skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Applications of metal oxide materials in dye sensitized photoelectrosynthesis cells for making solar fuels: let the molecules do the work

Journal Article · · Journal of Materials Chemistry. A
DOI:https://doi.org/10.1039/C2TA00935H· OSTI ID:1385209

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Center for Solar Fuels (UNC EFRC)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
SC0001011
OSTI ID:
1385209
Journal Information:
Journal of Materials Chemistry. A, Vol. 1, Issue 13; Related Information: UNC partners with University of North Carolina (lead); Duke University; University of Florida; Georgia Institute of Technology; University; North Carolina Central University; Research Triangle Institute; ISSN 2050-7488
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

References (136)

Highly active oxide photocathode for photoelectrochemical water reduction journal May 2011
Atomic Layer Deposition of Ta-doped TiO2 Electrodes for Dye-Sensitized Solar Cells journal January 2011
Synthesis, photophysical and photovoltaic investigations of acceptor-functionalized perylene monoimide dyes for nickel oxide p-type dye-sensitized solar cells journal January 2011
Sensitization of charge injection into semiconductors with large band gap journal June 1968
Electrochemical Photolysis of Water at a Semiconductor Electrode journal July 1972
Acid−Base Equilibria of (2,2‘-Bipyridyl-4,4‘-dicarboxylic acid)ruthenium(II) Complexes and the Effect of Protonation on Charge-Transfer Sensitization of Nanocrystalline Titania journal December 1999
ZnO-Based Dye-Sensitized Solar Cells journal April 2012
Large photocurrent generation in dye-sensitized ZnO solar cells journal January 2008
Dye-Sensitized Solar Cells Based on WO 3 journal December 2010
Selective CO2 conversion to formate in water using a CZTS photocathode modified with a ruthenium complex polymer journal January 2011
Visible Region Photooxidation on TiO 2 with a Chromophore−Catalyst Molecular Assembly journal October 1999
Theoretical Models for the Action Spectrum and the Current-Voltage Characteristics of Microporous Semiconductor Films in Photoelectrochemical Cells journal May 1994
Solution-derived ZnOnanostructures for photoanodes of dye-sensitized solar cells journal January 2011
Charge Transport versus Recombination in Dye-Sensitized Solar Cells Employing Nanocrystalline TiO 2 and SnO 2 Films journal June 2005
New Architectures for Dye-Sensitized Solar Cells journal May 2008
Sensitized layered metal oxide semiconductor particles for photochemical hydrogen evolution from nonsacrificial electron donors journal November 1993
Nanocrystalline Mesoporous Strontium Titanate as Photoelectrode Material for Photosensitized Solar Devices:  Increasing Photovoltage through Flatband Potential Engineering journal October 1999
Arylamine-Based Dyes for p-Type Dye-Sensitized Solar Cells journal August 2011
Tunability of the Band Energetics of Nanostructured SrTiO 3 Electrodes for Dye-Sensitized Solar Cells journal February 2010
Dye-Sensitized Solar Cells journal November 2010
Porphyrin-Sensitized Solar Cells with Cobalt (II/III)-Based Redox Electrolyte Exceed 12 Percent Efficiency journal November 2011
Ru-doped TiO2 nanotubes: Improved performance in dye-sensitized solar cells journal March 2012
Photoelectrochemical Properties of a Porous Nb 2 O 5 Electrode Sensitized by a Ruthenium Dye journal December 1998
Preparation and Photoelectrochemical Characterization of Thin SnO2 Nanocrystalline Semiconductor Films and Their Sensitization with Bis(2,2'-bipyridine)(2,2'-bipyridine-4,4'-dicarboxylic acid)ruthenium(II) Complex journal April 1994
Limiting efficiencies of ideal single and multiple energy gap terrestrial solar cells journal August 1980
Atomic layer deposition for electrochemical energy generation and storage systems
  • Peng, Qing; Lewis, Jay S.; Hoertz, Paul G.
