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Title: The Role of Surface Oxygen in the Growth of Large Single-Crystal Graphene on Copper

Authors:
; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ;
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Re-Defining Photovoltaic Efficiency Through Molecule Scale Control (RPEMSC)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1384251
DOE Contract Number:  
SC0001085
Resource Type:
Journal Article
Journal Name:
Science
Additional Journal Information:
Journal Volume: 342; Journal Issue: 6159; Related Information: RPEMSC partners with Columbia University (lead); Brookhaven National Laboratory; Purdue University; Journal ID: ISSN 0036-8075
Publisher:
AAAS
Country of Publication:
United States
Language:
English
Subject:
solar (photovoltaic), electrodes - solar, charge transport, materials and chemistry by design, optics, synthesis (novel materials)

Citation Formats

Hao, Y., Bharathi, M. S., Wang, L., Liu, Y., Chen, H., Nie, S., Wang, X., Chou, H., Tan, C., Fallahazad, B., Ramanarayan, H., Magnuson, C. W., Tutuc, E., Yakobson, B. I., McCarty, K. F., Zhang, Y. -W., Kim, P., Hone, J., Colombo, L., and Ruoff, R. S. The Role of Surface Oxygen in the Growth of Large Single-Crystal Graphene on Copper. United States: N. p., 2013. Web. doi:10.1126/science.1243879.
Hao, Y., Bharathi, M. S., Wang, L., Liu, Y., Chen, H., Nie, S., Wang, X., Chou, H., Tan, C., Fallahazad, B., Ramanarayan, H., Magnuson, C. W., Tutuc, E., Yakobson, B. I., McCarty, K. F., Zhang, Y. -W., Kim, P., Hone, J., Colombo, L., & Ruoff, R. S. The Role of Surface Oxygen in the Growth of Large Single-Crystal Graphene on Copper. United States. doi:10.1126/science.1243879.
Hao, Y., Bharathi, M. S., Wang, L., Liu, Y., Chen, H., Nie, S., Wang, X., Chou, H., Tan, C., Fallahazad, B., Ramanarayan, H., Magnuson, C. W., Tutuc, E., Yakobson, B. I., McCarty, K. F., Zhang, Y. -W., Kim, P., Hone, J., Colombo, L., and Ruoff, R. S. Thu . "The Role of Surface Oxygen in the Growth of Large Single-Crystal Graphene on Copper". United States. doi:10.1126/science.1243879.
@article{osti_1384251,
title = {The Role of Surface Oxygen in the Growth of Large Single-Crystal Graphene on Copper},
author = {Hao, Y. and Bharathi, M. S. and Wang, L. and Liu, Y. and Chen, H. and Nie, S. and Wang, X. and Chou, H. and Tan, C. and Fallahazad, B. and Ramanarayan, H. and Magnuson, C. W. and Tutuc, E. and Yakobson, B. I. and McCarty, K. F. and Zhang, Y. -W. and Kim, P. and Hone, J. and Colombo, L. and Ruoff, R. S.},
abstractNote = {},
doi = {10.1126/science.1243879},
journal = {Science},
issn = {0036-8075},
number = 6159,
volume = 342,
place = {United States},
year = {2013},
month = {10}
}

Works referenced in this record:

Carrier Transport in Two-Dimensional Graphene Layers
journal, May 2007


Graphene Nucleation on Transition Metal Surface: Structure Transformation and Role of the Metal Step Edge
journal, April 2011

  • Gao, Junfeng; Yip, Joanne; Zhao, Jijun
  • Journal of the American Chemical Society, Vol. 133, Issue 13, p. 5009-5015
  • DOI: 10.1021/ja110927p

Activation Energy Paths for Graphene Nucleation and Growth on Cu
journal, March 2012

  • Kim, HoKwon; Mattevi, Cecilia; Calvo, M. Reyes
  • ACS Nano, Vol. 6, Issue 4
  • DOI: 10.1021/nn3008965

Evolution of Graphene Growth on Ni and Cu by Carbon Isotope Labeling
journal, December 2009

  • Li, Xuesong; Cai, Weiwei; Colombo, Luigi
  • Nano Letters, Vol. 9, Issue 12
  • DOI: 10.1021/nl902515k

Phase-Field Models for Microstructure Evolution
journal, August 2002


Influence of Copper Morphology in Forming Nucleation Seeds for Graphene Growth
journal, October 2011

  • Han, Gang Hee; Güneş, Fethullah; Bae, Jung Jun
  • Nano Letters, Vol. 11, Issue 10, p. 4144-4148
  • DOI: 10.1021/nl201980p

Contrasting Behavior of Carbon Nucleation in the Initial Stages of Graphene Epitaxial Growth on Stepped Metal Surfaces
journal, May 2010


Diffusion-Limited Aggregation, a Kinetic Critical Phenomenon
journal, November 1981


Special points for Brillouin-zone integrations
journal, June 1976

  • Monkhorst, Hendrik J.; Pack, James D.
  • Physical Review B, Vol. 13, Issue 12, p. 5188-5192
  • DOI: 10.1103/PhysRevB.13.5188

Atomistic Processes in the Early Stages of Thin-Film Growth
journal, April 1997


Millimeter-Size Single-Crystal Graphene by Suppressing Evaporative Loss of Cu During Low Pressure Chemical Vapor Deposition
journal, February 2013


Norm-conserving and ultrasoft pseudopotentials for first-row and transition elements
journal, October 1994


Role of Hydrogen in Chemical Vapor Deposition Growth of Large Single-Crystal Graphene
journal, July 2011

  • Vlassiouk, Ivan; Regmi, Murari; Fulvio, Pasquale
  • ACS Nano, Vol. 5, Issue 7, p. 6069-6076
  • DOI: 10.1021/nn201978y

