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Title: Electrochemical reduction of an Ag 2 VO 2 PO 4 particle: dramatic increase of local electronic conductivity

Abstract

This work demonstrates that at the initial stages of reduction, individual particles of Ag 2VO 2PO 4show a drastic change in local resistance coincident with formation of Ag 0, indicating that decreased battery resistance is related to both intra- and interparticle conductivity.

Authors:
 [1];  [2];  [3];  [4];  [4];  [5]
  1. Brookhaven National Laboratory; Upton; USA
  2. Department of Chemistry; Stony Brook University; Stony Brook; USA
  3. Department of Materials Science and Engineering; Stony Brook University; Stony Brook; USA
  4. Department of Chemistry; Stony Brook University; Stony Brook; USA; Department of Materials Science and Engineering
  5. Brookhaven National Laboratory; Upton; USA; Department of Chemistry; Stony Brook University
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2M)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1384879
DOE Contract Number:  
SC0012673
Resource Type:
Journal Article
Journal Name:
Physical Chemistry Chemical Physics. PCCP (Print)
Additional Journal Information:
Journal Volume: 17; Journal Issue: 17; Related Information: m2M partners with Stony Brook University (lead); Brookhaven National Laboratory; Columbia University; Georgia Institute of Technology; Oak Ridge National Laboratory; Rensselaer Polytechnic Institute; University of California, Berkeley; University of North Carolina at Chapel Hill; Journal ID: ISSN 1463-9076
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
energy storage (including batteries and capacitors), charge transport, mesostructured materials

Citation Formats

Kirshenbaum, Kevin C., Bock, David C., Brady, Alexander B., Marschilok, Amy C., Takeuchi, Kenneth J., and Takeuchi, Esther S. Electrochemical reduction of an Ag 2 VO 2 PO 4 particle: dramatic increase of local electronic conductivity. United States: N. p., 2015. Web. doi:10.1039/C5CP00961H.
Kirshenbaum, Kevin C., Bock, David C., Brady, Alexander B., Marschilok, Amy C., Takeuchi, Kenneth J., & Takeuchi, Esther S. Electrochemical reduction of an Ag 2 VO 2 PO 4 particle: dramatic increase of local electronic conductivity. United States. doi:10.1039/C5CP00961H.
Kirshenbaum, Kevin C., Bock, David C., Brady, Alexander B., Marschilok, Amy C., Takeuchi, Kenneth J., and Takeuchi, Esther S. Thu . "Electrochemical reduction of an Ag 2 VO 2 PO 4 particle: dramatic increase of local electronic conductivity". United States. doi:10.1039/C5CP00961H.
@article{osti_1384879,
title = {Electrochemical reduction of an Ag 2 VO 2 PO 4 particle: dramatic increase of local electronic conductivity},
author = {Kirshenbaum, Kevin C. and Bock, David C. and Brady, Alexander B. and Marschilok, Amy C. and Takeuchi, Kenneth J. and Takeuchi, Esther S.},
abstractNote = {This work demonstrates that at the initial stages of reduction, individual particles of Ag2VO2PO4show a drastic change in local resistance coincident with formation of Ag0, indicating that decreased battery resistance is related to both intra- and interparticle conductivity.},
doi = {10.1039/C5CP00961H},
journal = {Physical Chemistry Chemical Physics. PCCP (Print)},
issn = {1463-9076},
number = 17,
volume = 17,
place = {United States},
year = {2015},
month = {1}
}

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