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Title: Progress and New Directions in Calorimetry: A 2014 Perspective

Authors:
 [1];
  1. Peter A. Rock Thermochemistry Laboratory and NEAT-ORU, University of California, Davis, Davis California 95616
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Materials Science of Actinides (MSA)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1385675
DOE Contract Number:  
SC0001089
Resource Type:
Journal Article
Journal Name:
Journal of the American Ceramic Society
Additional Journal Information:
Journal Volume: 97; Journal Issue: 11; Related Information: MSA partners with University of Notre Dame (lead); University of California, Davis; Florida State University; George Washington University; University of Michigan; University of Minnesota; Oak Ridge National Laboratory; Oregon state University; Rensselaer Polytechnic Institute; Savannah River National Laboratory; Journal ID: ISSN 0002-7820
Publisher:
American Ceramic Society
Country of Publication:
United States
Language:
English
Subject:
nuclear (including radiation effects), materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly)

Citation Formats

Navrotsky, Alexandra, and Green, D. J. Progress and New Directions in Calorimetry: A 2014 Perspective. United States: N. p., 2014. Web. doi:10.1111/jace.13278.
Navrotsky, Alexandra, & Green, D. J. Progress and New Directions in Calorimetry: A 2014 Perspective. United States. doi:10.1111/jace.13278.
Navrotsky, Alexandra, and Green, D. J. Thu . "Progress and New Directions in Calorimetry: A 2014 Perspective". United States. doi:10.1111/jace.13278.
@article{osti_1385675,
title = {Progress and New Directions in Calorimetry: A 2014 Perspective},
author = {Navrotsky, Alexandra and Green, D. J.},
abstractNote = {},
doi = {10.1111/jace.13278},
journal = {Journal of the American Ceramic Society},
issn = {0002-7820},
number = 11,
volume = 97,
place = {United States},
year = {2014},
month = {10}
}

Works referenced in this record:

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Synthesis, characterization, and thermochemistry of K-Na-H3O jarosites
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Effect of boron on the thermodynamic stability of amorphous polymer-derived Si(B)CN ceramics
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Silicon nitride: Enthalpy of formation of the α- and β-polymorphs and the effect of C and O impurities
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Thermochemistry of rare-earth orthophosphates
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Thermochemistry and melting properties of basalt
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Calorimetric study of high pressure polymorphism in FeTiO3: Stability of the perovskite phase
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Energetics of cubic Si 3 N 4
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Energetics of stable and metastable low-temperature iron oxides and oxyhydroxides
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High-temperature calorimetry of zirconia: Heat capacity and thermodynamics of the monoclinic–tetragonal phase transition
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Oxide-melt solution calorimetry of selenides: Enthalpy of formation of zinc, cadmium, and lead selenide
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Enthalpies of formation of Fe-Ni monosulfide solid solutions
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Energetics of oxidation of oxynitrides: Zr–N–O, Y–Zr–N–O, Ca–Zr–N–O, and Mg–Zr–N–O
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Energetics of Ternary Nitrides:  Li−Ca−Zn−N and Ca−Ta−N Systems
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Thermochemistry of onion-like carbons
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Thermochemistry of iron manganese oxide spinels
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Thermochemistry of stuffed quartz-derivative phases along the join LiAlSiO 4 -SiO 2
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Nanophase Transition Metal Oxides Show Large Thermodynamically Driven Shifts in Oxidation-Reduction Equilibria
journal, October 2010

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Thermochemistry, Morphology, and Optical Characterization of Germanium Allotropes
journal, May 2014

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Influence of antimony substitution on spontaneous strain and thermodynamic stability of lanthanum orthoniobate
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Calorimetric Study of Heats of Mixing in SnxTi1−xO2Rutile Solid Solutions: Calorimetric Study of SnxTi1−xO2 Rutile Solid Solutions
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Thermochemistry of two calcium silicate carbonate minerals: scawtite, Ca7(Si6O18)(CO3)·2H2O, and spurrite, Ca5(SiO4)2(CO3)
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Energetics of single-wall carbon nanotubes as revealed by calorimetry and neutron scattering
journal, March 2011


Thermodynamic Properties of Uranyl Minerals: Constraints from Calorimetry and Solubility Measurements
journal, June 2011

