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Title: Molecular diodes enabled by quantum interference

Authors:
; ; ; ; ; ;
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Re-Defining Photovoltaic Efficiency Through Molecule Scale Control (RPEMSC)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1384216
DOE Contract Number:  
SC0001085
Resource Type:
Journal Article
Journal Name:
Faraday Discussions
Additional Journal Information:
Journal Volume: 174; Related Information: RPEMSC partners with Columbia University (lead); Brookhaven National Laboratory; Purdue University; Journal ID: ISSN 1359-6640
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
solar (photovoltaic), electrodes - solar, charge transport, materials and chemistry by design, optics, synthesis (novel materials)

Citation Formats

Batra, Arunabh, Meisner, Jeffrey S., Darancet, Pierre, Chen, Qishui, Steigerwald, Michael L., Nuckolls, Colin, and Venkataraman, Latha. Molecular diodes enabled by quantum interference. United States: N. p., 2014. Web. doi:10.1039/C4FD00093E.
Batra, Arunabh, Meisner, Jeffrey S., Darancet, Pierre, Chen, Qishui, Steigerwald, Michael L., Nuckolls, Colin, & Venkataraman, Latha. Molecular diodes enabled by quantum interference. United States. doi:10.1039/C4FD00093E.
Batra, Arunabh, Meisner, Jeffrey S., Darancet, Pierre, Chen, Qishui, Steigerwald, Michael L., Nuckolls, Colin, and Venkataraman, Latha. Wed . "Molecular diodes enabled by quantum interference". United States. doi:10.1039/C4FD00093E.
@article{osti_1384216,
title = {Molecular diodes enabled by quantum interference},
author = {Batra, Arunabh and Meisner, Jeffrey S. and Darancet, Pierre and Chen, Qishui and Steigerwald, Michael L. and Nuckolls, Colin and Venkataraman, Latha},
abstractNote = {},
doi = {10.1039/C4FD00093E},
journal = {Faraday Discussions},
issn = {1359-6640},
number = ,
volume = 174,
place = {United States},
year = {2014},
month = {1}
}

Works referenced in this record:

Tetrathiafulvalenes, Oligoacenenes, and Their Buckminsterfullerene Derivatives:  The Brick and Mortar of Organic Electronics
journal, November 2004

  • Bendikov, Michael; Wudl, Fred; Perepichka, Dmitrii F.
  • Chemical Reviews, Vol. 104, Issue 11
  • DOI: 10.1021/cr030666m

Electronics using hybrid-molecular and mono-molecular devices
journal, November 2000

  • Joachim, C.; Gimzewski, J. K.; Aviram, A.
  • Nature, Vol. 408, Issue 6812, p. 541-548
  • DOI: 10.1038/35046000

A single-molecule diode
journal, June 2005

  • Elbing, M.; Ochs, R.; Koentopp, M.
  • Proceedings of the National Academy of Sciences, Vol. 102, Issue 25
  • DOI: 10.1073/pnas.0408888102

Mechanically controlled binary conductance switching of a single-molecule junction
journal, March 2009

  • Quek, Su Ying; Kamenetska, Maria; Steigerwald, Michael L.
  • Nature Nanotechnology, Vol. 4, Issue 4
  • DOI: 10.1038/nnano.2009.10

Single Molecule Electronic Devices
journal, February 2011

  • Song, Hyunwook; Reed, Mark A.; Lee, Takhee
  • Advanced Materials, Vol. 23, Issue 14
  • DOI: 10.1002/adma.201004291

Polymer Light-Emitting Electrochemical Cells
journal, August 1995


Measurement of voltage-dependent electronic transport across amine-linked single-molecular-wire junctions
journal, October 2009


Unimolecular Electrical Rectifiers
journal, September 2003


Molecular rectifiers
journal, November 1974


Molecular junctions based on aromatic coupling
journal, August 2008

  • Wu, Songmei; González, Maria Teresa; Huber, Roman
  • Nature Nanotechnology, Vol. 3, Issue 9
  • DOI: 10.1038/nnano.2008.237

A Single-Molecule Potentiometer
journal, April 2011

  • Meisner, Jeffrey S.; Kamenetska, Masha; Krikorian, Markrete
  • Nano Letters, Vol. 11, Issue 4
  • DOI: 10.1021/nl104411f

In situ formation of highly conducting covalent Au–C contacts for single-molecule junctions
journal, May 2011

  • Cheng, Z. -L.; Skouta, R.; Vazquez, H.
  • Nature Nanotechnology, Vol. 6, Issue 6
  • DOI: 10.1038/nnano.2011.66

Frustrated Rotations in Single-Molecule Junctions
journal, August 2009

  • Park, Young S.; Widawsky, Jonathan R.; Kamenetska, Maria
  • Journal of the American Chemical Society, Vol. 131, Issue 31
  • DOI: 10.1021/ja903731m

Observation of quantum interference in molecular charge transport
journal, March 2012

  • Guédon, Constant M.; Valkenier, Hennie; Markussen, Troels
  • Nature Nanotechnology, Vol. 7, Issue 5
  • DOI: 10.1038/nnano.2012.37

Electron transport in molecular junctions
journal, December 2006


Quantitative Current–Voltage Characteristics in Molecular Junctions from First Principles
journal, February 2012

  • Darancet, Pierre; Widawsky, Jonathan R.; Choi, Hyoung Joon
  • Nano Letters, Vol. 12, Issue 12
  • DOI: 10.1021/nl3033137

Coulomb blockade and the Kondo effect in single-atom transistors
journal, June 2002

