Time-resolved energy transfer from single chloride-terminated nanocrystals to graphene
Abstract
We examine the time-resolved resonance energy transfer of excitons from single n-butyl aminebound, chloride-terminated nanocrystals to two-dimensional graphene through time-correlated single photon counting. The radiative biexponential lifetime kinetics and blinking statistics of the individual surface-modified nanocrystal elucidate the non-radiative decay channels. Blinking modification as well as a 4x reduction in spontaneous emission were observed with the short chloride and n-butylamine ligands, probing the energy transfer pathways for the development of graphene-nanocrystal nanophotonic devices.
- Authors:
-
- Columbia Univ., New York, NY (United States). Optical Nanostructures Lab., Center for Integrated Science and Engineering, Solid-State Science and Engineering,
- Columbia Univ., New York, NY (United States)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Re-Defining Photovoltaic Efficiency Through Molecule Scale Control (RPEMSC)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1384422
- Grant/Contract Number:
- SC0001085
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- Applied Physics Letters
- Additional Journal Information:
- Journal Volume: 104; Journal Issue: 17; Related Information: RPEMSC partners with Columbia University (lead); Brookhaven National Laboratory; Purdue University; Journal ID: ISSN 0003-6951
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 42 ENGINEERING; solar (photovoltaic); electrodes - solar; charge transport; materials and chemistry by design; optics; synthesis (novel materials)
Citation Formats
Ajayi, O. A., Anderson, N. C., Cotlet, M., Petrone, N., Gu, T., Wolcott, A., Gesuele, F., Hone, J., Owen, J. S., and Wong, C. W. Time-resolved energy transfer from single chloride-terminated nanocrystals to graphene. United States: N. p., 2014.
Web. doi:10.1063/1.4874298.
Ajayi, O. A., Anderson, N. C., Cotlet, M., Petrone, N., Gu, T., Wolcott, A., Gesuele, F., Hone, J., Owen, J. S., & Wong, C. W. Time-resolved energy transfer from single chloride-terminated nanocrystals to graphene. United States. https://doi.org/10.1063/1.4874298
Ajayi, O. A., Anderson, N. C., Cotlet, M., Petrone, N., Gu, T., Wolcott, A., Gesuele, F., Hone, J., Owen, J. S., and Wong, C. W. 2014.
"Time-resolved energy transfer from single chloride-terminated nanocrystals to graphene". United States. https://doi.org/10.1063/1.4874298. https://www.osti.gov/servlets/purl/1384422.
@article{osti_1384422,
title = {Time-resolved energy transfer from single chloride-terminated nanocrystals to graphene},
author = {Ajayi, O. A. and Anderson, N. C. and Cotlet, M. and Petrone, N. and Gu, T. and Wolcott, A. and Gesuele, F. and Hone, J. and Owen, J. S. and Wong, C. W.},
abstractNote = {We examine the time-resolved resonance energy transfer of excitons from single n-butyl aminebound, chloride-terminated nanocrystals to two-dimensional graphene through time-correlated single photon counting. The radiative biexponential lifetime kinetics and blinking statistics of the individual surface-modified nanocrystal elucidate the non-radiative decay channels. Blinking modification as well as a 4x reduction in spontaneous emission were observed with the short chloride and n-butylamine ligands, probing the energy transfer pathways for the development of graphene-nanocrystal nanophotonic devices.},
doi = {10.1063/1.4874298},
url = {https://www.osti.gov/biblio/1384422},
journal = {Applied Physics Letters},
issn = {0003-6951},
number = 17,
volume = 104,
place = {United States},
year = {Mon Apr 28 00:00:00 EDT 2014},
month = {Mon Apr 28 00:00:00 EDT 2014}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Cited by: 22 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Soluble, Chloride-Terminated CdSe Nanocrystals: Ligand Exchange Monitored by 1 H and 31 P NMR Spectroscopy
journal, December 2012
- Anderson, Nicholas C.; Owen, Jonathan S.
- Chemistry of Materials, Vol. 25, Issue 1
Facts and Artifacts in the Blinking Statistics of Semiconductor Nanocrystals
journal, May 2010
- Crouch, Catherine H.; Sauter, Orion; Wu, Xiaohua
- Nano Letters, Vol. 10, Issue 5
Hybrid passivated colloidal quantum dot solids
journal, July 2012
- Ip, Alexander H.; Thon, Susanna M.; Hoogland, Sjoerd
- Nature Nanotechnology, Vol. 7, Issue 9
Experimental observation of the quantum Hall effect and Berry's phase in graphene
journal, November 2005
- Zhang, Yuanbo; Tan, Yan-Wen; Stormer, Horst L.
- Nature, Vol. 438, Issue 7065, p. 201-204
Colloidal-quantum-dot photovoltaics using atomic-ligand passivation
journal, September 2011
- Tang, Jiang; Kemp, Kyle W.; Hoogland, Sjoerd
- Nature Materials, Vol. 10, Issue 10
Graphene plasmonics
journal, November 2012
- Grigorenko, A. N.; Polini, M.; Novoselov, K. S.