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Oxide melt solution calorimetry of Fe2+-bearing oxides and application to the magnetite-maghemite (Fe3O4-Fe8/3O4) system
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Experimental Confirmation of Low Surface Energy in LiCoO 2 and Implications for Lithium Battery Electrodes
journal, September 2013

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  • Angewandte Chemie International Edition, Vol. 52, Issue 46
  • DOI: 10.1002/anie.201305375

High temperature calorimetric studies of the heat of solution of La2O3 in silicate liquids
journal, March 2000


Energetics of Ternary Nitride Formation in the (Li,Ca)−(B,Al)−N System
journal, April 1999

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  • DOI: 10.1021/cm981096n

Size-Driven Structural and Thermodynamic Complexity in Iron Oxides
journal, March 2008


Carbon substitution for oxygen in silicates in planetary interiors
journal, September 2013

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Thermochemical studies of nitrides and oxynitrides by oxidative oxide melt calorimetry
journal, June 2001


Polymer-derived SiCN and SiOC ceramics – structure and energetics at the nanoscale
journal, January 2013

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  • DOI: 10.1039/c2ta00727d

Enthalpy of formation of cubic yttria-stabilized hafnia
journal, June 2004

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  • Journal of Materials Research, Vol. 19, Issue 6
  • DOI: 10.1557/JMR.2004.0234

Direct Measurement of Relative Partial Molar Enthalpy of SiO 2 in SiO 2 -M 2 O (M=Li, Na, K, Cs) Binary and SiO 2 -CaO-Al 2 O 3 Ternary Melts
journal, August 2004


Enthalpies of formation of U-, Th-, Ce-brannerite: implications for plutonium immobilization
journal, August 2003


Thermochemical Insights into Rapid Solid-State Reaction Synthesis of β-Sialon
journal, November 1997

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Surface Energies and Thermodynamic Phase Stability in Nanocrystalline Aluminas
journal, August 1997


Uranyl peroxide enhanced nuclear fuel corrosion in seawater
journal, January 2012

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The Energy Landscape of Uranyl-Peroxide Species
journal, March 2014

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  • Chemistry - A European Journal, Vol. 20, Issue 13
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Enthalpy of Formation of Rare-earth Silicates Y 2 SiO 5 and Yb 2 SiO 5 and N-containing Silicate Y 10 (SiO 4 ) 6 N 2
journal, April 1999

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  • Journal of Materials Research, Vol. 14, Issue 4
  • DOI: 10.1557/JMR.1999.0158

Thermochemistry of Phosphorus Oxynitrides:  PON and LiNaPON Glasses
journal, January 2000

  • Tessier, Franck; Navrotsky, Alexandra; Le Sauze, André
  • Chemistry of Materials, Vol. 12, Issue 1
  • DOI: 10.1021/cm990495v

Thermochemistry of nanodiamond terminated by oxygen containing functional groups
journal, December 2014


Enthalpies of formation of rare earth orthovanadates, REVO4
journal, March 2007


Calorimetric study of olivine solid solutions in the system Mg2SiO4-Fe2SiO4
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High-Temperature Heat Contents of the Metatitanates of Calcium, Iron and Magnesium 1
journal, June 1946

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Nanoscale Effects on Thermodynamics and Phase Equilibria in Oxide Systems
journal, July 2011


Thermochemistry of lanthanum zirconate pyrochlore
journal, November 2009

  • Radha, A. V.; Ushakov, Sergey V.; Navrotsky, Alexandra
  • Journal of Materials Research, Vol. 24, Issue 11
  • DOI: 10.1557/jmr.2009.0401

Energetics of anhydrite, barite, celestine, and anglesite: a high-temperature and differential scanning calorimetry study
journal, May 2002


Direct Measurement of Fusion Enthalpy of LaAlO 3 and Comparison of Energetics of Melt, Glass, and Amorphous Thin Films
journal, January 2014

  • Ushakov, Sergey V.; Navrotsky, Alexandra
  • Journal of the American Ceramic Society, Vol. 97, Issue 5
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Synthesis, characterization and thermochemistry of synthetic Pb–As, Pb–Cu and Pb–Zn jarosites
journal, February 2014

