skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: The Mosaic of Surface Charge in Contact Electrification

Journal Article · · Science

When dielectric materials are brought into contact and then separated, they develop static electricity. For centuries, it has been assumed that such contact charging derives from the spatially homogeneous material properties (along the material’s surface) and that within a given pair of materials, one charges uniformly positively and the other negatively. We demonstrate that this picture of contact charging is incorrect. Whereas each contact-electrified piece develops a net charge of either positive or negative polarity, each surface supports a random “mosaic” of oppositely charged regions of nanoscopic dimensions. These mosaics of surface charge have the same topological characteristics for different types of electrified dielectrics and accommodate significantly more charge per unit area than previously thought.

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Center for Bio-Inspired Energy Science (CBES)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
SC0000989
OSTI ID:
1384508
Journal Information:
Science, Vol. 333, Issue 6040; Related Information: CBES partners with Northwestern University (lead); Harvard University; New York University; Pennsylvania State University; University of Michigan; University of Pittsburgh; ISSN 0036-8075
Publisher:
AAAS
Country of Publication:
United States
Language:
English

References (24)

The role of material transfer in contact electrification journal December 1977
Electrification of granular systems of identical insulators journal May 2009
Contact electrification of polymers journal July 1976
Contact charging between insulators journal June 1997
A Tool for Studying Contact Electrification in Systems Comprising Metals and Insulating Polymers journal September 2003
Nanocontact Electrification through Forced Delamination of Dielectric Interfaces journal October 2010
Chemical Redox Reactions Induced by Cryptoelectrons on a PMMA Surface journal April 2009
Contact Electrification between Identical Materials journal December 2009
Soft Lithography journal August 1998
Contact electrification induced by monolayer modification of a surface and relation to acid–base interactions journal December 1993
Correlation between nanosecond X-ray flashes and stick–slip friction in peeling tape journal October 2008
Photo-oxidation of polydimethylsiloxane oils Part III—effect of dimethylene groups journal January 1993
A semi-quantitative tribo-electric series for polymeric materials: the influence of chemical structure and properties journal November 2004
Ionic Electrets:  Electrostatic Charging of Surfaces by Transferring Mobile Ions upon Contact journal February 2007
Physics of electrophotography journal January 1993
Electrostatic Charging Due to Separation of Ions at Interfaces: Contact Electrification of Ionic Electrets journal March 2008
Contact Electrification and Adhesion Between Dissimilar Materials journal April 1992
The use of zeta-potential measurements in organic solvents to determine the donor—acceptor properties of solid surfaces journal February 1984
Double mass transfer during polymer‐polymer contacts journal January 1976
Charge generation on dielectric surfaces journal November 1969
Particle Triboelectrification and its use in the Electrostatic Separation Process journal January 1998
Electrostatic self-assembly of macroscopic crystals using contact electrification journal March 2003
Contact electrification journal December 1980
Electrostatic electrochemistry at insulators journal March 2008