- Nature Photonics, Vol. 6, Issue 11, p. 749-758
Lifetime blinking in nonblinking nanocrystal quantum dots
journal, January 2012
- Galland, Christophe; Ghosh, Yagnaseni; Steinbrück, Andrea
- Nature Communications, Vol. 3, Issue 1
Progress, Challenges, and Opportunities in Two-Dimensional Materials Beyond Graphene
journal, March 2013
- Butler, Sheneve Z.; Hollen, Shawna M.; Cao, Linyou
- ACS Nano, Vol. 7, Issue 4, p. 2898-2926
Simple Förster resonance energy transfer evidence for the ultrahigh quantum dot quenching efficiency by graphene oxide compared to other carbon structures
journal, July 2012
- Morales-Narváez, Eden; Pérez-López, Briza; Pires, Luis Baptista
- Carbon, Vol. 50, Issue 8
Hofstadter’s butterfly and the fractal quantum Hall effect in moiré superlattices
journal, May 2013
- Dean, C. R.; Wang, L.; Maher, P.
- Nature, Vol. 497, Issue 7451
Surface-Related Emission in Highly Luminescent CdSe Quantum Dots
journal, August 2003
- Wang, Xiaoyong; Qu, Lianhua; Zhang, Jiayu
- Nano Letters, Vol. 3, Issue 8
Electric Field Effect in Atomically Thin Carbon Films
journal, October 2004
- Novoselov, K. S.
- Science, Vol. 306, Issue 5696, p. 666-669
Fluorescence quenching in graphene: A fundamental ruler and evidence for transverse plasmons
journal, October 2011
- Gómez-Santos, G.; Stauber, T.
- Physical Review B, Vol. 84, Issue 16
A model for the multi-exponential excited-state decay of CdSe nanocrystals
journal, February 2009
- Al Salman, A.; Tortschanoff, A.; van der Zwan, G.
- Chemical Physics, Vol. 357, Issue 1-3
Measurement of the Optical Conductivity of Graphene
journal, November 2008
- Mak, Kin Fai; Sfeir, Matthew Y.; Wu, Yang
- Physical Review Letters, Vol. 101, Issue 19
Modified Power Law Behavior in Quantum Dot Blinking: A Novel Role for Biexcitons and Auger Ionization
journal, January 2009
- Peterson, Jeffrey J.; Nesbitt, David J.
- Nano Letters, Vol. 9, Issue 1
Distance-independent quenching of quantum dots by nanoscale-graphene in self-assembled sandwich immunoassay
journal, January 2010
- Liu, Meng; Zhao, Huimin; Quan, Xie
- Chemical Communications, Vol. 46, Issue 42
Cryogenic spectroscopy of ultra-low density colloidal lead chalcogenide quantum dots on chip-scale optical cavities towards single quantum dot near-infrared cavity QED
journal, January 2009
- Bose, Ranojoy; Gao, Jie; McMillan, James F.
- Optics Express, Vol. 17, Issue 25
Hybrid graphene–quantum dot phototransistors with ultrahigh gain
journal, May 2012
- Konstantatos, Gerasimos; Badioli, Michela; Gaudreau, Louis
- Nature Nanotechnology, Vol. 7, Issue 6
Efficient Exciton Transport between Strongly Quantum-Confined Silicon Quantum Dots
journal, April 2012
- Lin, Zhibin; Li, Huashan; Franceschetti, Alberto
- ACS Nano, Vol. 6, Issue 5
Energy Transfer from Individual Semiconductor Nanocrystals to Graphene
journal, March 2010
- Chen, Zheyuan; Berciaud, Stéphane; Nuckolls, Colin
- ACS Nano, Vol. 4, Issue 5
Two types of luminescence blinking revealed by spectroelectrochemistry of single quantum dots
journal, November 2011
- Galland, Christophe; Ghosh, Yagnaseni; Steinbrück, Andrea
- Nature, Vol. 479, Issue 7372
Fortification of CdSe Quantum Dots with Graphene Oxide. Excited State Interactions and Light Energy Conversion
journal, April 2012
- Lightcap, Ian V.; Kamat, Prashant V.
- Journal of the American Chemical Society, Vol. 134, Issue 16
Reaction Chemistry and Ligand Exchange at Cadmium−Selenide Nanocrystal Surfaces
journal, September 2008
- Owen, Jonathan S.; Park, Jungwon; Trudeau, Paul-Emile
- Journal of the American Chemical Society, Vol. 130, Issue 37
Long range resonance energy transfer from a dye molecule to graphene has (distance)−4 dependence
journal, February 2009
- Swathi, R. S.; Sebastian, K. L.