  • Forray, Ferenc Lázár; Smith, A. M. L.; Navrotsky, A.
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Thermochemistry of the Y 2 O 3 –BaO–Cu–O system
journal, November 1992

  • Zhou, Zhigang; Navrotsky, Alexandra
  • Journal of Materials Research, Vol. 7, Issue 11
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Energetic Effects of Substitution of La-Nd and Si-Ge Oxyapatite-Type Materials
journal, November 2013

  • Hosseini, Seyedeh Mahboobeh; Navrotsky, Alexandra
  • Journal of the American Ceramic Society, Vol. 96, Issue 12
  • DOI: 10.1111/jace.12705

Thermodynamic properties of magnesiochloritoid [Thermodynamic properties of magnesiochloritoid]
journal, July 2005


Enthalpy of formation of selected mixed oxides in a CaO–SrO–Bi2O3–Nb2O5 system
journal, April 2011


Energetics of CdSxSe1−x quantum dots in borosilicate glasses
journal, September 2007


Thermochemistry of a New Class of Materials Containing Dinitrogen Pairs in an Oxide Matrix
journal, June 2005

  • Tessier, Franck; Le Gendre, Laurent; Cheviré, François
  • Chemistry of Materials, Vol. 17, Issue 13
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Energetics of Spinels in the FeTiO System at the Nanoscale
journal, September 2014

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  • ChemPhysChem, Vol. 15, Issue 16
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Nuclear Fuel in a Reactor Accident
journal, March 2012

  • Burns, Peter C.; Ewing, Rodney C.; Navrotsky, Alexandra
  • Science, Vol. 335, Issue 6073
  • DOI: 10.1126/science.1211285

Thermodynamic Properties of Manganese Oxides
journal, July 1996


Synthesis, characterization, and enthalpy of mixing of the (Fe,Mg)C0 3 solid solution
journal, November 1996


Thermodynamically Stable Si w C x N y O z Polymer-Like, Amorphous Ceramics Made from Organic Precursors
journal, July 2008


Formation enthalpies and heat capacities of rear earth titanates: RE2TiO5 (RE=La, Nd and Gd)
journal, March 2012


Cadmium selenide: Surface and nanoparticle energetics
journal, March 2011

  • Xu, Fen; Zhou, Wei; Navrotsky, Alexandra
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Energetics of Dysprosia-Stabilized Bismuth Oxide Electrolytes
journal, October 2012

  • Tran, Tien B.; Navrotsky, Alexandra
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Energetics of magnesium, strontium, and barium doped lanthanum gallate perovskites
journal, January 2004


Energetics of binary iron nitrides
journal, June 2000


Co3O4–Co2ZnO4 spinels: The case for a solid solution
journal, June 2012


A correlation between the ionic conductivities and the formation enthalpies of trivalent-doped ceria at relatively low temperatures
journal, January 2009

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Surface Enthalpy, Enthalpy of Water Adsorption, and Phase Stability in Nanocrystalline Monoclinic Zirconia
journal, January 2009


High temperature calorimetric studies of heat of solution of NiO, CuO, La2O3, TiO2, HfO2 in sodium silicate liquids
journal, January 2008

  • Linard, Yannick; Wilding, Martin C.; Navrotsky, Alexandra
  • Geochimica et Cosmochimica Acta, Vol. 72, Issue 2
  • DOI: 10.1016/j.gca.2007.10.004

Thermodynamics of NiAl2O4-NiFe2O4 Spinel Solid Solutions
journal, November 2011


Effect of demixing and coarsening on the energetics of poly(boro)silazane-derived amorphous Si–(B–)C–N ceramics
journal, September 2013


Progress and new directions in high temperature calorimetry revisited
journal, April 1997


Thermodynamic properties of quartz, cristobalite and amorphous SiO2: drop calorimetry measurements between 1000 and 1800 K and a review from 0 to 2000 K
journal, December 1982


Thermodynamic Control of Phase Composition and Crystallization of Metal-Modified Silicon Oxycarbides
journal, April 2013

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Thermochemistry of rare-earth aluminate and aluminosilicate glasses
journal, August 2004


Thermochemistry of natural potassium sodium calcium leonhardite and its cation-exchanged forms
journal, June 1996

