materials and chemistry by design
synthesis (novel materials)
synthesis (self-assembly)

Title: Exploring supramolecular assembly and luminescent behavior in a series of RE-p-chlorobenzoic acid-1,10-phenanthroline complexes

Citation Formats

References (71)

Similar Records

Related Subjects