skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Nickel complexes of a binucleating ligand derived from an SCS pincer


A new heterobimetallic complex contains Ni IIin an SCS pincer and lithium in an ether loop, bridged by bromide.

 [1];  [1];  [1]
  1. Pacific Northwest National Laboratory; Richland; USA
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for Molecular Electrocatalysis (CME)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
DOE Contract Number:  
Resource Type:
Journal Article
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Volume: 44; Journal Issue: 2; Related Information: CME partners with Pacific Northwest National Laboratory (lead); University of Illinois, Urbana-Champaign; Pennsylvania State University; University of Washington; University of Wyoming; Journal ID: ISSN 1477-9226
Royal Society of Chemistry
Country of Publication:
United States
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; catalysis (homogeneous), catalysis (heterogeneous), solar (fuels), bio-inspired, energy storage (including batteries and capacitors), hydrogen and fuel cells, charge transport, materials and chemistry by design, synthesis (novel materials)

Citation Formats

Peterson, Sonja M., Helm, Monte L., and Appel, Aaron M. Nickel complexes of a binucleating ligand derived from an SCS pincer. United States: N. p., 2015. Web. doi:10.1039/C4DT02718C.
Peterson, Sonja M., Helm, Monte L., & Appel, Aaron M. Nickel complexes of a binucleating ligand derived from an SCS pincer. United States. doi:10.1039/C4DT02718C.
Peterson, Sonja M., Helm, Monte L., and Appel, Aaron M. Thu . "Nickel complexes of a binucleating ligand derived from an SCS pincer". United States. doi:10.1039/C4DT02718C.
title = {Nickel complexes of a binucleating ligand derived from an SCS pincer},
author = {Peterson, Sonja M. and Helm, Monte L. and Appel, Aaron M.},
abstractNote = {A new heterobimetallic complex contains NiIIin an SCS pincer and lithium in an ether loop, bridged by bromide.},
doi = {10.1039/C4DT02718C},
journal = {Dalton Transactions},
issn = {1477-9226},
number = 2,
volume = 44,
place = {United States},
year = {2015},
month = {1}

Works referenced in this record:

Trialkylborane-Assisted CO 2 Reduction by Late Transition Metal Hydrides
journal, August 2011

  • Miller, Alexander J. M.; Labinger, Jay A.; Bercaw, John E.
  • Organometallics, Vol. 30, Issue 16
  • DOI: 10.1021/om200364w

Catalytic Reduction of CO 2 to CO by Using Zinc(II) and In Situ Generated Carbodiphosphoranes
journal, January 2013

  • Dobrovetsky, Roman; Stephan, Douglas W.
  • Angewandte Chemie International Edition, Vol. 52, Issue 9
  • DOI: 10.1002/anie.201208817

Molecular Catalysis of Electrochemical Reactions. Mechanistic Aspects
journal, July 2008

  • Savéant, Jean-Michel
  • Chemical Reviews, Vol. 108, Issue 7, p. 2348-2378
  • DOI: 10.1021/cr068079z

Mild Reduction of Carbon Dioxide to Methane with Tertiary Silanes Catalyzed by Platinum and Palladium Silyl Pincer Complexes
journal, November 2012

  • Mitton, Samuel J.; Turculet, Laura
  • Chemistry - A European Journal, Vol. 18, Issue 48
  • DOI: 10.1002/chem.201203226

A short history of SHELX
journal, December 2007

  • Sheldrick, George M.
  • Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122
  • DOI: 10.1107/S0108767307043930

Selective Nitrite Reduction at Heterobimetallic CoMg Complexes
journal, July 2013

  • Uyeda, Christopher; Peters, Jonas C.
  • Journal of the American Chemical Society, Vol. 135, Issue 32
  • DOI: 10.1021/ja4053653

Molecular approaches to the electrochemical reduction of carbon dioxide
journal, January 2012

  • Finn, Colin; Schnittger, Sorcha; Yellowlees, Lesley J.
  • Chem. Commun., Vol. 48, Issue 10
  • DOI: 10.1039/C1CC15393E

Synthesis of Binucleating Macrocycles and Their Nickel(II) Hydroxo- and Cyano-Bridged Complexes with Divalent Ions: Anatomical Variation of Ligand Features
journal, October 2012