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 30, Issue 1 https://doi.org/10.1116/1.3672027
journal January 2012
Vectorial electron injection into transparent semiconductor membranes and electric field effects on the dynamics of light-induced charge separation journal November 1990
Synthesis and Mechanistic Studies of Organic Chromophores with Different Energy Levels for p-Type Dye-Sensitized Solar Cells journal March 2010
Oxide semiconductors in photoelectrochemical conversion of solar energy journal January 1980
Correlation of photocurrent-voltage curves with flat-band potential for stable photoelectrodes for the photoelectrolysis of water journal November 1976
Dye-sensitized solar cells journal October 2003
Linker effect in organic donor–acceptor dyes for p-type NiO dye sensitized solar cells journal January 2011
High-efficiency integrated multijunction photovoltaic/electrolysis systems for hydrogen production journal February 2001
ZnO−TiO 2 Core−Shell Nanorod/P3HT Solar Cells journal November 2007
Double-Layered NiO Photocathodes for p-Type DSSCs with Record IPCE journal April 2010
Electron Transfer Dynamics in Dye-Sensitized Solar Cells journal August 2011
SnO 2 -Based Dye-Sensitized Hybrid Solar Cells Exhibiting Near Unity Absorbed Photon-to-Electron Conversion Efficiency journal April 2010
Random walk models of charge transfer and transport in dye sensitized systems journal July 2004
Nanoforest Nb 2 O 5 Photoanodes for Dye-Sensitized Solar Cells by Pulsed Laser Deposition journal September 2011
Beyond Photovoltaics: Semiconductor Nanoarchitectures for Liquid-Junction Solar Cells journal November 2010
Search for improved transparent conducting oxides: A fundamental investigation of CdO, Cd2SnO4, and Zn2SnO4 journal November 2000
Preparation and Band Energetics of Transparent Nanostructured SrTiO 3 Film Electrodes journal December 2009
Wireless Solar Water Splitting Using Silicon-Based Semiconductors and Earth-Abundant Catalysts journal September 2011
Semiconductor-based Photocatalytic Hydrogen Generation journal November 2010
Nb2O5 as efficient and recyclable photocatalyst for indigo carmine degradation journal August 2008
Electron Injection Dynamics from Ru Polypyridyl Complexes to ZnO Nanocrystalline Thin Films journal December 2003
The Isoelectric Points of Solid Oxides, Solid Hydroxides, and Aqueous Hydroxo Complex Systems journal April 1965
Charge-Transfer Processes in Dye-Sensitized NiO Solar Cells journal September 2008
Metal Oxides for Dye-Sensitized Solar Cells journal February 2009
Limiting efficiencies for photovoltaic energy conversion in multigap systems journal September 1996
Dye-Sensitized Core−Shell Nanocrystals:  Improved Efficiency of Mesoporous Tin Oxide Electrodes Coated with a Thin Layer of an Insulating Oxide journal July 2002
Electronic states at oxygen deficient WO3(001) surfaces: a study by resonant photoemission journal March 1998
Conversion of light to electricity by cis-X2bis(2,2'-bipyridyl-4,4'-dicarboxylate)ruthenium(II) charge-transfer sensitizers (X = Cl-, Br-, I-, CN-, and SCN-) on nanocrystalline titanium dioxide electrodes journal July 1993
Dye Sensitized Solar Cells journal March 2010
Semiconducting oxide anodes in photoassisted electrolysis of water journal June 1977
Semiconductor Nanowires for Energy Conversion journal January 2010
Photocatalytic water splitting on nickel intercalated A4TaxNb6-xO17 (A = K, Rb) journal April 1996
Spectroelectrochemistry of Nanostructured NiO journal April 2001
Photoinduced Ultrafast Dye-to-Semiconductor Electron Injection from Nonthermalized and Thermalized Donor States journal January 2002
Chemical approaches to artificial photosynthesis journal May 1989
Electrical and Structural Characterization of a Low-Angle Tilt Grain Boundary in Iron-Doped Strontium Titanate journal June 2003
Photocatalytic decomposition of water at semiconductor electrodes journal January 1978
A p-Type NiO-Based Dye-Sensitized Solar Cell with an Open-Circuit Voltage of 0.35 V journal June 2009
ZnO−Al 2 O 3 and ZnO−TiO 2 Core−Shell Nanowire Dye-Sensitized Solar Cells journal November 2006
