Fast Pyrolysis of Wood for Biofuels: Spatiotemporally Resolved Diffuse Reflectance In situ Spectroscopy of Particles

Paulsen, Alex D.; Hough, Blake R.; Williams, C. Luke; Teixeira, Andrew R.; Schwartz, Daniel T.; Pfaendtner, Jim; Dauenhauer, Paul J.

doi:10.1002/cssc.201301056

Title: Fast Pyrolysis of Wood for Biofuels: Spatiotemporally Resolved Diffuse Reflectance In situ Spectroscopy of Particles

Journal Article · Thu Feb 20 00:00:00 EST 2014 · ChemSusChem

DOI:https://doi.org/10.1002/cssc.201301056· OSTI ID:1385163

Paulsen, Alex D.; Hough, Blake R.; Williams, C. Luke; Teixeira, Andrew R.; Schwartz, Daniel T.; Pfaendtner, Jim; Dauenhauer, Paul J.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Catalysis Center for Energy Innovation (CCEI)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: SC0001004

OSTI ID:: 1385163

Journal Information:: ChemSusChem, Vol. 7, Issue 3; Related Information: CCEI partners with the University of Delaware (lead); Brookhaven National Laboratory; California Institute of Technology; Columbia University; University of Delaware; Lehigh University; University of Massachusetts, Amherst; Massachusetts Institute of Technology; University of Minnesota; Pacific Northwest National Laboratory; University of Pennsylvania; Princeton University; Rutgers University; ISSN 1864-5631

Publisher:: ChemPubSoc Europe

Country of Publication:: United States

Language:: English

References (54)