  • Zhang, Xiaofeng; Huang, Deguang; Chen, Yu-Sheng
  • Inorganic Chemistry, Vol. 51, Issue 20
  • DOI: 10.1021/ic301506x

Bifunctional activation of carbon dioxide. Synthesis and structure of a reversible carbon dioxide carrier
journal, November 1978

  • Fachinetti, Giuseppe; Floriani, Carlo; Zanazzi, Pier Francesco
  • Journal of the American Chemical Society, Vol. 100, Issue 23
  • DOI: 10.1021/ja00491a045

Carbon dioxide fixation: bifunctional complexes containing acidic and basic sites working as reversible carriers
journal, September 1982

  • Gambarotta, Sandro; Arena, Francesco; Floriani, Carlo
  • Journal of the American Chemical Society, Vol. 104, Issue 19
  • DOI: 10.1021/ja00383a015

Nickel and palladium phosphinimine-imine ligand complexes
journal, January 2003

  • Masuda, Jason D.; Wei, Pingrong; Stephan, Douglas W.
  • Dalton Transactions, Issue 18
  • DOI: 10.1039/b306110h

Mechanisms for CO Production from CO 2 Using Reduced Rhenium Tricarbonyl Catalysts
journal, March 2012

  • Agarwal, Jay; Fujita, Etsuko; Schaefer, Henry F.
  • Journal of the American Chemical Society, Vol. 134, Issue 11
  • DOI: 10.1021/ja2105834

Chemical catalysis of electrochemical reactions. Homogeneous catalysis of the electrochemical reduction of carbon dioxide by iron("0") porphyrins. Role of the addition of magnesium cations
journal, October 1991

  • Hammouche, Mohamed; Lexa, Doris; Momenteau, Michel
  • Journal of the American Chemical Society, Vol. 113, Issue 22
  • DOI: 10.1021/ja00022a038

The Electronic States of Rhenium Bipyridyl Electrocatalysts for CO 2 Reduction as Revealed by X-ray Absorption Spectroscopy and Computational Quantum Chemistry
journal, March 2013

  • Benson, Eric E.; Sampson, Matthew D.; Grice, Kyle A.
  • Angewandte Chemie International Edition, Vol. 52, Issue 18
  • DOI: 10.1002/anie.201209911

Preparation and Reactivities of PCP-Type Pincer Complexes of Nickel. Impact of Different Ligand Skeletons and Phosphine Substituents
journal, November 2008

  • Castonguay, Annie; Beauchamp, André L.; Zargarian, Davit
  • Organometallics, Vol. 27, Issue 21
  • DOI: 10.1021/om8005454

Activation of CO 2 by a Heterobimetallic Zr/Co Complex
journal, September 2011

  • Krogman, Jeremy P.; Foxman, Bruce M.; Thomas, Christine M.
  • Journal of the American Chemical Society, Vol. 133, Issue 37
  • DOI: 10.1021/ja2071847

Coordination of 1,10-Phenanthroline and 2,2′-Bipyridine to Li + in Different Ionic Liquids. How Innocent Are Ionic Liquids?
journal, July 2011

  • Schmeisser, Matthias; Heinemann, Frank W.; Illner, Peter
  • Inorganic Chemistry, Vol. 50, Issue 14
  • DOI: 10.1021/ic200594e

Carbon Dioxide Activation at the Ni,Fe-Cluster of Anaerobic Carbon Monoxide Dehydrogenase
journal, November 2007

A Local Proton Source Enhances CO 2 Electroreduction to CO by a Molecular Fe Catalyst
journal, October 2012

Neue Komplexligand-Systeme für Alkalimetall-Ionen
journal, February 1974

Regioselective Hydroamination of Acrylonitrile Catalyzed by Cationic Pincer Complexes of Nickel(II)
journal, April 2009

  • Castonguay, Annie; Spasyuk, Denis M.; Madern, Nathalie
  • Organometallics, Vol. 28, Issue 7
  • DOI: 10.1021/om800840u

X-Ray and NMR Study of the Structural Features of SCS-Pincer Metal Complexes of the Group 10 Triad
journal, October 2008

  • Kruithof, Cornelis A.; Dijkstra, Harmen P.; Lutz, Martin
  • Organometallics, Vol. 27, Issue 19
  • DOI: 10.1021/om800324w