Vertically-aligned nanostructures of ZnO for excitonic solar cells: a review journal January 2009
Syntheses of NiO nanoporous films using nonionic triblock co-polymer templates and their application to photo-cathodes of p-type dye-sensitized solar cells journal September 2008
New Photovoltaic Devices Based on the Sensitization of p-type Semiconductors: Challenges and Opportunities journal August 2010
Opto-electronic properties of CuAlO2 journal January 1984
Design of an Organic Chromophore for P-Type Dye-Sensitized Solar Cells journal July 2008
Comparison of Electrode Structures and Photovoltaic Properties of Porphyrin-Sensitized Solar Cells with TiO 2 and Nb, Ge, Zr-Added TiO 2 Composite Electrodes journal December 2006
Heterogeneous photocatalyst materials for water splitting journal January 2009
Interfacial Electron Transfer Dynamics for [Ru(bpy) 2 ((4,4′-PO 3 H 2 ) 2 bpy)] 2+ Sensitized TiO 2 in a Dye-Sensitized Photoelectrosynthesis Cell: Factors Influencing Efficiency and Dynamics journal March 2011
Sensitized Hole Injection of Phosphorus Porphyrin into NiO:  Toward New Photovoltaic Devices journal December 2005
Nature of Photovoltaic Action in Dye-Sensitized Solar Cells journal March 2000
Photovoltaic performance improvement of dye-sensitized solar cells based on tantalum-doped TiO2 thin films journal December 2010
p-type oxide semiconductors as hole collectors in dye-sensitized solid-state solar cells journal November 2006
Dye-sensitized nanostructured tandem cell-first demonstrated cell with a dye-sensitized photocathode journal May 2000
Electrocatalytic process of CO selectivity in electrochemical reduction of CO2 at metal electrodes in aqueous media journal August 1994
Fabrication and Dye-Sensitized Solar Cell Performance of Nanostructured NiO/Coumarin 343 Photocathodes journal January 2008
Engineering of Efficient Panchromatic Sensitizers for Nanocrystalline TiO 2 -Based Solar Cells journal February 2001
Comparison of Electron-Transfer Dynamics from Coumarin 343 to TiO 2 , SnO 2 , and ZnO Nanocrystalline Thin Films: Role of Interface-Bound Charge-Separated Pairs journal March 2010
Series-connected tandem dye-sensitized solar cell for improving efficiency to more than 10% journal June 2009
Hierarchically Assembled ZnO Nanocrystallites for High-Efficiency Dye-Sensitized Solar Cells journal September 2011
High-Temperature Anodized WO 3 Nanoplatelet Films for Photosensitive Devices journal July 2009
Dye Sensitization of Nanocrystalline Tin Oxide by Perylene Derivatives journal June 1997
Ta 2 O 5 Nanowires: a novel synthetic method and their solar energy utilization journal January 2012
Tantalum-Doped Titanium Dioxide Nanowire Arrays for Dye-Sensitized Solar Cells with High Open-Circuit Voltage journal October 2009
Sn-Doped TiO 2 Photoanode for Dye-Sensitized Solar Cells journal April 2012
Solar Water Splitting Cells journal November 2010
Solid-state dye-sensitized solar cell with p-type NiO as a hole collector journal January 2005
Dye-Sensitized Nanostructured p-Type Nickel Oxide Film as a Photocathode for a Solar Cell journal October 1999
Photoinduced Ultrafast Dynamics of Coumarin 343 Sensitized p-Type-Nanostructured NiO Films journal October 2005
Making solar fuels by artificial photosynthesis journal March 2011
Enhanced electron diffusion length of mesoporous TiO2 film by using Nb2O5 energy barrier for dye-sensitized solar cells journal July 2006
Solar Fuels journal November 1978
Dye-sensitized solar cells using ZnO tetrapods journal April 2008
Advancing beyond current generation dye-sensitized solar cells journal January 2008
Highly efficient photocathodes for dye-sensitized tandem solar cells journal November 2009
Electronic structures and doping of SnO2, CuAlO2, and CuInO2 journal December 2007
Noble-Metal/Cr2O3 Core/Shell Nanoparticles as a Cocatalyst for Photocatalytic Overall Water Splitting journal November 2006
Electrochemical photovoltaic cells-review of recent developments journal November 2010
Recent advances and future directions to optimize the performances of p-type dye-sensitized solar cells journal November 2012
Dye-Sensitized Photocathodes: Efficient Light-Stimulated Hole Injection into p-GaP Under Depletion Conditions journal June 2012
