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Title: In situ diffraction of highly dispersed supported platinum nanoparticles

Abstract

In situsynchrotron diffraction in H 2reveals structural and microstructural details of supported 1–2 nm Pt nanoparticles.

Authors:
 [1];  [2];  [2];  [3];  [4];  [2];  [2];  [4];  [3];  [2];  [1]
  1. Chemical Science and Engineering Division; Argonne National Laboratory; Argonne, 60439 USA
  2. X-Ray Science Division; Advanced Photon Source; Argonne National Laboratory; Argonne, 60439 USA
  3. Department of Chemical Engineering University of Illinois; Chicago, 60607 USA
  4. Energy Systems Division; Argonne National Laboratory; Argonne, 60439 USA
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Institute for Atom-efficient Chemical Transformations (IACT)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1383991
DOE Contract Number:  
AC02-06CH11357
Resource Type:
Journal Article
Journal Name:
Catalysis Science and Technology
Additional Journal Information:
Journal Volume: 4; Journal Issue: 9; Related Information: IACT partners with Argonne National Laboratory (lead); Brookhaven National Laboratory; Northwestern University; Purdue University; University of Wisconsin at Madison; Journal ID: ISSN 2044-4753
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
catalysis (homogeneous), catalysis (heterogeneous), biofuels (including algae and biomass), bio-inspired, materials and chemistry by design, synthesis (novel materials), synthesis (scalable processing)

Citation Formats

Gallagher, James R., Li, Tao, Zhao, Haiyan, Liu, Jingjing, Lei, Yu, Zhang, Xiaoyi, Ren, Yang, Elam, Jeffrey W., Meyer, Randall J., Winans, Randall E., and Miller, Jeffrey T. In situ diffraction of highly dispersed supported platinum nanoparticles. United States: N. p., 2014. Web. doi:10.1039/C4CY00414K.
Gallagher, James R., Li, Tao, Zhao, Haiyan, Liu, Jingjing, Lei, Yu, Zhang, Xiaoyi, Ren, Yang, Elam, Jeffrey W., Meyer, Randall J., Winans, Randall E., & Miller, Jeffrey T. In situ diffraction of highly dispersed supported platinum nanoparticles. United States. doi:10.1039/C4CY00414K.
Gallagher, James R., Li, Tao, Zhao, Haiyan, Liu, Jingjing, Lei, Yu, Zhang, Xiaoyi, Ren, Yang, Elam, Jeffrey W., Meyer, Randall J., Winans, Randall E., and Miller, Jeffrey T. Wed . "In situ diffraction of highly dispersed supported platinum nanoparticles". United States. doi:10.1039/C4CY00414K.
@article{osti_1383991,
title = {In situ diffraction of highly dispersed supported platinum nanoparticles},
author = {Gallagher, James R. and Li, Tao and Zhao, Haiyan and Liu, Jingjing and Lei, Yu and Zhang, Xiaoyi and Ren, Yang and Elam, Jeffrey W. and Meyer, Randall J. and Winans, Randall E. and Miller, Jeffrey T.},
abstractNote = {In situsynchrotron diffraction in H2reveals structural and microstructural details of supported 1–2 nm Pt nanoparticles.},
doi = {10.1039/C4CY00414K},
journal = {Catalysis Science and Technology},
issn = {2044-4753},
number = 9,
volume = 4,
place = {United States},
year = {2014},
month = {1}
}

Works referenced in this record:

Determination of crystallite size and lattice distortions through X-ray diffraction line profile analysis: Vorschriften, Methoden und Bemerkungen
journal, January 1982

  • Delhez, R.; de Keijser, Th. H.; Mittemeijer, E. J.
  • Fresenius' Zeitschrift für analytische Chemie, Vol. 312, Issue 1
  • DOI: 10.1007/BF00482725

Determining Quantitative Kinetics and the Structural Mechanism for Particle Growth in Porous Templates
journal, October 2011

  • Zhao, Haiyan; Nenoff, Tina M.; Jennings, Guy
  • The Journal of Physical Chemistry Letters, Vol. 2, Issue 21
  • DOI: 10.1021/jz201260n

In Situ X-ray Diffraction and Solid-State NMR Study of the Fluorination of γ-Al 2 O 3 with HCF 2 Cl
journal, February 2001

  • Chupas, Peter J.; Ciraolo, Michael F.; Hanson, Jonathan C.
  • Journal of the American Chemical Society, Vol. 123, Issue 8
  • DOI: 10.1021/ja0032374

Texture, residual stress and structural analysis of thin films using a combined X-ray analysis
journal, February 2004