A kinetic model for pyrolysis of cellulose Bradbury, Allan G. W.; Sakai, Yoshio; Shafizadeh, Fred Journal of Applied Polymer Science, Vol. 23, Issue 11 https://doi.org/10.1002/app.1979.070231112	journal	June 1979
Birch wood particle shrinkage during rapid pyrolysis Davidsson, K. O.; Pettersson, J. B. C. Fuel, Vol. 81, Issue 3 https://doi.org/10.1016/S0016-2361(01)00169-7	journal	February 2002
Cellulose Pyrolysis Kinetics: The Current State of Knowledge Antal, Michael Jerry Jr.; Varhegyi, Gabor Industrial & Engineering Chemistry Research, Vol. 34, Issue 3 https://doi.org/10.1021/ie00042a001	journal	March 1995
A spectroscopic method for determining lignin content of softwood and hardwood kraft pulps Malkavaara, Petteri; Alén, Raimo Chemometrics and Intelligent Laboratory Systems, Vol. 44, Issue 1-2 https://doi.org/10.1016/S0169-7439(98)00068-9	journal	December 1998
Use of near infrared spectroscopy to measure the chemical and mechanical properties of solid wood Kelley, StephenS.; Rials, TimothyG.; Snell, Rebecca Wood Science and Technology, Vol. 38, Issue 4 https://doi.org/10.1007/s00226-003-0213-5	journal	May 2004
The Intrinsic Kinetics and Heats of Reactions for Cellulose Pyrolysis and Char Formation Cho, Joungmo; Davis, Jeffrey M.; Huber, George W. ChemSusChem, Vol. 3, Issue 10 https://doi.org/10.1002/cssc.201000119	journal	August 2010
A Generalized Biomass Pyrolysis Model Based on Superimposed Cellulose, Hemicelluloseand Liqnin Kinetics Miller, R. S.; Bellan, J. Combustion Science and Technology, Vol. 126, Issue 1-6 https://doi.org/10.1080/00102209708935670	journal	July 1997
TG-FTIR analysis of biomass pyrolysis Bassilakis, R.; Carangelo, R. M.; Wójtowicz, M. A. Fuel, Vol. 80, Issue 12 https://doi.org/10.1016/S0016-2361(01)00061-8	journal	October 2001
Synthesis of Transportation Fuels from Biomass: Chemistry, Catalysts, and Engineering Huber, George W.; Iborra, Sara; Corma, Avelino Chemical Reviews, Vol. 106, Issue 9, p. 4044-4098 https://doi.org/10.1021/cr068360d	journal	September 2006
Heat transfer and kinetics in the low temperature pyrolysis of solids Pyle, D. L.; Zaror, C. A. Chemical Engineering Science, Vol. 39, Issue 1 https://doi.org/10.1016/0009-2509(84)80140-2	journal	January 1984
Spectral characteristics of lignin and soluble phenolics in the near infrared- a comparative study Soukupova, J.; Rock, B. N.; Albrechtova, J. International Journal of Remote Sensing, Vol. 23, Issue 15 https://doi.org/10.1080/01431160110104683	journal	January 2002
The chain length effect in pyrolysis: bridging the gap between glucose and cellulose Mettler, Matthew S.; Paulsen, Alex D.; Vlachos, Dionisios G. Green Chemistry, Vol. 14, Issue 5 https://doi.org/10.1039/c2gc35184f	journal	January 2012
Renewable Chemical Commodity Feedstocks from Integrated Catalytic Processing of Pyrolysis Oils Vispute, T. P.; Zhang, H.; Sanna, A. Science, Vol. 330, Issue 6008 https://doi.org/10.1126/science.1194218	journal	November 2010
The Path Forward for Biofuels and Biomaterials Ragauskas, Arthur J.; Williams, Charlotte K.; Davison, Brian H. Science, Vol. 311, Issue 5760, p. 484-489 https://doi.org/10.1126/science.1114736	journal	January 2006
Ab Initio Dynamics of Cellulose Pyrolysis: Nascent Decomposition Pathways at 327 and 600 °C Agarwal, Vishal; Dauenhauer, Paul J.; Huber, George W. Journal of the American Chemical Society, Vol. 134, Issue 36 https://doi.org/10.1021/ja305135u	journal	August 2012
Pyrolytic conversion of cellulose to fuels: levoglucosan deoxygenation via elimination and cyclization within molten biomass Mettler, Matthew S.; Paulsen, Alex D.; Vlachos, Dionisios G. Energy & Environmental Science, Vol. 5, Issue 7 https://doi.org/10.1039/c2ee21305b	journal	January 2012
Concerted Reactions and Mechanism of Glucose Pyrolysis and Implications for Cellulose Kinetics Seshadri, Vikram; Westmoreland, Phillip R. The Journal of Physical Chemistry A, Vol. 116, Issue 49 https://doi.org/10.1021/jp3085099	journal	November 2012
Improved utilization of biomass-derived carbon by co-processing with hydrogen-rich feedstocks in millisecond reactors Colby, Joshua L.; Dauenhauer, Paul J.; Michael, Brian C. Green Chemistry, Vol. 12, Issue 3 https://doi.org/10.1039/b920387g	journal	January 2010