A stable quasi-solid-state dye-sensitized solar cell with an amphiphilic ruthenium sensitizer and polymer gel electrolyte journal May 2003
TiO 2 -Coated Multilayered SnO 2 Hollow Microspheres for Dye-Sensitized Solar Cells journal September 2009
Ambipolar Diffusion of Photocarriers in Electrolyte-Filled, Nanoporous TiO 2 journal April 2000
Improved Photon-to-Current Conversion Efficiency with a Nanoporous p-Type NiO Electrode by the Use of a Sensitizer-Acceptor Dyad journal February 2008
Photoelectrochemical characteristics of cells with dyed and undyed nanoporous p-type semiconductor CuO electrodes journal February 2008
A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films journal October 1991
Whither solar fuels? journal August 2012
Photoassisted Overall Water Splitting in a Visible Light-Absorbing Dye-Sensitized Photoelectrochemical Cell
  • Youngblood, W. Justin; Lee, Seung-Hyun Anna; Kobayashi, Yoji
  • Journal of the American Chemical Society, Vol. 131, Issue 3, p. 926-927 https://doi.org/10.1021/ja809108y
journal January 2009
p-Type Dye-Sensitized Solar Cells Based on Delafossite CuGaO 2 Nanoplates with Saturation Photovoltages Exceeding 460 mV journal April 2012
Physical Properties of SnO[sub 2] Materials journal January 1976
Electron Mobility and Injection Dynamics in Mesoporous ZnO, SnO 2 , and TiO 2 Films Used in Dye-Sensitized Solar Cells journal May 2011
ZnO Nanostructures for Dye-Sensitized Solar Cells journal November 2009
Cobalt Polypyridyl-Based Electrolytes for p-Type Dye-Sensitized Solar Cells journal April 2011
Epitaxial growth of TiO2 thin films on SrTiO3, LaAlO3 and yttria-stabilized zirconia substrates by electron beam evaporation journal February 2007
Selective CO 2 Conversion to Formate Conjugated with H 2 O Oxidation Utilizing Semiconductor/Complex Hybrid Photocatalysts journal October 2011
Recent advances in hybrid photocatalysts for solar fuel production journal January 2012
Panchromatic engineering for dye-sensitized solar cells journal January 2011
Electron Lifetime in Dye-Sensitized Solar Cells: Theory and Interpretation of Measurements journal August 2009
Ultrafast electron injection from metal polypyridyl complexes to metal-oxide nanocrystalline thin films journal July 2004
Enhanced Rates of Photocatalytic Degradation of an Azo Dye Using SnO2/TiO2 Coupled Semiconductor Thin Films journal March 1995
Catalytic and Surface-Electrocatalytic Water Oxidation by Redox Mediator-Catalyst Assemblies journal November 2009
Near band-edge electron diffusion in electrospun Nb-doped anatase TiO2 nanofibers probed by electrochemical impedance spectroscopy journal April 2011
Dye sensitised zinc oxide: aqueous electrolyte: platinum photocell journal June 1976
Nanostructured Zinc Stannate as Semiconductor Working Electrodes for Dye-Sensitized Solar Cells journal March 2007
Efficient Solar Water Splitting, Exemplified by RuO 2 -Catalyzed AlGaAs/Si Photoelectrolysis journal September 2000
High Incident Photon-to-Current Conversion Efficiency of p-Type Dye-Sensitized Solar Cells Based on NiO and Organic Chromophores journal August 2009
Nanostructured Semiconductor Films for Photocatalysis. Photoelectrochemical Behavior of SnO 2 /TiO 2 Composite Systems and Its Role in Photocatalytic Degradation of a Textile Azo Dye journal January 1996
Elevated Temperature Anodized Nb 2 O 5 : A Photoanode Material with Exceptionally Large Photoconversion Efficiencies journal April 2012
Chemical Approaches to Artificial Photosynthesis. 2 journal October 2005
Visible light driven hydrogen production from a photo-active cathode based on a molecular catalyst and organic dye-sensitized p-type nanostructured NiO journal January 2012
Enhance the Performance of Dye-Sensitized Solar Cells by Co-grafting Amphiphilic Sensitizer and Hexadecylmalonic Acid on TiO 2 Nanocrystals journal December 2003
Surface Photovoltage Spectroscopy of Dye-Sensitized Solar Cells with TiO 2 , Nb 2 O 5 , and SrTiO 3 Nanocrystalline Photoanodes:  Indication for Electron Injection from Higher Excited Dye States journal July 2001
Synthesis of single-crystal niobium pentoxide nanobelts journal June 2008