Energetics of metastudtite and implications for nuclear waste alteration
- Authors:
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Materials Science of Actinides (MSA)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1385677
- DOE Contract Number:
- SC0001089
- Resource Type:
- Journal Article
- Journal Name:
- Proceedings of the National Academy of Sciences of the United States of America
- Additional Journal Information:
- Journal Volume: 111; Journal Issue: 50; Related Information: MSA partners with University of Notre Dame (lead); University of California, Davis; Florida State University; George Washington University; University of Michigan; University of Minnesota; Oak Ridge National Laboratory; Oregon state University; Rensselaer Polytechnic Institute; Savannah River National Laboratory; Journal ID: ISSN 0027-8424
- Publisher:
- National Academy of Sciences, Washington, DC (United States)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- nuclear (including radiation effects), materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly)
Citation Formats
Guo, Xiaofeng, Ushakov, Sergey V., Labs, Sabrina, Curtius, Hildegard, Bosbach, Dirk, and Navrotsky, Alexandra. Energetics of metastudtite and implications for nuclear waste alteration. United States: N. p., 2014.
Web. doi:10.1073/pnas.1421144111.
Guo, Xiaofeng, Ushakov, Sergey V., Labs, Sabrina, Curtius, Hildegard, Bosbach, Dirk, & Navrotsky, Alexandra. Energetics of metastudtite and implications for nuclear waste alteration. United States. https://doi.org/10.1073/pnas.1421144111
Guo, Xiaofeng, Ushakov, Sergey V., Labs, Sabrina, Curtius, Hildegard, Bosbach, Dirk, and Navrotsky, Alexandra. 2014.
"Energetics of metastudtite and implications for nuclear waste alteration". United States. https://doi.org/10.1073/pnas.1421144111.
@article{osti_1385677,
title = {Energetics of metastudtite and implications for nuclear waste alteration},
author = {Guo, Xiaofeng and Ushakov, Sergey V. and Labs, Sabrina and Curtius, Hildegard and Bosbach, Dirk and Navrotsky, Alexandra},
abstractNote = {},
doi = {10.1073/pnas.1421144111},
url = {https://www.osti.gov/biblio/1385677},
journal = {Proceedings of the National Academy of Sciences of the United States of America},
issn = {0027-8424},
number = 50,
volume = 111,
place = {United States},
year = {Mon Nov 24 00:00:00 EST 2014},
month = {Mon Nov 24 00:00:00 EST 2014}
}
Other availability
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Raspite and studtite: Raman spectra of two unique minerals
journal, July 2004
- Bastians, Simon; Crump, Gregory; Griffith, William P.
- Journal of Raman Spectroscopy, Vol. 35, Issue 89
Enthalpies of formation of Ce-pyrochlore, Ca0.93Ce1.00Ti2.035O7.00, U-pyrochlore, Ca1.46U4+0.23U6+0.46Ti1.85O7.00 and Gd-pyrochlore, Gd2Ti2O7: three materials relevant to the proposed waste form for excess weapons plutonium
journal, June 2002
- Helean, K. B.; Navrotsky, A.; Vance, E. R.
- Journal of Nuclear Materials, Vol. 303, Issue 2-3
Alteration of dehydrated schoepite and soddyite to studtite, [(UO2)(O2)(H2O)2](H2O)2
journal, December 2010
- Forbes, T. Z.; Horan, P.; Devine, T.
- American Mineralogist, Vol. 96, Issue 1
Observation of Studtite and Metastudtite on Spent Fuel
journal, January 2002
- McNamara, Bruce; Buck, Edgar; Hanson, Brady
- MRS Proceedings, Vol. 757
Nuclear Fuel in a Reactor Accident
journal, March 2012
- Burns, Peter C.; Ewing, Rodney C.; Navrotsky, Alexandra
- Science, Vol. 335, Issue 6073
Pseudomorphic decomposition of uranium peroxide into UO3
journal, May 1963
- Cordfunke, E. H. P.; Van Der Giessen, A. A.
- Journal of Inorganic and Nuclear Chemistry, Vol. 25, Issue 5
Structures of uranyl peroxide hydrates: a first-principles study of studtite and metastudtite
journal, January 2012
- Weck, Philippe F.; Kim, Eunja; Jové-Colón, Carlos F.
- Dalton Transactions, Vol. 41, Issue 32
Enthalpies of formation of U-, Th-, Ce-brannerite: implications for plutonium immobilization
journal, August 2003
- Helean, K. B.; Navrotsky, A.; Lumpkin, G. R.
- Journal of Nuclear Materials, Vol. 320, Issue 3
Uranyl peroxide enhanced nuclear fuel corrosion in seawater
journal, January 2012
- Armstrong, C. R.; Nyman, M.; Shvareva, T.