Modeling thermally thick pyrolysis of wood Bryden, Kenneth M.; Ragland, Kenneth W.; Rutland, Christopher J. Biomass and Bioenergy, Vol. 22, Issue 1 https://doi.org/10.1016/S0961-9534(01)00060-5	journal	January 2002
Kinetics and reaction chemistry for slow pyrolysis of enzymatic hydrolysislignin and organosolv extracted lignin derived from maplewood Cho, Joungmo; Chu, Sheng; Dauenhauer, Paul J. Green Chem., Vol. 14, Issue 2 https://doi.org/10.1039/C1GC16222E	journal	January 2012
An overview of fast pyrolysis of biomass Bridgwater, A. V.; Meier, D.; Radlein, D. Organic Geochemistry, Vol. 30, Issue 12, p. 1479-1493 https://doi.org/10.1016/S0146-6380(99)00120-5	journal	December 1999
Overview of Applications of Biomass Fast Pyrolysis Oil Czernik, S.; Bridgwater, A. V. Energy & Fuels, Vol. 18, Issue 2, p. 590-598 https://doi.org/10.1021/ef034067u	journal	March 2004
Lignin Biosynthesis and Structure Vanholme, R.; Demedts, B.; Morreel, K. Plant Physiology, Vol. 153, Issue 3, p. 895-905 https://doi.org/10.1104/pp.110.155119	journal	May 2010
Reactive boiling of cellulose for integrated catalysis through an intermediate liquid Dauenhauer, Paul J.; Colby, Joshua L.; Balonek, Christine M. Green Chemistry, Vol. 11, Issue 10 https://doi.org/10.1039/b915068b	journal	January 2009
Heat, momentum and mass transport through a shrinking biomass particle exposed to thermal radiation Di Blasi, Colomba Chemical Engineering Science, Vol. 51, Issue 7 https://doi.org/10.1016/S0009-2509(96)80011-X	journal	April 1996
Top ten fundamental challenges of biomass pyrolysis for biofuels Mettler, Matthew S.; Vlachos, Dionisios G.; Dauenhauer, Paul J. Energy & Environmental Science, Vol. 5, Issue 7 https://doi.org/10.1039/c2ee21679e	journal	January 2012
Pyrolysis of large wood particles: a study of shrinkage importance in simulations☆ Bellais, Michel; Davidsson, K. O.; Liliedahl, T. Fuel, Vol. 82, Issue 12 https://doi.org/10.1016/S0016-2361(03)00062-0	journal	August 2003
The Role of Sample Dimension and Temperature in Cellulose Pyrolysis Paulsen, Alex D.; Mettler, Matthew S.; Dauenhauer, Paul J. Energy & Fuels, Vol. 27, Issue 4 https://doi.org/10.1021/ef302117j	journal	March 2013
Production of hydrocarbons by catalytic upgrading of a fast pyrolysis bio-oil. Part I: Conversion over various catalysts Adjaye, J. D.; Bakhshi, N. N. Fuel Processing Technology, Vol. 45, Issue 3 https://doi.org/10.1016/0378-3820(95)00034-5	journal	December 1995
Compositional analysis of biomass feedstocks by near infrared reflectance spectroscopy Sanderson, Matt A.; Agblevor, Foster; Collins, Michael Biomass and Bioenergy, Vol. 11, Issue 5 https://doi.org/10.1016/S0961-9534(96)00039-6	journal	January 1996
Opportunities for biomass-derived “bio-oil” in European heat and power markets Brammer, J. G.; Lauer, M.; Bridgwater, A. V. Energy Policy, Vol. 34, Issue 17 https://doi.org/10.1016/j.enpol.2005.05.005	journal	November 2006
Is the Broido-Shafizadeh Model for Cellulose Pyrolysis True? Varhegyi, Gabor; Jakab, Emma; Antal, Michael Jerry Energy & Fuels, Vol. 8, Issue 6 https://doi.org/10.1021/ef00048a025	journal	November 1994
Millisecond Reforming of Solid Biomass for Sustainable Fuels Dauenhauer, Paul J.; Dreyer, Bradon J.; Degenstein, Nick J. Angewandte Chemie International Edition, Vol. 46, Issue 31 https://doi.org/10.1002/anie.200701238	journal	August 2007
Critical evaluation of global mechanisms of wood devolatilization Branca, Carmen; Albano, Alessandro; Di Blasi, Colomba Thermochimica Acta, Vol. 429, Issue 2 https://doi.org/10.1016/j.tca.2005.02.030	journal	May 2005
Mathematical Model for Wood PyrolysisComparison of Experimental Measurements with Model Predictions Grønli, Morten G.; Melaaen, Morten C. Energy & Fuels, Vol. 14, Issue 4 https://doi.org/10.1021/ef990176q	journal	July 2000
The facts and hypotheses relating to the phenomenological model of cellulose pyrolysis Mamleev, Vadim; Bourbigot, Serge; Le Bras, Michel Journal of Analytical and Applied Pyrolysis, Vol. 84, Issue 1 https://doi.org/10.1016/j.jaap.2008.10.014	journal	January 2009