  • Kiseleva, Irina; Navrotsky, Alexandra; Belitsky, Igor A.
  • American Mineralogist, Vol. 81, Issue 5-6
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Olivine-modified spinel-spinel transitions in the system Mg 2 SiO 4 -Fe 2 SiO 4 : Calorimetric measurements, thermochemical calculation, and geophysical application
journal, November 1989

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  • Journal of Geophysical Research: Solid Earth, Vol. 94, Issue B11
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Formation enthalpy of ThSiO4 and enthalpy of the thorite → huttonite phase transition
journal, October 2005

  • Mazeina, Lena; Ushakov, Sergey V.; Navrotsky, Alexandra
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  • DOI: 10.1016/j.gca.2005.03.053

Effect of Precursor on Speciation and Nanostructure of SiBCN Polymer-Derived Ceramics
journal, January 2013

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  • Journal of the American Ceramic Society, Vol. 96, Issue 5
  • DOI: 10.1111/jace.12192

Thermodynamics of Formation of Binary and Ternary Nitrides in the System Ce/Mn/N
journal, February 2001


High-temperature oxide melt calorimetry of oxides and nitrides
journal, August 2001


DTA method applikation to the highest refractory oxide systems investigation
journal, September 1985


Experimental Approaches to the Thermodynamics of Ceramics Above 1500°C
journal, March 2012


Calorimetric determination of the enthalpy of formation of InN and comparison with AlN and GaN
journal, October 2001

  • Ranade, M. R.; Tessier, F.; Navrotsky, A.
  • Journal of Materials Research, Vol. 16, Issue 10
  • DOI: 10.1557/JMR.2001.0389

Thermodynamics of CoO–MgO solid solutions
journal, July 2003


Energetics of Nitridophosphates PON and “LiNaPON Glasses”
journal, January 1998


Energetics of nanocrystalline TiO2
journal, March 2002

  • Ranade, M. R.; Navrotsky, A.; Zhang, H. Z.
  • Proceedings of the National Academy of Sciences, Vol. 99, Issue Supplement 2
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Energetic basis of catalytic activity of layered nanophase calcium manganese oxides for water oxidation
journal, May 2013

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Enthalpy of Formation of Gallium Nitride
journal, May 2000

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  • The Journal of Physical Chemistry B, Vol. 104, Issue 17
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Calorimetric studies of the energetics of order-disorder in the system Mg (sub 1-x) Fe x Ca(CO 3 ) 2
journal, October 1999

  • Navrotsky, Alexandra; Dooley, Debra; Reeder, Richard
  • American Mineralogist, Vol. 84, Issue 10
  • DOI: 10.2138/am-1999-1016

Thermodynamically Stable Si x O y C z Polymer-Like Amorphous Ceramics
journal, October 2007


Direct measurements of fusion and phase transition enthalpies in lanthanum oxide
journal, February 2011

  • Ushakov, Sergey V.; Navrotsky, Alexandra
  • Journal of Materials Research, Vol. 26, Issue 7
  • DOI: 10.1557/jmr.2010.79

Spinel disproportionation at high pressure: calorimetric determination of enthalpy of formation of Mg2SnO4 and Co2SnO4 and some implications for silicates
journal, July 1976


Thermochemistry of Framework and Layer Manganese Dioxide Related Phases
journal, February 1998

  • Fritsch, Sophie; Post, Jeffrey E.; Suib, Steven L.
  • Chemistry of Materials, Vol. 10, Issue 2
  • DOI: 10.1021/cm970104h

Energetics of oxidation of RE–Si–Al–O–N glasses
journal, July 2003

  • Zhang, Yahong; Navrotsky, Alexandra; Matusch, Dirk
  • Journal of Materials Research, Vol. 18, Issue 7
  • DOI: 10.1557/JMR.2003.0221

The Energetics of La2-xAxNiO4-y (A = Ba, Sr)
journal, March 1993

  • DiCarlo, Joseph; Mehta, Apurva; Banschick, David
  • Journal of Solid State Chemistry, Vol. 103, Issue 1
  • DOI: 10.1006/jssc.1993.1091

An aerodynamic levitation system for drop tube and quenching experiments
journal, February 2003