  • Park, Jiwoong; Pasupathy, Abhay N.; Goldsmith, Jonas I.
  • Nature, Vol. 417, Issue 6890
  • DOI: 10.1038/nature00791

Kondo resonance in a single-molecule transistor
journal, June 2002

  • Liang, Wenjie; Shores, Matthew P.; Bockrath, Marc
  • Nature, Vol. 417, Issue 6890
  • DOI: 10.1038/nature00790

Probing the conductance superposition law in single-molecule circuits with parallel paths
journal, September 2012


Electrical Rectification by a Molecule:  The Advent of Unimolecular Electronic Devices
journal, November 1999

  • Metzger, Robert M.
  • Accounts of Chemical Research, Vol. 32, Issue 11
  • DOI: 10.1021/ar9900663

Molecular rectification: why is it so rare?
journal, August 2002


Efficient photodiodes from interpenetrating polymer networks
journal, August 1995

  • Halls, J. J. M.; Walsh, C. A.; Greenham, N. C.
  • Nature, Vol. 376, Issue 6540, p. 498-500
  • DOI: 10.1038/376498a0

Importance of Direct Metal−π Coupling in Electronic Transport Through Conjugated Single-Molecule Junctions
journal, December 2012

  • Meisner, Jeffrey S.; Ahn, Seokhoon; Aradhya, Sriharsha V.
  • Journal of the American Chemical Society, Vol. 134, Issue 50
  • DOI: 10.1021/ja308626m

Rectification and stability of a single molecular diode with controlled orientation
journal, October 2009

  • Díez-Pérez, Ismael; Hihath, Joshua; Lee, Youngu
  • Nature Chemistry, Vol. 1, Issue 8
  • DOI: 10.1038/nchem.392

Progress and Challenges in Commercialization of Organic Electronics
journal, July 2008

  • Loo, Yueh-Lin; McCulloch, Iain
  • MRS Bulletin, Vol. 33, Issue 07, p. 653-662
  • DOI: 10.1557/mrs2008.149

Length-Dependent Thermopower of Highly Conducting Au–C Bonded Single Molecule Junctions
journal, May 2013

  • Widawsky, J. R.; Chen, W.; Vázquez, H.
  • Nano Letters, Vol. 13, Issue 6
  • DOI: 10.1021/nl4012276

Single-molecule junctions beyond electronic transport
journal, June 2013

  • Aradhya, Sriharsha V.; Venkataraman, Latha
  • Nature Nanotechnology, Vol. 8, Issue 6
  • DOI: 10.1038/nnano.2013.91

Conductance of a Molecular Junction
journal, October 1997


Quantifying through-space charge transfer dynamics in π-coupled molecular systems
journal, January 2012

  • Batra, Arunabh; Kladnik, Gregor; Vázquez, Héctor
  • Nature Communications, Vol. 3, Issue 1
  • DOI: 10.1038/ncomms2083

Tuning Rectification in Single-Molecular Diodes
journal, November 2013

  • Batra, Arunabh; Darancet, Pierre; Chen, Qishui
  • Nano Letters, Vol. 13, Issue 12
  • DOI: 10.1021/nl403698m

Theoretical Characterization of Charge Transport in One-Dimensional Collinear Arrays of Organic Conjugated Molecules
journal, March 2010

  • Viani, Lucas; Olivier, Yoann; Athanasopoulos, Stavros
  • ChemPhysChem, Vol. 11, Issue 5
  • DOI: 10.1002/cphc.200900892

Polymer Photovoltaic Cells: Enhanced Efficiencies via a Network of Internal Donor-Acceptor Heterojunctions
journal, December 1995


Highly Conducting π-Conjugated Molecular Junctions Covalently Bonded to Gold Electrodes
journal, November 2011

  • Chen, Wenbo; Widawsky, Jonathan R.; Vázquez, Héctor
  • Journal of the American Chemical Society, Vol. 133, Issue 43
  • DOI: 10.1021/ja208020j

Generalized many-channel conductance formula with application to small rings
journal, May 1985


Reversible and Controllable Switching of a Single-Molecule Junction
journal, August 2006


Theory of Rectification in Tour Wires: The Role of Electrode Coupling
journal, September 2002


Synthetic Chemistry for Ultrapure, Processable, and High-Mobility Organic Transistor Semiconductors
journal, March 2001

  • Katz, Howard E.; Bao, Zhenan; Gilat, Sylvain L.
  • Accounts of Chemical Research, Vol. 34, Issue 5, p. 359-369
  • DOI: 10.1021/ar990114j

A 160-kilobit molecular electronic memory patterned at 1011 bits per square centimetre
journal, January 2007

  • Green, Jonathan E.; Wook Choi, Jang; Boukai, Akram
  • Nature, Vol. 445, Issue 7126, p. 414-417
  • DOI: 10.1038/nature05462

Contact Chemistry and Single-Molecule Conductance:  A Comparison of Phosphines, Methyl Sulfides, and Amines
journal, December 2007

  • Park, Young S.; Whalley, Adam C.; Kamenetska, Maria
  • Journal of the American Chemical Society, Vol. 129, Issue 51
  • DOI: 10.1021/ja0773857

Quantum-Interference-Controlled Molecular Electronics
journal, October 2008

  • Ke, San-Huang; Yang, Weitao; Baranger, Harold U.
  • Nano Letters, Vol. 8, Issue 10
  • DOI: 10.1021/nl8016175

Formation and Evolution of Single-Molecule Junctions
journal, March 2009