A mechanistic model of fast pyrolysis of glucose-based carbohydrates to predict bio-oil composition Vinu, R.; Broadbelt, Linda J. Energy & Environmental Science, Vol. 5, Issue 12 https://doi.org/10.1039/c2ee22784c	journal	January 2012
A CFD model for thermal conversion of thermally thick biomass particles Mehrabian, Ramin; Zahirovic, Selma; Scharler, Robert Fuel Processing Technology, Vol. 95 https://doi.org/10.1016/j.fuproc.2011.11.021	journal	March 2012
Unraveling the Reactions that Unravel Cellulose Mayes, Heather B.; Broadbelt, Linda J. The Journal of Physical Chemistry A, Vol. 116, Issue 26 https://doi.org/10.1021/jp300405x	journal	June 2012
Review of fast pyrolysis of biomass and product upgrading Bridgwater, A. V. Biomass and Bioenergy, Vol. 38, p. 68-94 https://doi.org/10.1016/j.biombioe.2011.01.048	journal	March 2012
Aerosol generation by reactive boiling ejection of molten cellulose Teixeira, Andrew R.; Mooney, Kyle G.; Kruger, Jacob S. Energy & Environmental Science, Vol. 4, Issue 10 https://doi.org/10.1039/c1ee01876k	journal	January 2011
High-Temperature Behavior of Cellulose I Matthews, James F.; Bergenstråhle, Malin; Beckham, Gregg T. The Journal of Physical Chemistry B, Vol. 115, Issue 10 https://doi.org/10.1021/jp1106839	journal	March 2011
Techno-economic comparison of biomass-to-transportation fuels via pyrolysis, gasification, and biochemical pathways Anex, Robert P.; Aden, Andy; Kazi, Feroz Kabir Fuel, Vol. 89, p. S29-S35 https://doi.org/10.1016/j.fuel.2010.07.015	journal	November 2010
Recent developments in fast pyrolysis of ligno-cellulosic materials Kersten, Sascha; Garcia-Perez, Manuel Current Opinion in Biotechnology, Vol. 24, Issue 3 https://doi.org/10.1016/j.copbio.2013.04.003	journal	June 2013
Modeling the combined impact of moisture and char shrinkage on the pyrolysis of a biomass particle☆ Bryden, Kenneth M.; Hagge, Mathew J. Fuel, Vol. 82, Issue 13 https://doi.org/10.1016/S0016-2361(03)00108-X	journal	September 2003
Revealing pyrolysis chemistry for biofuels production: Conversion of cellulose to furans and small oxygenates Mettler, Matthew S.; Mushrif, Samir H.; Paulsen, Alex D. Energy Environ. Sci., Vol. 5, Issue 1 https://doi.org/10.1039/C1EE02743C	journal	January 2012
Char yield on pyrolysis of cellulose Broido, A.; Nelson, Maxine A. Combustion and Flame, Vol. 24 https://doi.org/10.1016/0010-2180(75)90156-X	journal	February 1975
Upgrading of liquid fuel from the pyrolysis of biomass Zhang, S.; Yan, Y.; Li, T. Bioresource Technology, Vol. 96, Issue 5 https://doi.org/10.1016/j.biortech.2004.06.015	journal	March 2005
Review of literature on catalysts for biomass gasification Sutton, David; Kelleher, Brian; Ross, Julian R. H. Fuel Processing Technology, Vol. 73, Issue 3 https://doi.org/10.1016/S0378-3820(01)00208-9	journal	November 2001
Green Gasoline by Catalytic Fast Pyrolysis of Solid Biomass Derived Compounds Carlson, Torren R.; Vispute, Tushar P.; Huber, George W. ChemSusChem, Vol. 1, Issue 5 https://doi.org/10.1002/cssc.200800018	journal	May 2008
Modeling chemical and physical processes of wood and biomass pyrolysis Diblasi, C. Progress in Energy and Combustion Science, Vol. 34, Issue 1 https://doi.org/10.1016/j.pecs.2006.12.001	journal	February 2008
A field in ferment Sanderson, Katharine Nature, Vol. 444, Issue 7120 https://doi.org/10.1038/444673a	journal	December 2006
Aromatic Production from Catalytic Fast Pyrolysis of Biomass-Derived Feedstocks Carlson, Torren R.; Tompsett, Geoffrey A.; Conner, William C. Topics in Catalysis, Vol. 52, Issue 3 https://doi.org/10.1007/s11244-008-9160-6	journal	January 2009
Simulating infrared spectra and hydrogen bonding in cellulose Iβ at elevated temperatures Agarwal, Vishal; Huber, George W.; Conner, W. Curtis The Journal of Chemical Physics, Vol. 135, Issue 13 https://doi.org/10.1063/1.3646306	journal	October 2011

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Title: Fast Pyrolysis of Wood for Biofuels: Spatiotemporally Resolved Diffuse Reflectance In situ Spectroscopy of Particles

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