  • Arai, Yasutomo; Paradis, Paul-François; Aoyama, Tomotsugu
  • Review of Scientific Instruments, Vol. 74, Issue 2
  • DOI: 10.1063/1.1531826

Heats of Formation for Several Crystalline Polymorphs and Pressure-Induced Amorphous Forms of AMo 2 O 8 (A = Zr, Hf) and ZrW 2 O 8
journal, February 2007

  • Varga, Tamas; Lind, Cora; Wilkinson, Angus P.
  • Chemistry of Materials, Vol. 19, Issue 3
  • DOI: 10.1021/cm0617743

Progress and new directions in high temperature calorimetry
journal, January 1977

  • Navrotsky, Alexandra
  • Physics and Chemistry of Minerals, Vol. 2, Issue 1-2
  • DOI: 10.1007/BF00307526

Enthalpies of formation of LaBO 3 perovskites (B = Al, Ga, Sc, and In)
journal, October 2003

  • Cheng, Jihong; Navrotsky, Alexandra
  • Journal of Materials Research, Vol. 18, Issue 10
  • DOI: 10.1557/JMR.2003.0348

Formation enthalpies of rare earth titanate pyrochlores
journal, June 2004


Calorimetric study of the stability of high pressure phases in the systems CoOSiO2 and “FeO”SiO2, and calculation of phase diagrams in MOSiO2 systems
journal, August 1979

  • Navrotsky, Alexandra; Pintchovski, Faivel S.; Akimoto, Syun-Iti
  • Physics of the Earth and Planetary Interiors, Vol. 19, Issue 4
  • DOI: 10.1016/0031-9201(79)90001-3

Enthalpies of formation of CdS x Se 1– x solid solutions
journal, April 2009

  • Xu, Fen; Ma, Xuchu; Kauzlarich, Susan M.
  • Journal of Materials Research, Vol. 24, Issue 4
  • DOI: 10.1557/jmr.2009.0164

Enthalpy of Formation of Carbon-Rich Polymer-Derived Amorphous SiCN Ceramics
journal, October 2008


Thermochemical Studies of Ln Ba 2 Cu 3 O 7-δ ( Ln = Pr, Nd, Eu, Gd, Dy, Ho, Tm), Ln Ba 2 Cu 4 O 8 ( Ln = Sm, Eu, Gd, Dy, Ho), and Y 1- x Pr x Ba 2 Cu 3 O 7-δ
journal, April 1997

  • Lamberti, V. E.; Rodriguez, M. A.; Trybulski, J. D.
  • Chemistry of Materials, Vol. 9, Issue 4
  • DOI: 10.1021/cm9604928

Nanostructure and Energetics of Carbon-Rich SiCN Ceramics Derived from Polysilylcarbodiimides: Role of the Nanodomain Interfaces
journal, March 2012

  • Widgeon, S.; Mera, G.; Gao, Y.
  • Chemistry of Materials, Vol. 24, Issue 6
  • DOI: 10.1021/cm2038238

Thermochemistry of Lanthana- and Yttria-Doped Thoria: Thermochemistry of Lanthana- and Yttria-Doped Thoria
journal, September 2010

  • Aizenshtein, Michael; Shvareva, Tatiana Y.; Navrotsky, Alexandra
  • Journal of the American Ceramic Society, Vol. 93, Issue 12
  • DOI: 10.1111/j.1551-2916.2010.04001.x

Thermochemistry of the alkali rare-earth double phosphates, A 3 RE(PO 4 ) 2
journal, July 2004

  • Ushakov, Sergey V.; Navrotsky, Alexandra; Farmer, J. Matt
  • Journal of Materials Research, Vol. 19, Issue 7
  • DOI: 10.1557/JMR.2004.0283

Enthalpies of Formation of LaMO 3 Perovskites (M = Cr, Fe, Co, and Ni)
journal, January 2005

  • Cheng, Jihong; Navrotsky, Alexandra; Zhou, Xiao-Dong
  • Journal of Materials Research, Vol. 20, Issue 1
  • DOI: 10.1557/JMR.2005.0018

Crystal Chemistry and Stabilization in Air of Brannerite, UTi 2 O 6
journal, January 2001