Effect of Particle Size and Adsorbates on the L3, L2 and L1 X-ray Absorption Near Edge Structure of Supported Pt Nanoparticles
journal, February 2011


Lattice contractions of a nanoparticle due to the surface tension: A model of elasticity
journal, April 2007

  • Huang, Zaixing; Thomson, Peter; Di, Shenglin
  • Journal of Physics and Chemistry of Solids, Vol. 68, Issue 4
  • DOI: 10.1016/j.jpcs.2007.01.016

Simultaneous structure and size–strain refinement by the Rietveld method
journal, August 1990


A review of the selective reduction of NOx with hydrocarbons under lean-burn conditions with non-zeolitic oxide and platinum group metal catalysts
journal, December 2002


Metastable Alumina Polymorphs: Crystal Structures and Transition Sequences
journal, August 1998


Low-pressure hydrogenolysis of glycerol to propylene glycol
journal, March 2005

  • Dasari, Mohanprasad A.; Kiatsimkul, Pim-Pahn; Sutterlin, Willam R.
  • Applied Catalysis A: General, Vol. 281, Issue 1-2, p. 225-231
  • DOI: 10.1016/j.apcata.2004.11.033

Platinum-tin reforming catalysts II. Activity and selectivity in hydrocarbon reactions
journal, October 1981


Collapse in Crystalline Structure and Decline in Catalytic Activity of Pt Nanoparticles on Reducing Particle Size to 1 nm
journal, December 2007

  • Sun, Yubao; Zhuang, Lin; Lu, Juntao
  • Journal of the American Chemical Society, Vol. 129, Issue 50
  • DOI: 10.1021/ja076177b

Platinum-Based Nanostructured Materials: Synthesis, Properties, and Applications
journal, June 2010

  • Chen, Aicheng; Holt-Hindle, Peter
  • Chemical Reviews, Vol. 110, Issue 6
  • DOI: 10.1021/cr9003902

Atomic Layer Deposition of Platinum Thin Films
journal, May 2003

  • Aaltonen, Titta; Ritala, Mikko; Sajavaara, Timo
  • Chemistry of Materials, Vol. 15, Issue 9, p. 1924-1928
  • DOI: 10.1021/cm021333t

The effect of gold particle size on AuAu bond length and reactivity toward oxygen in supported catalysts
journal, June 2006


Viscous flow reactor with quartz crystal microbalance for thin film growth by atomic layer deposition
journal, August 2002

  • Elam, J. W.; Groner, M. D.; George, S. M.
  • Review of Scientific Instruments, Vol. 73, Issue 8, p. 2981-2987
  • DOI: 10.1063/1.1490410

Irena : tool suite for modeling and analysis of small-angle scattering
journal, February 2009


Ab-initio structure determination of LiSbWO6 by X-ray powder diffraction
journal, March 1988


Supported Metal Clusters: Synthesis, Structure, and Catalysis
journal, May 1995


Unusual Non-Bulk Properties in Nanoscale Materials:  Thermal Metal−Metal Bond Contraction of γ-Alumina-Supported Pt Catalysts
journal, September 2006

  • Kang, Joo H.; Menard, Laurent D.; Nuzzo, Ralph G.
  • Journal of the American Chemical Society, Vol. 128, Issue 37
  • DOI: 10.1021/ja064207p

Recent developments in catalysis using nanostructured materials
journal, March 2009


A versatile sample-environment cell for non-ambient X-ray scattering experiments
journal, July 2008

  • Chupas, Peter J.; Chapman, Karena W.; Kurtz, Charles
  • Journal of Applied Crystallography, Vol. 41, Issue 4
  • DOI: 10.1107/S0021889808020165

In Situ and Real-Time Monitoring of Oxide Growth in a Few Monolayers at Surfaces of Platinum Nanoparticles in Aqueous Media
journal, May 2009

  • Imai, Hideto; Izumi, Koichi; Matsumoto, Masashi
  • Journal of the American Chemical Society, Vol. 131, Issue 17
  • DOI: 10.1021/ja810036h

Two-dimensional detector software: From real detector to idealised image or two-theta scan
journal, January 1996

  • Hammersley, A. P.; Svensson, S. O.; Hanfland, M.
  • High Pressure Research, Vol. 14, Issue 4-6, p. 235-248
  • DOI: 10.1080/08957959608201408

Microstructure of Supported Cobalt Fischer-Tropsch Catalysts
journal, October 2008

  • Ducreux, O.; Rebours, B.; Lynch, J.
  • Oil & Gas Science and Technology - Revue de l'IFP, Vol. 64, Issue 1
  • DOI: 10.2516/ogst:2008039