Modeling and numerical simulations of dendritic crystal growth
journal, March 1993


Toward the Synthesis of Wafer-Scale Single-Crystal Graphene on Copper Foils
journal, September 2012

  • Yan, Zheng; Lin, Jian; Peng, Zhiwei
  • ACS Nano, Vol. 6, Issue 10
  • DOI: 10.1021/nn303352k

Controllable Synthesis of Submillimeter Single-Crystal Monolayer Graphene Domains on Copper Foils by Suppressing Nucleation
journal, February 2012

  • Wang, Hong; Wang, Guanzhong; Bao, Pengfei
  • Journal of the American Chemical Society, Vol. 134, Issue 8, p. 3627-3630
  • DOI: 10.1021/ja2105976

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996


Tailoring Electrical Transport Across Grain Boundaries in Polycrystalline Graphene
journal, May 2012


First-Principles Thermodynamics of Graphene Growth on Cu Surfaces
journal, August 2011

  • Zhang, Wenhua; Wu, Ping; Li, Zhenyu
  • The Journal of Physical Chemistry C, Vol. 115, Issue 36
  • DOI: 10.1021/jp2006827

Oxidation of Graphene on Metals
journal, March 2010

  • Starodub, Elena; Bartelt, Norman C.; McCarty, Kevin F.
  • The Journal of Physical Chemistry C, Vol. 114, Issue 11
  • DOI: 10.1021/jp912139e

Role of Kinetic Factors in Chemical Vapor Deposition Synthesis of Uniform Large Area Graphene Using Copper Catalyst
journal, October 2010

  • Bhaviripudi, Sreekar; Jia, Xiaoting; Dresselhaus, Mildred S.
  • Nano Letters, Vol. 10, Issue 10, p. 4128-4133
  • DOI: 10.1021/nl102355e

Graphene on metals: A van der Waals density functional study
journal, February 2010


Origin of the mosaicity in graphene grown on Cu(111)
journal, October 2011


Pushing the boundaries
journal, May 2011

  • Ajayan, Pulickel M.; Yakobson, Boris I.
  • Nature Materials, Vol. 10, Issue 6
  • DOI: 10.1038/nmat3027

Self-organized graphene crystal patterns
journal, February 2013

  • Wu, Bin; Geng, Dechao; Xu, Zhiping
  • NPG Asia Materials, Vol. 5, Issue 2
  • DOI: 10.1038/am.2012.68

Ground State of the Electron Gas by a Stochastic Method
journal, August 1980


Soft self-consistent pseudopotentials in a generalized eigenvalue formalism
journal, April 1990


Equilibrium at the edge and atomistic mechanisms of graphene growth
journal, September 2012

  • Artyukhov, V. I.; Liu, Y.; Yakobson, B. I.
  • Proceedings of the National Academy of Sciences, Vol. 109, Issue 38
  • DOI: 10.1073/pnas.1207519109

Ab initiomolecular dynamics for liquid metals
journal, January 1993


Reactivity Theory of Transition-Metal Surfaces: A Brønsted−Evans−Polanyi Linear Activation Energy−Free-Energy Analysis
journal, December 2009

  • van Santen, Rutger A.; Neurock, Matthew; Shetty, Sharan G.
  • Chemical Reviews, Vol. 110, Issue 4
  • DOI: 10.1021/cr9001808

Boron nitride substrates for high-quality graphene electronics
journal, August 2010

  • Dean, C. R.; Young, A. F.; Meric, I.
  • Nature Nanotechnology, Vol. 5, Issue 10, p. 722-726
  • DOI: 10.1038/nnano.2010.172

C–H bond activation of methane on clean and oxygen pre-covered metals: A systematic theoretical study
journal, August 2011


Large-Area Synthesis of High-Quality and Uniform Graphene Films on Copper Foils
journal, May 2009


Chemical Vapor Deposition-Derived Graphene with Electrical Performance of Exfoliated Graphene
journal, May 2012

  • Petrone, Nicholas; Dean, Cory R.; Meric, Inanc
  • Nano Letters, Vol. 12, Issue 6
  • DOI: 10.1021/nl204481s

The interaction of CH4 at high temperatures with clean and oxygen precovered Cu(100)
journal, March 1992


Controlling the Orientation, Edge Geometry, and Thickness of Chemical Vapor Deposition Graphene
journal, January 2013

  • Murdock, Adrian T.; Koos, Antal; Britton, T. Ben
  • ACS Nano, Vol. 7, Issue 2, p. 1351-1359
  • DOI: 10.1021/nn3049297

Probing Layer Number and Stacking Order of Few-Layer Graphene by Raman Spectroscopy
journal, January 2010


Control and characterization of individual grains and grain boundaries in graphene grown by chemical vapour deposition
journal, May 2011

  • Yu, Qingkai; Jauregui, Luis A.; Wu, Wei
  • Nature Materials, Vol. 10, Issue 6, p. 443-449
  • DOI: 10.1038/nmat3010

Transfer of CVD-Grown Monolayer Graphene onto Arbitrary Substrates
journal, August 2011

  • Suk, Ji Won; Kitt, Alexander; Magnuson, Carl W.
  • ACS Nano, Vol. 5, Issue 9
  • DOI: 10.1021/nn201207c

Roll-to-roll production of 30-inch graphene films for transparent electrodes
journal, June 2010

  • Bae, Sukang; Kim, Hyeongkeun; Lee, Youngbin
  • Nature Nanotechnology, Vol. 5, Issue 8, p. 574-578
  • DOI: 10.1038/nnano.2010.132

Theoretical surface science and catalysis—calculations and concepts
book, January 2000