- Proceedings of the National Academy of Sciences, Vol. 109, Issue 6
Uranium trioxide and the UO3 hydrates
journal, November 1964
- Wheeler, V. J.; Dell, R. M.; Wait, E.
- Journal of Inorganic and Nuclear Chemistry, Vol. 26, Issue 11
Thermal decomposition of uranium peroxide hydrate
journal, January 1961
- Sato, Taichi
- Die Naturwissenschaften, Vol. 48, Issue 22
Progress and new directions in high temperature calorimetry
journal, January 1977
- Navrotsky, Alexandra
- Physics and Chemistry of Minerals, Vol. 2, Issue 1-2
Secondary Uranium Minerals on the Surface of Chernobyl “Lava”
journal, January 1996
- Burakov, B. E.; Strykanova, E. E.; Anderson, E. B.
- MRS Proceedings, Vol. 465
Thermal decomposition of hydrated uranium peroxides
journal, January 1963
- Cordfunke, E. H. P.; Aling, P.
- Recueil des Travaux Chimiques des Pays-Bas, Vol. 82, Issue 3
Corrosion of commercial spent nuclear fuel. 1. Formation of studtite and metastudtite
journal, January 2005
- Hanson, Brady D.; McNamara, Bruce; Buck, Edgar C.
- Radiochimica Acta, Vol. 93, Issue 3
Thermal decomposition of uranium peroxide hydrates
journal, April 1976
- Sato, Taichi
- Journal of Applied Chemistry and Biotechnology, Vol. 26, Issue 4
Alpha-radiolysis effects on UO2 alteration in water
journal, January 2001
- Sattonnay, G.; Ardois, C.; Corbel, C.
- Journal of Nuclear Materials, Vol. 288, Issue 1
Progress and new directions in high temperature calorimetry revisited
journal, April 1997
- Navrotsky, Alexandra
- Physics and Chemistry of Minerals, Vol. 24, Issue 3
Effect of temperature on studtite stability: Thermogravimetry and differential scanning calorimetry investigations
journal, March 2009
- Rey, A.; Casas, I.; Giménez, J.
- Journal of Nuclear Materials, Vol. 385, Issue 2
Stability of Peroxide-Containing Uranyl Minerals
journal, November 2003
- Kubatko, K. -A. H.
- Science, Vol. 302, Issue 5648
On the Reactivity of Uranouranic Oxide, (I) [八三酸化ウランの反応活性に関する研究, (I)]
journal, January 1959
- Ukazi, R.
- Journal of the Atomic Energy Society of Japan / Atomic Energy Society of Japan, Vol. 1, Issue 7
Contrary effects of the water radiolysis product H2O2 upon th dissolution of nuclear fuel in natural ground water and deionized water
journal, January 2002
- Amme, M.
- Radiochimica Acta, Vol. 90, Issue 7
Ab initio study of uranyl peroxides: Electronic factors behind the phase stability
journal, February 2007
- Ostanin, S.; Zeller, P.
- Physical Review B, Vol. 75, Issue 7
Studtite, [(UO 2 )(O 2 )(H 2 O) 2 ](H 2 O) 2 : The first structure of a peroxide mineral
journal, July 2003
- Burns, Peter C.; Hughes, Karrie-Ann
- American Mineralogist, Vol. 88, Issue 7
Works referencing / citing this record:
Uranyl–Peroxide Capsule Self‐Assembly in Slow Motion
journal, February 2019
- Arteaga, Ana; Zhang, Lei; Hickam, Sarah
- Chemistry – A European Journal, Vol. 25, Issue 24
Synthesis, structural analysis, and supramolecular assembly of a series of in situ generated uranyl–peroxide complexes with functionalized 2,2′-bipyridine and varied carboxylic acid ligands
journal, January 2018
- Ridenour, J. August; Cahill, Christopher L.
- New Journal of Chemistry, Vol. 42, Issue 3
Structure–thermodynamics relationship of schoepite from first-principles
journal, January 2019
- Weck, Philippe F.; Jové-Colón, Carlos F.; Kim, Eunja
- Physical Chemistry Chemical Physics, Vol. 21, Issue 46
Sample seal-and-drop device and methodology for high temperature oxide melt solution calorimetric measurements of PuO 2
journal, April 2019
- Guo, Xiaofeng; Boukhalfa, Hakim; Mitchell, Jeremy N.
- Review of Scientific Instruments, Vol. 90, Issue 4
Thermal desulfurization of pyrite: An in situ high-T neutron diffraction and DTA–TGA study
journal, June 2019
- Xu, Hongwu; Guo, Xiaofeng; Seaman, Lani A.
- Journal of Materials Research, Vol. 34, Issue 19
Energetics of hydration on uranium oxide and peroxide surfaces
journal, June 2019
- Guo, Xiaofeng; Wu, Di; Ushakov, Sergey V.
- Journal of Materials Research, Vol. 34, Issue 19