- The Journal of Chemical Physics, Vol. 130, Issue 8
Nonexponential “blinking” kinetics of single CdSe quantum dots: A universal power law behavior
journal, February 2000
- Kuno, M.; Fromm, D. P.; Hamann, H. F.
- The Journal of Chemical Physics, Vol. 112, Issue 7
Fluorescence intermittency in single cadmium selenide nanocrystals
journal, October 1996
- Nirmal, M.; Dabbousi, B. O.; Bawendi, M. G.
- Nature, Vol. 383, Issue 6603
The rise of graphene
journal, March 2007
- Geim, A. K.; Novoselov, K. S.
- Nature Materials, Vol. 6, Issue 3, p. 183-191
The electronic properties of graphene
journal, January 2009
- Castro Neto, A. H.; Guinea, F.; Peres, N. M. R.
- Reviews of Modern Physics, Vol. 81, Issue 1, p. 109-162
Ultrahigh electron mobility in suspended graphene
journal, June 2008
- Bolotin, K. I.; Sikes, K. J.; Jiang, Z.
- Solid State Communications, Vol. 146, Issue 9-10, p. 351-355
Chemical Vapor Deposition-Derived Graphene with Electrical Performance of Exfoliated Graphene
journal, May 2012
- Petrone, Nicholas; Dean, Cory R.; Meric, Inanc
- Nano Letters, Vol. 12, Issue 6
Universal Distance-Scaling of Nonradiative Energy Transfer to Graphene
journal, April 2013
- Gaudreau, L.; Tielrooij, K. J.; Prawiroatmodjo, G. E. D. K.
- Nano Letters, Vol. 13, Issue 5
Photoluminescence Quenching and Intensity Fluctuations of CdSe−ZnS Quantum Dots on an Ag Nanoparticle Film
journal, December 2007
- Matsumoto, Yuusuke; Kanemoto, Ryodai; Itoh, Tamitake
- The Journal of Physical Chemistry C, Vol. 112, Issue 5
Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene
journal, July 2008
- Lee, C.; Wei, X.; Kysar, J. W.
- Science, Vol. 321, Issue 5887, p. 385-388
Resonance energy flow dynamics of coherently delocalized excitons in biological and macromolecular systems: Recent theoretical advances and open issues: Resonance energy flow dynamics of coherently delocalized excitons in biological and macromolecular systems
journal, August 2012
- Jang, Seogjoo; Cheng, Yuan-Chung
- Wiley Interdisciplinary Reviews: Computational Molecular Science, Vol. 3, Issue 1
Temperature-Tuning of Near-Infrared Monodisperse Quantum Dot Solids at 1.5 µm for Controllable Förster Energy Transfer
journal, July 2008
- Bose, Ranojoy; McMillan, James F.; Gao, Jie
- Nano Letters, Vol. 8, Issue 7
Fiber-based cryogenic and time-resolved spectroscopy of PbS quantum dots
journal, January 2011
- Rakher, Matthew T.; Bose, Ranojoy; Wong, Chee Wei
- Optics Express, Vol. 19, Issue 3
Fine Structure Constant Defines Visual Transparency of Graphene
journal, June 2008
- Nair, R. R.; Blake, P.; Grigorenko, A. N.
- Science, Vol. 320, Issue 5881
Ligand Exchange and the Stoichiometry of Metal Chalcogenide Nanocrystals: Spectroscopic Observation of Facile Metal-Carboxylate Displacement and Binding
journal, November 2013
- Anderson, Nicholas C.; Hendricks, Mark P.; Choi, Joshua J.
- Journal of the American Chemical Society, Vol. 135, Issue 49, p. 18536-18548
Works referencing / citing this record:
Near-Field Energy Transfer Using Nanoemitters For Optoelectronics
journal, October 2016
- Guzelturk, Burak; Demir, Hilmi Volkan
- Advanced Functional Materials, Vol. 26, Issue 45
0D-2D and 1D-2D Semiconductor Hybrids Composed of All Inorganic Perovskite Nanocrystals and Single-Layer Graphene with Improved Light Harvesting
journal, December 2017
- Chen, Jia-Shiang; Doane, Tennyson L.; Li, Mingxing
- Particle & Particle Systems Characterization, Vol. 35, Issue 2
Charge transfer state emission dynamics in blue-emitting functionalized silicon nanocrystals
journal, January 2015
- De los Reyes, Glenda B.; Dasog, Mita; Na, MengXing
- Physical Chemistry Chemical Physics, Vol. 17, Issue 44
Ultrafast Hyperspectral Transient Absorption Spectroscopy: Application to Single Layer Graphene
journal, August 2019
- Gesuele, Felice
- Photonics, Vol. 6, Issue 3
Protection of Molecular Microcrystals by Encapsulation under Single-Layer Graphene
journal, July 2018
- Li, Wangxiang; Tierce, Nathan T.; Bekyarova, Elena
- ACS Omega, Vol. 3, Issue 7