Molecular recognition of nucleobases via simultaneous first- and second-sphere coordination
journal, July 1993

  • Kickham, James E.; Loeb, Stephen J.; Murphy, Shannon L.
  • Journal of the American Chemical Society, Vol. 115, Issue 15
  • DOI: 10.1021/ja00068a094

Structural Diversity in Lewis-Base Complexes of Lithium Triflamide
journal, September 2003

  • Davidson, Matthew G.; Raithby, Paul R.; Johnson, Andrew L.
  • European Journal of Inorganic Chemistry, Vol. 2003, Issue 18
  • DOI: 10.1002/ejic.200300372

Simultaneous First- and Second-Sphere Coordination. Organopalladium Crown Ether Complexes as Metalloreceptors for o-Aminopyridine Derivatives
journal, September 1994

  • Kickham, James E.; Loeb, Stephen J.
  • Inorganic Chemistry, Vol. 33, Issue 19
  • DOI: 10.1021/ic00097a024

Access to formally Ni( i ) states in a heterobimetallic NiZn system
journal, January 2013

  • Uyeda, Christopher; Peters, Jonas C.
  • Chem. Sci., Vol. 4, Issue 1
  • DOI: 10.1039/C2SC21231E

Receptors for the hydrazinium ion. Simultaneous first- and second-sphere coordination inside organopalladium crown ether complexes
journal, January 1993

  • Kickham, James E.; Loeb, Stephen J.
  • Journal of the Chemical Society, Chemical Communications, Issue 24
  • DOI: 10.1039/c39930001848

Development of Molecular Electrocatalysts for CO2 Reduction and H2 Production/Oxidation
journal, December 2009

  • Rakowski Dubois, M.; Dubois, Daniel L.
  • Accounts of Chemical Research, Vol. 42, Issue 12, p. 1974-1982
  • DOI: 10.1021/ar900110c

Electrocatalytic and homogeneous approaches to conversion of CO 2 to liquid fuels
journal, January 2009

  • Benson, Eric E.; Kubiak, Clifford P.; Sathrum, Aaron J.
  • Chem. Soc. Rev., Vol. 38, Issue 1
  • DOI: 10.1039/B804323J

Metal centers in the anaerobic microbial metabolism of CO and CO2
journal, January 2011

  • Bender, Güneş; Pierce, Elizabeth; Hill, Jeffrey A.
  • Metallomics, Vol. 3, Issue 8
  • DOI: 10.1039/c1mt00042j

Structural and spectroscopic studies of reduced [Re(bpy-R)(CO)3]−1 species relevant to CO2 reduction
journal, July 2013

Poly[bis(acetonitrile-κ N )bis[μ 3 -bis(trifluoromethanesulfonyl)imido-κ 4 O , O ′: O ′′: O ′′′]dilithium]
journal, April 2011

  • Seo, Daniel M.; Boyle, Paul D.; Henderson, Wesley A.
  • Acta Crystallographica Section E Structure Reports Online, Vol. 67, Issue 5
  • DOI: 10.1107/S1600536811011561

The First Heterobimetallic Metallasilsesquioxane Derivatives of Manganese
journal, December 2008

  • Lorenz, Volker; Blaurock, Steffen; Edelmann, Frank T.
  • Zeitschrift für anorganische und allgemeine Chemie, Vol. 634, Issue 15
  • DOI: 10.1002/zaac.200800292

Organometallic Ni Pincer Complexes for the Electrocatalytic Production of Hydrogen
journal, July 2012

  • Luca, Oana R.; Blakemore, James D.; Konezny, Steven J.
  • Inorganic Chemistry, Vol. 51, Issue 16
  • DOI: 10.1021/ic300009a

Frustrated Lewis Pair Inspired Carbon Dioxide Reduction by a Ruthenium Tris(aminophosphine) Complex
journal, October 2012

  • Sgro, Michael J.; Stephan, Douglas W.
  • Angewandte Chemie International Edition, Vol. 51, Issue 45
  • DOI: 10.1002/anie.201205741

Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO 2 Fixation
journal, June 2013

  • Appel, Aaron M.; Bercaw, John E.; Bocarsly, Andrew B.
  • Chemical Reviews, Vol. 113, Issue 8
  • DOI: 10.1021/cr300463y